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公开(公告)号：US20090162264A1
公开(公告)日：2009-06-25
申请号：US12238980
申请日：2008-09-26
IPC分类号： B01J19/00
CPC分类号： C10G45/02 , C10G45/12 , C10G45/58 , C10G45/64 , C10G47/00 , C10G47/16 , C10G65/043 , C10G65/12 , C10G2300/1011 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process has been developed for producing aviation fuel from renewable feedstocks such as plant oils and animals fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide n-paraffins having from about 8 to about 24 carbon atoms. At least some of the n-paraffins are isomerized to improve cold flow properties. At least a portion of the paraffins are selectively cracked to provide paraffins meeting specifications for different fuels such as JP-8.
摘要翻译： 已经开发了用于从可再生原料如植物油和动物脂肪和油生产航空燃料的过程。 该方法包括通过氢化和脱氧处理可再生原料以提供具有约8至约24个碳原子的正链烷烃。 至少一些正链烷烃被异构化以改善冷流特性。 选择性裂化至少一部分链烷烃以提供满足不同燃料如JP-8的规格的石蜡。
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42.发明申请CATALYST FOR SELECTIVE OPENING OF CYCLIC NAPHTHA AND PROCESS FOR USING THE CATALYST 审中-公开催化剂用于选择性地打开循环硫酸盐和使用催化剂的方法公开(公告)号：US20080249346A1
公开(公告)日：2008-10-09
申请号：US12141967
申请日：2008-06-19
IPC分类号： C07C4/08
CPC分类号： B01J23/40 , B01J29/06 , B01J29/70 , B01J29/74 , B01J29/78 , B01J29/85 , B01J35/0006 , B01J35/002 , B01J37/0009 , B01J37/0201 , B01J2229/20 , B01J2229/42 , C07C5/31 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/12 , C07C2523/02 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2529/70 , C07C2529/84 , C07C2529/85 , C10G45/64 , Y10S423/30 , C07C9/15
摘要： A catalyst and process for opening aliphatic cyclic hydrocarbons have been developed. The catalyst comprises a catalytic metal component, a molecular sieve and refractory inorganic oxide component. The molecular sieve is selected from the group consisting of MAPSOs, SAPOs, UZM-8, UZM-8HS, UZM-15, UZM-15HS, UZM-16, UZM-16HS and mixtures thereof. Preferred catalytic metals include platinum, palladium and rhodium. The catalyst may also contain a modifier such as niobium, titanium, or rare earth metals.
摘要翻译： 已经开发了用于开启脂肪族环烃的催化剂和方法。 催化剂包括催化金属组分，分子筛和耐火无机氧化物组分。 分子筛选自MAPSO，SAPO，UZM-8，UZM-8HS，UZM-15，UZM-15HS，UZM-16，UZM-16HS及其混合物。 优选的催化金属包括铂，钯和铑。 催化剂还可以含有诸如铌，钛或稀土金属的改性剂。
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43.发明授权Dual functional catalyst for selective opening of cyclic paraffins and process for using the catalyst 有权用于选择性打开环状链烷烃的双官能催化剂和使用催化剂的方法公开(公告)号：US07407907B2
公开(公告)日：2008-08-05
申请号：US11467189
申请日：2006-08-25
申请人： Leonid B. Galperin , Irina Galperin, legal representative , Michael J. McCall , Joseph A. Kocal
发明人： Leonid B. Galperin , Irina Galperin, legal representative , Michael J. McCall , Joseph A. Kocal
CPC分类号： B01J23/42 , B01J21/00 , B01J23/40 , B01J23/60 , B01J23/62 , B01J23/63 , B01J23/648 , B01J23/6484 , B01J23/656 , B01J23/6567 , B01J27/00 , B01J27/182 , B01J29/04 , B01J29/06 , B01J29/70 , B01J29/84 , B01J35/00 , B01J35/0006 , B01J37/00 , B01J37/0072 , C07C5/31 , C07C2529/85 , C07C9/00
摘要： A catalyst for selectively opening cyclic paraffins has been developed. The catalyst comprises a Group VIII metal, such as platinum, a modifier component, such as niobium or ytterbium, a molecular sieve, such as UZM-16 and a refractory inorganic oxide such as alumina. The Group VIII metal and modifier component are preferably deposited on the refractory inorganic oxide. A process for using the catalyst is also disclosed.
摘要翻译： 已经开发了用于选择性打开环状链烷烃的催化剂。 该催化剂包括Ⅷ族金属如铂，改性剂组分如铌或镱，分子筛如UZM-16和耐火无机氧化物如氧化铝。 优选将VIII族金属和改性剂组分沉积在耐火无机氧化物上。 还公开了使用催化剂的方法。
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公开(公告)号：US08742183B2
公开(公告)日：2014-06-03
申请号：US12238945
申请日：2008-09-26
CPC分类号： C10L1/04 , C10G45/02 , C10G45/12 , C10G45/58 , C10G45/64 , C10G47/00 , C10G47/16 , C10G65/043 , C10G65/12 , C10G2300/1011 , Y02P30/20
摘要： A process has been developed for producing aviation fuel from renewable feedstocks such as plant oils and animal fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide n-paraffins having from about 8 to about 24 carbon atoms. At least some of the n-paraffins are isomerized to improve cold flow properties. At least a portion of the paraffins are selectively cracked to provide paraffins meeting specifications for different aviation fuels such as JP-8.
摘要翻译： 已经开发了用于从可再生原料如植物油和动物脂肪和油生产航空燃料的方法。 该方法包括通过氢化和脱氧处理可再生原料以提供具有约8至约24个碳原子的正链烷烃。 至少一些正链烷烃被异构化以改善冷流特性。 选择性裂化至少一部分石蜡以提供符合不同航空燃料如JP-8的规格的石蜡。
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公开(公告)号：US20090158637A1
公开(公告)日：2009-06-25
申请号：US12238945
申请日：2008-09-26
CPC分类号： C10L1/04 , C10G45/02 , C10G45/12 , C10G45/58 , C10G45/64 , C10G47/00 , C10G47/16 , C10G65/043 , C10G65/12 , C10G2300/1011 , Y02P30/20
摘要： A process has been developed for producing aviation fuel from renewable feedstocks such as plant oils and animal fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide n-paraffins having from about 8 to about 24 carbon atoms. At least some of the n-paraffins are isomerized to improve cold flow properties. At least a portion of the paraffins are selectively cracked to provide paraffins meeting specifications for different aviation fuels such as JP-8.
摘要翻译： 已经开发了用于从可再生原料如植物油和动物脂肪和油生产航空燃料的方法。 该方法包括通过氢化和脱氧处理可再生原料以提供具有约8至约24个碳原子的正链烷烃。 至少一些正链烷烃被异构化以改善冷流特性。 选择性裂化至少一部分石蜡以提供符合不同航空燃料如JP-8的规格的石蜡。
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公开(公告)号：US5739074A
公开(公告)日：1998-04-14
申请号：US453044
申请日：1995-05-30
申请人： Joseph A. Kocal , Anil R. Oroskar
发明人： Joseph A. Kocal , Anil R. Oroskar
IPC分类号： B01J23/02 , B01J23/04 , B01J27/08 , C07C2/58 , B01J27/135
CPC分类号： B01J23/02 , B01J23/04 , B01J27/08 , C07C2/58 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2527/125 , C07C2527/126
摘要： A catalytic composite of a refractory inorganic oxide whose bound surface hydroxyl group has reacted with a Friedel-Crafts type metal halide and whose acidity has been modified by the deposition of a monovalent metal cation, especially an alkali metal cation, or alkaline earth metal cation shows superior selectivity and a significantly decreased cracking tendency relative to similar catalysts without the monovalent metal or alkaline earth metal cation. The resulting alkylate from an isobutane-butene feedstock shows a substantial increase in research octane number relative to the alkylate formed by a similar catalyst which has not been so modified by an alkali or alkaline earth metal cation.
摘要翻译： 结合表面羟基与Friedel-Crafts型金属卤化物反应并且酸性已经通过沉积一价金属阳离子，特别是碱金属阳离子或碱土金属阳离子而改性的耐火无机氧化物的催化复合物显示出 优异的选择性和相对于没有一价金属或碱土金属阳离子的类似催化剂显着降低的开裂趋势。 从异丁烷 - 丁烯原料得到的烷基化物相对于由未被碱金属或碱土金属阳离子改性的类似催化剂形成的烷基化物，研究辛烷值显着增加。
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47.发明授权Alkylation of aromatics using a metal cation-modified friedel-crafts type catalyst 失效使用金属阳离子改性的Friedel-Crafts型催化剂烷基化芳族化合物
公开(公告)号：US5672797A
公开(公告)日：1997-09-30
申请号：US533576
申请日：1995-09-25
申请人： Joseph A. Kocal
发明人： Joseph A. Kocal
IPC分类号： B01J23/02 , B01J23/04 , B01J27/08 , C07C2/66 , C07C2/68 , C07C2/86 , C07C29/44 , C07C41/30 , C07C2/70
CPC分类号： B01J27/08 , B01J23/02 , B01J23/04 , C07C2/66 , C07C2/68 , C07C2/861 , C07C2/864 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/26 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2527/125 , C07C2527/126
摘要： A process for the alkylation of aromatic compounds with an olefin, alcohol, or alkyl halide having from 1 to 24 carbon atoms comprising reacting in the liquid phase the aromatic and alkylating agent under alkylation conditions in the presence of a novel catalyst comprising: a) a refractory inorganic oxide, b) the reaction product of a first metal halide and bound surface hydroxyl groups of the refractory inorganic oxide, c) a second metal cation, and d) optionally a zerovalent third metal. The refractory inorganic oxide is selected from the group consisting of alumina, titania, zirconia, chromia, silica, boria, silica-alumina, and combinations thereof and the first metal halide is a fluoride, chloride, or bromide of aluminum. The second metal cation is selected from the group consisting of: monovalent metal cations in an amount from 0.0026 up to about 0.20 gram atoms per 100 grams refractory inorganic oxide for lithium, potassium, cerium, rubidium, silver, and copper, and from 0.009 to about 0.20 gram atoms for sodium; and alkaline earth metal cations in an mount from about 0.0013 up to about 0.01 gram atoms per 100 grams of refractory inorganic oxide for beryllium; strontium, and barium; and in an amount from about 0.004 up to about 0.1 gram atoms per 100 grams support for magnesium and calcium, or combinations thereof. The third metal is selected from the group consisting of platinum, palladium, nickel ruthenium, rhodium, osmium and iridium, and any combination thereof.
摘要翻译： 一种用烯烃，醇或具有1至24个碳原子的烷基卤烷基化芳族化合物的方法，包括在烷烃化条件下在液相中使芳族和烷基化剂在新催化剂存在下反应，包括：a） 耐火无机氧化物，b）第一金属卤化物和耐火无机氧化物的结合表面羟基的反应产物，c）第二金属阳离子，和d）任选的零价第三金属。 耐火无机氧化物选自氧化铝，二氧化钛，氧化锆，氧化铬，二氧化硅，氧化硼，二氧化硅 - 氧化铝及其组合，第一种金属卤化物是铝的氟化物，氯化物或溴化物。 第二金属阳离子选自：一价金属阳离子，其量为0.0026至约0.20克原子/ 100克锂，钾，铈，铷，银和铜的难熔无机氧化物，和0.009至 钠约0.20克原子; 和碱土金属阳离子的量为约0.0013至约0.01克原子/ 100克用于铍的耐火无机氧化物; 锶和钡; 并且其量为约0.004至约0.1克原子/ 100克镁和钙的载体或其组合。 第三种金属选自铂，钯，镍钌，铑，锇和铱，以及它们的任何组合。
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公开(公告)号：US5196574A
公开(公告)日：1993-03-23
申请号：US816341
申请日：1991-12-23
申请人： Joseph A. Kocal
发明人： Joseph A. Kocal
IPC分类号： C07C2/66 , C07C309/31
CPC分类号： C07C309/31 , C07C2/66 , C07C2521/12
摘要： A fluorided silca-alumina catalyst, particularly one with a silica:alumina ratio in the range of 1:1-9:1 containing from 1 to 6 weight percent fluoride, is particularly effective in the liquid phase alkylation of benzene to produce linear alkyl benzenes at temperatures no greater than 140.degree. C. Conversions in excess of 98% with selectivity exceeding 85% and linearity exceeding 90% may be achieved readily.
摘要翻译： 氟化硅铝氧化物催化剂，特别是含有1至1：1：1重量百分比氟化物的二氧化硅：氧化铝比为1：1-9：1的氟硅烷氧化铝催化剂在苯的液相烷基化中特别有效，生成直链烷基苯 在不大于140℃的温度下，可以容易地实现超过98％的转化率，选择性超过85％，线性超过90％。
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公开(公告)号：US5160032A
公开(公告)日：1992-11-03
申请号：US808136
申请日：1991-12-16
CPC分类号： C10G47/12 , B01J21/16 , B01J29/049 , C07C4/06 , B01J2229/42 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/16 , C07C2527/16
摘要： This invention relates to hydrocarbon conversion process using a catalyst consisting essentially of a layered clay homogeneously dispersed in an inorganic oxide matrix. The clay is dispersed in such a way that the clay layers are completely surrounded by the inorganic oxide matrix. The inorganic oxide is selected from the group consisting of alumina, titania, silica, zirconia, P.sub.2 O.sub.5 and mixtures thereof. The clay can be a natural clay such as montmorillonite, a metal exchanged clay (Fe.sup.+3 exchanged) or a pillared clay such as aluminum chlorohydrate (ACH) pillared clay. The hydrocarbon conversion process is carried out by contacting a hydrocarbon feed with the catalyst at hydrocarbon conversion conditions to give a hydroconverted product. Examples of the hydrocarbon conversion processes are alkylation and hydrocracking.
摘要翻译： 本发明涉及使用基本上由均匀分散在无机氧化物基质中的层状粘土组成的催化剂的烃转化方法。 粘土以这样的方式分散，即粘土层被无机氧化物基体完全包围。 无机氧化物选自氧化铝，二氧化钛，二氧化硅，氧化锆，P 2 O 5及其混合物。 粘土可以是天然粘土，例如蒙脱石，金属交换的粘土（Fe + 3交换的）或柱状粘土如水合氯化铝（ACH）柱状粘土。 烃转化过程是通过在烃转化条件下使烃进料与催化剂接触以得到加氢转化产物来进行的。 烃转化方法的实例是烷基化和加氢裂化。
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公开(公告)号：US4921946A
公开(公告)日：1990-05-01
申请号：US265729
申请日：1988-11-01
CPC分类号： B01J29/90 , B01J38/12 , C07C2/76 , C07C2529/40 , Y02P20/584
摘要： A hydrocarbon conversion process is disclosed which extends the useful life of a regenerable zeolite-containing hydrocarbon conversion catalyst. In one aspect of this process, a hydrocarbon feed containing fluorides is passed through a fluoride removal system which reduces the fluoride concentration of the feed to below 100 ppb. The hydrocarbon feed containing less than 100 ppb fluorine is then converted over a regenerable zeolite-containing hydrocarbon conversion catalyst. The zeolite-containing hydrocarbon conversion catalyst is regenerated with an oxygen-containing gas stream as necessary to burn off carbonaceous deposits on the catalyst so as to return the zeolite catalyst to a high level of activity.
摘要翻译： 公开了一种延长可再生沸石烃转化催化剂的使用寿命的烃转化方法。 在该方法的一个方面，含氟化物的烃进料通过氟化物去除系统，其将进料的氟化物浓度降低至低于100ppb。 然后将含有少于100ppb氟的烃原料转化为可再生的含沸石的烃转化催化剂。 含有沸石的烃转化催化剂根据需要用含氧气体气流再生，以将催化剂上的碳质沉积物烧掉，使沸石催化剂回复到高水平的活性。
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