公开(公告)号：US08546626B2

公开(公告)日：2013-10-01

申请号：US12644710

申请日：2009-12-22

Applicant: Antoine Daudin ,  Laurent Bournay ,  Thierry Chapus

Inventor： Antoine Daudin ,  Laurent Bournay ,  Thierry Chapus

IPC: C07C1/00

CPC classification number: B01J23/28 ,  B01J27/051 ,  B01J27/0515 ,  B01J27/19 ,  B01J29/74 ,  C10G3/44 ,  C10G3/48 ,  C10G3/50 ,  C10G3/54 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

Abstract: The invention is concerned with a supported or unsupported catalyst comprising an active phase constituted by a sulfur-containing group VIB element, the group VIB element being molybdenum, and a hydrodeoxygenation process with a yield of hydrodeoxygenation product which is greater than or equal to 90% of charges from renewable sources using a catalyst according to the invention.

Abstract translation: 本发明涉及负载或未负载的催化剂，其包含由含硫基团VIB元素，VIB族元素为钼构成的活性相和加氢脱氧方法，其加氢脱氧产物的产率大于或等于90％ 使用根据本发明的催化剂的可再生能源的电荷。

公开(公告)号：US20130245337A1

公开(公告)日：2013-09-19

申请号：US13419617

申请日：2012-03-14

Applicant: Heiko Weiner ,  Zhenhua Zhou

Inventor： Heiko Weiner ,  Zhenhua Zhou

IPC: C07C29/149

CPC classification number: C07C29/149 ,  B01J23/002 ,  B01J23/20 ,  B01J23/24 ,  B01J23/34 ,  B01J23/648 ,  B01J23/652 ,  B01J23/682 ,  B01J23/683 ,  B01J23/88 ,  B01J23/888 ,  B01J23/898 ,  B01J23/8993 ,  B01J27/188 ,  B01J27/19 ,  B01J27/195 ,  B01J37/0205 ,  B01J37/0244 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/43 ,  B01J2523/69 ,  B01J2523/828 ,  B01J2523/845 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/56 ,  B01J2523/55 ,  C07C31/08

Abstract: The present invention relates to hydrogenation catalysts prepared from polyoxometalate precursors. The polyoxometalate precursors introduce a support modifier to the catalyst. The catalysts are used for hydrogenating alkanoic acids and/or esters thereof to alcohols with relatively low ether formation, preferably with conversion of the ester coproduct. The catalyst may also comprise one or more active metals.

Abstract translation: 本发明涉及由多金属氧酸盐前体制备的氢化催化剂。 多金属氧酸盐前体向催化剂中引入载体改性剂。 催化剂用于将链烷酸和/或其酯加成到具有较低醚形成的醇中，优选转化酯副产物。 催化剂还可以包含一种或多种活性金属。

公开(公告)号：US08530373B2

公开(公告)日：2013-09-10

申请号：US12831335

申请日：2010-07-07

Applicant: Opinder Kishan Bhan

Inventor： Opinder Kishan Bhan

IPC: B01J27/19

CPC classification number: C10G45/12 ,  B01J23/882 ,  B01J23/883 ,  B01J27/1853 ,  B01J27/19 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0009 ,  B01J37/04 ,  C01G45/08 ,  C10G45/08 ,  C10G2300/1037 ,  C10G2300/202 ,  C10G2300/4018

Abstract: Described is a catalyst and process useful in the hydrodesulfurization of a distillate feedstock to manufacture a low-sulfur distillate product. The catalyst comprises a calcined mixture of inorganic oxide material, a high concentration of a molybdenum component, and a high concentration of a Group VIII metal component. The mixture that is calcined to form the calcined mixture comprises molybdenum trioxide, a Group VIII metal compound, and an inorganic oxide material. The catalyst is made by mixing the aforementioned starting materials and forming therefrom an agglomerate that is calcined to yield the calcined mixture that may be used as the catalyst or catalyst precursor.

Abstract translation: 描述了可用于馏出物原料的加氢脱硫以制备低硫馏出物产物的催化剂和方法。 催化剂包括无机氧化物材料，高浓度的钼组分和高浓度的VIII族金属组分的煅烧混合物。 煅烧形成煅烧混合物的混合物包括三氧化钼，第Ⅷ族金属化合物和无机氧化物材料。 催化剂是通过混合上述起始原料并由其形成的聚集体，其被煅烧以产生可用作催化剂或催化剂前体的煅烧混合物。

公开(公告)号：US20130165316A1

公开(公告)日：2013-06-27

申请号：US13720026

申请日：2012-12-19

Applicant: Total Raffinage Marketing ,  IFP Energies Nouvelles

Inventor： Bertrand GUICHARD ,  Laurent SIMON ,  Sylvie LOPEZ ,  Valentina DE GRANDI ,  Delphine MINOUX ,  Jean-Pierre DATH

IPC: B01J31/34 ,  C07C5/10 ,  C10G45/12

CPC classification number: B01J37/0205 ,  B01J21/04 ,  B01J23/24 ,  B01J23/28 ,  B01J23/85 ,  B01J23/882 ,  B01J23/90 ,  B01J27/14 ,  B01J27/19 ,  B01J29/076 ,  B01J31/0201 ,  B01J31/0209 ,  B01J35/002 ,  B01J37/0203 ,  B01J37/20 ,  B01J37/28 ,  B01J38/52 ,  B01J38/62 ,  C07C5/10 ,  C07C2601/14 ,  C10G45/08 ,  C10G45/50 ,  Y02P20/584 ,  C07C13/18

Abstract: A process for the preparation of a catalyst from a catalytic precursor comprising a support based on alumina and/or silica-alumina and/or zeolite and comprising at least one element of group VIB and optionally at least one element of group VIII, by impregnation of said precursor with a solution of a C1-C4 dialkyl succinate. An impregnation step for impregnation of said precursor which is dried, calcined or regenerated, with at least one solution containing at least one carboxylic acid other than acetic acid, then maturing and drying at a temperature less than or equal to 200° C., optionally a heat treatment at a temperature lower than 350° C., followed by an impregnation step with a solution containing at least one C1-C4 dialkyl succinate followed by maturing and drying at a temperature less than 200° C. without subsequent calcination step. The catalyst is used in hydrotreatment and/or hydroconversion.

Abstract translation: 一种从催化前体制备催化剂的方法，其包含基于氧化铝和/或二氧化硅 - 氧化铝和/或沸石的载体，并且包含至少一种VIB族元素和任选的至少一种VIII族元素，通过浸渍 所述前体与C1-C4二烷基琥珀酸酯的溶液。 浸渍步骤，用于用至少一种含有至少一种不同于乙酸的羧酸的溶液干燥，煅烧或再生的所述前体浸渍，然后在小于或等于200℃的温度下熟化和干燥，任选地 在低于350℃的温度下进行热处理，随后用含有至少一种C 1 -C 4二烷基琥珀酸酯的溶液进行浸渍步骤，然后在低于200℃的温度下熟化和干燥，而无需随后的煅烧步骤。 催化剂用于加氢处理和/或加氢转化。

公开(公告)号：US20130105364A1

公开(公告)日：2013-05-02

申请号：US13283389

申请日：2011-10-27

Applicant: Opinder K. BHAN

Inventor： Opinder K. BHAN

IPC: B01J27/19 ,  C10G45/08

CPC classification number: B01J27/19 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/04 ,  C10G45/08

Abstract: A catalyst for hydrotreating heavy hydrocarbon feedstocks that comprises a calcined particle comprising a co-mulled mixture made by co-mulling an inorganic oxide material, molybdenum trioxide, a nickel compound and phosphorus pentoxide (P2O5) solid, forming said co-mulled mixture into a particle, and calcining said particle to thereby provide said calcined particle.

Abstract translation: 一种用于加氢处理重质烃原料的催化剂，其包含煅烧颗粒，该煅烧颗粒包含通过共研磨无机氧化物材料，三氧化钼，镍化合物和五氧化二磷（P 2 O 5）固体制成的共研磨混合物，将所述共研磨混合物形成 颗粒，并煅烧所述颗粒，从而提供所述煅烧颗粒。

公开(公告)号：US20120323026A1

公开(公告)日：2012-12-20

申请号：US13581641

申请日：2011-02-24

Applicant: John Robert Lockemeyer ,  Marek Matusz ,  Randall Clayton Yeates

Inventor： John Robert Lockemeyer ,  Marek Matusz ,  Randall Clayton Yeates

IPC: B01J23/50 ,  B01J27/188 ,  B01J27/19 ,  B01J27/24 ,  B01J27/132 ,  C07D301/04 ,  C07C29/00 ,  C07C41/02 ,  C07C68/00 ,  C07C209/00 ,  B01J27/02 ,  B01J27/199

CPC classification number: B01J27/051 ,  B01J27/047 ,  B01J27/188 ,  B01J27/19 ,  B01J35/108 ,  B01J35/1095 ,  B01J37/0201 ,  C07C213/04 ,  C07D301/10 ,  Y02P20/142 ,  C07C215/08

Abstract: A catalyst for the epoxidation of an olefin comprising a carrier and, deposited thereon, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; the total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 5.0 mmole/kg, relative to the weight of the catalyst; and wherein the carrier has a monomodal, bimodal or multimodal pore size distribution, a pore diameter of 0.01-200 μm, a specific surface area of 0.03-10 m2/g, a pore volume of 0.2-0.7 cm3/g, wherein the median pore diameter is 0.1-100 μm, and a water absorption of 10-80%.

Abstract translation: 一种用于环氧化包含载体并在其上沉积有银，铼助催化剂，第一共助催化剂和第二共助催化剂的烯烃的催化剂; 其中沉积在载体上的铼助催化剂的量相对于催化剂的重量大于1mmol / kg; 第一共助催化剂选自硫，磷，硼及其混合物; 第二共助催化剂选自钨，钼，铬及其混合物; 沉积在载体上的第一助催化剂和第二助催化剂的总量相对于催化剂的重量为至多5.0mmol / kg; 并且其中所述载体具有单峰，双峰或多峰孔径分布，孔径为0.01-200μm，比表面积为0.03-10m 2 / g，孔体积为0.2-0.7cm 3 / g，其中中值 孔径为0.1〜100μm，吸水率为10-80％。

公开(公告)号：US20120317873A1

公开(公告)日：2012-12-20

申请号：US13495817

申请日：2012-06-13

Applicant: Kimberly Ann JOHNSON ,  Glenn Charles KOMPLIN ,  Joseph Broun POWELL ,  John Anthony SMEGAL

Inventor： Kimberly Ann JOHNSON ,  Glenn Charles KOMPLIN ,  Joseph Broun POWELL ,  John Anthony SMEGAL

IPC: C10L1/00 ,  C10G1/00 ,  C07C51/00 ,  C07C29/132 ,  C07C45/26

CPC classification number: C10L9/086 ,  B01J27/047 ,  B01J27/0515 ,  B01J27/188 ,  B01J27/19 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/20 ,  C10G1/065 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/4081 ,  C10G2400/04 ,  C10G2400/08 ,  C10L5/44 ,  C10L9/08 ,  Y02E50/10 ,  Y02E50/13 ,  Y02E50/30 ,  Y02P30/20 ,  Y02T50/678

Abstract: A method of hydrothermal hydrocatalytic treating biomass is provided. Lignocellulosic biomass is treated with a digestive solvent to form a pretreated biomass containing soluble carbohydrates. The pretreated biomass is contacted, with hydrogen at a temperature in the range of 150° C. to less than 300° C. in the presence of a pH buffering agent and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into a suitable support, to form a plurality of oxygenated hydrocarbons.

Abstract translation: 提供了一种水热催化处理生物质的方法。 用消化溶剂处理木质纤维素生物质以形成含有可溶性碳水化合物的经预处理的生物质。 在pH缓冲剂和负载氢解催化剂存在下，将预处理的生物质与氢气在150℃至小于300℃的温度下接触，所述氢解催化剂含有（a）硫，（b）Mo或 W和（c）Co，Ni或其混合物，并入合适的载体中以形成多个含氧烃。

公开(公告)号：US08309486B2

公开(公告)日：2012-11-13

申请号：US12915534

申请日：2010-10-29

Applicant: Yigong He ,  Zheng Man ,  Xuhong Mu

Inventor： Yigong He ,  Zheng Man ,  Xuhong Mu

IPC: B01J27/00 ,  B01J27/182 ,  B01J27/188 ,  B01J27/19

CPC classification number: B01J23/28 ,  B01J21/063 ,  B01J21/08 ,  B01J21/18 ,  B01J27/188 ,  B01J27/19 ,  B01J27/199 ,  B01J29/06 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/08 ,  C07C2/58 ,  C07C9/14

Abstract: The present invention provides a composite solid acid catalyst consisting of from 50%-80% by weight of a porous inorganic support, from 15% to 48% by weight of a heteropoly compound loaded thereon, and from 2% to 6% by weight of an inorganic acid. The present invention further provides a process for preparing said composite solid acid catalyst and a process for conducting an alkylation reaction by using such catalyst. The composite solid acid catalyst of the present invention has the acid sites type of Brönsted acid and has an acid sites density of not less than 1.4×10−3 mol H+/g. Moreover, said composite solid acid catalyst has the homogeneous acid strength distribution, and is a solid acid catalyst having excellent performances.

Abstract translation: 本发明提供一种复合固体酸催化剂，其由50重量％〜80重量％的多孔无机载体，15〜48重量％的负载于其上的杂多化合物和2重量％〜6重量％ 无机酸。 本发明还提供了一种制备所述复合固体酸催化剂的方法和使用这种催化剂进行烷基化反应的方法。 本发明的复合固体酸催化剂具有酸性位点布朗斯台德酸，酸性位点密度不小于1.4×10 -3 mol H + / g。 此外，所述复合固体酸催化剂具有均匀的酸强度分布，并且是具有优异性能的固体酸催化剂。

公开(公告)号：US20120205292A1

公开(公告)日：2012-08-16

申请号：US13208057

申请日：2011-08-11

Applicant: Alexei Grigorievich GABRIELOV ,  Ed GANJA ,  Salvatore Philip TORRISI

Inventor： Alexei Grigorievich GABRIELOV ,  Ed GANJA ,  Salvatore Philip TORRISI

IPC: C10G45/08 ,  B01J37/02 ,  B01J21/12 ,  B01J23/28 ,  B01J23/30 ,  B01J21/08 ,  C10G45/04 ,  B01J31/34

CPC classification number: B01J35/026 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J31/0202 ,  B01J31/0237 ,  B01J31/0247 ,  B01J31/0254 ,  B01J31/0271 ,  B01J31/04 ,  B01J31/06 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0207 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202

Abstract: A hydroprocessing catalyst composition that comprises a chelant treated metal containing support material having incorporated therein a polar additive. The catalyst composition is prepared by incorporating at least one metal component into a support material followed by treating the metal incorporated support with a chelating agent and thereafter incorporating a polar additive into the chelant treated composition.

Abstract translation: 一种加氢处理催化剂组合物，其包含螯合剂处理的含金属的载体材料，其中掺入极性添加剂。 催化剂组合物通过将至少一种金属组分并入支持材料中制备，然后用螯合剂处理掺入金属的载体，然后将极性添加剂掺入到经过螯合剂处理的组合物中。

公开(公告)号：US08242044B2

公开(公告)日：2012-08-14

申请号：US12887623

申请日：2010-09-22

Applicant: Wilhelm Quittman ,  Thomas Peter Belser ,  Rhony Niklaus Aufdenblatten

Inventor： Wilhelm Quittman ,  Thomas Peter Belser ,  Rhony Niklaus Aufdenblatten

IPC: B01J27/19 ,  C07D239/02

CPC classification number: B01J27/1856 ,  B01J21/18 ,  B01J23/6525 ,  B01J27/19 ,  C07C209/36 ,  C07D239/47

Abstract: Aromatic or heteroaromatic nitro compounds are catalytically hydrogenated to the corresponding amines in the presence of a platinum catalyst comprising elemental platinum on a support; the platinum catalyst is modified with a molybdenum compound and a phosphorus compound wherein the phosphorus has an oxidation state of less than +5, e.g. hypophosphorous acid; the catalyst is particularly useful in the hydrogenation of nitro compounds with halogen and/or sulfur-containing substituents.

Abstract translation: 在载体上包含元素铂的铂催化剂存在下，将芳族或杂芳族硝基化合物催化氢化成相应的胺; 铂催化剂用钼化合物和磷化合物改性，其中磷具有小于+5的氧化态，例如， 次磷酸; 催化剂特别可用于具有卤素和/或含硫取代基的硝基化合物的氢化。