Powder coating of epoxy resin and epoxidized polydiene block polymer
    7.
    发明授权
    Powder coating of epoxy resin and epoxidized polydiene block polymer 失效
    环氧树脂和环氧化聚二烯嵌段聚合物的粉末涂料

    公开(公告)号:US5969043A

    公开(公告)日:1999-10-19

    申请号:US54578

    申请日:1998-04-03

    摘要: An epoxy resin composition for powder coatings which comprises (a) 40 to 95 parts by weight of a solid epoxy resin having at least two epoxy groups in a molecule, an epoxy equivalent of 400 to 2500, and a softening point of 50.degree. C. to 150.degree. C., and (b) 5 to 60 parts by weight of an epoxidized polydiene polymer having a main structure of general Formula (I) in which aliphatic double bonds are partially epoxidized. Formula (I) is(A--B--Ap)n--Yr--(Aq--B)m (I)in which Y is a coupling agent, a monomer for coupling, or an initiator, A is a polymer block selected from a homopolymer block of a conjugated diolefine monomer, a copolymer block of a conjugated diolefine monomer, a copolymer block composed of a conjugated diolefine monomer and an aromatic hydrocarbon monomer having one alkenyl group, B is a polymer block selected from a homopolymer block of an aromatic hydrocarbon monomer having one alkenyl group or a copolymer block thereof, or a copolymer block composed of an aromatic hydrocarbon having one alkenyl group and a conjugated diolefine monomer, n is not less than 0, r is 0 or 1, and m is 0 or more, the total of n and m is 1 to 100, and p and q are 0 or 1).

    摘要翻译: 一种用于粉末涂料的环氧树脂组合物,其包含(a)40至95重量份的分子中具有至少两个环氧基的固体环氧树脂,环氧当量为400至2500,软化点为50℃。 至150℃,和(b)5至60重量份具有通式(I)的主要结构的环氧化聚二烯烃聚合物,其中脂族双键部分环氧化。 式(I)是其中Y是偶联剂,偶联单体或引发剂的(AB-Ap)n-Yr-(Aq-B)m(I),A是选自均聚物嵌段 的共轭二烯单体,共轭二烯单体的共聚物嵌段,由共轭二烯单体和具有一个烯基的芳族烃单体组成的共聚物嵌段,B是选自具有芳族烃单体的均聚物嵌段的聚合物嵌段, 一个烯基或其共聚物嵌段,或由具有一个烯基的芳族烃和共轭二烯单体构成的共聚物嵌段,n不小于0,r为0或1,m为0以上, n和m为1〜100,p和q为0或1)。