公开(公告)号：US11269121B2

公开(公告)日：2022-03-08

申请号：US16071544

申请日：2016-05-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Guanglei Du ,  John A. Wheatley ,  Yi Hang Lv ,  Anthony M. Renstrom ,  Neeraj Sharma ,  Fuguo Xu

IPC: G02B5/26 ,  G02B5/22 ,  G02B5/20 ,  G02B5/28

Abstract: A system may include one or both of a light emitter (46) and a light receiver (40), and an optical filter (10). The optical filter (10) includes a wavelength selective scattering layer (14). The wavelength selective scattering layer (14) may have a near-infrared scattering ratio of less than about 0.9. The filter (10) may have a visible reflective haze ratio of greater than about 0.5. A method may include disposing the wavelength selective scattering layer (14) adjacent one or both of the light emitter (46) and the light receiver (40). The optical filter (10) may include a wavelength selective reflective layer (16). The optical filter (10) may include a wavelength selective absorbing layer (34). An article may include the optical filter (10). The wavelength selective scattering layer (14) may have an average near-infrared scattering of less than 60%, an average visible scattering of greater than 10%, and a difference between the % total visible reflectance and the % diffuse visible reflectance of less than 20.

公开(公告)号：US11034830B2

公开(公告)日：2021-06-15

申请号：US15777686

申请日：2016-12-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jonathan E. Janoski ,  Carla S. Thomas ,  Anthony F. Schultz ,  Tien Y. H. Whiting ,  Kevin M. Lewandowski ,  Duane D. Fansler ,  Keith R. Lyon ,  Arlin L. Weikel ,  Timothy J. Hebrink ,  Amanda K. Hulke ,  Eric D. Shockey ,  Anthony M. Renstrom ,  Sonja S. Mackey ,  Thomas P. Klun

IPC: C08L33/10 ,  B32B27/08 ,  B32B27/30 ,  B32B27/20 ,  B32B27/10 ,  B32B27/32 ,  B32B15/082 ,  B32B27/36 ,  B32B5/02 ,  C08L43/04 ,  B32B15/14 ,  B32B27/06 ,  B32B29/02 ,  B32B15/04 ,  B32B15/12 ,  B32B23/22 ,  B32B5/18 ,  B32B27/40 ,  C08L33/08 ,  B32B27/42 ,  B32B27/28 ,  B32B27/34 ,  B32B23/08 ,  B32B5/24 ,  B32B27/12 ,  B32B23/20 ,  B32B29/00 ,  B32B5/26 ,  B32B7/02 ,  B32B7/12 ,  C08J7/04 ,  C08J5/18 ,  C08L29/14

Abstract: A film is described comprising a first film layer having a Tg ranging from 30° C. to 60° C. The first film layer comprises a (meth)acrylic polymer and polyvinyl acetal polymer composition. The film further comprises a second layer proximate the first film layer. The second layer is different than the first film layer. The second may be a cured (meth)acrylic polymer film or coating; a backing such as thermoplastic polymer, woven or nonwoven fabrics, metal foils, paper, foams; or a coverfilm such as a fluoropolymer.

公开(公告)号：US20150141692A1

公开(公告)日：2015-05-21

申请号：US14503459

申请日：2014-10-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Bryan V. Hunt ,  Kyle J. Lindstrom ,  Judith M. Invie ,  David B. Olson ,  Anthony M. Renstrom

IPC: C07C69/78 ,  C07C69/734 ,  C07C43/23

CPC classification number: G02B1/10 ,  C07C43/23 ,  C07C69/734 ,  C07C69/78 ,  C08F32/06 ,  C08J5/18 ,  C08J2335/02 ,  G02B1/04 ,  G02B5/0231 ,  G02B5/045 ,  G02F1/133504 ,  G02F2001/133507 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/105

Abstract: Optical films are described having a polymerized microstructured surface that comprises the reaction product of a polymerizable resin composition comprising at least one polymerizable ethylenically unsaturated triphenyl monomer. Also described are certain triphenyl (meth)acrylate monomers and polymerizable resin compositions.

Abstract translation: 描述了具有聚合的微结构化表面的光学膜，其包含包含至少一个可聚合烯属不饱和三苯基单体的可聚合树脂组合物的反应产物。 还描述了某些三苯基（甲基）丙烯酸酯单体和可聚合树脂组合物。

公开(公告)号：US20230341615A1

公开(公告)日：2023-10-26

申请号：US17996676

申请日：2021-05-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Bharat R. Acharya ,  Robert D. Taylor ,  Joseph P. Attard ,  Benjamin J. Forsythe ,  David T. Yust ,  Matthew E. Sousa ,  Jason S. Petaja ,  Anthony M. Renstrom ,  William Blake Kolb ,  Matthew S. Cole ,  Matthew S. Stay ,  Matthew R.D. Smith ,  Jeremy O. Swanson ,  Tri D. Pham ,  David A. Rosen ,  Qunyi Chen ,  Lisa A. DeNicola ,  Quinn D. Sanford ,  Carl A. Stover ,  Lin Zhao ,  Gilles J. Benoit

IPC: F21V8/00 ,  G06V40/13

CPC classification number: G02B6/0056 ,  G02B6/0051 ,  G06V40/1318

Abstract: An optical construction includes a reflective polarizer and an optically diffusive film disposed on the reflective polarizer. The reflective polarizer includes an outer layer including a plurality of first particles partially protruding from a first major surface thereof to form a structured major surface. A first optically diffusive layer is conformably disposed on the structured major surface. The optically diffusive film includes a second optically diffusive layer including a plurality of nanoparticles dispersed therein, and a structured layer including a structured major surface. For a substantially normally incident light and a visible wavelength range from about 450 nm to about 650 nm and an infrared wavelength range from about 930 nm to about 970 nm, the second optically diffusive layer has an average specular transmittance Vs in the visible wavelength range and an average specular transmittance Is in the infrared wavelength range, where Is/Vs≥2.5.

公开(公告)号：US20230228919A1

公开(公告)日：2023-07-20

申请号：US17996511

申请日：2021-04-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Matthew E. Sousa ,  Matthew S. Cole ,  Jeremy O. Swanson ,  Bharat R. Acharya ,  Jason S. Petaja ,  Anthony M. Renstrom ,  Tri D. Pham ,  David A. Rosen ,  Qunyi Chen ,  Lisa A. DeNicola ,  Quinn D. Sanford

IPC: G02B5/02 ,  G02B1/04

CPC classification number: G02B5/0242 ,  G02B1/04 ,  G02B2207/101 ,  G02B27/0093

Abstract: Optical films and stacks include at least one optically diffusive layer. The optically diffusive layer can include a plurality of nanoparticles and a polymeric material bonding the nanoparticles to each other to form a plurality of nanoparticle aggregates defining a plurality of voids therebetween. For substantially normally incident light and a visible wavelength range from about 450 nm to about 650 nm and an infrared wavelength range from about 930 nm to about 970 nm: in the visible wavelength range, the optical film or optically diffusive layer has an average specular transmittance Vs; and in the infrared wavelength range, the optical film or optically diffusive layer has an average total transmittance It and an average specular transmittance Is, Is/It≥0.6, Is/Vs≥2.5.

公开(公告)号：US09885807B2

公开(公告)日：2018-02-06

申请号：US14947421

申请日：2015-11-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Bryan V. Hunt ,  Kyle J. Lindstrom ,  Judith M. Invie ,  David B. Olson ,  Anthony M. Renstrom

IPC: C09K19/00 ,  G02B1/04 ,  C08F32/06 ,  G02B1/10 ,  C07C43/23 ,  C07C69/734 ,  C07C69/78 ,  C08J5/18 ,  G02B5/02 ,  G02F1/1335

CPC classification number: G02B1/10 ,  C07C43/23 ,  C07C69/734 ,  C07C69/78 ,  C08F32/06 ,  C08J5/18 ,  C08J2335/02 ,  G02B1/04 ,  G02B5/0231 ,  G02B5/045 ,  G02F1/133504 ,  G02F2001/133507 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/105

Abstract: Optical films are described having a polymerized microstructured surface that comprises the reaction product of a polymerizable resin composition comprising at least one polymerizable ethylenically unsaturated triphenyl monomer. Also described are certain triphenyl (meth)acrylate monomers and polymerizable resin compositions.

公开(公告)号：US20160245962A1

公开(公告)日：2016-08-25

申请号：US15145331

申请日：2016-05-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Bryan V. Hunt ,  Judith M. Invie ,  Anthony M. Renstrom ,  David B. Olson

IPC: G02B5/02 ,  C09D133/16 ,  C09D133/06 ,  G02B1/04

CPC classification number: G02B5/0231 ,  C08F290/06 ,  C08L33/14 ,  C09D4/06 ,  C09D133/06 ,  C09D133/16 ,  G02B1/04 ,  G02B6/0053 ,  Y10T428/24355 ,  Y10T428/264 ,  Y10T428/265

Abstract: Presently described are optical films, such as a brightness enhancing film, having a polymerized microstructured surface disposed on a preformed polymeric film wherein the film has a thickness of no greater than 3 mils and the polymerized microstructured surface consists of the reaction product of a substantially non-brominated polymerizable resin composition.

公开(公告)号：US20150132583A1

公开(公告)日：2015-05-14

申请号：US14404970

申请日：2013-07-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Richard J. Pokorny ,  Steven D. Solomonson ,  Robert F. Kamrath ,  Anthony M. Renstrom ,  Roger W. Barton ,  Craig R. Sykora

IPC: C09D135/02 ,  C09D7/12 ,  C08K3/36

CPC classification number: C09D4/00 ,  C08F2/48 ,  C08F222/1006 ,  C08K3/36 ,  C08K2201/005 ,  C09D7/61 ,  C09D7/67 ,  C09D135/02 ,  G02B1/04 ,  G02B1/14 ,  G03F7/0046 ,  G03F7/0047 ,  G03F7/027 ,  G03F7/0757 ,  G06F3/044 ,  Y10T428/31544

Abstract: Presently described are hardcoat compositions comprising at least one first (meth)acrylate monomer comprising at least three (meth)acrylate groups and C2-C4 alkoxy repeat units wherein the monomer has a molecular weight per (meth)acrylate group ranging from about 220 to 375 g/mole and at least one second (meth)acrylate monomer comprising at least three (meth)acrylate groups. In one embodiment, the hardcoat composition further comprises and at least 30 wt-% solids of silica nanoparticles having an average particle size ranging from 50 to 150 nm. In another embodiment, the hardcoat composition further comprises and at least 30 wt-% solids of inorganic oxide nanoparticles having an average particle size ranging from 50 to 150 nm. Also described are articles, such as protective films, displays, and touch screens comprising such cured hardcoat compositions.

Abstract translation: 目前描述的是包含至少一种包含至少三个（甲基）丙烯酸酯基团和C 2 -C 4烷氧基重复单元的至少一种第一（甲基）丙烯酸酯单体的硬涂层组合物，其中该单体具有约220至375的（甲基）丙烯酸酯基团的分子量 g / mol和至少一种包含至少三个（甲基）丙烯酸酯基团的第（甲基）丙烯酸酯单体。 在一个实施方案中，硬涂层组合物还包含平均粒径为50至150nm的二氧化硅纳米颗粒和至少30重量％的固体。 在另一个实施方案中，硬涂层组合物还包含平均粒度范围为50-150nm的无机氧化物纳米颗粒和至少30重量％的固体。 还描述了诸如保护膜，显示器和包含这种固化的硬涂层组合物的触摸屏的制品。

公开(公告)号：US20130149495A1

公开(公告)日：2013-06-13

申请号：US13759134

申请日：2013-02-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Judith M. Invie ,  Bryan V. Hunt ,  Kyle J. Lindstrom ,  David B. Olson ,  Anthony M. Renstrom ,  Clinton L. Jones

IPC: G02B1/04

CPC classification number: G02B1/04 ,  C08F20/06 ,  C08F20/30 ,  C08F20/38 ,  C08K3/22 ,  C08K2201/011 ,  Y10T428/24355

Abstract: A method of making optical films having a polymerized microstructured surface are described. The polymerized microstructured surface comprises the reaction product of a polymerizable resin composition comprising 10% to 100 wt-% of at least one biphenyl di(meth)acrylate monomer. The di(meth)acrylate monomer comprises a core biphenyl structure having two aromatic rings connected with a C—C bond. The biphenyl di(meth)acrylate monomer preferably comprises a sufficient amount of ortho and/or meta(meth)acrylate substituents such that the monomer is a liquid at 25° C.

Abstract translation: 描述了制造具有聚合的微结构化表面的光学膜的方法。 聚合的微结构表面包含含有10％至100％重量的至少一种二（甲基）丙烯酸联苯酯单体的可聚合树脂组合物的反应产物。 二（甲基）丙烯酸酯单体包括具有两个与C-C键连接的芳环的核心联苯结构。 联苯二（甲基）丙烯酸酯单体优选包含足够量的邻位和/或间位（甲基）丙烯酸酯取代基使得单体在25℃下为液体。

公开(公告)号：US12216298B2

公开(公告)日：2025-02-04

申请号：US17302662

申请日：2021-05-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： John A. Wheatley ,  Guanglei Du ,  David T. Yust ,  Neeraj Sharma ,  Gilles J. Benoit ,  Ellison G. Kawakami ,  Anthony M. Renstrom

IPC: G02B5/20 ,  G02B5/28 ,  G02B5/30

Abstract: An article includes an optical filter that comprises a wavelength selective reflective layer and at least one wavelength selective absorbing layer. The optical filter has visible transmittance between 400 nm-700 nm of less than about 30% and near infrared transmittance at 830 nm-900 nm greater than about 30%.