摘要:
An aqueous coating composition containing A) one or more water-dilutable polyester polyols having an OH number of from 20 to 300 mg KOH/g and an acid number of from 20 to 80 mg KOH/g, obtained by reacting a) 49 to 40 mol % of a carboxylic acid component containing a1) one or more aliphatic, cycloaliphatic, araliphatic and/or aromatic carboxylic acids with a COOH functionality ≧2 and a2) optionally, aromatic, cycloaliphatic and/or aliphatic monocarboxylic acids with b) 51 to 60 mol % of an alcohol component containing b1) one or more aliphatic, cycloaliphatic and/or araliphatic polyols with Mn of from 62 to 272 g/mol and an average OH functionality ≧2 and b2) optionally, aliphatic, cycloaliphatic and/or araliphatic mono alcohols, B) one or more OH-reactive crosslinkers C) water, D) neutralizing agents and E) optionally solvents, auxiliaries and additives. The aqueous coating compositions can be used for coating metal substrates, such as cans.
摘要:
The present invention relates to inner coatings of metal food containers and packaging and to a process for their production. The coatings are appied to the inside of at least a portion of the surface area of containers that are in direct contact with foods or other consumable products and subsequently cured. The coatings include a) at least one polyisocyanate containing an average of at least two NCO groups per molecule, at least 95% of the NCO groups being blocked with a blocking agent, and b) at least one polyhydroxyl compound containing an average of at least two hydroxyl groups per molecule that react with NCO groups.
摘要:
The present invention relates to aqueous coating compositions containing A) at least one polyisocyanate which contains an average of at least two NCO groups per molecule and in which at least 85% of the NCO groups are blocked with a blocking agent selected from ε-caprolactam and/or a hydroxycarboxylic acid, and B) at least one hydrophilic polyester polyol containing an average of at least two reactive hydroxyl groups per molecule, or a mixture of hydrophilic and non-hydrophilic polyester polyols, wherein component B) has an acid number of ≧15 mg KOH/g, a hydroxyl number of 20 to 300 mg KOH/g and a weight average molecular weight, Mw, of >1500 g/mol, wherein the equivalent ratio between the blocked isocyanate groups of component A) and the isocyanate-reactive groups of component B) is 0.5 to 5.0:1. The present invention also relates to a process for preparing these aqueous coating compositions, to coatings obtained from these aqueous coating compositions, particularly coatings for packaging and for the interior of cans.
摘要:
The invention provides polyisocyanate prepolymers, characterised in that they contain polyether carbonate polyols as structural component, their preparation and their use as isocyanate component in 1- and 2-component systems for surface-coating compositions, adhesives and sealing materials.
摘要:
An aqueous coating composition containing A) one or more water-dilutable polyester polyols having an OH number of from 20 to 300 mg KOH/g and an acid number of from 20 to 80 mg KOH/g, obtained by reacting a) 49 to 40 mol % of a carboxylic acid component containing a1) one or more aliphatic, cycloaliphatic, araliphatic and/or aromatic carboxylic acids with a COOH functionality ≧2 and a2) optionally, aromatic, cycloaliphatic and/or aliphatic monocarboxylic acids with b) 51 to 60 mol % of an alcohol component containing b1) one or more aliphatic, cycloaliphatic and/or araliphatic polyols with Mn of from 62 to 272 g/mol and an average OH functionality ≧2 and b2) optionally, aliphatic, cycloaliphatic and/or araliphatic monoalcohols, B) one or more OH-reactive crosslinkers C) water, D) neutralizing agents and E) optionally solvents, auxiliaries and additives. The aqueous coating compositions can be used for coating metal substrates, such as cans.
摘要:
The present invention relates to inner coatings of metal food containers and packaging and to a process for their production. The coatings are applied to the inside of at least a portion of the surface area of containers that are in direct contact with foods or other consumable products and subsequently cured. The coatings include a) at least one polyisocyanate containing an average of at least two NCO groups per molecule, at least 95% of the NCO groups being blocked with a blocking agent, and b) at least one polyhydroxyl compound containing an average of at least two hydroxyl groups per molecule that react with NCO groups.
摘要:
The present invention relates to a coating composition, a process for its preparation, and to its use for the production of textured coated surfaces on heat-resistant substrates, in which coating composition is based on hydroxyl group-containing binders, cross-linking agents and particular amine compounds.
摘要:
The present invention relates to novel aqueous or water-dilutable blocked polyisocyanates and to their use for the production of one-component polyurethane coating compositions, which are stovable at relatively low temperatures of 130.degree. to 150.degree. C. and provide clear coatings having substantially reduced thermal yellowing.
摘要:
Storage-stable blocked polyisocyanates prepared by reacting one or more polyisocyanates with one or more biuretizing agents and optionally, catalysts such that in the blocked end product there are 5-45 equivalent percent of biuret groups according to formula (I) based on the sum total of all free and blocked NCO groups; optionally modifying the resulting biuret polyisocyanates with the aid of isocyanate-reactive compounds and/or catalysts, with further reaction of free NCO groups; and subsequently blocking at least 95 mol percent of the remaining free NCO groups with a blocking agent according to the formula R1R2NH, where R1 and R2 independently of one another are aliphatic or cycloaliphatic C1-C12 alkyl radicals. The blocked polyisocyanates can be used to make polyurethane polymers and coating compositions, which can be used to coat substrates.
摘要:
Blocked polyisocyanates, their preparation and use in one-component coating materials. In organic polyisocyanates having at least two isocyanate groups, the isocyanate groups are blocked with OH acidic cyclic ketones of the general formula (I). The blocked polyisocyanate system of the invention reacts without elimination of the blocking agent and possesses low crosslinking temperatures.