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公开(公告)号：US09018427B2
公开(公告)日：2015-04-28
申请号：US14183273
申请日：2014-02-18
Applicant: Greenyug, LLC
Inventor： Sagar B. Gadewar , Brian Christopher Vicente , Peter K. Stoimenov , Vivek Julka
CPC classification number: B01J23/00 , B01D3/009 , B01J8/0221 , B01J8/025 , B01J8/0278 , B01J8/0285 , B01J8/0453 , B01J8/0457 , B01J8/0492 , B01J8/0496 , B01J23/72 , B01J23/78 , B01J23/80 , B01J23/868 , B01J27/1806 , B01J2208/00176 , B01J2208/00247 , B01J2208/00274 , B01J2208/00283 , B01J2208/025 , B01J2523/00 , C07C29/34 , C07C67/00 , Y02P20/127 , Y02P20/582 , C07C31/12 , C07C69/14 , C07C31/125 , B01J2523/17 , B01J2523/27 , B01J2523/41 , B01J2523/48 , B01J2523/22 , B01J2523/23 , B01J2523/24 , B01J2523/25 , B01J2523/31 , B01J2523/12 , B01J2523/3712 , B01J2523/67
Abstract: A reactive distillation method comprises introducing a feed stream to a reactive distillation column, contacting the feed stream with one or more catalysts in the reactive distillation column during a distillation, and removing one or more higher alcohols during the distillation from the reactive distillation column as a bottoms stream. The feed stream comprises one or more alpha hydrogen alcohols, and the feed stream reacts in the presence of the one or more catalysts to produce a reaction product comprising the one or more higher alcohols.
Abstract translation: 反应蒸馏方法包括将进料流引入反应性蒸馏塔，在蒸馏期间使进料流与反应蒸馏塔中的一种或多种催化剂接触，以及在蒸馏期间将反应性蒸馏塔中的一种或多种高级醇作为 底部流。 进料流包含一种或多种α氢醇，并且进料流在一种或多种催化剂的存在下反应以产生包含一种或多种高级醇的反应产物。
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32.发明授权公开(公告)号：US08999013B2
公开(公告)日：2015-04-07
申请号：US13665438
申请日：2012-10-31
Applicant: Saudi Arabian Oil Company
Inventor： Wei Xu , Thamer Mohammad , Kareemuddin M. Shaik , Aadesh Harale
CPC classification number: C10L10/10 , C07C2/28 , C07C29/04 , C07C2531/10 , C10G50/00 , C10G2300/305 , C10G2400/02 , C10L1/023 , C10L1/06 , C10L1/125 , C10L1/1608 , C10L1/182 , C10L1/1824 , C10L2200/0254 , C10L2270/023 , C10L2290/24 , C07C31/12 , C07C11/02
Abstract: Methods for producing alcohols and oligomers contemporaneously from a hydrocarbon feed containing mixed butenes using an acid based catalyst are provided. Additionally, methods for producing fuel compositions having alcohols and oligomers prepared from mixed olefins are also provided as embodiments of the present invention. In certain embodiments, the catalyst can include a dual phase catalyst system that includes a water soluble acid catalyst and a solid acid catalyst.
Abstract translation: 提供了使用酸性催化剂从含有混合丁烯的烃进料同时生产醇和低聚物的方法。 此外，作为本发明的实施方案，也提供了制备具有由混合烯烃制备的醇和低聚物的燃料组合物的方法。 在某些实施方案中，催化剂可以包括包含水溶性酸催化剂和固体酸催化剂的双相催化剂体系。
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公开(公告)号：US20150045586A1
公开(公告)日：2015-02-12
申请号：US14368569
申请日：2012-12-21
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C45/50 , C01B3/16 , C07C1/20 , C07C1/22 , C07C4/06 , C07C29/14 , C07C29/141 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/40 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42 , C07C11/06 , C07C11/04 , C07C31/12 , C07C47/02
Abstract: The present invention provides a process for the production of aldehydes and/or alcohols, which process comprises the steps of: (a) reacting an oxygenate and/or olefinic feed in a reactor in the presence of a molecular sieve catalyst to form an effluent comprising olefins, comprising propylene; (b) separating the effluent comprising olefins as obtained in step (a) into at least a first olefinic product fraction comprising propylene and a second olefinic product fraction; (c) subjecting at least part of the first olefinic product fraction as obtained in step (b) to a hydroformylation process to form aldehydes; (d) separating at least part of the aldehydes as obtained in step (c) into at least a first product fraction of aldehydes and a second product fraction of aldehydes; and (e) hydrogenating at least part of the aldehydes in the first and/or second product fraction of aldehydes as obtained in step (d) to form a first product fraction of alcohols and/or a second product fraction of alcohols; (f) recycling at least part of the first and/or second product fraction of alcohols obtained in step (e) to step (a).
Abstract translation: 本发明提供了一种生产醛和/或醇的方法，该方法包括以下步骤：（a）在分子筛催化剂存在下使反应器中的含氧化合物和/或烯烃进料反应形成流出物，其包含 烯烃，包括丙烯; （b）将步骤（a）中获得的包含烯烃的流出物分离成至少包含丙烯和第二烯属产物馏分的第一烯烃产物级分; （c）将步骤（b）中获得的至少部分第一烯属产物级分进行加氢甲酰化过程以形成醛; （d）将步骤（c）中获得的至少一部分醛分离成至少醛的第一产物级分和醛的第二产物级分; 和（e）将步骤（d）中获得的醛的第一和/或第二产物级分中的至少部分醛氢化以形成醇的第一产物级分和/或醇的第二产物级分; （f）将步骤（e）中获得的醇的第一和/或第二产物馏分的至少一部分再循环到步骤（a）。
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公开(公告)号：US20140364351A1
公开(公告)日：2014-12-11
申请号：US14366281
申请日：2012-12-20
Applicant: RHODIA OPERATIONS
Inventor： Virginie Belliere-Baca , Didier Morvan , Loïc Baussaron , Gérald Bocquenet , Roland Jacquot , Philippe Marion , Jun Kubo , Tetsuya Yoshioka
IPC: C07C29/36
Abstract: A method for preparing a mixture (M) including at least one alcohol (Aj), wherein said method includes a gas-phase oligomerization reaction of at least one alcohol (Ai) with a solid acid-base catalyst doped with one or more metals, said reaction being carried out in the presence of hydrogen and at a temperature of no less than 50° C. and strictly less than 200° C.
Abstract translation: 一种制备包含至少一种醇（Aj）的混合物（M）的方法，其中所述方法包括至少一种醇（A 1）与掺杂有一种或多种金属的固体酸 - 碱催化剂的气相低聚反应， 所述反应在氢存在下进行，温度不低于50℃，严格低于200℃。
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公开(公告)号：US20140284501A1
公开(公告)日：2014-09-25
申请号：US14299003
申请日：2014-06-09
Applicant: Xyleco, Inc.
Inventor： Marshall MEDOFF , Thomas Craig MASTERMAN , Robert PARADIS
CPC classification number: D21C9/007 , B01D15/02 , B01D53/32 , B01D61/44 , B01D61/445 , B01J19/085 , B01J2219/0869 , B01J2219/0879 , B01J2219/0886 , B65G27/00 , B65G53/04 , B65G53/40 , C07C29/149 , C07C31/12 , C10G1/00 , C10L1/023 , C10L1/026 , C10L9/08 , C10L2200/0469 , C10L2200/0476 , C10L2290/36 , C12M47/00 , C12M47/10 , C12P7/04 , C12P7/06 , C12P7/10 , C12P7/52 , C12P7/56 , C12P19/02 , C12P19/14 , C12P2201/00 , C12P2203/00 , C13K1/02 , C13K13/002 , E04B1/92 , E04B2001/925 , G21F7/00 , H01J37/317 , H01J2237/202 , H01J2237/31 , H01J2237/3165 , Y02E50/16 , Y02E50/17 , Y02E50/32 , Y02E50/343 , Y02E60/17 , Y02P20/136 , Y02W10/33 , Y02W10/37
Abstract: Biomass feedstocks (e.g., plant biomass, animal biomass, and municipal waste biomass) are processed to produce useful products, such as fuels. For example, novel systems, methods and equipment for conveying and/or cooling treated biomass are described.
Abstract translation: 加工生物质原料（如植物生物质，动物生物质和城市垃圾生物质）以生产有用的产品，如燃料。 例如，描述了用于输送和/或冷却经处理的生物质的新型系统，方法和设备。
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Patent Agency Ranking
公开(公告)号：US20140245658A1
公开(公告)日：2014-09-04
申请号：US14175880
申请日：2014-02-07
Applicant: Pioneer Energy Inc
Inventor： John T. Henri , Jan Zygmunt , Mark Berggren , Robert Zubrin
CPC classification number: C07C29/175 , C07C27/04 , C07C67/46 , C10L1/02 , C07C31/08 , C07C31/12 , C07C69/14 , C07C69/24
Abstract: Ketene chemistry and hydrogenation reactions are used to synthesize fuels and chemicals. Ketene from acetic acid is hydrogenated to form fuels and chemicals; acetic acid can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc. In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass.
Abstract translation: 氯仿化学和氢化反应用于合成燃料和化学品。 乙酸从乙酸中氢化形成燃料和化学物质; 乙酸可以由从煤，生物质，天然气等产生的合成气合成。在一个实施方案中，本申请公开了选择性地合成可用作燃料的高级醇和烃以及来自合成气和生物质的工业化学品的方法。
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公开(公告)号：US08809600B2
公开(公告)日：2014-08-19
申请号：US13144654
申请日：2010-01-14
Applicant: Harald Kohnz , Thomas Urban , Detlef Hoell , Bernhard Pfeuffer , Ulrich Hoffmann , Ulrich Kunz
Inventor： Harald Kohnz , Thomas Urban , Detlef Hoell , Bernhard Pfeuffer , Ulrich Hoffmann , Ulrich Kunz
CPC classification number: C07C29/04 , C12C11/02 , C07C31/10 , C07C31/125 , C07C31/08 , C07C31/12 , C07C31/04
Abstract: An improved process for the hydration of C2-C5 olefins to the corresponding alcohols via heterogeneous reactive extraction with ion exchange resin catalysts is provided. The improvements are based on the application of a structured catalytic packing, a simultaneous product extraction in multiple condensed phases for enhancement of the overall alcohol production rate and a simplified product purification procedure.
Abstract translation: 提供了一种通过离子交换树脂催化剂通过非均相反应萃取将C2-C5烯烃水合成相应的醇的改进方法。 改进是基于结构化催化填料的应用，在多个凝结相中同时产物萃取以提高整体醇生产速率和简化的产物纯化程序。
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公开(公告)号：US08785700B2
公开(公告)日：2014-07-22
申请号：US13984371
申请日：2012-02-10
Applicant: Kunio Yamauchi
Inventor： Kunio Yamauchi
CPC classification number: C07C29/76 , B29C47/0021 , B29C47/0064 , B29C47/025 , B29K2067/003 , B32B5/022 , B32B27/10 , B32B27/12 , B32B27/36 , B32B2307/31 , B32B2307/724 , C07C29/74 , C07C31/02 , C07C31/04 , C07C31/08 , Y10T428/249991 , C07C31/10 , C07C31/12
Abstract: The present invention relates to an alcohol concentration method which comprises sealing in an alcohol aqueous solution by a laminate formed by extrusion lamination of polyethylene terephthalate onto at least one surface of an air permeable film-shaped substrate; and storing the alcohol aqueous solution in the laminate for a predetermined period of time, whereby the alcohol in the alcohol aqueous solution can be concentrated easily and conveniently.
Abstract translation: 本发明涉及一种醇浓缩方法，其包括通过将聚对苯二甲酸乙二醇酯挤出层压而形成的层压体在醇水溶液中密封在透气膜状基材的至少一个表面上; 并将醇水溶液在该层压体中保存一定时间，由此可以容易且方便地浓缩醇水溶液中的醇。
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公开(公告)号：US20140142352A1
公开(公告)日：2014-05-22
申请号：US14084881
申请日：2013-11-20
Applicant: BUTAMAX ADVANCED BIOFUELS LLC
Inventor： MICHAEL DAUNER , Robert Dicosimo , Steven D. Doig , Adam David Henry , Joseph J. Zaher
Abstract: Provided herein are processes for adjusting a fermentation medium to reduce the activity of one or more carboxylic acids. The processes comprise (a) providing a recombinant microorganism comprising an engineered butanol biosynthetic pathway, (b) contacting the recombinant microorganism with a fermentation medium whereby butanol is produced and wherein the fermentation medium comprises one or more carboxylic acids, and (c) adjusting the fermentation medium to reduce the activity of the one or more carboxylic acids. Also provided are processes for reducing the activity of one or more carboxylic acids in a feed. The processes comprise (a) providing a feed from a fermentation vessel, wherein the feed comprises a composition produced by a recombinant microorganism comprising an engineered butanol biosynthetic pathway, wherein the composition comprises butanol, water, and one or more carboxylic acids; and (b) adjusting the feed, wherein adjusting the feed reduces the activity of the one or more carboxylic acids.
Abstract translation: 本文提供了调节发酵培养基以降低一种或多种羧酸的活性的方法。 所述方法包括（a）提供包含工程改造的丁醇生物合成途径的重组微生物，（b）使重组微生物与发酵培养基接触，由此产生丁醇，其中发酵培养基包含一种或多种羧酸，和（c） 发酵培养基以降低一种或多种羧酸的活性。 还提供了降低进料中一种或多种羧酸的活性的方法。 所述方法包括（a）提供来自发酵容器的进料，其中所述进料包含由包含工程丁醇生物合成途径的重组微生物产生的组合物，其中所述组合物包含丁醇，水和一种或多种羧酸; 和（b）调节进料，其中调节进料降低了一种或多种羧酸的活性。
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40.发明授权Conversion of organosulfur compounds to hydrogen sulfide in mixed alcohol synthesis reactor effluent 有权在混合醇合成反应器流出物中将有机硫化合物转化为硫化氢公开(公告)号：US08721995B2
公开(公告)日：2014-05-13
申请号：US13667279
申请日：2012-11-02
Applicant: Fluor Technologies Corporation
Inventor： Martin West
CPC classification number: C10G45/02 , B01D53/1468 , C01B17/16 , C07C29/90 , Y02P20/52 , C07C31/08 , C07C31/04 , C07C31/10 , C07C31/12
Abstract: Plants and methods are presented in which organosulfur compounds in a mixed alcohol synthesis reactor effluent are converted into hydrogen sulfide (H2S). The volatility and relative insolubility of H2S reduces the overall sulfur content of the mixed alcohol synthesis product stream while significantly reducing or even eliminating the need for process steps/equipment to remove organosulfur compounds from liquid and gaseous products.
Abstract translation: 提出了将混合醇合成反应器流出物中的有机硫化合物转化为硫化氢（H 2 S）的工厂和方法。 H2S的挥发性和相对不溶性降低了混合醇合成产物流的总体硫含量，同时显着降低甚至消除了从液体和气态产物中除去有机硫化合物的工艺步骤/设备的需要。
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