Two-component polyurethane binders as primers
    71.
    发明申请
    Two-component polyurethane binders as primers 失效
    双组分聚氨酯粘合剂作为底漆

    公开(公告)号:US20020142169A1

    公开(公告)日:2002-10-03

    申请号:US10054386

    申请日:2002-01-22

    IPC分类号: C08G018/00

    摘要: The invention relates to a primer containing a solvent-containing two-component polyurethane binder comprising I) a curing component (A), comprising an addition product of at least one organic polyisocyanate (B) with an average NCO functionality of 2.5 to 5.0 and an isocyanate content of 8 to 27 wt. % and an alkoxysilane (C) of formula (I) with at least one isocyanate-reactive group, QnullZnullSiXaY3-anullnull(I), in which Q represents an isocyanate-reactive group, Z represents a linear or branched C1-C12 alkylene group, X represents a hydrolyzable group, Y represents identical or different C1-C4 alkyl groups and a is an integer from 1 to 3, and II) a lacquer resin (D) which can react with isocyanate groups as adhesion promoter.

    摘要翻译: 本发明涉及含有含溶剂的双组分聚氨酯粘合剂的底漆,其包含I)固化组分(A),其包含至少一种平均NCO官能度为2.5至5.0的有机聚异氰酸酯(B)的加成产物和 异氰酸酯含量为8〜27wt。 %和具有至少一个异氰酸酯反应性基团的式(I)的烷氧基​​硅烷(C),其中在线式> QZ-SiXaY3-a(I)中, 其中Q表示异氰酸酯反应性基团,Z表示直链或支链C 1 -C 12亚烷基,X表示可水解基团,Y表示相同或不同的C 1 -C 4烷基,a为1至3的整数 ,和II)可与异氰酸酯基团反应的漆树脂(D)作为粘合促进剂。

    Process for the production of rigid polyurethane foams
    72.
    发明授权
    Process for the production of rigid polyurethane foams 失效
    生产刚性聚氨酯泡沫的方法

    公开(公告)号:US5223549A

    公开(公告)日:1993-06-29

    申请号:US744210

    申请日:1991-08-13

    摘要: Rigid polyurethane foams are produced by reacting a polyisocyanate with a polyester containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight of 400 to 10,000 in the presence of water, an organic blowing agent, a flameproofing agent and a compound containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight in the range from 32 to 399 as crosslinking agent, optionally in the presence of known auxiliaries and additives. The polyester, the flameproofing agent and the crosslinking agent are used in quantities such that from about 15 to about 35 parts by weight of polyester, from about 50 to about 80 parts by weight flameproofing agent and from about 5 to about 15 parts by weight of crosslinking agent (with the sum of the parts by weight of these components adding up to 100) are present. These foams are useful as insulating materials in applications where flame resistance is important.

    摘要翻译: 刚性聚氨酯泡沫体是通过使多异氰酸酯与含有至少两个异氰酸酯反应性氢原子并在水,有机发泡剂,防火剂和至少包含至少一种的化合物的存在下分子量为400至10,000的聚酯反应来制备的 两个异氰酸酯反应性氢原子,分子量范围为32至399,作为交联剂,任选地在已知助剂和添加剂的存在下。 聚酯,防火剂和交联剂的使用量使得约15至约35重量份的聚酯,约50至约80重量份的防火剂和约5至约15重量份的聚酯, 存在交联剂(这些组分的重量份数相加至100)。 这些泡沫在阻燃性很重要的应用中可用作绝缘材料。

    Polyurethane dispersions and the use thereof as finishing agents
    73.
    发明授权
    Polyurethane dispersions and the use thereof as finishing agents 失效
    聚氨酯分散体及其作为整理剂的用途

    公开(公告)号:US4876302A

    公开(公告)日:1989-10-24

    申请号:US284970

    申请日:1988-12-15

    摘要: The present invention is directed to aqueous coating compositions suitable for use as coating and finishing agents for surface coatings, preferably PVC or polyurethane coatings, based on sedimentation-stable polyurethane dispersions having a solids content of about 10-70% by weight wherein the polyurethane-urea solids material is based on polyester diols, low molecular weight diols and optionally triols, chemically incorporated hydrophilic groups, specific mixtures of diisocyanates and polyamine chain extenders having an average functionality of greater than 2 and wherein the aqueous preparations additionally contain alkoxylated dimethyl-polysiloxanes and water-soluble polyethylene oxides. The present invention is also directed to a process for applying top coats and finishes to surface coatings, preferably PVC or polyurethane surface coatings, wherein the above-described aqueous coating and finishing agents are used as the top coat and the coatings are cured at about 70.degree.-170.degree. C.

    摘要翻译: 本发明涉及适用于基于沉积稳定的聚氨酯分散体的表面涂层(优选PVC或聚氨酯涂层)的涂层和整理剂的水性涂料组合物,其中固体含量为约10-70%(重量),其中聚氨酯 - 脲固体材料基于聚酯二醇,低分子量二醇和任选的三醇,化学引入的亲水基团,二异氰酸酯的特定混合物和平均官能度大于2的多胺扩链剂,其中所述水性制剂另外含有烷氧基化二甲基 - 聚硅氧烷, 水溶性聚环氧乙烷。 本发明还涉及一种将表面涂层和表面涂层施用于表面涂层,优选PVC或聚氨酯表面涂层的方法,其中上述水性涂料和整理剂用作顶涂层,并且涂层在约70℃下固化 DEG-170℃

    Polyol blend and polyisocyanurate foam produced therefrom
    74.
    发明授权
    Polyol blend and polyisocyanurate foam produced therefrom 失效
    由此产生的多元醇共混物和聚异氰脲酸酯泡沫

    公开(公告)号:US4544679A

    公开(公告)日:1985-10-01

    申请号:US703849

    申请日:1985-02-21

    摘要: The present invention is directed to a polyol blend comprising:(a) from about 30 to about 90 percent by weight of a polyester diol having an OH number of from about 50 to about 500 and having the structure: ##STR1## wherein each R may be the same or different and represents a radical of the formula: ##STR2## where R" represents H or CH.sub.3 with the proviso that both R"s cannot be CH.sub.3, and y represents a number of from 1 to 5,wherein R' represents an aromatic radical having from 6 to 12 carbon atoms, and wherein x represents a number of from 0 to 5,(b) from about 2 to about 40 percent by weight of an organic compound containing from 3 to 8 hydroxyl groups and being selected from the group consisting of(i) compounds having OH numbers of from about 250 to about 1830 and being free of carboxylic acid ester groups,(ii) compounds having OH numbers of from about 150 to about 1000 and containing at least one carboxylic acid ester group, and(iii) mixtures thereof,(c) from about 5 to about 30 percent by weight of a condensation product formed from 1 mole of a phenol and from 4 to 15 moles of ethylene oxide, and(d) from 0 to about 40 percent by weight of at least one diol of the structure: ##STR3## where R" and y are as defined above, and to an isocyanurate foam prepared therefrom.

    摘要翻译: 本发明涉及多元醇共混物,其包含:(a)约30至约90重量%的OH数为约50至约500的聚酯二醇,并具有以下结构:其中每个R可以 相同或不同,表示下式的基团:其中R“表示H或CH 3,条件是两个R'不能为CH3,y表示1至5的数,其中R “表示具有6至12个碳原子的芳族基团,其中x表示0至5的数,(b)约2至约40重量%的含有3至8个羟基的有机化合物,并且为 选自(i)具有约250至约1830的OH数的化合物和不含羧酸酯基的化合物,(ii)OH值为约150至约1000的化合物,并含有至少一种羧酸 酯基,和(iii)它们的混合物,(c)约5至约3 0重量%由1摩尔酚和4至15摩尔环氧乙烷形成的缩合产物,和(d)0至约40重量%的至少一种以下结构的二醇:其中 R“和y如上所定义,和由其制备的异氰脲酸酯泡沫。

    Additives for improving the diecuttability of diecuttable polyester
urethane foam
    76.
    发明授权
    Additives for improving the diecuttability of diecuttable polyester urethane foam 失效
    用于改善可加工聚酯聚氨酯泡沫塑料的可执行性的添加剂

    公开(公告)号:US4146498A

    公开(公告)日:1979-03-27

    申请号:US877973

    申请日:1978-02-15

    摘要: Improved diecuttable polyester urethane foams are provided by the inclusion in the foam formulation of specified minor amounts of certain low molecular weight polyols, typically having hydroxyl numbers of 100 or greater. Representative useful species of such polyols include aliphatic alcohols, such as glycerol and erythritol, polymethylols such as trimethylolpropane, alkanolamines such as triethanolamine and relatively low molecular weight alkylene oxide adducts such as propylene-glycerol adducts and the like. Especially effective diecuttable foam formulations are provided by further employing, as co-additives, certain alkylene oxide adducts of linear alcohols or phenols, sulfonated petroleum oils, ammonium salts and silicone-containing copolymers. If desired, the viscosity and compatibility characteristics of the additive and/or additive and co-additive mixture may be modified by the incorporation of a diluent.

    摘要翻译: 通过在泡沫制剂中包含特定的少量某些低分子量多元醇(通常具有100或更大的羟基数)来提供改进的可重复性聚酯聚氨酯泡沫。 这种多元醇的代表性有用物质包括脂族醇,例如甘油和赤藓糖醇,多羟基甲烷如三羟甲基丙烷,链烷醇胺如三乙醇胺和相对低分子量的烯化氧加合物如丙烯 - 甘油加合物等。 通过进一步使用直链醇或酚的某些烯化氧加合物,磺化石油,铵盐和含硅氧烷的共聚物作为共添加剂,提供了特别有效的可再加工泡沫配方。 如果需要,可以通过掺入稀释剂来改变添加剂和/或添加剂和共添加剂混合物的粘度和相容性。

    U.V. curable poly(ester-urethane) polyacrylate polymers and wet look
coatings therefrom
    77.
    发明授权
    U.V. curable poly(ester-urethane) polyacrylate polymers and wet look coatings therefrom 失效
    U.V. 可聚合的(酯 - 氨基甲酸酯)聚丙烯酸酯聚合物和湿式外观涂料

    公开(公告)号:US4072770A

    公开(公告)日:1978-02-07

    申请号:US685373

    申请日:1976-05-11

    申请人: Vincent W. Ting

    发明人: Vincent W. Ting

    摘要: Polyester-urethane polymers, prepared from the reaction of specific molar ratios of diisocyanates with specific mixtures of polyesterdiols, glycols, triols and tetraols, and having 4-10 reactive isocyanate groups are further reacted with hydroxyalkyl acrylates through the free isocyanate functionality to provide oligomers having from about 4-10 acrylates units per each mole unit of polyurethane chain. Such polymers when crosslinked under ultraviolet radiation in the presence of photosensitizers, specific reactive monofunctional acrylate solvents and multifunctional acrylate cross-linking agents cure without air inhibition to yield superior "wet look" finishes especially useful for coating metal, wood and floor tile.

    摘要翻译: 由二异氰酸酯与聚酯二醇,二醇,三醇和四醇的特定混合物的特定摩尔比与4-10个活性异氰酸酯基团的特定摩尔比的反应制备的聚酯 - 氨基甲酸酯聚合物通过游离异氰酸酯官能团进一步与丙烯酸羟烷基酯反应,以提供具有 每单位聚氨酯链约4-10个丙烯酸酯单元。 这种聚合物当在光敏剂,特定反应性单官能丙烯酸酯溶剂和多官能丙烯酸酯交联剂存在下在紫外线辐射下交联时,无空气抑制而固化,以产生优异的“湿润外观”表面,特别适用于涂覆金属,木材和地砖。