公开(公告)号：US4826583A

公开(公告)日：1989-05-02

申请号：US137330

申请日：1987-12-23

申请人： Alain Biernaux ,  Lucien Laude

发明人： Alain Biernaux ,  Lucien Laude

IPC分类号： C25D5/02 ,  C25D17/00

CPC分类号： C25D5/024

摘要： Apparatus for laser-assisted electroplating of metals in closed circuit, comprising a flexible capillary duct into which an electrolyte is injected and at the center of which is located an optical fibre channelling the laser beam. The flexible capillary injecting duct being possibly also centered in a second suction duct allowing the electrolyte to be recovered and recycled. The electrolyte source and the radiation source are combined at the end itself of the capillary duct, and the deposit action can be carried out at any location difficult to access, thanks to the flexibility of the capillary tube-fibre assembly.

摘要翻译： 用于在闭路中金属激光辅助电镀的装置，包括柔性毛细管，电解质注入其中，其中心位于将激光束引导的光纤。 柔性毛细管注入管道也可能在第二抽吸管道的中心位置，允许回收和回收电解质。 电解质源和辐射源在毛细管的端部本身被组合，并且由于毛细管 - 纤维组件的灵活性，沉积作用可以在难以进入的任何位置进行。

公开(公告)号：US20080085376A1

公开(公告)日：2008-04-10

申请号：US11924363

申请日：2007-10-25

申请人： Lucien Laude ,  Neil Talbot ,  Robert Greenberg

发明人： Lucien Laude ,  Neil Talbot ,  Robert Greenberg

IPC分类号： B05D3/06

CPC分类号： H05K3/185 ,  C23C18/1608 ,  C23C18/1612 ,  C23C18/1653 ,  C23C18/1692 ,  C23C18/204 ,  H05K1/0289 ,  H05K1/032 ,  H05K1/0373 ,  H05K1/0393 ,  H05K3/0035 ,  H05K3/007 ,  H05K3/107 ,  H05K3/28 ,  H05K3/4661 ,  H05K3/4682 ,  H05K2201/0162 ,  H05K2201/0209 ,  H05K2203/016 ,  H05K2203/1105

摘要： The present invention relates to a process for embedding at least one layer of at least one metal trace in a silicone containing polymer, comprising: a) applying a non adhering on a substrate; b) applying a polymer layer on the non adhering agent; c) irradiation at least one surface area of said polymer with a light beam emitted by an excimer laser; d) immersing said irradiated polymer in at least one autocatalytic bath containing metal ions of at least one metal and metallizing the polymer; e) thermally treating said metallized polymer; f) applying a polymer layer on said thermally treated metallized polymer; and g) thermally treating said metallized polymer.

摘要翻译： 本发明涉及一种在含硅氧烷聚合物中嵌入至少一层至少一种金属迹线的方法，包括：a）将不粘附在基底上; b）在非粘合剂上施加聚合物层; c）用由准分子激光器发射的光束照射所述聚合物的至少一个表面积; d）将所述照射的聚合物浸入至少一种含有至少一种金属的金属离子并使聚合物金属化的自催化浴; e）热处理所述金属化聚合物; f）将聚合物层施加在所述热处理的金属化聚合物上; 和g）热处理所述金属化聚合物。

公开(公告)号：US20080305320A1

公开(公告)日：2008-12-11

申请号：US12041652

申请日：2008-03-03

申请人： Lucien Laude ,  Adrian Rowley ,  Mark Humayun ,  James Weiland

发明人： Lucien Laude ,  Adrian Rowley ,  Mark Humayun ,  James Weiland

IPC分类号： B32B27/16

CPC分类号： C08J7/123 ,  C08J2383/04 ,  Y10T428/249987

摘要： The invention provides a method of activating a silicone polymer surface using a laser, particularly an excimer laser, so that the silicone is more reactive. A silicone article containing an activated surface is also provided, and can be used to make silicone implants that can be securely fixed to tissue. One example is an implantable prosthesis to treat blindness caused by outer retinal degenerative diseases. The device bypasses damaged photoreceptors and electrically stimulates the undamaged neurons of the retina. Electrical stimulation is achieved using a silicone microelectrode array (MEA). A safe, protein adhesive is used in attaching the MEA to the retinal surface and assist in alleviating focal pressure effects.

摘要翻译： 本发明提供使用激光器，特别是准分子激光器激活硅氧烷聚合物表面的方法，使得硅氧烷更具反应性。 还提供了含活化表面的硅胶制品，可用于制造可固定固定在组织上的硅胶植入物。 一个例子是用于治疗由视网膜外变性疾病引起的失明的可植入假体。 该装置绕过受损的光感受器并电刺激视网膜的未损伤的神经元。 使用硅微电极阵列（MEA）实现电刺激。 使用安全的蛋白质粘合剂将MEA附着到视网膜表面并有助于减轻焦点压力的影响。

公开(公告)号：US20080044591A1

公开(公告)日：2008-02-21

申请号：US11924752

申请日：2007-10-26

申请人： Lucien Laude ,  Robert Greenberg

发明人： Lucien Laude ,  Robert Greenberg

IPC分类号： B05D3/00

CPC分类号： H05K3/185 ,  C23C18/1612 ,  C23C18/1639 ,  C23C18/1641 ,  C23C18/1692 ,  C23C18/1868 ,  C23C18/204 ,  C25D5/02 ,  C25D5/56 ,  H05K1/032 ,  H05K1/0393 ,  H05K3/0035 ,  H05K3/28 ,  H05K3/421 ,  H05K3/4661 ,  H05K2201/0162

摘要： The present invention provides a flexible electrode array, comprising a silicone containing body, at least one metal trace layer and at least one electrode pad on the surface. The present invention further provides a process of manufacturing a flexible electrode array, comprising: a) irradiating a surface area of a molded silicone containing layer yielding traces with a light beam emitted by a pulsed UV laser source, b) immersing said irradiated molded silicone layer for inducing the deposit of metal ions to form metal traces, c) applying a silicone containing layer on said silicone containing layer and said metal traces, d) irradiating the surface for drilling holes into the surface of the molded silicone containing layer, and e) immersing said irradiated molded silicone layer for inducing the deposit of metal ions to form metal electrode pads.

摘要翻译： 本发明提供了一种柔性电极阵列，其包括硅氧烷容纳体，至少一个金属迹线层和表面上的至少一个电极焊盘。 本发明还提供一种制造柔性电极阵列的方法，包括：a）照射模制的含硅氧烷层的表面积，产生具有由脉冲UV激光源发射的光束的痕迹，b）将所述照射的模制硅氧烷层 用于诱导金属离子的沉积以形成金属迹线，c）在所述含硅层和所述金属迹线上施加含硅氧烷层，d）将所述表面照射到所述模制的含硅氧烷层的表面中，e） 浸渍所述照射的模制的硅氧烷层以诱导金属离子的沉积形成金属电极焊盘。

公开(公告)号：US20070104967A1

公开(公告)日：2007-05-10

申请号：US11270907

申请日：2005-11-10

申请人： Lucien Laude ,  Robert Greenberg

发明人： Lucien Laude ,  Robert Greenberg

IPC分类号： B32B15/04 ,  B05D1/38 ,  B05D1/36

CPC分类号： H05K3/185 ,  C08J7/12 ,  C08J2383/04 ,  C23C18/1608 ,  C23C18/1612 ,  C23C18/1657 ,  C23C18/204 ,  C23C18/206 ,  H05K3/28 ,  H05K3/387 ,  H05K2201/0133 ,  H05K2201/0162 ,  H05K2201/0209 ,  H05K2201/0236 ,  H05K2203/107 ,  H05K2203/1105 ,  Y10T428/26 ,  Y10T428/31663

摘要： The present invention provides a process for embedding at least one layer of at least one metal trace in a silicone-containing polymer, comprising: a) applying a polymer layer on a substrate; b) thermally treating the polymer; c) irradiating at least one surface area of the polymer with a light beam emitted by an excimer laser; d) immersing the irradiated polymer in at least one autocatalytic bath containing ions of at least one metal, and metallizing the polymer; e) thermally treating the metallized polymer; f) applying a polymer layer covering the thermally treated metallized polymer; and g) thermally treating the metallized covered polymer. The present invention further provides a polymer layer comprising silicone containing oxide particles of SiO2, TiO2, Sb2O3, SnO2, Al2O3, ZnO, Fe2O3, Fe3O4, talc, hydroxyapatite or mixtures thereof and at least one metal trace embedded in said polymer layer. The present invention further provides a flexible electrode array comprising silicone containing oxide particles of SiO2, TiO2, Sb2O3, SnO2, Al2O3, ZnO, Fe2O3, Fe3O4, talc, hydroxyapatite or mixtures thereof and at least one metal trace embedded in said polymer layer.

摘要翻译： 本发明提供了一种在含硅酮聚合物中嵌入至少一层至少一种金属痕迹的方法，包括：a）在基底上施加聚合物层; b）热处理聚合物; c）用由准分子激光器发射的光束照射所述聚合物的至少一个表面积; d）将经辐射的聚合物浸入至少一种含有至少一种金属的离子的自催化浴中，并对聚合物进行金属化; e）热处理金属化聚合物; f）涂覆覆盖热处理的金属化聚合物的聚合物层; 和g）热处理金属化被覆聚合物。 本发明还提供一种聚合物层，其包含含硅氧烷的SiO 2，TiO 2，Sb 2 O 3， N 2，N 2 O 3，N 2，N 2 O 3， Fe 3 O 3，滑石，羟基磷灰石或其混合物，以及嵌入所述聚合物层中的至少一种金属迹线。 本发明还提供了一种柔性电极阵列，其包括含硅氧烷的SiO 2，TiO 2，Sb 2 O 3， / SUB>，SnO 2，Al 2 O 3，ZnO，Fe 2 O 3，3 < Fe 3 O 3，滑石，羟基磷灰石或其混合物，以及嵌入所述聚合物层中的至少一种金属迹线。

公开(公告)号：US20070292667A1

公开(公告)日：2007-12-20

申请号：US11810758

申请日：2007-06-06

申请人： Lucien Laude ,  Robert Greenberg

发明人： Lucien Laude ,  Robert Greenberg

IPC分类号： B32B3/00

CPC分类号： H05K3/185 ,  A61N1/0543 ,  C23C18/1639 ,  C23C18/1653 ,  C23C18/1692 ,  C23C18/1868 ,  C23C18/1882 ,  C23C18/31 ,  H05K1/032 ,  H05K3/0035 ,  H05K3/107 ,  H05K3/465 ,  H05K3/4661 ,  H05K2201/0162 ,  H05K2201/096 ,  H05K2203/107 ,  Y10T428/24917 ,  Y10T428/31663

摘要： The present invention provides a flexible electrode array, comprising a silicone containing body, at least one metal trace layer and at least one electrode pad on the surface. The present invention further provides a process of manufacturing a flexible electrode array, comprising: a) irradiating a surface area of a molded silicone containing layer yielding traces with a light beam emitted by a pulsed UV laser source, b) immersing said irradiated molded silicone layer for inducing the deposit of metal ions to form metal traces, c) applying a silicone containing layer on said silicone containing layer and said metal traces, d) irradiating the surface for drilling holes into the surface of the molded silicone containing layer, and e) immersing said irradiated molded silicone layer for inducing the deposit of metal ions to form metal electrode pads.

摘要翻译： 本发明提供了一种柔性电极阵列，其包括硅氧烷容纳体，至少一个金属迹线层和表面上的至少一个电极焊盘。 本发明还提供一种制造柔性电极阵列的方法，包括：a）照射模制的含硅氧烷层的表面积，产生具有由脉冲UV激光源发射的光束的痕迹，b）将所述照射的模制硅氧烷层 用于诱导金属离子的沉积以形成金属迹线，c）在所述含硅层和所述金属迹线上施加含硅氧烷层，d）将所述表面照射到所述模制的含硅氧烷层的表面中，e） 浸渍所述照射的模制的硅氧烷层以诱导金属离子的沉积形成金属电极焊盘。

公开(公告)号：US20070104944A1

公开(公告)日：2007-05-10

申请号：US11506617

申请日：2006-08-17

申请人： Lucien Laude ,  Robert Greenberg

发明人： Lucien Laude ,  Robert Greenberg

IPC分类号： B32B27/20 ,  C08L83/04 ,  B05D1/38

CPC分类号： H05K3/185 ,  C08J7/12 ,  C08J2383/04 ,  C23C18/1608 ,  C23C18/1612 ,  C23C18/1657 ,  C23C18/204 ,  C23C18/206 ,  H05K3/28 ,  H05K3/387 ,  H05K2201/0133 ,  H05K2201/0162 ,  H05K2201/0209 ,  H05K2201/0236 ,  H05K2203/107 ,  H05K2203/1105 ,  Y10T428/26 ,  Y10T428/31663

摘要： The present invention provides a process for embedding at least one layer of at least one metal trace in a silicone-containing polymer, comprising: a) applying a polymer layer on a substrate; b) thermally treating the polymer; c) irradiating at least one surface area of the polymer with a light beam emitted by an excimer laser; d) immersing the irradiated polymer in at least one autocatalytic bath containing ions of at least one metal, and metallizing the polymer; e) thermally treating the metallized polymer; f) applying a polymer layer covering the thermally treated metallized polymer; and g) thermally treating the metallized covered polymer. The present invention further provides a polymer layer comprising silicone containing oxide particles of SiO2, TiO2, Sb2O3, SnO2, Al2O3, ZnO, Fe2O3, Fe3O4, talc, hydroxyapatite or mixtures thereof and at least one metal trace embedded in said polymer layer. The present invention further provides a flexible electrode array comprising silicone containing oxide particles of SiO2, TiO2, Sb2O3, SnO2, A1203, ZnO, Fe2O3, Fe3O4, talc, hydroxyapatite or mixtures thereof and at least one metal trace embedded in said polymer layer.

摘要翻译： 本发明提供了一种在含硅酮聚合物中嵌入至少一层至少一种金属痕迹的方法，包括：a）在基底上施加聚合物层; b）热处理聚合物; c）用由准分子激光器发射的光束照射所述聚合物的至少一个表面积; d）将经辐射的聚合物浸入至少一种含有至少一种金属的离子的自催化浴中，并对该聚合物进行金属化; e）热处理金属化聚合物; f）涂覆覆盖热处理的金属化聚合物的聚合物层; 和g）热处理金属化被覆聚合物。 本发明还提供一种聚合物层，其包含含硅氧烷的SiO 2，TiO 2，Sb 2 O 3， N 2，N 2 O 3，N 2，N 2 O 3， Fe 3 O 3，滑石，羟基磷灰石或其混合物，以及嵌入所述聚合物层中的至少一种金属迹线。 本发明还提供了一种柔性电极阵列，其包括含硅氧烷的SiO 2，TiO 2，Sb 2 O 3， / SUB>，SnO 2，Al 2 O 3，ZnO，Fe 2 O 3， Fe 3 O 3，滑石，羟基磷灰石或其混合物，以及嵌入所述聚合物层中的至少一种金属迹线。