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公开(公告)号：US10040938B2
公开(公告)日：2018-08-07
申请号：US14489612
申请日：2014-09-18
CPC分类号： C08L77/06 , C08K3/16 , C08K5/005 , C08K5/18 , C08L2201/08 , C08L2203/18 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/1397
摘要： A moulding composition contains at least 40 wt % of components a) and b). Based on the sum of components a) and b), there are 60-99 wt % of component a) and 40-1 wt % of component b). Component a) is a partially aromatic copolyamide containing, as polymerized monomer units, 30-90 mol % of a combination of hexamethylenediamine and terephthalic acid and 70-10 mol % of a combination of hexamethylenediamine and a linear aliphatic dicarboxylic acid having 8-19 C atoms. Component b) is an olefinic copolymer containing, as polymerized monomer units, i) 35-94.9 wt % of ethene-based monomer units, ii) 5-65 wt % of monomer units based on a 1-alkene having 4-8 C atoms, iii) 0-10 wt % of monomer units based on an olefin different from i) and ii), and iv) 0.1-2.5 wt % of monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride, where the sum of wt % of i), ii), iii) and iv) is 100%.
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公开(公告)号：US09919494B2
公开(公告)日：2018-03-20
申请号：US14835215
申请日：2015-08-25
IPC分类号： B32B15/088 , C08L77/02 , C08J5/00 , C08G73/02 , C08L77/06 , B32B15/08 , B32B27/18 , B32B27/28 , B32B27/34 , B32B1/08 , F16L11/04 , F16L9/147 , F16L58/10
CPC分类号： B32B15/088 , B32B1/08 , B32B15/08 , B32B27/18 , B32B27/28 , B32B27/34 , B32B2270/00 , B32B2307/306 , B32B2307/714 , B32B2597/00 , B32B2605/08 , C08G73/028 , C08J5/00 , C08J2377/02 , C08J2477/02 , C08L77/02 , C08L77/06 , F16L9/147 , F16L11/04 , F16L58/10 , C08L79/02
摘要： A metallic pipe for contact with a hydrolyzing medium provides longer operating times and improved high temperature resistance. The pipe contains a layer of a polyamide moulding composition containing at least 50% by weight of polyamide content containing: I) 60 to 98 parts by weight of a polyamide which contains 10 to 70 meq/kg of a terminal carboxy group and has a relative solution viscosity ηrel of at least 1.90, and II) 2 to 40 parts by weight of a polyamine-polyamide graft copolymer produced from: a) 0.5 to 25% by weight, based on the entire monomer mixture, of a polyamine having at least 4 nitrogen atoms, and b) 75 to 99.5% by weight, based on the entire monomer mixture, of polyamide-forming monomers selected from lactams, ω-aminocarboxylic acids and/or equimolar combinations of diamine and dicarboxylic acid, with the proviso that the amino group concentration of the graft copolymer is in the range from 100 to 2500 meq/kg, wherein the sum of the parts by weight of I) and II) is 100.
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43.发明授权Process for producing a molding composition or a molding with an increase in the melt stiffness 有权用于生产模塑组合物或模塑料的方法，其中熔体刚度提高公开(公告)号：US08697814B2
公开(公告)日：2014-04-15
申请号：US13063134
申请日：2009-11-17
CPC分类号： F16L11/06 , B29C47/00 , B29C47/0016 , B29C47/0021 , B29C47/0026 , C08G69/40 , C08G69/46 , C08J3/226 , C08J2377/00 , C08J2477/00 , C08L77/00 , C08L77/06 , C08L2205/02 , F16L9/147 , Y10T428/1352 , Y10T428/139 , C08L2666/20
摘要： A polyamide molding composition is condensed up in the melt by means of a masterbatch containing a compound having at least two carbonate units and also a polyetheramide in which at least 50% of the end groups are present as amino end groups, whereupon the melt mixture is discharged and solidified to give a molding composition or a molding. The product obtained has an increased amino end group content and consequently an improved hydrolysis resistance.
摘要翻译： 聚酰胺模塑组合物通过含有至少两个碳酸酯单元的化合物的母料在熔体中缩合，并且其中至少有50％的端基作为氨基端基存在的聚醚酰胺，因此熔融混合物是 排出并固化，得到模塑组合物或模制品。 所得产物具有增加的氨基端基含量，因此具有改善的耐水解性。
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公开(公告)号：US08647551B2
公开(公告)日：2014-02-11
申请号：US11354114
申请日：2006-02-15
申请人： Andreas Dowe , Rainer Goering , Martin Himmelmann , Sonja Bollmann , Franz-Erich Baumann , Roland Wursche
发明人： Andreas Dowe , Rainer Goering , Martin Himmelmann , Sonja Bollmann , Franz-Erich Baumann , Roland Wursche
IPC分类号： C08F283/04 , C08L77/00 , B29C49/00
CPC分类号： C08K5/098 , C08L69/00 , C08L77/02 , Y10T428/1352 , Y10T428/139 , C08L77/00 , C08L2666/14
摘要： A process for producing moldings with condensing-up of a polyamide molding composition whose polyamide component contains, as a result of the method of preparation, at least 5 ppm of phosphorus in the form of an acidic compound by means of a compound having at least two carbonate units, wherein a) from 0.001 to 10% by weight, based on the polyamide, of a salt of a weak acid is added to the polyamide molding composition prior to compounding or during compounding, b) a mixture of the finished composition and the compound having at least two carbonate units is prepared, c) the mixture is, if appropriate, stored and/or transported and d) the mixture is subsequently processed to produce the molding, with the condensing-up occurring only in this step, effects a significant increase in the melt stiffness combined with moderate processing pressures, which considerably simplifies, in particular, the production of hollow bodies and hollow profiles having large diameters.
摘要翻译： 一种聚酰胺成型组合物的制造用模制品的制造方法，其聚酰胺成分作为制备方法的结果，含有至少5ppm的酸性化合物形式的磷，该化合物具有至少两个 碳酸酯单元，其中a）基于聚酰胺的0.001至10重量％的弱酸盐在配混之前或在配混期间加入到聚酰胺模塑组合物中，b）成品组合物和 制备具有至少两个碳酸酯单元的化合物，c）如果合适的话，该混合物被储存和/或运输，以及d）随后将该混合物加工以产生模制物，其中仅在该步骤中发生冷凝， 结合中等加工压力的熔体刚度的显着增加，这特别地简化了具有大直径的中空体和中空型材的生产。
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公开(公告)号：US08604227B2
公开(公告)日：2013-12-10
申请号：US13634111
申请日：2010-11-19
申请人： Frank-Martin Petrat , Franz-Erich Baumann , Harald Haeger , Guido Walther , Andreas Martin , Angela Koeckritz
发明人： Frank-Martin Petrat , Franz-Erich Baumann , Harald Haeger , Guido Walther , Andreas Martin , Angela Koeckritz
IPC分类号： C07C51/10
摘要： The invention provides a process for preparing linear alpha,omega-dicarboxylic diesters by reacting a triglyceride containing fatty acid residues having monounsaturated or polyunsaturated carbon chains with carbon monoxide, an acid and an OH-group donor in one reaction step in the presence of a catalyst.
摘要翻译： 本发明提供了通过在一个反应步骤中在催化剂存在下使含有单不饱和或多不饱和碳链的脂肪酸残基与一氧化碳，酸和OH-给体的甘油三酯反应制备线性α，ω-二羧酸二酯的方法 。
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公开(公告)号：US08580899B2
公开(公告)日：2013-11-12
申请号：US11354100
申请日：2006-02-15
IPC分类号： C08F283/04 , C08L77/00
CPC分类号： C08G69/48 , B29C47/0023 , B29C47/0054 , B29C47/043 , B29C47/065 , B29C49/04 , B29C2791/006 , B29K2023/06 , B29K2023/12 , B29K2055/02 , B29K2077/00 , B29K2105/0008 , B29K2105/0026 , B29K2105/0032 , B29K2105/0038 , B29K2105/0044 , B29K2105/16 , B29L2023/22 , B29L2031/7172 , C08K5/098 , F16L9/127 , Y10T428/139 , C08L77/00
摘要： A process for producing moldings with condensing-up of a polyamide molding composition by means of a compound having at least two carbonate units, wherein a) a polyamide molding composition is made available, b) a mixture of the polyamide molding composition and the compound having at least two carbonate units is prepared, c) the mixture is, if appropriate, stored and/or transported and d) the mixture is subsequently processed to produce the molding, with the condensing-up occurring only in this step, and the molding is a hollow body or hollow profile having an external diameter of at least 30 mm and a wall thickness of at least 1 mm, effects a significant increase in the melt stiffness combined with moderate processing presssures, which considerably simplifies the production of these moldings.
摘要翻译： 一种通过具有至少两个碳酸酯单元的化合物聚酰胺模塑组合物生产模制品的方法，其中a）聚酰胺模塑组合物可获得，b）聚酰胺模塑组合物和具有 制备至少两个碳酸酯单元，c）如果适当，储存和/或运输混合物，以及d）随后将该混合物加工以产生模制品，其中仅在该步骤中发生冷凝，并且模塑是 具有至少30mm的外径和至少1mm的壁厚的中空本体或中空型材，与中等加工压力结合使熔体刚度显着提高，这大大简化了这些模制品的生产。
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47.发明授权Polymer powder comprising polyamide use thereof in a moulding method and moulded body made from said polymer powder 有权包含聚酰胺用途的聚合物粉末的成型方法和由所述聚合物粉末制成的成型体公开(公告)号：US08449809B2
公开(公告)日：2013-05-28
申请号：US13281000
申请日：2011-10-25
IPC分类号： H05B6/00
CPC分类号： C08L77/06 , B29C64/153 , B33Y70/00
摘要： A molding, produced by a layer-by-layer process in which regions of respective polymer pulverulent layers are selectively melted via introduction of electromagnetic energy, where the process employs a powder which comprises at least one homopolyamide prepared via polycondensation of diamines and dicarboxylic acids, wherein the homopolyamide has an enthalpy of fusion of at least 125 J/g and a recrystallization temperature of at least 148° C.
摘要翻译： 通过逐层方法制造的成型体，其中通过引入电磁能选择性地熔融各聚合物粉状层的区域，其中该方法使用包含至少一种通过二胺和二羧酸的缩聚制备的均聚酰胺的粉末， 其中均聚酰胺具有至少125J / g的熔融焓和至少148℃的重结晶温度。
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公开(公告)号：US20130012643A1
公开(公告)日：2013-01-10
申请号：US13541181
申请日：2012-07-03
申请人： Sylvia MONSHEIMER , Wolfgang Diekmann , Franz-Erich Baumann , Sigrid Hessel-Geldmann , Kristiane Warnke , Heike Stemmer , Stefan Altkemper
发明人： Sylvia MONSHEIMER , Wolfgang Diekmann , Franz-Erich Baumann , Sigrid Hessel-Geldmann , Kristiane Warnke , Heike Stemmer , Stefan Altkemper
CPC分类号： C08K9/08 , B29C64/153 , B29C67/04 , B33Y10/00 , B33Y70/00 , C01P2002/88 , C01P2004/61 , C01P2004/84 , C01P2006/12 , C09C1/28 , C09C3/10 , Y10T428/2996
摘要： Composite particles comprising core particles completely or partially coated with a precipitated polymer, where the d50 median diameter of the core particles is from 3 to 100 μm and wherein the glass core particle material is at least one selected from the group consisting of a solid glass bead, a hollow glass bead, a porous glass bead, and a foamed glass particle. A method to prepare the particles includes dissolution of a polymer in a solvent and precipitation of the polymer in the presence of a suspension of the core glass particles. Further provided is a layer by layer moulding process employing the composite particles and mouldings obtained therefrom.
摘要翻译： 包含完全或部分被沉淀的聚合物涂覆的核心颗粒的复合颗粒，其中核心颗粒的d50中值直径为3至100μm，并且其中所述玻璃核心颗粒材料是选自固体玻璃珠 ，中空玻璃珠，多孔玻璃珠和发泡玻璃颗粒。 制备颗粒的方法包括将聚合物溶解在溶剂中并在核心玻璃颗粒的悬浮液存在下沉淀聚合物。 还提供了使用由其获得的复合颗粒和模制品的逐层模制方法。
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公开(公告)号：US20130006005A1
公开(公告)日：2013-01-03
申请号：US13634111
申请日：2010-11-19
申请人： Frank-Martin Petrat , Franz-Erich Baumann , Harald Haeger , Guido Walther , Andreas Martin , Angela Koeckritz
发明人： Frank-Martin Petrat , Franz-Erich Baumann , Harald Haeger , Guido Walther , Andreas Martin , Angela Koeckritz
IPC分类号： C07C67/36
摘要： The invention provides a process for preparing linear alpha,omega-dicarboxylic diesters by reacting a triglyceride containing fatty acid residues having monounsaturated or polyunsaturated carbon chains with carbon monoxide, an acid and an OH-group donor in one reaction step in the presence of a catalyst.
摘要翻译： 本发明提供了通过在一个反应步骤中在催化剂存在下使含有单不饱和或多不饱和碳链的脂肪酸残基与一氧化碳，酸和OH-给体的甘油三酯反应制备线性α，ω-二羧酸二酯的方法 。
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50.发明授权公开(公告)号：US08119715B2
公开(公告)日：2012-02-21
申请号：US12853632
申请日：2010-08-10
IPC分类号： C08K3/32
CPC分类号： C08K3/32 , B33Y70/00 , B33Y80/00 , C08K2003/323
摘要： A pulverulent composition that is a powder containing at least one polymer, and at least one flame retardant that contains ammonium polyphosphate, the powder having a maximum particle size of ≦150 μm and a median particle size of from 20 to 100 μm.
摘要翻译： 粉末组合物，其是含有至少一种聚合物的粉末和至少一种包含多磷酸铵的阻燃剂，所述粉末的最大粒度为＆lt; NlE;150μm，中值粒径为20〜100μm。
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