公开(公告)号：US09434709B2

公开(公告)日：2016-09-06

申请号：US14854780

申请日：2015-09-15

Applicant: Rennovia Inc.

Inventor： Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

IPC: C07C51/36 ,  C07C51/31 ,  C07D309/30 ,  B01J23/40 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/652 ,  B01J23/656 ,  B01J23/89 ,  B01J35/00 ,  B01J37/02 ,  C07C51/235 ,  C07C51/377 ,  C07C51/41 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  C07C201/08 ,  B01J21/06 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/8926 ,  B01J35/006 ,  B01J37/0205 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/31 ,  C07C51/412 ,  C07C201/08 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

公开(公告)号：US20160200677A1

公开(公告)日：2016-07-14

申请号：US14963114

申请日：2015-12-08

Applicant: Genomatica, Inc.

Inventor： Rudolf Philippus Maria GUIT ,  Thomas VAN DER DOES ,  Lourina Madeleine RAAMSDONK

IPC: C07D201/08 ,  C07D201/16 ,  C08G69/16

CPC classification number: C07D201/08 ,  C07D201/16 ,  C07D223/10 ,  C08G69/16

Abstract: The invention relates to a method for preparing caprolactam comprising recovering a mixture containing 6-aminocaproic acid, from a culture medium comprising biomass, and thereafter cyclising the 6-aminocaproic acid in the presence of superheated steam, thereby forming caprolactam, wherein the weight to weight ratio carbohydrate to 6-aminocaproic acid in said mixture is 0.03 or less.

公开(公告)号：US20160075676A1

公开(公告)日：2016-03-17

申请号：US14854780

申请日：2015-09-15

Applicant: Rennovia Inc.

Inventor： Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

IPC: C07D309/30 ,  C07C51/377 ,  C07C51/235

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/8926 ,  B01J35/006 ,  B01J37/0205 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/31 ,  C07C51/412 ,  C07C201/08 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

Abstract translation: 本发明一般涉及将葡萄糖源化学转化为己二酸产物的方法。 本发明包括通过葡糖二酸或其衍生物将葡萄糖转化成己二酸产物的方法。 本发明还包括将葡萄糖催化氧化成葡糖二酸或其衍生物的方法和包括将葡糖二酸或其衍生物催化加氢脱氧至己二酸产物的方法。 本发明还包括由己二酸产物生产的产品和由己二酸产物生产的产品。

公开(公告)号：US09115080B2

公开(公告)日：2015-08-25

申请号：US13701622

申请日：2011-06-10

Applicant: Olan S. Fruchey ,  Leo E. Manzer ,  Dilum Dunuwila ,  Brian T. Keen ,  Brooke A. Albin ,  Nye A. Clinton ,  Bernard D. Dombek

Inventor： Olan S. Fruchey ,  Leo E. Manzer ,  Dilum Dunuwila ,  Brian T. Keen ,  Brooke A. Albin ,  Nye A. Clinton ,  Bernard D. Dombek

IPC: C07D223/10 ,  C12P7/44 ,  C12P17/10 ,  C07D201/08

CPC classification number: C07D201/08 ,  C07D223/10 ,  C12P7/44 ,  C12P17/10

Abstract: Processes for producing caprolactam (CL) and derivatives thereof from adipic acid (AA) obtained from fermentation broths containing diammonium adipate (DAA) or monoammonium adipate (MAA).

Abstract translation: 从含有己二酸二铵（DAA）或己二酸单铵（MAA）的发酵液获得的己二酸（AA）制备己内酰胺（CL）及其衍生物的方法。

公开(公告)号：US09023255B2

公开(公告)日：2015-05-05

申请号：US13915106

申请日：2013-06-11

Applicant: UOP LLC

Inventor： Jeffery C. Bricker ,  John Q. Chen ,  Peter K. Coughlin ,  Debarshi Majumder

IPC: C09B63/00 ,  C07D213/12 ,  C07C253/18 ,  C07D207/06 ,  C07D201/08 ,  C01B3/26 ,  C01B3/02 ,  C01B3/36

CPC classification number: C07D213/12 ,  C01B3/025 ,  C01B3/26 ,  C01B3/36 ,  C01B2203/025 ,  C01B2203/04 ,  C01B2203/048 ,  C01B2203/068 ,  C07C253/18 ,  C07D201/08 ,  C07D207/06 ,  C07C255/03

Abstract: Methods and systems are provided for converting methane in a feed stream to acetylene. The hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to nitrogen based hydrocarbon compounds such as pyridines. The method includes the reaction of acetylene with ammonia and controlling the ratio of acetylene to ammonia to generate the desired nitrogen based hydrocarbon compound.

Abstract translation: 提供了将进料流中的甲烷转化为乙炔的方法和系统。 将烃流引入超音速反应器中并热解以将至少一部分甲烷转化为乙炔。 可以处理反应器流出物流以将乙炔转化为氮基烃化合物，例如吡啶。 该方法包括乙炔与氨反应并控制乙炔与氨的比例，产生所需的氮基烃化合物。

公开(公告)号：US08669397B2

公开(公告)日：2014-03-11

申请号：US12814188

申请日：2010-06-11

Applicant: Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

Inventor： Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

IPC: C07C51/36

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/8926 ,  B01J35/006 ,  B01J37/0205 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/31 ,  C07C51/412 ,  C07C201/08 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

Abstract translation: 本发明一般涉及将葡萄糖源化学转化为己二酸产物的方法。 本发明包括通过葡糖二酸或其衍生物将葡萄糖转化成己二酸产物的方法。 本发明还包括将葡萄糖催化氧化成葡糖二酸或其衍生物的方法和包括将葡糖二酸或其衍生物催化加氢脱氧至己二酸产物的方法。 本发明还包括由己二酸产物生产的产品和由己二酸产物生产的产品。

公开(公告)号：US20130131306A1

公开(公告)日：2013-05-23

申请号：US13701622

申请日：2011-06-10

Applicant: Olan S. Fruchey ,  Leo E. Manzer ,  Dilum Dunuwila ,  Brian T. Keen ,  Brooke A. Albin ,  Nye A. Clinton ,  Bernard D. Dombek

Inventor： Olan S. Fruchey ,  Leo E. Manzer ,  Dilum Dunuwila ,  Brian T. Keen ,  Brooke A. Albin ,  Nye A. Clinton ,  Bernard D. Dombek

IPC: C07D201/08

CPC classification number: C07D201/08 ,  C07D223/10 ,  C12P7/44 ,  C12P17/10

Abstract: Processes for producing caprolactam (CL) and derivatives thereof from adipic acid (AA) obtained from fermentation broths containing diammonium adipate (DAA) or monoammonium adipate (MAA).

Abstract translation: 从含有己二酸二铵（DAA）或己二酸单铵（MAA）的发酵液获得的己二酸（AA）制备己内酰胺（CL）及其衍生物的方法。

公开(公告)号：US20120095212A1

公开(公告)日：2012-04-19

申请号：US13260268

申请日：2010-04-27

Applicant: Philippe Leconte

Inventor： Philippe Leconte

IPC: C07D223/10

CPC classification number: C07D201/08 ,  C07D223/10

Abstract: A method for preparing lactams by cyclizing hydrolysis of a corresponding aminonitrile is described. A method for manufacturing a lactam by reacting an aminonitrile with water in the presence of a catalyst involving placing the water and the aminonitrile in contact in vapor phase, passing the mixture of vapors through a bed of catalyst arranged in at least one tube forming a reaction chamber and recovering the lactam at the outlet of the tube is also described.

Abstract translation: 描述了通过环化相应的氨基腈的水解制备内酰胺的方法。 一种在催化剂存在下使氨基腈与水反应的方法，所述催化剂涉及使水和氨基腈气相接触，使蒸汽混合物通过排列在形成反应的至少一个管中的催化剂床 还描述了在管的出口处回收内酰胺的腔室。

公开(公告)号：US20110306790A1

公开(公告)日：2011-12-15

申请号：US12966702

申请日：2010-12-13

Applicant: Vincent J. Murphy ,  James Shoemaker ,  Guang Zhu ,  Raymond Archer ,  George Frederick Salem ,  Eric L. Dias

Inventor： Vincent J. Murphy ,  James Shoemaker ,  Guang Zhu ,  Raymond Archer ,  George Frederick Salem ,  Eric L. Dias

IPC: B01J23/52 ,  B01J21/08 ,  B01J29/04 ,  B01J21/18 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  C07C51/235 ,  B01J23/652 ,  B01J21/06 ,  B01J21/16 ,  B82Y30/00

CPC classification number: B01J23/52 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/42 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J37/0211 ,  B01J37/0236 ,  B01J37/0248 ,  B01J37/18 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C59/285 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts.

Abstract translation: 公开了由铂和金组成的催化剂。 催化剂通常可用于选择性氧化由伯醇基团和至少一个仲醇基团组成的组合物，其中至少伯醇基团转化为羧基。 更具体地说，催化剂是负载催化剂，包括包含金的颗粒和包含铂的颗粒，其中铂与金的摩尔比在约100:1至约1:4的范围内，铂基本上以Pt（0）的形式存在， 并且含铂颗粒的尺寸在约2至约50nm的范围内。 还公开了将碳水化合物转化为羧酸或其衍生物的氧化化学催化转化的方法。 此外，公开了使用包含铂和金的催化剂将葡萄糖选择性氧化成葡糖二酸或其衍生物的方法。 此外，公开了用于生产这种催化剂的方法。

公开(公告)号：US20100317823A1

公开(公告)日：2010-12-16

申请号：US12814188

申请日：2010-06-11

Applicant: Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

Inventor： Thomas R. Boussie ,  Eric L. Dias ,  Zachary M. Fresco ,  Vincent J. Murphy ,  James Shoemaker ,  Raymond Archer ,  Hong Jiang

IPC: C07C51/377 ,  C07C51/235 ,  C07C253/00 ,  C07C255/04 ,  C07C209/48 ,  C07D201/08 ,  C07C29/147 ,  C07D223/10 ,  C07D309/30 ,  C07C55/14 ,  C08G69/26 ,  C08G69/28 ,  C08G69/14 ,  C08G69/16 ,  C08G63/16

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/6525 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/8926 ,  B01J35/006 ,  B01J37/0205 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/31 ,  C07C51/412 ,  C07C201/08 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: The present invention generally relates to processes for the chemocatalytic conversion of a glucose source to an adipic acid product. The present invention includes processes for the conversion of glucose to an adipic acid product via glucaric acid or derivatives thereof. The present invention also includes processes comprising catalytic oxidation of glucose to glucaric acid or derivative thereof and processes comprising the catalytic hydrodeoxygenation of glucaric acid or derivatives thereof to an adipic acid product. The present invention also includes products produced from adipic acid product and processes for the production thereof from such adipic acid product.

Abstract translation: 本发明一般涉及将葡萄糖源化学转化为己二酸产物的方法。 本发明包括通过葡糖二酸或其衍生物将葡萄糖转化成己二酸产物的方法。 本发明还包括将葡萄糖催化氧化成葡糖二酸或其衍生物的方法和包括将葡糖二酸或其衍生物催化加氢脱氧至己二酸产物的方法。 本发明还包括由己二酸产物生产的产品和由己二酸产物生产的产品。