Polymerization process to make low density polyethylene
    47.
    发明授权
    Polymerization process to make low density polyethylene 有权
    聚合过程制备低密度聚乙烯

    公开(公告)号:US09534064B2

    公开(公告)日:2017-01-03

    申请号:US14980701

    申请日:2015-12-28

    Abstract: A high pressure polymerization process to form an ethylene-based polymer comprises the steps of: A. Injecting a first feed comprising a chain transfer agent system (CTA system) and ethylene into a first autoclave reactor zone operating at polymerization conditions to produce a first zone reaction product, the CTA system of the first reactor zone having a transfer activity Z1; and B. (1) Transferring at least part of the first zone reaction product to a second reactor zone selected from a second autoclave reactor zone or a tubular reactor zone and operating at polymerization conditions, and, optionally, (2) freshly injecting, a second feed into the second reactor zone to produce a second zone reaction product, with the proviso that at least one of the first reactor zone product and the freshly injected feed comprises a CTA system with a transfer activity of Z2; and with the proviso that the ratio of Z1:Z2 is greater than 1.

    Abstract translation: 形成乙烯基聚合物的高压聚合方法包括以下步骤:A.将包含链转移剂体系(CTA体系)和乙烯的第一种进料注入到在聚合条件下操作的第一高压釜反应器区域中以产生第一区 反应产物,具有转移活性Z1的第一反应器区域的CTA体系; (1)将至少部分第一区反应产物转移到选自第二高压釜反应器区或管式反应器区并在聚合条件下操作的第二反应器区,以及任选地(2)新鲜地注入, 第二进料到第二反应器区以产生第二区反应产物,条件是第一反应器区产物和新注入的进料中的至少一个包含具有Z 2的转移活性的CTA体系; 并且条件是Z1:Z2的比率大于1。

    ADHESIVE FORMULATIONS FOR CARPETS
    49.
    发明申请
    ADHESIVE FORMULATIONS FOR CARPETS 审中-公开
    地毯的粘合剂

    公开(公告)号:US20160298003A1

    公开(公告)日:2016-10-13

    申请号:US14290991

    申请日:2014-05-30

    Abstract: The invention is a formulation for use in the manufacture of carpets. The formulation is combined with polymers such as, but not limited to, ethylene vinyl acetate (EVA, a co-polymer) to provide carpet backing formulations which exhibit excellent tensile strength. The formulation of the invention can be provided to carpet manufacturers as a separate product to be added later to a polymer for a use in carpet backings. Alternatively, the formulation can be added to a polymer such as EVA or compositions comprising EVA and then applied to a carpet backing to provide a carpet with a carpet backing exhibiting excellent tensile strength.

    Abstract translation: 本发明是用于制造地毯的制剂。 该制剂与聚合物(例如但不限于乙烯醋酸乙烯酯(EVA,共聚物))结合,以提供表现出优异拉伸强度的地毯背衬制剂。 本发明的制剂可以作为单独的产品提供给地毯制造商,以便稍后添加到聚合物中以用于地毯背衬中。 或者,可以将制剂加入聚合物如EVA或包含EVA的组合物中,然后施加到地毯背衬上,以提供具有优异拉伸强度的地毯背衬的地毯。

    FLOOR COVERING ADHESIVE COMPOSITION COMPRISING A VINYL ACETATE-ETHYLENE COPOLYMER
    50.
    发明申请
    FLOOR COVERING ADHESIVE COMPOSITION COMPRISING A VINYL ACETATE-ETHYLENE COPOLYMER 有权
    乙烯乙酸乙烯酯共聚物的地板覆盖胶粘剂组合物

    公开(公告)号:US20160289512A1

    公开(公告)日:2016-10-06

    申请号:US15035875

    申请日:2014-10-28

    Abstract: The invention relates to a floor covering adhesive composition, based on an aqueous, emulsifier-stabilized polymer dispersion of vinyl acetate-ethylene copolymer, containing A) tackifying resin, B) one or more fillers, and C) a vinyl acetate-ethylene copolymer in the form of an emulsifier-stabilized aqueous dispersion, characterized in that the vinyl acetate-ethylene copolymer is obtained by radical-initiated emulsion polymerization in an aqueous medium, of a) 60 to 89.9% by weight of vinyl acetate, b) 10 to 36% by weight of ethylene, c) 0 to 2% by weight of one or more monomers selected from the group of vinyl esters of carboxylic acids having 8 to 12 C atoms and acrylic acid alkyl esters having a C to C8 alkyl radical, d) 0.1 to 5% by weight of one or more ethylenically unsaturated auxiliary monomers having a carboxylic acid group, amide group, nitrile group or sulfonic acid (salt) group, wherein the percentages stated in % by weight are each in relation to the total weight of the comonomers and add up to 100% by weight, and the polymerization is carried out in the presence of one or more emulsifiers.

    Abstract translation: 本发明涉及一种基于乙酸乙烯酯 - 乙烯共聚物的水性乳化剂稳定的聚合物分散体的地板覆盖粘合剂组合物,其包含A)增粘树脂,B)一种或多种填料,和C)乙酸乙烯酯 - 乙烯共聚物 乳化剂稳定的水分散体的形式,其特征在于乙酸乙烯酯 - 乙烯共聚物通过在水性介质中自由基引发的乳液聚合获得,a)60至89.9重量%的乙酸乙烯酯,b)10至36 重量百分比的乙烯,c)0至2重量%的一种或多种选自具有8至12个碳原子的羧酸的乙烯基酯和具有C 8至C 8烷基的丙烯酸烷基酯的单体,d) 0.1至5重量%的具有羧酸基,酰胺基,腈基或磺酸(盐)基团的一种或多种烯键式不饱和辅助单体,其中以重量%计的百分比各自相对于 公司 单体并加入至100重量%,聚合在一种或多种乳化剂存在下进行。

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