Process for air enrichment in producing hydrogen for use with fuel cells
    71.
    发明申请
    Process for air enrichment in producing hydrogen for use with fuel cells 审中-公开
    生产用于燃料电池的氢的空气富集方法

    公开(公告)号:US20020142198A1

    公开(公告)日:2002-10-03

    申请号:US09733362

    申请日:2000-12-08

    IPC分类号: H01M008/06

    摘要: Hydrogen generation and fuel cell operation are integrated through the use of a fuel processor or hydrogen generation zone which comprises a pre-reforming zone, a partial oxidation zone, a reforming zone, a water gas shift zone and a preferential oxidation zone. According to the present invention, an oxygen-enriched stream is provided to the fuel processor and to the fuel cell from the adsorption effluent withdrawn from an adsorption zone. The oxygen-enriched stream is depleted in nitrogen which improved the efficiency of the fuel processor and the fuel cell by reducing nitrogen dilution. A further advantage resulted in fuel processor/fuel cell systems which burn the anode waste gas in a combustion zone to provide heat to the fuel processor zone. By diluting the anode waste gas with an oxygen-reduced gas, it is possible to maintain the combustion temperature in the convection range and reduce or eliminate the amount of excess air employed in the combustion zone

    摘要翻译: 通过使用包括预重整区,部分氧化区,重整区,水煤气换挡区和优先氧化区的燃料处理器或氢生成区来集成氢发生和燃料电池操作。 根据本发明,从吸附区抽出的吸附流出物向燃料处理器和燃料电池提供富氧流。 富氧流在氮中耗尽,通过减少氮稀释来提高燃料处理器和燃料电池的效率。 另一个优点是燃料处理器/燃料电池系统在燃烧区燃烧阳极废气以向燃料处理器区域提供热量。 通过用氧还原气体稀释阳极废气,可以将燃烧温度保持在对流范围内并减少或消除在燃烧区中使用的过量空气的量

    System and method for preparing a synthesis gas stream and converting hydrocarbons
    73.
    发明申请
    System and method for preparing a synthesis gas stream and converting hydrocarbons 审中-公开
    用于制备合成气流和转化烃的系统和方法

    公开(公告)号:US20010051662A1

    公开(公告)日:2001-12-13

    申请号:US09782102

    申请日:2001-02-12

    IPC分类号: C07C027/06

    摘要: A system and method of operating a pre-reformer in a gas-to-liquids plant at minimum steam/carbon levels in order to reduce the C2null content is provided that allows for the efficient production of synthesis gas to be used in producing liquid hydrocarbons preferably through a Fischer-Tropsch synthesis. The process and system involves providing steam, natural gas having greater than 3 percent C2null, and possibly hydrogen to a pre-reformer and converting a significant amount of the C2null to methane and CO2 and then using a synthesis gas generator to prepare a synthesis gas feedstock with about a 2:1 H2:CO ratio and without undue soot formation. The synthesis gas is used in a Fischer-Tropsch synthesis unit to convert the synthesis gas to the heavier hydrocarbons. Water, light hydrocarbons, and portions of the tail gas may be recycled in different embodiments.

    摘要翻译: 提供了以最小蒸汽/碳水平操作气体 - 液体设备中的预重整器以减少C2 +含量的系统和方法,其允许有效地生产用于生产液体烃的合成气 通过费 - 托合成。 该方法和系统包括向预重整器提供具有大于3%的C2 +的蒸气,天然气和可能的氢气,并将大量的C2 +转化成甲烷和CO 2,然后使用合成气发生器来制备合成气原料 具有约2:1的H 2 :CO比例,并且没有不适当的烟灰形成。 合成气在费 - 托合成装置中用于将合成气转化为较重的烃。 水,轻烃和尾气的一部分可以在不同的实施方案中再循环。

    Process for the production of synthesis gas
    75.
    发明授权
    Process for the production of synthesis gas 有权
    合成气生产工艺

    公开(公告)号:US06207078B1

    公开(公告)日:2001-03-27

    申请号:US09428658

    申请日:1999-09-24

    申请人: Marco Badano

    发明人: Marco Badano

    IPC分类号: C07C102

    摘要: A process for the production of synthesis gas for obtaining compounds such as ammonia or methanol, in which hydrocarbons and steam are reacted first in a primary reforming section (11) and then—together with oxygen—in a secondary reforming section (12), thus obtaining CO, CO2, H2 and possibly N2 which are then fed to a carbon monoxide conversion section (13, 14), is distinguished by the fact of reacting hydrocarbons, steam and oxygen in an autothermal reforming section (20) provided in parallel with respect to other reforming sections (11, 12), and feeding the so produced CO, CO2, H2 and possibly N2 to the carbon monoxide conversion section (13, 14).

    摘要翻译: 制备用于获得诸如氨或甲醇的化合物的合成气的方法,其中烃和蒸汽首先在初级重整段(11)中反应,然后与二次重整段(12)中的氧反应,因此 获得CO,CO 2,H 2和可能的N 2,然后将其进料到一氧化碳转化部分(13,14),其特征在于在与热交换重整部分(20)中平行地提供的烃,蒸汽和氧气的反应 与其他重整段(11,12)反应,并将如此产生的CO,CO 2,H 2和可能的N 2进料到一氧化碳转化段(13,14)。

    Process for the ammonia and methanol co-production
    77.
    发明授权
    Process for the ammonia and methanol co-production 失效
    氨和甲醇联合生产工艺

    公开(公告)号:US6106793A

    公开(公告)日:2000-08-22

    申请号:US983496

    申请日:1997-12-29

    摘要: A process for ammonia and methanol co-production in a plant comprising a first primary reforming section (11) and a secondary reforming section (12) arranged in series, an ammonia synthesis section (13) and a methanol synthesis section (22), is distinguished by the fact that ammonia and methanol are produced in independent synthesis processes where the heat required for the reforming reaction in the methanol process is advantageously obtained by utilizing the high heat content present in the gas flow coming from the secondary reforming section (12) of the ammonia process.

    摘要翻译: PCT No.PCT / IB96 / 01248 Sec。 371 1997年12月29日第 102(e)1997年12月29日PCT PCT 1996年11月19日PCT公布。 出版物WO97 / 19018 日期:1997年5月29日一种在植物中氨和甲醇共同生产的方法,其包括串联排列的第一初级重整段(11)和二级转化段(12),氨合成段(13)和甲醇合成段 22)的区别在于,在独立的合成方法中生产氨和甲醇,其中通过利用来自二次转化段的气流中存在的高热含量有利地获得甲醇工艺中的重整反应所需的热量 (12)的氨法。

    Reactor for the autothermal conversion of hydrocarbons
    78.
    发明授权
    Reactor for the autothermal conversion of hydrocarbons 失效
    碳氢化合物自热转化反应器

    公开(公告)号:US5934897A

    公开(公告)日:1999-08-10

    申请号:US963338

    申请日:1997-11-03

    申请人: Hermann Gohna

    发明人: Hermann Gohna

    摘要: A reactor comprises at least one burner, to which hydrocar-bonaceous gas and gas rich in 0.sub.2 are supplied. The hydrocar-bonaceous gas is supplied to the burner through a transfer line at temperatures of 100 to 1300.degree. C. and a pressure in the range from 10 to 70 bar. Adjacent the orifice end of the transfer line, which is connected with the burner, there is provided a screen-like perforated wall through which the hy-drocarbonaceous gas can flow. This wall ensures a uniform gas flow in the burner, and at the same time it prevents solid matter from a certain size onwards from penetrating into the sensitive portion of the burner and settling there.

    摘要翻译: 一个反应器包括至少一个燃烧器,供给富含O 2的烃类气体和气体。 通过输送线在100至1300℃的温度和10至70巴范围内的压力下将烃类气体供应给燃烧器。 在与燃烧器连接的传送管线的孔口端部附近,设置有可以流过碳氢化合物气体的筛网状穿孔壁。 该壁确保燃烧器中的气体均匀流动,并且同时防止固体物质从一定尺寸向前侵入燃烧器的敏感部分并在那里沉降。