POROUS/NANOPOROUS PHT
    35.
    发明申请

    公开(公告)号:US20170114186A1

    公开(公告)日:2017-04-27

    申请号:US15399365

    申请日:2017-01-05

    Abstract: Methods of forming nanoporous materials are described herein that include forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. The method generally includes forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a base-reactive substituent, and heating the reaction mixture to a temperature of between about 50 degC and about 150 degC to form a polymer. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix.

    POROUS/NANOPOROUS PHT
    37.
    发明申请
    POROUS/NANOPOROUS PHT 有权
    POROUS / NANOPOROUS PHT

    公开(公告)号:US20160108175A1

    公开(公告)日:2016-04-21

    申请号:US14564650

    申请日:2014-12-09

    Abstract: Methods of forming nanoporous materials are described herein that include forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. The method generally includes forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a base-reactive substituent, and heating the reaction mixture to a temperature of between about 50 deg C. and about 150 deg C. to form a polymer. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix.

    Abstract translation: 本文描述形成纳米多孔材料的方法,包括用化学可除去部分形成聚合物网络。 化学可除去部分可以是聚碳酸酯聚合物,其可在施加热或暴露于在暴露于酸中时可去除的碱或聚六氢三嗪(PHT)或聚乙烯胺(PHA))聚合物上除去。 该方法通常包括形成包含甲醛,溶剂,伯芳族二胺和具有伯氨基和仲氨基的二胺的反应混合物,仲氨基具有碱反应性取代基,并加热反应混合物 至约50摄氏度至约150摄氏度的温度以形成聚合物。 当聚合物链分解时,去除聚合物的任何部分导致纳米孔的形成,在聚合物基体中留下孔。

    METHOD FOR MANUFACTURING POROUS SHEET AND POROUS SHEET MANUFACTURED BY THE METHOD
    40.
    发明申请
    METHOD FOR MANUFACTURING POROUS SHEET AND POROUS SHEET MANUFACTURED BY THE METHOD 审中-公开
    方法制造多孔板和方法制造的多孔板

    公开(公告)号:US20120085038A1

    公开(公告)日:2012-04-12

    申请号:US13377792

    申请日:2010-06-10

    Abstract: The present invention provides a method for producing a porous sheet, including the steps of a) producing a polymer resin sheet containing an object to be processed by supercritical fluid extraction which is dissolved in supercritical fluid; and b) injecting the supercritical fluid into the polymer resin sheet to extract the object to be processed by supercritical fluid extraction that is contained in the polymer resin sheet, thereby forming pores in the polymer resin sheet, and a porous sheet produced by the same.

    Abstract translation: 本发明提供一种多孔片的制造方法,包括以下步骤:a)通过超临界流体萃取法生产含有超临界流体萃取物的聚合物树脂片,所述超临界流体萃取溶解在超临界流体中; 以及b)将超临界流体注入到聚合物树脂片中,通过聚合物树脂片中所含的超临界流体萃取提取待处理物体,从而在聚合物树脂片中形成孔,以及由其制造的多孔片。

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