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31.发明授权
公开(公告)号：US5296428A
公开(公告)日：1994-03-22
申请号：US929070
申请日：1992-08-12
申请人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Kenneth G. Simons, deceased , Hye K. C. Timken , James C. Vartuli
发明人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Kenneth G. Simons, deceased , Hye K. C. Timken , James C. Vartuli
CPC分类号： B01J29/049 , C01B39/026
摘要： There is provided a catalyst comprising MCM-36 and a hydrogenation/dehydrogenation component. A particular example of such a catalyst comprises MCM-36, nickel and tungsten.
摘要翻译： 提供了包含MCM-36和氢化/脱氢组分的催化剂。 这种催化剂的具体实例包括MCM-36，镍和钨。
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公开(公告)号：US5292698A
公开(公告)日：1994-03-08
申请号：US929061
申请日：1992-08-12
申请人： Cynthia T-W. Chu , Charles T. Kresge , Wieslaw J. Roth , Kenneth G. Simmons, deceased , James C. Vartuli
发明人： Cynthia T-W. Chu , Charles T. Kresge , Wieslaw J. Roth , Kenneth G. Simmons, deceased , James C. Vartuli
CPC分类号： B01J29/049 , B01J29/70 , C01B39/026 , B01J2229/42
摘要： There is provided a catalyst comprising MCM-36 and a binder material.
摘要翻译： 提供了包含MCM-36和粘合剂材料的催化剂。
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公开(公告)号：US5250277A
公开(公告)日：1993-10-05
申请号：US811360
申请日：1991-12-20
CPC分类号： B01J29/049 , B01J29/70 , C01B39/026 , B01J2229/42
摘要： There is provided a crystalline oxide material with a characteristic X-ray diffraction pattern. This material may be a layered material, which is swollen or pillared. Upon calcination of the swollen material, the layers collapse and condense upon one another in a somewhat disordered fashion to form a non-swellable material. However, the swollen layered material may be intercalated with polymeric oxide pillars to maintain layer separation, even after calcination.
摘要翻译： 提供具有特征X射线衍射图案的结晶氧化物材料。 该材料可以是分层的材料，其被肿胀或支撑。 在煅烧膨胀的材料时，层以相当混乱的方式相互折叠并相互凝结形成不溶胀的材料。 然而，即使在煅烧之后，溶胀的层状材料也可以插入聚合氧化物柱以保持层分离。
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公开(公告)号：US4599475A
公开(公告)日：1986-07-08
申请号：US747736
申请日：1985-06-19
CPC分类号： C07C5/2708 , B01J29/70 , B01J29/74 , C07C5/2724 , B01J2229/20 , B01J2229/26 , B01J2229/42 , Y02P20/52
摘要： An improved process is disclosed for the isomerization of xylenes over a zeolite which may contain a platinum group metal. The improvement resides in the use of ZSM-23 zeolite which exhibits enhanced selectivity which inhibits the production of undesired C.sub.9.sup.+ aromatic transalkylation by-products. ZSM-23 having pores substantially unobstructed by silica, such as that made from a forming mixture containing amorphous precipitated silica as a silica source, has been found to be particularly useful in the process of the present invention.
摘要翻译： 公开了一种用于二甲苯异构化的改进方法，其可以含有铂族金属的沸石。 改进在于使用ZSM-23沸石，其表现出增强的选择性，其抑制不需要的C9 +芳族烷基转移副产物的产生。 已经发现具有基本上不被二氧化硅阻挡的孔的ZSM-23，例如由含有无定形沉淀二氧化硅作为二氧化硅源的形成混合物制成的孔，其在本发明的方法中特别有用。
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35.发明授权公开(公告)号：US06869587B2
公开(公告)日：2005-03-22
申请号：US10465960
申请日：2001-11-14
CPC分类号： B01J29/74 , B01J29/04 , B01J29/70 , B01J2229/42 , C01B37/02 , C01B39/48 , C10G35/095 , C10G45/64
摘要： This invention relates to a novel synthetic porous crystalline molecular sieve material, MCM-65, to a reaction mixture and method for its preparation, and to use of the MCM-65 in catalytic conversion of organic compounds. The crystalline material exhibits a distinctive X-ray diffraction pattern as shown in Table 1.
摘要翻译： 本发明涉及一种新型合成多孔结晶分子筛材料MCM-65，用于制备反应混合物及其制备方法，以及使用MCM-65进行有机化合物的催化转化。 结晶材料显示出如表1所示的独特的X射线衍射图。
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公开(公告)号：US6063262A
公开(公告)日：2000-05-16
申请号：US223657
申请日：1998-12-30
摘要： This invention relates to a new synthetic porous crystalline material, designated MCM-67, a method for its preparation and use thereof in catalytic conversion of organic compounds. MCM-67 appears to be closely related in structure to VPI-8 and SSZ-41 but is synthesized without zinc and in the presence of manganese and/or cobalt ions.
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公开(公告)号：US5837639A
公开(公告)日：1998-11-17
申请号：US734998
申请日：1991-07-24
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/10 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J29/00 , B01J29/064
CPC分类号： C01B37/02 , B01D53/8628 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/10 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： A catalytic composition comprises a metal hydrogenation- dehydrogenation component supported on a support material comprising an ultra-large pore crystalline material of high surface area and porosity. The crystalline material exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C., and has uniformly sized pores with a maximum perpendicular cross section of at least about 13 .ANG.. In a preferred form, the support material, which is preferably a metallosilicate such as an aluminosilicate, has the pores in a hexagonal arrangement, giving rise to a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG..
摘要翻译： 催化组合物包含负载在包含高表面积和孔隙率的超大孔结晶材料的载体材料上的金属氢化 - 脱氢组分。 结晶材料表现出非常大的吸附能力，其在50托和25℃下苯吸附能力大于约15克苯/ 100克，具有均匀尺寸的孔，其最大垂直横截面至少约为13安培 。 在优选的形式中，优选为金属硅酸盐如硅铝酸盐的载体材料具有六边形排列的孔，产生六角形电子衍射图，其可以以大于约18的d100值进行索引。
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公开(公告)号：US5779882A
公开(公告)日：1998-07-14
申请号：US684673
申请日：1996-07-22
IPC分类号： B01J20/10 , B01J29/04 , B01J29/80 , C01B33/38 , C01B39/00 , C01B39/02 , C01B39/46 , C07C2/58 , C07C2/66 , C07C15/00 , C07C15/02 , C10G11/02 , C10G11/05 , C10G35/06 , C10G35/095 , B01J29/06
CPC分类号： B01J29/80 , B01J29/70 , C01B33/38 , C07C2/58 , C07C2/66 , C10G11/05 , B01J2229/12 , B01J2229/42 , B01J29/084 , B01J29/7038 , C07C2529/70
摘要： A layered composition of matter, MCM-56, has an X-ray diffraction pattern including lines at d-spacing values of 12.4.+-.0.2, 9.9.+-.0.3, 6.9.+-.0.1, 6.2.+-.0.1, 3.55.+-.0.07 and 3.42.+-.0.07 Angstroms and has been selectively modified so that the ratio of the number of active acid sites at its external surface to the number of internal active acid sites is greater than that of the unmodified material. When used as an additive to a large pore zeolite catalyst in the catalytic cracking of a petroleum feedstock, the modified MCM-56 gives an improved gasoline yield/octane relationship, an improved coke selectivity and a higher combined gasoline and potential alkylate yield than an identical catalyst containing unmodified MCM-56.
摘要翻译： 物质的分层组合物MCM-56具有X射线衍射图，其包括d间距值为12.4 +/- 0.2,9.9 +/- 0.3,6.9 +/- 0.1,6.2 +/- 0.1,3.55的线 +/- 0.07和3.42 +/- 0.07埃，并且已被选择性地修饰，使得其外表面上的活性酸位数与内部活性酸位点数之比大于未改性材料的比例。 当在石油原料的催化裂化中用作大孔沸石催化剂的添加剂时，改性的MCM-56可提供改善的汽油产率/辛烷关系，改善的焦炭选择性和较高的组合汽油和潜在的烷基化产物比相同 含有未改性MCM-56的催化剂。
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39.发明授权Supported heteropoly acid catalysts for isoparaffin-olefin alkylation reactions 失效用于异链烷烃 - 烷基烷基化反应的负载型杂多酸催化剂
公开(公告)号：US5324881A
公开(公告)日：1994-06-28
申请号：US46041
申请日：1993-04-12
IPC分类号： B01J27/188 , B01J29/03 , B01J29/04 , C07C2/62 , C07C2/58
CPC分类号： B01J27/188 , B01J29/0341 , B01J29/041 , B01J29/043 , C07C2/62 , B01J29/0308 , C07C2527/188 , Y02P20/588
摘要： The alkylation of isoparaffin with olefin to provide alkylate is carried out in the presence of, as catalyst, a supported heteropoly acid. The support may be MCM-41, and the heteropoly acid may be dodecawolframophosphoric acid (i.e., phosphotungstic acid, i.e., H.sub.3 PW.sub.12 O.sub.40).
摘要翻译： 异链烷烃与烯烃的烷基化以提供烷基化物在作为催化剂的载体杂多酸的存在下进行。 载体可以是MCM-41，并且杂多酸可以是十二碳六氟磷酸（即磷钨酸，即H3PW12O40）。
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公开(公告)号：US5264203A
公开(公告)日：1993-11-23
申请号：US735224
申请日：1991-07-24
申请人： Jeffrey S. Beck , Charles T. Kresge , Michael E. Leonowicz , Wieslaw J. Roth , James C. Vartuli
发明人： Jeffrey S. Beck , Charles T. Kresge , Michael E. Leonowicz , Wieslaw J. Roth , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , C01B33/34
CPC分类号： B01J29/04 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J29/0308 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： This invention relates to a new synthetic composition of ultra-large pore crystalline material, e.g., [metallo]silicoaluminophosphate, having a composition, expressed on an anhydrous basis as follows:M.sub.n/q (W.sub.a X.sub.b Y.sub.c Z.sub.d O.sub.h)wherein M is one or more ions; n is the charge of the composition excluding M expressed as oxides; q is the weighted molar average valence of M; n/q is the number of moles or mole fraction of M; W is one or more divalent elements; X is one or more trivalent elements; Y is one or more tetravalent elements; Z is one or more pentavalent elements; a, b, c, and d are mole fractions of W, X, Y, and Z, respectively; (a+b+c+d)=1; a .gtoreq. 0; b, c, and d are each>0; and h is a number of from 1 to 2.5. The crystalline material is prepared by i) crystallizing a reaction mixture comprising sources of W, X, Z and an organic directing agent; ii) contacting the product of i) with a reaction mixture comprising sources of Y and organic directing agent; and iii) maintaining the mixture of ii) under conditions sufficient to form said composition of matter. The composition is suited to use for catalytic conversion of organic compounds.
摘要翻译： 本发明涉及具有如下无水基础的组成的[金属]硅铝磷酸盐的超大孔结晶材料的新合成组合物：Mn / q（WaXbYcZdOh）其中M是一个或多个离子; n是不含M表示为氧化物的组成的电荷; q是M的加权摩尔平均化合价; n / q是M的摩尔数或摩尔分数; W是一个或多个二价元素; X是一个或多个三价元素; Y是一种或多种四价元素; Z是一种或多种五价元素; a，b，c和d分别为W，X，Y和Z的摩尔分数; （a + b + c + d）= 1; a> / = 0; b，c和d各自> 0; h为1〜2.5的数。 晶体材料通过i）使含有W，X，Z和有机导向剂的反应混合物结晶来制备; ii）使i）的产物与包含Y和有机导向剂的反应混合物接触; 和iii）保持ii）的混合物在足以形成所述组合物的条件下。 该组合物适用于有机化合物的催化转化。
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