摘要:
Linked aromatic compounds found to act as potent soot dispersants in lubricating oil compositions; lubricating, oil compositions containing such soot dispersants and precursor compounds from which the soot dispersants are derived.
摘要:
Lubricating oil compositions and viscosity index (VI) improver concentrates containing combinations of first polymers that are amorphous ethylene α-olefin copolymers; and second polymers that are star polymers, the arms of which are derived from diene, and optionally vinyl aromatic hydrocarbon monomer, wherein the star polymers have a Shear Stability Index (SSI) of from about 1% to about 35% (30 cycle).
摘要:
A diesel fuel composition made up of a major amount of a diesel fuel, a minor amount of at least one metallic species and a minor amount of a detergent additive is disclosed. The detergent additive includes a compound of formula: wherein:each Ar independently represents an aromatic moiety having 0 to 3 substituents selected from the group consisting of alkyl alkoxy, alkoxyalkyl, hydroxy, hydroxyalkyl, halo and combinations thereof or additionally, in the case of formula II, acyloxy, acyloxyalkyl, aryloxy, aryloxy alkyl, halo and combinations thereof, each L is independently a linking moiety comprising a carbon-carbon single bond or a linking group;each Y is independently a moiety of the formula H(O(CR2)n)yX—, wherein X is selected from the group consisting of (CR′2)2, O and S; R and R′ are each independently selected from H, C1 to C6 alkyl and aryl; z is 1 to 10; n is 0 to 10 when X is (CR′2)7, and 2 to 10 when X is O or S; and y is 1 to 30; each Y′ is independently a moiety of the formula Z(O(CR2)n)yX—, wherein X is selected from the group consisting of (CR′2)2, O and S; R and R′ are each independently selected from H, C1 to C6 alkyl and aryl; z is 1 to 10; n is 0 to 10 when X is (CR′2)z, and 2 to 10 when X is O or S; y is 1 to 30; Z is H, an acyl group, an alkyl group or an aryl group;each a is independently 0 to 3, with the proviso that in formula (I), at least one Ar moiety bears at least one group Y; and with the proviso that in formula (II), at least one Ar moiety bears at least one group Y′ in which Z is not H; and m is 1 to 100.
摘要:
Linked aromatic compounds found to act as potent soot dispersants in lubricating oil compositions; lubricating oil compositions containing such soot dispersants and precursor compounds from which the soot dispersants are derived.
摘要:
Lubricating oil compositions providing superior soot dispersing characteristics, which contain a combination of a high molecular weight dispersant and a soot dispersant comprising a linked aromatic oligomer
摘要:
Soot induced kinematic viscosity increase of lubricating oil compositions for diesel engines can be ameliorated by combined use of derivatized high molecular weight olefin copolymers and high molecular weight nitrogen-containing dispersant.
摘要:
A dispersant that is a reaction product of a polyalkenyl-substituted mono- or dicarboxylic acid, anhydride or ester; and a polyamine, wherein the reaction product has from greater than about 1.3 to less than about 1.7 mono- or di-carboxylic acid producing moieties per polyalkenyl moiety, and the polyalkenyl moiety has a number average molecular weight of at least about 1800, and a molecular weight distribution (Mw/Mn) of from about 1.5 to about 2.0.
摘要:
Hydrocarbyl substituted C.sub.4 to C.sub.10 monounsaturated dicarboxylic acid, anhydrides or esters, e.g. polyisobutenyl succinic anhydride, preferably made by reacting polymer of C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a molecular weight of about 1500 to 5,000, preferably with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 1.05 to 1.25 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting materials are useful per se as oil additives, or may be further reacted with amines, alcohols, amino alcohols, boric acid, etc. to form dispersants.
摘要:
Novel dispersant mixtures are provided, having improved lubricating oil performance characteristics, comprising nitrogen or ester containing dispersants selected from the group consisting of oil soluble salts, amides, imides, oxazoline and esters or mixtures thereof, wherein a first dispersant comprises a long chain hydrocarbon substituted mono- and dicarboxylic acid or their anhydrides derived from polymers of C.sub.2 to C.sub.10 monoolefins wherein the polymer has a number average molecular weight of at least about 1300 and wherein the second dispersant component is derived from such polymers having a number average molecular weight of from about 700 to 1150. The relatively high molecular weight dispersant is provided with from about 1.05 to 1.25 moles per mole of polyolefin of an alpha or beta unsaturated C.sub.4 to C.sub.10 dicarboxylic acid or anhydride or ester thereof. The relatively lower molecular weight dispersant is provided with from about 1.2 to 2.0 moles per mole of polyolefin of an alpha or beta unsaturated C.sub.4 to C.sub.10 dicarboxylic acid, anhydride or ester thereof. It has been found that mixtures of such high molecular weight-low functionality dispersants and low molecular weight-high functionality dispersants provides a dispersant, suitable for use in oleaginous materials such as lubricating oils, which provide surprisingly improved engine performance properties.
摘要:
The invention pertains to oil soluble copolymers derived from ethylene and 1-butene which have a number average molecular weight between about 1,500 and 7,500, at least about 30 percent of all polymer chains terminated with ethylvinylidene groups, and ethylene-derived content of not greater than about 50 weight percent, and which form solutions in mineral oil free of polymer aggregates, as determined by light scattering measurements. Lubricating oil additives, particularly dispersants, produced by the functionalization and derivatization of these copolymers have enhanced performance (e.g., improved dispersancy and pour point) in lubricating oil compositions, attributable in part to the combination of properties characterizing the copolymers.