摘要:
The invention relates to a continuous method for N-acylating amino group-carrying organic acids by reacting at least one carboxylic acid of formula (I) R1—COOH (I), wherein R1 represents hydrogen or an optionally substituted hydrocarbon group with 1 to 50 carbon atoms, with at least one at least one amino group-carrying organic acid of formula (II) R2NH-A-X (II), wherein A represents an optionally substituted hydrocarbon group with 1 to 50 carbon atoms, X represents an acid group or the metal salt thereof and R2 represents hydrogen, an optionally substituted hydrocarbon group with 1 to 50 C atoms or a group of the formula -A-X, wherein A and X independently are defined as above, in a reaction tube the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form amide.
摘要:
The invention relates to a device for continuously carrying out chemical reactions. The device comprises a microwave generator, a microwave applicator accommodating a microwave-transparent tube, and an isothermal reaction section which is arranged such that the material to be reacted is guided inside the microwave-transparent tube through a microwave applicator which is used as the heating zone and in which it is heated to reaction temperature by means of microwaves that are emitted from the microwave generator into the microwave applicator. The material to be reacted, which is heated and optionally under pressure, is transferred from the microwave applicator to an isothermal reaction zone once it has left the heating zone, said reaction zone being arranged downstream of the heating zone, and is cooled once it has left the isothermal reaction zone.
摘要:
The invention relates to a method for producing fatty acid alkanol amides by reacting at least one amine that contains at least one primary or secondary amino group and at least one hydroxyl group with at least one fatty acid to form an ammonium salt, said ammonium salt being subsequently converted into the alkanol amide by means of microwave radiation.
摘要:
The invention relates to a continuous method for producing fatty acid amides, according to which at least one fatty acid of formula (I), R3—COOH (I) wherein R3 is an optionally substituted aliphatic hydrocarbon radical, is reacted with at least one amine of formula (II), HNR1R2 (II) wherein R1 and R2 are independently hydrogen or a hydrocarbon radical comprising between 1 and 100 C atoms, to form an ammonium salt, and said ammonium salt is then reacted to form a fatty acid amide, under microwave irradiation in a reaction pipe, the longitudinal axis of the pipe being oriented in the direction of propagation of the microwaves of a monomode microwave applicator.
摘要:
The present invention provides oily liquids comprising A) at least one ester of fatty acids whose carbon chain lengths are between 8 and 30 carbon atoms, and a monohydric C1-C5-alcohol, at least 50% of the fatty acid radicals containing at least one double bond, and B) at least one alkylphenol-aldehyde resin, obtainable by condensing (i) at least one alkylphenol having at least one C6-C24-alkyl or C6-C24-alkenyl radical and (ii) at least one aldehyde or ketone to a degree of condensation of between 2 and 50 alkylphenol units.
摘要:
The invention provides a fuel oil composition F) comprising F1) 89-50% by volume of a fuel oil of mineral origin and F2) 11-50% by volume of a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units composed of B1) at least one olefin as monomer 1 which bears at least one C8-C18-alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16-alkyl radical bonded via an ester moiety, where the sum Q Q = ∑ i w 1 i · n 1 i + ∑ j w 2 j · n 2 j of the molar averages of the carbon chain length distributions in the alkyl radicals of monomer 1 on the one hand and the alkyl radicals of the ester groups of monomer 2 on the other is from 21.0 to 28.0, where w1 is the molar proportion of the individual chain lengths in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths in the alkyl radicals of the ester groups of monomer 2, n1 are the individual chain lengths in the alkyl radicals of monomer 1, n2 are the individual chain lengths in the alkyl radicals of the ester groups of monomer 2, i is the serial variable for the individual chain lengths in the alkyl radicals of monomer 1, and j is the serial variable for the individual chain lengths in the alkyl radicals in the ester groups of monomer 2.
摘要:
The invention relates to additives for middle distillates with a maximum sulfur content of 0.05 percent by weight, containing at least one fatty acid ester of alkoxylated polyols with at least 3 OH groups (A) and at least one alkylphenol-aldehyde resin (C).
摘要:
Copolymers based on ethylene and unsaturated carboxylic esters and their use as mineral oil additives. The invention relates to copolymers of low olefins and vinyl esters, containing a) from 85 to 97 mol % of bivalent structural units of the formula 1 —CH2—CR1R2— 1 in which R1 and R2, independently of one another, are hydrogen or methyl, and b) at least 3 mol % of bivalent structural units of the formula 2 in which R3 is saturated, branched C6-C16-alkyl which has a tertiary carbon atom, wherein R3 is bonded by its tertiary carbon atom to the carboxyl function. The copolymers according to the invention are used as flow improvers for mineral oil distillates.
摘要:
Copolymers containing A) from 45 to 54 mol % of divalent structural units of the formula 1 in which a and b=0 or 1 and a+b=1, B) from 35 to 53 mol % of divalent structural units of the formula 2 —H2C—CHR2— (2) and C) from 1 to 25 mol % of divalent structural units derived from polyolefins, where the polyolefins can be derived from monoolefins having 3 to 5 carbon atoms, wherein a) R1 is an alkyl or alkenyl radical having 10 to 40 carbon atoms or an alkoxyalkyl radical having 1 to 100 alkoxy units and 1 to 30 carbon atoms in the alkyl radical, and b) R2 is an alkyl radical having 10 to 50 carbon atoms, c) the alkylvinylidene content of the polyolefins on which the structural units C) are based is at least 50 mol %, and d) the number of carbon atoms in the polyolefin molecules on which the structural units C) are based is from 35 to 350.
摘要:
The invention relates to a method for producing alkaline amides or imides of ethylenically unsaturated C3 to C6 carboxylic acids by reacting amines that contain at least one primary and/or secondary amino group and at least one tertiary amino group with ethylenically unsaturated C3 to C6 carboxlic acids to form an ammonium salt and said ammonium salt is subsequently converted into the alkaline amide or imide by means of microwave radiation, with the proviso that the primary and/or secondary amino group is devoid of alkoxy groups.