公开(公告)号：US20160244548A1

公开(公告)日：2016-08-25

申请号：US15023346

申请日：2014-09-18

Applicant: QUEEN'S UNIVERSITY AT KINGSTON ,  GREENCENTRE CANADA

Inventor： Kyle J. Boniface ,  Timothy James Clark ,  Michael F. Cunningham ,  Philip G. Jessop ,  Brian Ernest Mariampillai ,  Sean M. Mercer ,  Rui Resendes ,  Tobias Robert

IPC: C08F292/00 ,  B01J20/286 ,  G01N30/02 ,  B01D15/42 ,  B01D15/40 ,  B01D53/26 ,  B01J20/26 ,  B01D15/10

CPC classification number: C08F292/00 ,  B01D15/10 ,  B01D15/40 ,  B01D15/426 ,  B01D53/26 ,  B01D53/261 ,  B01J19/02 ,  B01J20/265 ,  B01J20/286 ,  B01J20/289 ,  B01J20/3204 ,  B01J20/3219 ,  B01J20/3259 ,  B01J20/3293 ,  B01J2219/00024 ,  B01J2219/0245 ,  B01J2220/54 ,  C08L101/12 ,  G01N30/02 ,  G01N2030/027

Abstract: The present application provides a composite material that comprises a solid and solid-supported non-polymeric switchable moiety, wherein the switchable moiety comprises a functional group that is switchable between a first form and a second form, said first form being neutral and hydrophobic, and said second form being ionized and hydrophilic. The composite material converts to, or is maintained in, said second form when the switchable moiety is exposed to CO2 at amounts sufficient to maintain the ionized form. The composite material converts to, or is maintained in, said first form when CO2 is removed or reduced to an amount insufficient to maintain the ionized form. CO2 is removed or reduced by exposing the composite material to heat and/or a flushing inert gas such as N2, Ar, or air. Envisioned uses of these composite materials includes removing water from non-aqueous solvents, removing water vapour from gaseous mixtures, and cleaning industrial reaction vessels and/or pipelines.

Abstract translation: 本申请提供了一种复合材料，其包含固体和固体支持的非聚合物可切换部分，其中可切换部分包括可在第一形式和第二形式之间切换的官能团，所述第一形式是中性和疏水性的，以及 所述第二形式被离子化和亲水化。 当可切换部分以足以维持电离形式的量暴露于CO 2时，复合材料转化为或保持在所述第二形式中。 当将CO 2除去或减少到不足以维持电离形式的量时，复合材料转化为或保持在所述第一形式中。 通过将复合材料暴露于加热和/或冲洗惰性气体如N 2，Ar或空气来除去或减少CO 2。 这些复合材料的设想用途包括从非水溶剂中除去水分，从气体混合物中除去水蒸气，以及清洁工业反应容器和/或管道。

公开(公告)号：US20140235908A1

公开(公告)日：2014-08-21

申请号：US14075445

申请日：2013-11-08

Applicant: GreenCentre Canada ,  Queen's University at Kingston

Inventor： Philip G. JESSOP ,  Lam N. Phan ,  Andrew J. Carrier ,  Rui Resendes ,  Dominik Wechsler

IPC: C10G1/04

CPC classification number: C08K5/17 ,  B01D11/0492 ,  C07C257/14 ,  C08J11/08 ,  C08J2325/06 ,  C10G1/04 ,  C10G2300/1011 ,  C10G2300/44 ,  C11D3/30 ,  C11D3/43 ,  Y02P30/20 ,  Y02W30/701 ,  Y10S516/924

Abstract: A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.

Abstract translation: 描述了当与水接触并且选择的触发器例如与CO 2接触时可逆地从疏水性液体形式转化为亲水性液体的溶剂。 亲水性液体形式容易转化回疏水性液体形式和水。 疏水性液体是脒或胺。 亲水性液体形式包括脒鎓盐或铵盐。

公开(公告)号：US20170073361A1

公开(公告)日：2017-03-16

申请号：US15274997

申请日：2016-09-23

Applicant: Greencentre Canada

Inventor： Sean BARRY ,  Jason COYLE ,  Timothy James CLARK ,  Jeffrey J.M. HASTIE

IPC: C07F7/10 ,  C07F1/08 ,  C23C16/50 ,  H01L21/3205 ,  C23C16/18 ,  C23C16/455 ,  C09D5/24 ,  C07F1/00

CPC classification number: C07F7/10 ,  C07F1/00 ,  C07F1/005 ,  C07F1/08 ,  C09D5/24 ,  C23C16/18 ,  C23C16/45553 ,  C23C16/50 ,  H01L21/32051

Abstract: The present application provides precursor compounds useful for deposition of a group 11 metal on a substrate, for example, a microelectronic device substrate, as well as methods of synthesizing such precursor compounds. The precursor compounds provided are mono-metallic compounds comprising a diaminocarbene (DAC) having the general formula: “DAC-M-X”, where the diaminocarbene is an optionally substituted, saturated N-heterocyclic diaminocarbene (sNHC) or an optionally substituted acyclic diaminocarbene, M is a group 11 metal, such as copper, silver or gold; and X is an anionic ligand. Also provided are methods of synthesizing the precursor compounds, metal deposition methods utilizing such precursor compounds, and to composite materials, such as, e.g., microelectronic device structures, and products formed by use of such precursors and deposition methods.

Abstract translation: 本申请提供了可用于在基底上沉积11族金属的前体化合物，例如微电子器件底物，以及合成这些前体化合物的方法。 所提供的前体化合物是包含具有以下通式的二氨基卡宾（DAC）的单金属化合物：DAC-MX，其中二氨基碳烯是任选取代的饱和N-杂环二氨基卡宾（sNHC）或任选取代的非环状二氨基碳烯，M 是一组11金属，如铜，银或金; X是阴离子配体。 还提供了合成前体化合物的方法，利用这种前体化合物的金属沉积方法以及复合材料，例如微电子器件结构，以及通过使用这些前体形成的产物和沉积方法。

公开(公告)号：US20150018493A1

公开(公告)日：2015-01-15

申请号：US14384839

申请日：2013-03-13

Applicant: GREENCENTRE CANADA ,  THE UNIVERSITY OF BRITISH COLUMBIA

Inventor： Parisa Mehrkhodavandi ,  Dinesh C. Aluthge ,  Timothy James Clark ,  Brian Mariampillai ,  Yun Yang

IPC: C08G63/82 ,  C08G63/08 ,  C08G63/91

CPC classification number: C08G63/823 ,  C07C251/24 ,  C08G63/08 ,  C08G63/84 ,  C08G63/912

Abstract: The present application provides salen indium catalysts of the following general structure and the corresponding dimers. The salen indium catalysts are particularly useful in catalyzing ring-opening polymerizations of cyclic ester monomers, such as lactides. Also provided herein are methods of using the salen indium complexes to catalyze polymerization of cyclic ester monomers. Of particular interest is the successful polymerization of lactides using the present salen indium catalysts to produce poly(lactic acid) having high isotacticity.

Abstract translation: 本申请提供了以下一般结构的salen铟催化剂和相应的二聚体。 盐酸铟催化剂特别可用于催化环酯单体如丙交酯的开环聚合。 本文还提供了使用salen铟络合物催化环酯单体聚合的方法。 特别令人感兴趣的是使用本发明的salen铟催化剂成功地聚合丙交酯以产生具有高全同立构规整度的聚（乳酸）。

公开(公告)号：US20180142117A1

公开(公告)日：2018-05-24

申请号：US15579424

申请日：2016-06-06

Applicant: GREENCENTRE CANADA ,  QUEEN'S UNIVERSITY AT KINGSTON

Inventor： Rui RESENDES ,  Philip G. JESSOP ,  Michael F. CUNNINGHAM ,  Bhanu Prakash MUDRABOYINA ,  Adam Michael OZVALD ,  Timothy James CLARK ,  Brian MARIAMPILLAI ,  Yun YANG ,  Amy Marie HOLLAND ,  Charles Howard HONEYMAN

IPC: C09D133/10 ,  C08K3/18 ,  C08L101/12 ,  C09D11/107 ,  C09D201/00 ,  C09D5/08

CPC classification number: C09D133/10 ,  C08K3/18 ,  C08L101/12 ,  C09D5/08 ,  C09D11/106 ,  C09D11/107 ,  C09D201/00

Abstract: The present application provides switchable, homogeneous paint composition and methods of painting and/or forming films or coatings using the composition. The composition includes a liquid having an aqueous solution and dissolved acid gas (e.g., carbonated water), and a switchable polymer. The switchable polymer converts from a protonated, water-soluble form in the liquid to a water-insoluble unprotonated form following removal or substantial removal of the liquid and acid gas.

公开(公告)号：US20150240051A1

公开(公告)日：2015-08-27

申请号：US14522693

申请日：2014-10-24

Applicant: Queen's University at Kingston ,  GreenCentre Canada

Inventor： Philip G. JESSOP ,  Lam N. PHAN ,  Andrew J. CARRIER ,  Rui RESENDES ,  Dominik WECHSLER

IPC: C08K5/17 ,  C11D3/43 ,  C11D3/30 ,  B01D11/04

CPC classification number: C08K5/17 ,  B01D11/0492 ,  C07C257/14 ,  C08J11/08 ,  C08J2325/06 ,  C10G1/04 ,  C10G2300/1011 ,  C10G2300/44 ,  C11D3/30 ,  C11D3/43 ,  Y02P30/20 ,  Y02W30/701 ,  Y10S516/924

Abstract: A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.

Abstract translation: 描述了当与水接触并且选择的触发器例如与CO 2接触时可逆地从疏水性液体形式转化为亲水性液体的溶剂。 亲水性液体形式容易转化回疏水性液体形式和水。 疏水性液体是脒或胺。 亲水性液体形式包括脒鎓盐或铵盐。

公开(公告)号：US08900444B2

公开(公告)日：2014-12-02

申请号：US14075445

申请日：2013-11-08

Applicant: Queen's University at Kingston ,  GreenCentre Canada

Inventor： Philip G. Jessop ,  Lam N. Phan ,  Andrew J. Carrier ,  Rui Resendes ,  Dominik Wechsler

IPC: C10G1/04

CPC classification number: C08K5/17 ,  B01D11/0492 ,  C07C257/14 ,  C08J11/08 ,  C08J2325/06 ,  C10G1/04 ,  C10G2300/1011 ,  C10G2300/44 ,  C11D3/30 ,  C11D3/43 ,  Y02P30/20 ,  Y02W30/701 ,  Y10S516/924

Abstract: A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.

Abstract translation: 描述了当与水接触并且选择的触发器例如与CO 2接触时可逆地从疏水性液体形式转化为亲水性液体的溶剂。 亲水性液体形式容易转化回疏水性液体形式和水。 疏水性液体是脒或胺。 亲水性液体形式包括脒鎓盐或铵盐。

公开(公告)号：US20140323562A1

公开(公告)日：2014-10-30

申请号：US14360392

申请日：2012-11-23

Applicant: Universition of Ottawa ,  GreenCentre Canada

Inventor： Philip Jessop ,  Paul David Thornton ,  Shannon Marie Decker ,  Derek Pratt ,  Feng Zheng ,  Donna Lynn Leger

IPC: C07C381/00 ,  C10L1/24 ,  A61K31/198 ,  A61Q19/00 ,  A61K31/341 ,  A61K8/49 ,  A61K8/46 ,  A61K31/105 ,  C07D407/12

CPC classification number: C07C381/00 ,  A61K8/46 ,  A61K8/4973 ,  A61K31/105 ,  A61K31/198 ,  A61K31/341 ,  A61K38/063 ,  A61K47/20 ,  A61K2800/10 ,  A61K2800/522 ,  A61Q19/00 ,  C07D407/12 ,  C09K15/12 ,  C09K15/14 ,  C09K15/28 ,  C09K15/30 ,  C09K15/324 ,  C09K15/328 ,  C10L1/2431 ,  C10L1/2443 ,  A61K2300/00

Abstract: The present application provides compound of Formula X wherein A is an optionally substituted aliphatic or an optionally substituted aryl, and B is a moiety that stabilizes the partial positive charge at the carbon adjacent the divalent sulfur. The compound of Formula X is useful as a reversible antioxidant in a variety of applications. Also provided are methods of synthesizing the compound of Formula X.

Abstract translation: 本申请提供式X的化合物，其中A是任选取代的脂族或任选取代的芳基，B是在邻近二价硫的碳上稳定部分正电荷的部分。 式X的化合物可用作各种应用中的可逆抗氧化剂。 还提供了合成式X化合物的方法。