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41.发明申请MONOLITHIC CATALYST COMPRISING MOLECULAR SIEVE MEMBRANE AND METHOD FOR PERPARING THE MONOLITHIC CATALYST 审中-公开包含分子筛膜的单晶催化剂和单晶催化剂的方法公开(公告)号：US20160288104A1
公开(公告)日：2016-10-06
申请号：US15186583
申请日：2016-06-20
发明人： Changyuan LI , Qianqian LIU , Dechen SONG , Weiguang YANG , Xiaodong ZHAN , Jiaqi JIN , Yanfeng ZHANG
CPC分类号： B01J23/894 , B01J29/0333 , B01J29/70 , B01J35/023 , B01J35/04 , B01J37/0217 , B01J37/0225 , B01J37/0242 , B01J37/0246 , B01J37/06 , B01J37/343 , B01J2229/66 , B01J2523/00 , C10G2/332 , C10G2/333 , C10G2/334 , B01J2523/3712 , B01J2523/828 , B01J2523/845
摘要： A monolithic catalyst, including cobalt, a metal matrix, a molecular sieve membrane, and an additive. The metal matrix is silver, gold, copper, platinum, titanium, molybdenum, iron, tin, or an alloy thereof. The molecular sieve membrane is mesoporous silica SBA-16 which is disposed on the surface of the metal matrix and is a carrier of the active component and the additive. The thickness of the carrier is between 26 and 67 μm. The additive is lanthanum, zirconium, cerium, rhodium, platinum, rhenium, ruthenium, titanium, magnesium, calcium, strontium, or a mixture thereof. A method for preparing the monolithic catalyst is also provided.
摘要翻译： 包括钴，金属基质，分子筛膜和添加剂的整体式催化剂。 金属基体是银，金，铜，铂，钛，钼，铁，锡或它们的合金。 分子筛膜是介孔二氧化硅SBA-16，其设置在金属基质的表面上，并且是活性组分和添加剂的载体。 载体的厚度在26和67μm之间。 添加剂是镧，锆，铈，铑，铂，铼，钌，钛，镁，钙，锶或它们的混合物。 还提供了制备整体式催化剂的方法。
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42.发明授权公开(公告)号：US09255226B2
公开(公告)日：2016-02-09
申请号：US14571240
申请日：2014-12-15
发明人： Yilong Chen , Kan Song , Pingyu Kuai , Yanfeng Zhang , Jiaqi Jin
CPC分类号： C10G2/40 , B01D53/047 , B01D2257/108 , B01D2257/7025 , C01B3/34 , C01B3/56 , C01B2203/0283 , C01B2203/043 , C01B2203/062 , C01B2203/148 , C10G2/332 , C10G2300/4081 , C10K1/32 , C10K3/00 , Y02C20/20 , Y02P20/156
摘要： A method for improving Fischer-Tropsch synthesis and recycling exhaust gases therefrom. The method includes: 1) transforming raw gas for Fischer-Tropsch synthesis using a water-gas shift reaction, transporting the transformed raw gas to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis in the presence of a Fe-based or Co-based catalyst; 2) introducing exhaust gases from the Fischer-Tropsch synthesis device to a first pressure-swing adsorber for hydrogen recovery; 3) introducing the exhaust gases from 2) to a second pressure-swing adsorber for methane recovery; 4) returning part of the hydrogen obtained from 2) to 1) to mix with the raw gas, and transforming a resulting mixed gas to adjust a hydrogen/carbon ratio of the raw gas; and 5) introducing the methane in 3) to a methane reforming device to reform the methane whereby yielding syngas having relatively high hydrogen/carbon ratio, and transporting the syngas to 1) to mix with the raw gas.
摘要翻译： 费 - 托合成和废气再循环的方法。 该方法包括：1）使用水煤气变换反应转化费 - 托合成的原料气体，在Fe基或Co-Fe合金存在下，将转化后的原料气转移至费 - 托合成装置进行费 - 托合成， 基催化剂; 2）将来自费 - 托合成装置的废气引入第一变压吸附器进行氢回收; 3）将来自2）的废气引入用于甲烷回收的第二变压吸附器; 4）将从2）获得的部分氢气返回到1）与原料气体混合，转化所得混合气体以调节原料气体的氢/碳比; 和5）在甲烷重整装置中将甲烷引入甲烷重整装置以重整甲烷，由此产生具有相对较高氢/碳比的合成气，并将合成气输送至1）与原料气体混合。
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43.发明授权Polymer material having high capacity for hydrogen storage and preparation method thereof 有权具有高储氢能力的聚合物材料及其制备方法公开(公告)号：US09234082B2
公开(公告)日：2016-01-12
申请号：US14660962
申请日：2015-03-18
发明人： Zhangjian Fang , Yilong Chen , Yanfeng Zhang , Xingcai Zheng , Yongjie Xue , Leiming Tao
CPC分类号： C08J5/18 , C01B3/0015 , C08F8/04 , C08F8/32 , C08G73/0226 , C08G77/26 , C08J2325/06 , C08J2325/08 , C08J2327/06 , C08J2333/02 , C08J2379/02 , Y02E60/328
摘要： A high capacity polymer hydrogen storage material, including a linear high molecular polymer as a main chain. At least one side chain or a terminal group of the linear high molecular polymer is first aminated using a polyamine compound and then reacts with a borohydride to yield an ammonia borane derivative grafted to the side chain or the terminal group of the linear high molecular polymer.
摘要翻译： 高容量聚合物储氢材料，包括线性高分子聚合物作为主链。 首先使用多胺化合物将线性高分子聚合物的至少一个侧链或末端基团胺化，然后与硼氢化物反应，得到接枝到线性高分子聚合物的侧链或末端基团的氨硼烷衍生物。
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44.发明申请公开(公告)号：US20150119595A1
公开(公告)日：2015-04-30
申请号：US14569771
申请日：2014-12-14
发明人： Leiming TAO , Yilong CHEN , Yanfeng ZHANG , Yongjie XUE
IPC分类号： C07F7/02
摘要： A method for preparing surface-modified nano silicon dioxide from rice hulls. The method includes: 1) pretreating rice hulls using a treating gas containing CO2 to remove metal ions, impurities, and dusts, and desiccating and grinding the rice hulls; 2) submerging the rice hulls into a dilute solution of phosphoric acid, boric acid, hydrochloric acid, formic acid, acetic acid, propionic acid, butyric acid, or a strong-acid-weak-base salt for between 4 and 8 hrs, controlling the immersion temperature not to exceed 10° C., leaching a resulting mixture, removing a filtrate, and desiccating the rice hulls; and 3) calcining the rice hulls in the absence of oxygen at a temperature of between 300 and 450° C.
摘要翻译： 一种从稻壳中制备表面改性纳米二氧化硅的方法。 该方法包括：1）使用含CO2处理气体去除稻壳，去除金属离子，杂质和粉尘，干燥和研磨米壳; 2）将稻壳浸入磷酸，硼酸，盐酸，甲酸，乙酸，丙酸，丁酸或强酸 - 弱碱盐的稀溶液中4〜8小时，控制 浸渍温度不超过10℃，浸出得到的混合物，除去滤液，干燥稻壳; 和3）在300-450℃的温度下，在不存在氧的情况下煅烧稻壳。
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45.发明申请CATALYST FOR METHANATION OF CARBON DIOXIDE, PREPARATION METHOD AND USAGE THEREOF 有权二氧化碳甲烷的催化剂，制备方法及其用途公开(公告)号：US20140200279A1
公开(公告)日：2014-07-17
申请号：US14242816
申请日：2014-04-01
发明人： Zhilong WANG , Yanfeng ZHANG , Yilong CHEN , Yongjie XUE , Leiming TAO , Zhixiang LUO , Xingcai ZHENG
IPC分类号： B01J23/755 , C07C1/04
CPC分类号： C07C1/12 , B01J21/18 , B01J23/755 , B01J37/04 , B01J37/08 , B01J37/082 , B01J37/084 , C07C1/0435 , C07C2521/18 , C07C2523/755 , C10L3/06 , C10L3/08 , Y02P20/142 , Y02P20/52 , C07C9/04
摘要： A catalyst for methanation of carbon dioxide. The catalyst is formed by mixing ash from a biomass power plant with a nickel compound and calcining the resulting mixture. The catalyst formed by calcination includes between 2 and 20 wt. % of nickel.
摘要翻译： 二氧化碳甲烷化催化剂。 催化剂是通过将来自生物质发电厂的灰与镍化合物混合并煅烧得到的混合物形成的。 通过煅烧形成的催化剂包括2-20wt。 镍的百分比。
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46.发明授权公开(公告)号：US10450519B2
公开(公告)日：2019-10-22
申请号：US15693467
申请日：2017-08-31
发明人： Weiguang Yang , Youliang Shi
摘要： A method for hydrofining of middle distillates of Fischer-Tropsch synthetic full-range distillates, the method including: 1) separating middle distillates of Fischer-Tropsch synthetic full-range distillates to yield light distillates, heavy distillates and intermediate distillates; 2) metering the light distillates, the heavy distillates and the intermediate distillates; providing a hydrogenation reactor filled with a hydrofining catalyst and including a first feed inlet, a second feed inlet and a third feed inlet from the top down; mixing hydrogen and the light distillates, the heavy distillates and the intermediate distillates, respectively, and introducing resulting mixtures to the hydrogenation reactor via the first feed inlet, the second feed inlet and the third feed inlet, respectively; and 3) introducing products from 2) to a gas-liquid separator to yield hydrogen and liquid products, returning the hydrogen to the hydrogenation reactor, and introducing the liquid products to a fractionating column for further separation.
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公开(公告)号：US10220375B2
公开(公告)日：2019-03-05
申请号：US14923404
申请日：2015-10-26
发明人： Weiguang Yang , Qianqian Liu , Dechen Song , Changyuan Li , Xiaodong Zhan , Jiaqi Jin , Yanfeng Zhang
IPC分类号： B01J29/06 , B01J29/85 , B01J29/00 , B01J29/035 , B01J29/072 , B01J29/76 , B01J29/70 , B01J29/78 , B01J29/46 , B01J37/30 , B01J23/889 , B01J29/40 , B01J29/48 , C10G2/00 , C07C1/04 , B01J37/02 , B01J37/08
摘要： A catalyst, including a molecular sieve carrier and an active component. The active component includes: iron, manganese, copper, and a basic promoter potassium. The molecular sieve carrier is a cerium salt and/or praseodymium salt modified-aluminosilicate molecular sieve carrier and/or silica-rich molecular sieve carrier. A method for preparing a catalyst for Fischer-Tropsch synthesis, includes: 1) fully dissolving a ferric salt, a manganese salt, a copper salt, and an alkali or a salt containing potassium element in water to yield an aqueous solution, stirring and adding sodium lauryl sulfate to the aqueous solution, and continuing stirring to yield a uniform solution; and impregnating a modified molecular sieve in the uniform solution to yield a mixed solution; and 2) drying and calcining the mixed solution to yield the catalyst.
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48.发明申请公开(公告)号：US20170362518A1
公开(公告)日：2017-12-21
申请号：US15694878
申请日：2017-09-04
发明人： Tao ZHAO , Bo LAI , Weiguang YANG , Dawei WANG , Xuewen HAO , Yanjie ZHOU , Li XU
CPC分类号： C10G67/02 , B01J19/245 , B01J2219/24 , C10G45/02 , C10G47/00 , C10G65/12 , C10G65/14 , C10G2300/1022 , C10G2400/04
摘要： An apparatus for producing diesel fuel and jet fuel using Fischer-Tropsch synthetic oil, the apparatus including a hydrofining reactor, a hot separator, a first rectifying column, a hydrocracking reactor, a hydroisomerization reactor, a second rectifying column, a first mixing chamber and a second mixing chamber. The hydrofining reactor includes a raw material inlet and a hydrofining product outlet. The hot separator includes a separated oil outlet and a hydrofining product inlet which is connected to the hydrofining product outlet. The first rectifying column includes a tail oil fraction outlet, a diesel fraction outlet and a separated oil inlet which is connected to the separated oil outlet. The first mixing chamber includes a circulating hydrogen inlet, a first mixture outlet and a tail oil fraction inlet which is connected to the tail oil fraction outlet.
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49.发明授权公开(公告)号：US09795950B2
公开(公告)日：2017-10-24
申请号：US15350132
申请日：2016-11-14
发明人： Wanwan Wang , Dechen Song , Li Xu
IPC分类号： B01J21/04 , B01J23/28 , B01J23/755 , B01J23/883 , B01J29/48 , B01J29/78 , B01J35/02 , B01J37/00 , B01J37/02 , B01J37/04 , B01J37/06 , B01J37/08 , C10G49/04 , C10G49/08
CPC分类号： B01J29/7884 , B01J29/076 , B01J29/48 , B01J35/002 , B01J35/026 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0018 , B01J37/009 , B01J37/02 , B01J37/0201 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/343 , B01J2229/16 , B01J2229/20 , B01J2229/36 , B01J2229/40 , B01J2229/42 , B01J2523/00 , C10G49/04 , C10G49/08 , C10G2300/1022 , C10G2300/1081 , B01J2523/68 , B01J2523/847
摘要： A catalyst for preparing aviation fuel from synthetic oil obtained by Fischer-Tropsch process, including: between 20 and 50 percent by weight of an amorphous aluminum silicate, between 5 and 20 percent by weight of alumina, between 20 and 60 percent by weight of a hydrothermally modified zeolite, between 0.5 and 1.0 percent by weight of a Sesbania powder, between 0.5 and 5 percent by weight of nickel oxide, and between 5 and 15 percent by weight of molybdenum oxide. The invention also provides a method for preparing the catalyst.
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公开(公告)号：US09758740B2
公开(公告)日：2017-09-12
申请号：US14920907
申请日：2015-10-23
发明人： Yanfeng Zhang , Yilong Chen , Zhilong Wang , Zhangjian Fang , Xingcai Zheng
CPC分类号： C10L3/08 , B01J7/00 , C07C1/12 , C10L3/06 , C10L2290/06 , C10L2290/10 , C10L2290/38 , C10L2290/42 , C10L2290/54 , Y02E60/366 , Y02P20/133 , C07C9/04
摘要： A device for converting carbon dioxide in flue gas into natural gas using dump energy. The device includes a transformer and rectifier device, an electrolytic cell, a turbine, a carbon dioxide heater, a primary fixed bed reactor, a secondary fixed bed reactor, a natural gas condenser, and a process water line. An outlet of the transformer and rectifier device is connected to a power interface of the electrolytic cell, a gas-liquid outlet of a cathode of the electrolytic cell is connected to a gas-liquid inlet of a hydrogen separator, and a liquid outlet of the hydrogen separator is connected to a liquid reflux port of the cathode of the electrolytic cell.
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