摘要:
Polytetrahydrofuran, tetrahydrofuran copolymers, diesters or monoesters of these polymers are prepared by polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer on a heterogeneous carrier catalyst which contains on an oxidic carrier material as active mass a catalytically active amount of at least one oxygenous molybdenum and/or tungsten compound and, when the precursor compounds of the active mass have been applied to the carrier material precursor, has been calcined at temperatures of between 500° C. and 1000° C. The catalyst used contains a promotor which comprises at least one element or a compound of an element of the 2nd, 3rd including the lanthanides, 5th, 6th, 7th, 8th or 14th group of the periodic system of elements.
摘要:
The new arylacetamides are obtained by first converting appropriately substituted arylacetic acids into the acetyl chlorides and then converting these into the amides using the appropriate amines. The new arylacetamides can be used as active compounds in medicaments, in particular in antiatherosclerotic medicaments.
摘要:
The present invention relates to a process for the preparation of a zeolitic material having a structure comprising YO2 and optionally comprising X2O3, preferably comprising YO2 and X2O3, wherein said process comprises the steps of (1) providing a mixture comprising one or more ammonium compounds of which the ammonium cation has the formula (I): [R1R2NR3R4]+ (I) and further comprising one or more sources for YO2 and one or more sources for X2O3; (2) crystallizing the mixture provided in (1); wherein Y is a tetravalent element, and X is a trivalent element, and wherein in formula (I) R1 and R2 are independently from one another derivatized or underivatized methyl, and R3 and R4 are independently from one another derivatized or underivatized (C3-C5)alkyl, and wherein the molar ratio of ammonium cation having the formula (I) to Y in the mixture provided in step (1) and crystallized in step (2) is equal to or greater than 0.25.
摘要:
A process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X203, wherein said process comprises preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, and wherein the crystallized mixture contains 0.1 wt.-% or less, more preferably 0.01 wt.-% or less of one or more metals M based on 100 wt.-% of YO2, wherein even more preferably the crystallized mixture contains no metal M, wherein M stands for sodium and/or potassium, wherein preferably M stands for the group of alkali and alkaline earth metals.
摘要翻译:一种制备具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的方法,其中所述方法包括制备包含一种或多种YO 2,一种或多种溶剂和任选地包含晶种的源的混合物; 并使混合物结晶; 其中Y是四价元素,X是三价元素,并且其中所述结晶混合物含有基于100重量%的0.1重量%或更少,更优选0.01重量%或更少的一种或多种金属M, 的YO 2,其中甚至更优选结晶的混合物不含金属M,其中M代表钠和/或钾,其中优选M代表碱金属和碱土金属。
摘要:
The present invention relates to a process for the preparation of a zeolitic material having a CHA framework structure, said zeolitic material comprising zeolite crystals having a core-shell structure, wherein said process comprises the steps of (1) providing a mixture comprising one or more sources for Z2O5, one or more sources for X2O3, optionally one or more structure directing agents, and seed crystals having a CHA framework structure, wherein the CHA framework structure of the seed crystals comprises YO2, X2O3, and optionally Z2O5, and wherein the seed crystals have a diameter of 450 nm or greater; (2) crystallizing the mixture provided in (1) to afford zeolite crystals comprising a core of seed crystal provided in step (1) and a shell crystallized on the seed crystal; wherein Z is a pentavalent element, Y is a tetravalent element, and X is a trivalent element.
摘要翻译:本发明涉及一种制备具有CHA骨架结构的沸石材料的方法,所述沸石材料包含具有核 - 壳结构的沸石晶体,其中所述方法包括以下步骤:(1)提供包含一种或多种 Z 2 O 5的源,X 2 O 3,任选的一种或多种结构导向剂的一种或多种来源,以及具有CHA骨架结构的晶种,其中晶种的CHA骨架结构包含YO 2,X 2 O 3和任选的Z 2 O 5,并且其中所述种子 晶体的直径为450nm以上; (2)使(1)中提供的混合物结晶,得到包含步骤(1)中提供的晶种核心的沸石晶体和在晶种上结晶的壳; 其中Z为五价元素,Y为四价元素,X为三价元素。
摘要:
An image detection system having a camera unit for detecting images of the outside area of a motor vehicle, and a protection element that can be moved from a closed position to an open position by a mechanism through a drive. At least one lens of the camera unit is located behind the protection element inaccessible from the outside when the protection element is located in the closed position. At least the lens is released by the protection element for image detection in the open position. At least the camera unit with the mechanism and the protection element is disposed in a first module and the drive is provided in a second module separate from the first module. The first and second modules are mechanically connected to one another by at least one actuation element so that the drive drives the mechanism by way of the actuation element.
摘要:
Aspects of the present invention relates to a copper containing Levyne molecular sieve having a silica to alumina mole ratio less than 30 and a Cu:Al atomic ratio less than 0.45, wherein the Levyne molecular sieve retains at least 60% of its surface area after exposure to a temperature of from about 750° C. to about 950° C. in the present of up to 10 volume percent water vapor for a time ranging from about 1 to about 48 hours.
摘要:
The present invention relates to a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YO2 and optionally comprises X2O3, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.
摘要翻译:本发明涉及一种有机化合物的烷基化方法,包括:(a)提供包含一种或多种具有BEA骨架结构的沸石材料的催化剂,其中所述BEA骨架结构包含YO 2并且任选地包含X 2 O 3,其中Y是 四价元素,X是三价元素,(b)在一个或多个烷基化剂存在下,在一个或多个烷基化剂存在下使催化剂与一种或多种可烷基化的有机化合物接触,以获得一种或多种烷基化有机化合物,其中所述一种或多种烷基化有机化合物, 更多的沸石材料可以从不使用有机模板作为结构导向剂的合成方法获得。
摘要:
Described is a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is a zinc ion and the at least one at least bidentate organic compound is based on 2-methylimidazole, which comprises the steps (a) addition of a first water-based solution comprising zinc ions to a second water-based solution comprising 2-methylimidazole, with a suspension being formed after addition of the second solution; (b) addition of a third solution comprising a strong base to the suspension formed in step (a).
摘要:
A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile: water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene: propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile: water in L2 is less than 1; (iv) separating L1 from L2.