Photoresists for visible light imaging
    1.
    发明授权
    Photoresists for visible light imaging 有权
    用于可见光成像的光致抗蚀剂

    公开(公告)号:US07354692B2

    公开(公告)日:2008-04-08

    申请号:US11125971

    申请日:2005-05-09

    IPC分类号: G03F7/031 G03F7/038 G03F7/039

    摘要: A class of lithographic photoresist combinations is disclosed which is suitable for use with visible light and does not require a post-exposure bake step. The disclosed photoresists are preferably chemical amplification photoresists and contain a photosensitizer having the structure of formula (I): where Ar1 and Ar2 are independently selected from monocyclic aryl and monocyclic heteroaryl, R1 and R2 may be the same or different, and have the structure —X—R3 where X is O or S and R3 is C1-C6 hydrocarbyl or heteroatom-containing C1-C6 hydrocarbyl, and R4 and R5 are independently selected from the group consisting of hydrogen and —X—R3, or, if ortho to each other, may be taken together to form a five- or six-membered aromatic ring, with the proviso that any heteroatom contained within Ar1, Ar2, or R3 is O or S. The use of the disclosed photoresists, particularly for the manufacture of holographic diffraction gratings, is also disclosed.

    摘要翻译: 公开了一类光刻抗蚀剂组合物,其适用于可见光并且不需要曝光后烘烤步骤。 所公开的光致抗蚀剂优选是化学放大光致抗蚀剂,并含有具有式(I)结构的光敏剂:其中Ar 1和Ar 2独立地选自单环芳基和单环杂芳基 R 1和R 2可以相同或不同,并且具有结构-XR 3,其中X是O或S,R“ SUP> 3是C 1 -C 6烃基或含杂原子的C 1 -C 6 N >烃基,R 4和R 5独立地选自氢和-XR 3 O 3,或者如果各自的邻位 另一个可以一起形成五元或六元芳环,条件是含有Ar 1,Ar 2或R 0的任何杂原子 > 3 是O或S.还公开了所公开的光致抗蚀剂的使用,特别是用于制造全息衍射光栅。

    Composition for photoimaging
    3.
    发明授权
    Composition for photoimaging 失效
    光成像用组合物

    公开(公告)号:US06180317B2

    公开(公告)日:2001-01-30

    申请号:US07793889

    申请日:1991-11-18

    IPC分类号: G03C1725

    CPC分类号: G03F7/038

    摘要: An improved photoimagable cationically polymerizable epoxy based coating material is provided, that is suitable for use on a variety of substrates including epoxy-glass laminate boards cured with dicyandiamide. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; and between about 35% and 72% by weight of an epoxidized glycidyl ether of a brominated bisphenol A having a softening point of between about 60° C. and about 110° C. and a molecular weight of between about 600 and 2,500. Optionally, a third resin may be added to the resin system. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.

    摘要翻译: 提供了一种改进的可光成像的可阳离子聚合的环氧基涂料,适用于各种基材,包括用双氰胺固化的环氧玻璃层压板。 该材料包括基本上由约10重量%至约80重量%的多元醇树脂组成的环氧树脂体系,多元醇树脂是分子量为约40,000至130,000的表氯醇和双酚A的缩合产物; 和约35重量%至72重量%的软化点在约60℃至约110℃之间且分子量为约600至2,500之间的溴化双酚A的环氧化缩水甘油醚。 任选地,可以向树脂体系中加入第三树脂。 向该树脂体系中添加约0.1〜约15重量份/ 100份阳离子光引发剂的树脂,其能够在暴露于光化辐射下引发所述环氧化树脂体系的聚合; 该系统的特征还在于,对于2.0密耳厚的膜,在330至700nm区域中的光的吸光度小于0.1。 任选地,可加入光敏剂如苝及其衍生物或蒽及其衍生物。

    Composition for photoimaging
    5.
    发明授权
    Composition for photoimaging 失效
    光成像用组合物

    公开(公告)号:US5747223A

    公开(公告)日:1998-05-05

    申请号:US677230

    申请日:1996-07-09

    IPC分类号: G03C5/00 G03F7/038 H05K3/28

    CPC分类号: G03F7/038 H05K3/287

    摘要: An improved photoimagable cationically polymerizable epoxy based coating material is provided, that is suitable for use on a variety of substrates including epoxy-glass laminate boards cured with dicyandiamide. The material includes an epoxy resin system consisting essentially of between about 10% and about 80% by weight of a polyol resin which is a condensation product of epichlorohydrin and bisphenol A having a molecular weight of between about 40,000 and 130,000; and between about 35% and 72% by weight of an epoxidized glycidyl ether of a brominated bisphenol A having a softening point of between about 60.degree. C. and about 110.degree. C. and a molecular weight of between about 600 and 2,500. Optionally, a third resin may be added to the resin system. To this resin system is added about 0.1 to about 15 parts by weight per 100 parts of resin of a cationic photoinitiator capable of initiating polymerization of said epoxidized resin system upon exposure to actinic radiation; the system being further characterized by having an absorbance of light in the 330 to 700 nm region of less than 0.1 for a 2.0 mil thick film. Optionally a photosensitizer such as perylene and its derivatives or anthracene and its derivatives may be added.

    摘要翻译: 提供了一种改进的可光成像的可阳离子聚合的环氧基涂料,适用于各种基材,包括用双氰胺固化的环氧玻璃层压板。 该材料包括基本上由约10重量%至约80重量%的多元醇树脂组成的环氧树脂体系,多元醇树脂是分子量为约40,000至130,000的表氯醇和双酚A的缩合产物; 和约35重量%至72重量%的软化点为约60℃至约110℃,分子量为约600至2,500的溴化双酚A的环氧化缩水甘油醚。 任选地,可以向树脂体系中加入第三树脂。 向该树脂体系中添加约0.1〜约15重量份/ 100份阳离子光引发剂的树脂,其能够在暴露于光化辐射下引发所述环氧化树脂体系的聚合; 该系统的特征还在于,对于2.0密耳厚的膜,在330至700nm区域中的光的吸光度小于0.1。 任选地,可加入光敏剂如苝及其衍生物或蒽及其衍生物。

    Alkaline Rinse Agents For Use In Lithographic Patterning
    7.
    发明申请
    Alkaline Rinse Agents For Use In Lithographic Patterning 有权
    用于平版印刷图案的碱性漂洗剂

    公开(公告)号:US20110104900A1

    公开(公告)日:2011-05-05

    申请号:US12611043

    申请日:2009-11-02

    IPC分类号: H01L21/311

    摘要: Lithographic patterning methods involve the formation of a (one or more) metal oxide capping layer, which is rinsed with an aqueous alkaline solution as part of the method. The rinse solution does not damage the capping layer, but rather allows for lithographic processing without thinning the capping layer or introducing defects into it. Ammoniated water is a preferred rinse solution, which advantageously leaves behind no nonvolatile residue.

    摘要翻译: 平版印刷图案方法包括形成(一种或多种)金属氧化物覆盖层,其作为该方法的一部分用碱性水溶液冲洗。 冲洗溶液不会损坏盖层,而是允许光刻处理,而不会使封盖层变薄或引入缺陷。 氨水是优选的漂洗溶液,其有利地不留下非挥发性残余物。

    Bilayer film including an underlayer having vertical acid transport properties
    8.
    发明授权
    Bilayer film including an underlayer having vertical acid transport properties 失效
    双层膜包括具有垂直酸运输性质的底层

    公开(公告)号:US07585609B2

    公开(公告)日:2009-09-08

    申请号:US11492276

    申请日:2006-07-25

    IPC分类号: G03F7/11 G03F7/09 G03F7/095

    摘要: The present invention provides methods for forming images in positive- or negative-tone chemically amplified photoresists. The methods of the present invention rely on the vertical up-diffusion of photoacid generated by patternwise imaging of an underlayer disposed on a substrate and overcoated with a polymer containing acid labile functionality. In accordance with the present invention, the vertical up-diffusion can be the sole mechanism for imaging formation or the methods of the present invention can be used in conjunction with conventional imaging processes.

    摘要翻译: 本发明提供了在正或负色调化学放大的光致抗蚀剂中形成图像的方法。 本发明的方法依赖于通过对设置在基底上的底层的图案成像产生的光酸的垂直向上扩散,并且用含有酸不稳定性功能的聚合物涂覆。 根据本发明,垂直向上扩散可以是用于成像成像的唯一机构,或者本发明的方法可以与传统的成像过程结合使用。

    Lithographic photoresist composition and process for its use
    9.
    发明授权
    Lithographic photoresist composition and process for its use 有权
    平版光刻胶组合物及其使用方法

    公开(公告)号:US06730452B2

    公开(公告)日:2004-05-04

    申请号:US09771261

    申请日:2001-01-26

    IPC分类号: G03F7039

    摘要: A lithographic photoresist composition is provided that can be used as a chemical amplification photoresist. In a preferred embodiment, the composition is substantially transparent to deep ultraviolet radiation, i.e., radiation of a wavelength less than 250 nm, including 157 nm, 193 nm and 248 nm radiation, and has improved sensitivity and resolution. The composition comprises a fluorinated vinylic polymer, particularly a fluorinated methacrylate, a fluorinated methacrylonitrile, or a fluorinated methacrylic acid, and a photoacid generator. The polymer may be a homopolymer or a copolymer. A process for using the composition to generate resist images on a substrate is also provided, i.e., in the manufacture of integrated circuits or the like.

    摘要翻译: 提供可用作化学扩增光致抗蚀剂的平版光刻胶组合物。 在优选的实施方案中,组合物对深紫外辐射即波长小于250nm(包括157nm,193nm和248nm辐射)的辐射基本上是透明的,并具有改进的灵敏度和分辨率。 组合物包含氟化乙烯基聚合物,特别是氟化甲基丙烯酸酯,氟化甲基丙烯腈或氟化甲基丙烯酸,以及光酸产生剂。 聚合物可以是均聚物或共聚物。 还提供了使用该组合物在衬底上产生抗蚀剂图像的方法,即在集成电路等的制造中。