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    Antistatic fiber containing chain-extended tetrols based on diamines
    62.
    发明授权
    Antistatic fiber containing chain-extended tetrols based on diamines 失效
    基于二胺的含有链延长四氢呋喃的抗静电纤维

    公开(公告)号：US3887638A

    公开(公告)日：1975-06-03

    申请号：US49442174

    申请日：1974-08-05

    申请人： ALLIED CHEM

    发明人： CRESCENTINI LAMBERTO ,  WELLS RODNEY LEE

    IPC分类号： C08K5/134 ,  C08L77/00 ,  C08G41/04

    CPC分类号： C08K5/1345 ,  C08L77/00 ,  Y10S260/17 ,  Y10S260/21 ,  Y10S524/913 ,  C08L2666/20

    摘要： It has been suggested that antistatic properties of fibers of polyamide could be improved by dispersing in the polyamide a small proportion of a reaction product of a tetrol compound represented by the formula:

    WHERE A, B, C, D, E, F, G, AND H ARE EACH A WHOLE NUMBER AND A is a difunctional radical from a hydrocarbon containing 1 to 13 carbon atoms, said tetrol compound having a molecular weight between about 4,000 and about 50,000, and at least one compound selected from the group consisting of diepoxides and compounds which yield the following divalent radicals:

    WHERE A'' is a difunctional radical from a hydrocarbon containing 1 to 30 carbon atoms. However, with incorporation of this antistatic additive in the polyamide, serious problems have been encountered in meltspinning due to the frequent occurrence of ''''nubs'''' or enlarged places in the extruded polyamide filament. It has now been found that the occurrence of said nubs in the antistatic polyamide fiber can be greatly reduced by dispersing in the polymer an additional small proportion of a hindered phenol represented by the formulae:

    IN WHICH X HAS A VALUE OF FROM 1 TO 6 AND Y HAS A VALUE OF FROM 6 TO 30; AND

    IN WHICH R is

    WHEREIN X'' HAS A VALUE FROM 1 TO 6 AND Y'' HAS A VALUE OF 1 TO 6. When the term ''''alkyl'''' is qualified by the designation ''''(lower),'''' there is intended a branched or straight chain hydrocarbon of from 1 to about 6 carbon atoms. Preferably, the phenol compound is used with at least 0.1% by weight, based on the weight of the antistatic additive, of a sulfur compound of the formula:

    WHEREIN R'''' is an alkyl radical containing 8 to 18 carbon atoms and n is 1 to 3.

    摘要翻译： 已经提出通过在聚酰胺中分散一小部分由下式表示的四元醇化合物的反应产物可以提高聚酰胺纤维的抗静电性能：

    Antistatic polyethylene compositions
    67.
    发明授权
    Antistatic polyethylene compositions 失效
    抗静电聚乙烯组合物

    公开(公告)号：US3365437A

    公开(公告)日：1968-01-23

    申请号：US47557865

    申请日：1965-07-28

    申请人： HERCULES INC

    发明人： MARRA JOSEPH V ,  SPURLIN HAROLD M

    IPC分类号： C08K3/00 ,  C08K5/098 ,  C08K5/20 ,  C08K5/21

    CPC分类号： C08K5/20 ,  C08K3/10 ,  C08K3/105 ,  C08K5/098 ,  C08K5/21 ,  Y10S260/19 ,  Y10S524/913 ,  C08L23/02

    摘要： An antistatic polyolefin composition comprises a polyolefin mixed with a N,N-bis-(hydroxyalkyl) fatty acid amide and an ionic salt of a monovalent metal. The preferred amides are of the formula where n is 7 to 17 and R and R1 are alkylene radicals of 1 to 4 carbon atoms. The amide and salt are preferably present in amount of 0.1 to 1.0% by weight of the polymer, the preferred weight ratio of amide to salt being from 1:1 to 10:1. The preferred monovalent metal is an alkali metal, e.g. lithium, potassium and sodium the preferred salts being halides, thiocyanates, nitrates, nitrites, phosphates, organosulphonates and carboxylates of up to 18 carbon atoms. In the examples, N,N-bis-(hydroxyethl) lauramide, N,N - bis - (hydroxyethyl) stearamide and N,N - bis - (hydroxyethyl) caprylamide are employed. The salts used in the examples are sodium acetate, sodium butyrate, sodium caprylate, sodium laurate, sodium stearate, lithium acetate, potassium thiocyanate, sodium nitrite, potassium toluene sulphonate, sodium methane sulphonate, sodium nitrate, sodium dibutyl phosphate and potassium bromide. Polymers used in the examples are polyethylene, polypropylene and a copolymer of propylene and ethylene.

    摘要翻译： 抗静电聚烯烃组合物包含与N，N-双 - （羟基烷基）脂肪酸酰胺和一价金属的离子盐混合的聚烯烃。 优选的酰胺具有式，其中n为7至17，R和R 1为具有1至4个碳原子的亚烷基。 酰胺和盐的含量优选为聚合物重量的0.1至1.0％，酰胺与盐的优选重量比为1:1至10:1。 优选的一价金属是碱金属，例如。 锂，钾和钠是卤化物的优选盐，至少18个碳原子的硫氰酸盐，硝酸盐，亚硝酸盐，磷酸盐，有机磺酸盐和羧酸盐。 在实施例中，使用N，N-双 - （羟基乙基）月桂酰胺，N，N-双 - （羟乙基）硬脂酰胺和N，N-二 - （羟乙基）辛酰胺。 实施例中使用的盐是乙酸钠，丁酸钠，辛酸钠，月桂酸钠，硬脂酸钠，乙酸锂，硫氰酸钾，亚硝酸钠，甲苯磺酸钾，甲磺酸钠，硝酸钠，磷酸二氢钠和溴化钾。 实施例中使用的聚合物是聚乙烯，聚丙烯和丙烯与乙烯的共聚物。