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公开(公告)号：US06307116B1
公开(公告)日：2001-10-23
申请号：US08490573
申请日：1995-06-15
IPC分类号： C07C502
CPC分类号： B01J23/40 , B01J37/033 , B01J37/036
摘要： A process for preparing a supported catalyst comprising a transition metal selected from palladium, platinum, nickel, cobalt or copper on an aerogel support, which includes the steps of providing a mixture containing an alkoxide precursor of the aerogel, a chelate complex of the transition metal with a chelating agent having Si(OR)3 anchor groups, and an organic solvent in which the chelate complex is soluble; hydrolyzing the mixture by admixing it with water to form a gel; and converting the gel under supercritical conditions into the transition metal aerogel-supported catalyst. The supported catalyst has an especially homogeneous distribution of the metal component and is suitable, for example, for use as a hydrogenation catalyst.
摘要翻译： 一种制备负载型催化剂的方法，该催化剂包含在气凝胶载体上选自钯，铂，镍，钴或铜的过渡金属，其包括以下步骤：提供含有气凝胶的醇盐前体的混合物，过渡金属的螯合络合物 与具有Si（OR）3锚定基团的螯合剂和螯合络合物可溶的有机溶剂; 通过将混合物与水混合以形成凝胶来水解混合物; 并在超临界条件下将凝胶转化为过渡金属气凝胶负载的催化剂。 负载型催化剂具有金属组分特别均匀的分布，并且适用于例如用作氢化催化剂。
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2.发明申请Solid Mineral Composition, Method for Preparing Same and Use Thereof for Reducing Heavy Metals in Flue Gas 有权固体矿物成分，制备方法及其用途，用于减少烟道气中的重金属公开(公告)号：US20120167762A1
公开(公告)日：2012-07-05
申请号：US13383352
申请日：2010-07-13
申请人： Alain Brasseur , Jean-Paul Pirard , Alain Laudet
发明人： Alain Brasseur , Jean-Paul Pirard , Alain Laudet
CPC分类号： B01D53/64 , B01D2251/306 , B01D2251/402 , B01D2251/404 , B01D2251/604 , B01D2251/606 , B01D2257/602 , B01D2258/0283 , B01J20/041 , B01J20/043 , B01J20/046 , B01J20/165 , B01J20/28004 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J2220/42 , B01J2220/56
摘要： The invention relates to a solid mineral composition of heavy metals, in particular mercury, in flue gas, to a method for preparing such a solid mineral compound and to the use thereof for reducing heavy metals, in particular mercury, in flue gas, by placing the flue gas in contact with the solid mineral composition.
摘要翻译： 本发明涉及烟道气中的重金属固体矿物组合物，特别是汞，制备这种固体矿物化合物的方法及其用于减少烟道气中的重金属，特别是汞的用途，通过放置 烟气与固体矿物组合物接触。
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3.发明授权Process for the manufacture of hydrogen peroxide by direct synthesis from hydrogen and oxygen 失效通过从氢气和氧气直接合成制造过氧化氢的方法
公开(公告)号：US5500202A
公开(公告)日：1996-03-19
申请号：US338796
申请日：1994-11-07
CPC分类号： B01J8/0005 , B01J8/02 , C01B15/029 , B01J2208/00061 , B01J2208/00088 , B01J2208/00212 , B01J2208/00539 , B01J2208/00548 , B01J2208/0061
摘要： Process for the manufacture of an aqueous solution of hydrogen peroxide by direct synthesis from hydrogen and oxygen in a three-phase system, according to which hydrogen and oxygen are reacted directly in the gaseous state at the surface of a solid heterogeneous catalyst, the reaction being performed continuously in a reactor with a stationary trickle bed, filled with solid catalyst particles forming the stationary bed through which a liquid consisting of an aqueous solution and the gas phase containing the hydrogen and oxygen are made to trickle concurrently.
摘要翻译： 通过在三相体系中由氢气和氧气直接合成制造过氧化氢水溶液的方法，根据该方法，氢气和氧气在气态下直接在固体多相催化剂的表面反应，反应为 在具有固定滴流床的反应器中连续进行，填充形成固定床的固体催化剂颗粒，使由水溶液组成的液体和含有氢气和氧气的气体同时滴流。
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公开(公告)号：US5538931A
公开(公告)日：1996-07-23
申请号：US258627
申请日：1994-06-10
申请人： Benoit Heinrichs , Jean-Paul Pirard , Rene Pirard
发明人： Benoit Heinrichs , Jean-Paul Pirard , Rene Pirard
IPC分类号： B01J13/00 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/72 , B01J23/75 , B01J23/755 , B01J37/03 , C07B61/00 , C07C5/03 , C07C5/05 , C07C5/09 , C07C9/06 , C07C11/04 , C07C13/18 , C07C209/36 , C07C211/46 , B01J21/08 , B01J21/12
CPC分类号： B01J23/40 , B01J37/033 , B01J37/036
摘要： A process for preparing a supported catalyst comprising a transition metal selected from palladium, platinum, nickel, cobalt or copper on an aerogel support, which includes the steps of providing a mixture containing an alkoxide precursor of the aerogel, a chelate complex of the transition metal with a chelating agent having Si(OR).sub.3 anchor groups, and an organic solvent in which the chelate complex is soluble; hydrolyzing the mixture by admixing it with water to form a gel; and converting the gel under supercritical conditions into the transition metal aerogel-supported catalyst. The supported catalyst has an especially homogeneous distribution of the metal component and is suitable, for example, for use as a hydrogenation catalyst.
摘要翻译： 一种制备负载型催化剂的方法，该催化剂包含在气凝胶载体上选自钯，铂，镍，钴或铜的过渡金属，其包括以下步骤：提供含有气凝胶的醇盐前体的混合物，过渡金属的螯合络合物 与具有Si（OR）3锚定基团的螯合剂和螯合络合物可溶的有机溶剂; 通过将混合物与水混合以形成凝胶来水解混合物; 并在超临界条件下将凝胶转化为过渡金属气凝胶负载的催化剂。 负载型催化剂具有金属组分特别均匀的分布，并且适用于例如用作氢化催化剂。
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公开(公告)号：US20120269696A1
公开(公告)日：2012-10-25
申请号：US13489171
申请日：2012-06-05
CPC分类号： B82Y30/00 , B01J8/003 , B01J8/10 , B01J2208/00212 , B82Y40/00 , C01B32/162 , C01P2004/13
摘要： Method for the manufacture of carbon nanotubes by thermal decomposition of at least one gaseous hydrocarbon (14) in the presence of a solid catalyst in a reactor (4) into which the catalyst is introduced via an inlet lock chamber (17) flushed by an inert gas (21, 22, 25, 26) and from which the carbon nanotubes are withdrawn via an outlet lock chamber (37) which is flushed with a flow of inert gas (39, 40).
摘要翻译： 通过在反应器（4）中的固体催化剂存在下热分解至少一种气态烃（14）来制造碳纳米管的方法，其中通过惰性物质冲洗的入口锁定室（17）引入催化剂 气体（21,22,25,26），并且通过出口锁定室（37）从中排出碳纳米管，该出口锁定室用惰性气体流（39,40）冲洗。
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公开(公告)号：US20070025906A1
公开(公告)日：2007-02-01
申请号：US11196736
申请日：2005-08-04
CPC分类号： B82Y30/00 , B01J8/003 , B01J8/10 , B01J2208/00212 , B82Y40/00 , C01B32/162 , C01P2004/13
摘要： Method for the manufacture of carbon nanotubes by thermal decomposition of at least one gaseous hydrocarbon (14) in the presence of a solid catalyst in a reactor (4) into which the catalyst is introduced via an inlet lock chamber (17) flushed by an inert gas (21, 22, 25, 26) and from which the carbon nanotubes are withdrawn via an outlet lock chamber (37) which is flushed with a flow of inert gas (39, 40).
摘要翻译： 通过在反应器（4）中的固体催化剂存在下热分解至少一种气态烃（14）来制造碳纳米管的方法，其中通过惰性物质冲洗的入口锁定室（17）引入催化剂 气体（21,22,25,26），并且通过出口锁定室（37）从中排出碳纳米管，该出口锁定室用惰性气体流（39,40）冲洗。
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7.发明授权Solid mineral composition, method for preparing same and use thereof for reducing heavy metals in flue gas 有权固体矿物组合物，其制备方法及其用于还原废气中重金属的用途公开(公告)号：US08871006B2
公开(公告)日：2014-10-28
申请号：US13383352
申请日：2010-07-13
申请人： Alain Brasseur , Jean-Paul Pirard , Alain Laudet
发明人： Alain Brasseur , Jean-Paul Pirard , Alain Laudet
CPC分类号： B01D53/64 , B01D2251/306 , B01D2251/402 , B01D2251/404 , B01D2251/604 , B01D2251/606 , B01D2257/602 , B01D2258/0283 , B01J20/041 , B01J20/043 , B01J20/046 , B01J20/165 , B01J20/28004 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J2220/42 , B01J2220/56
摘要： The invention relates to a solid mineral composition of heavy metals, in particular mercury, in flue gas, to a method for preparing such a solid mineral compound and to the use thereof for reducing heavy metals, in particular mercury, in flue gas, by placing the flue gas in contact with the solid mineral composition.
摘要翻译： 本发明涉及烟道气中的重金属固体矿物组合物，特别是汞，制备这种固体矿物化合物的方法及其用于减少烟道气中的重金属，特别是汞的用途，通过放置 烟气与固体矿物组合物接触。
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8.发明申请Solid Inorganic Composition, Method for Preparing Same, and Use Thereof for Reducing Dioxins and Heavy Metals in Flue Gas 审中-公开固体无机组合物，其制备方法及其在烟气中还原二恶英和重金属的用途公开(公告)号：US20120134903A1
公开(公告)日：2012-05-31
申请号：US13383347
申请日：2010-07-13
申请人： Alain Brasseur , Jean-Paul Pirard , Alain Laudet
发明人： Alain Brasseur , Jean-Paul Pirard , Alain Laudet
CPC分类号： B01D53/64 , B01D53/70 , B01D2253/106 , B01D2253/11 , B01D2253/116 , B01D2253/304 , B01D2253/306 , B01D2253/311 , B01D2257/206 , B01D2257/602 , B01J20/0288 , B01J20/046 , B01J20/10 , B01J20/12 , B01J20/28059 , B01J20/28061 , B01J20/28071 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J21/16 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/0201
摘要： The invention relates to a solid inorganic composition for reducing dioxins and furans, as well as heavy metals, in particular mercury, present in flue gases, to a method for preparing such a composition, and to the use thereof for reducing dioxins and furans as well as heavy metals, in particular mercury, present in flue gases, by contacting said flue gases with said solid inorganic composition.
摘要翻译： 本发明涉及用于还原二恶英和呋喃的固体无机组合物，以及存在于烟道气中的重金属，特别是汞，用于制备这种组合物的方法，以及用于还原二恶英和呋喃的用途 作为存在于烟道气中的重金属，特别是汞，通过使所述烟道气与所述固体无机组合物接触。
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9.发明授权Process for the preparation of a catalyst and its use for the conversion of chloroalkanes into alkenes containing less chlorine 失效用于制备催化剂的方法及其用于将氯代烷烃转化为含有较少氯的烯烃的用途
公开(公告)号：US6072096A
公开(公告)日：2000-06-06
申请号：US645330
申请日：1996-05-13
IPC分类号： B01J31/22 , B01J21/06 , B01J23/38 , B01J23/48 , B01J37/03 , C07B61/00 , C07C1/26 , C07C21/04
CPC分类号： B01J23/44 , B01J23/48 , B01J35/006 , B01J37/033 , B01J37/036
摘要： Process for the preparation of a catalyst including a metal of group VIII and a metal of group Ib, according to which the mixture including the alkoxide precursor of an inorganic oxide and complexes including the metals of group VIII and Ib and difunctional complexing compounds including an electron-donor group and a hydrolysable group is hydrolysed in order to form a gel. Process for the conversion of chloroalkanes into alkenes containing less chlorine by means of hydrogen, using such a catalyst.
摘要翻译： 制备包括第VIII族金属和第Ib族金属的催化剂的方法，根据该方法，包括无机氧化物的醇盐前体和包含VIII族和Ib族金属的络合物的混合物和包含电子的二官能络合化合物 - 供体基团和可水解基团被水解以形成凝胶。 使用这种催化剂通过氢将氯代烷烃转化为含有较少氯的烯烃的方法。
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公开(公告)号：US20150099076A1
公开(公告)日：2015-04-09
申请号：US14401100
申请日：2013-05-16
申请人： Dimitri Liquet , Carlos Alberto Paez , Cedric Calberg , David Eskenazi , Jean-Paul Pirard , Benoit Heinrichs
发明人： Dimitri Liquet , Carlos Alberto Paez , Cedric Calberg , David Eskenazi , Jean-Paul Pirard , Benoit Heinrichs
CPC分类号： C23C22/05 , B82Y30/00 , C09D5/03 , C23C18/04 , C23C18/1216 , C23C18/1225 , C23C18/1241 , C23C18/1245 , C23C18/125 , C23C18/1254 , C23C18/127 , C23C18/1279 , C23C18/1283 , C23C18/1295 , C23C22/78 , C23C22/82 , C23C24/082 , Y10T428/1317 , Y10T428/2964
摘要： A process for manufacturing a composite material comprising a functionalization of the substrate, which comprises treatment of said substrate with at least one first alcoholic solvent, functionalization of a first powder and formation of a first colloidal sol of said functionalized first powder in a second solvent, at least one application of a layer of said first colloidal sol of said first powder to the substrate, drying of said layer of said first colloidal sol and formation of a layer of first coating formed by said first colloidal sol, adherent to said substrate, by heating at a temperature above 50° C. and below 500° C.
摘要翻译： 一种制备复合材料的方法，该复合材料包括基材的功能化，其包括用至少一种第一醇溶剂处理所述基材，第一粉末的官能化和在第二溶剂中形成所述官能化的第一粉末的第一胶体溶胶， 将所述第一粉末的所述第一胶体溶胶层的至少一个应用施加到所述基底上，干燥所述第一胶体溶胶层并形成由所述第一胶体溶胶形成的第一涂层，所述第一涂层粘合到所述基底上，通过 在高于50℃和低于500℃的温度下加热
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