公开(公告)号：US20160083331A1

公开(公告)日：2016-03-24

申请号：US14891931

申请日：2014-06-11

Applicant: DAICEL CORPORATION

Inventor： Nobuhiko HARADA ,  Ichiro TAKASE

IPC: C07C69/54 ,  C09D4/00 ,  C08F220/18 ,  C07C67/26 ,  C08F222/14

CPC classification number: C07C69/54 ,  C07C67/26 ,  C07C2603/68 ,  C08F220/18 ,  C08F222/14 ,  C09D4/00

Abstract: Provided are: a multifunctional (meth)acrylate compound that has excellent curability and can form a polymer or cured product having hardness and durability at excellent levels; and a method for easily and selectively producing the multifunctional (meth)acrylate compound. The multifunctional (meth)acrylate compound according to the present invention is represented by Formula (1) below. In the formula, Ring Z1 represents a tricyclo[5.2.1.02,6]decane ring, R is selected from a hydrogen atom and a methyl group, and n1 and n2 meet a condition that n1 is 2 or 3 and n2 is 1, or a condition that n1 is 3 or 4 and n2 is 0.

Abstract translation: 提供：具有优异的固化性并可形成具有优异水平的硬度和耐久性的聚合物或固化产物的多官能（甲基）丙烯酸酯化合物; 以及容易且选择性地制造多官能（甲基）丙烯酸酯化合物的方法。 根据本发明的多官能（甲基）丙烯酸酯化合物由下式（1）表示。 在该式中，环Z1表示三环[5.2.1.02,6]癸烷环，R选自氢原子和甲基，n1和n2满足n1为2或3且n2为1的条件，或 n1为3或4，n2为0的条件。

公开(公告)号：US20160297933A1

公开(公告)日：2016-10-13

申请号：US15100733

申请日：2014-11-14

Applicant: DAICEL CORPORATION

Inventor： Akihiro KUWANA ,  Nobuhiko HARADA ,  Maya MASUI ,  Ichiro TAKASE ,  Shinji MAETANI ,  Naoko TSUJI

IPC: C08G77/14 ,  B32B7/12 ,  C09J7/02 ,  C09D183/06 ,  C09J183/06

CPC classification number: C08G77/14 ,  B32B7/12 ,  B32B9/005 ,  B32B9/045 ,  B32B15/08 ,  B32B21/08 ,  B32B27/08 ,  B32B27/10 ,  B32B27/28 ,  B32B27/281 ,  B32B27/283 ,  B32B27/285 ,  B32B27/30 ,  B32B27/302 ,  B32B27/304 ,  B32B27/308 ,  B32B27/325 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B27/38 ,  B32B27/42 ,  B32B29/00 ,  B32B2250/02 ,  B32B2250/03 ,  B32B2250/04 ,  B32B2250/05 ,  B32B2255/26 ,  B32B2307/306 ,  B32B2307/412 ,  B32B2307/536 ,  B32B2307/546 ,  B32B2307/732 ,  B32B2405/00 ,  B32B2457/208 ,  C08G59/24 ,  C08J7/047 ,  C08J2483/06 ,  C08K5/5415 ,  C08L63/00 ,  C08L83/06 ,  C09D183/06 ,  C09J7/20 ,  C09J183/06 ,  C09J2483/00

Abstract: Provided is a polyorganosilsesquioxane capable of forming, when cured, a cured product that offers high surface hardness and good heat resistance, is highly flexible, and has excellent processability. The present invention relates to a polyorganosilsesquioxane including a constitutional unit represented by Formula (1). The polyorganosilsesquioxane includes a constitutional unit represented by Formula (I) and a constitutional unit represented by Formula (II) in a mole ratio of the constitutional unit represented by Formula (I) to the constitutional unit represented by Formula (II) of 5 or more. The polyorganosilsesquioxane has a total proportion of the constitutional unit represented by Formula (1) and a constitutional unit represented by Formula (4) of 55% to 100% by mole based on the total amount (100% by mole) of all siloxane constitutional units. The polyorganosilsesquioxane has a number-average molecular weight of 1000 to 3000 and a molecular-weight dispersity (weight-average molecular weight to number-average molecular weight ratio) of 1.0 to 3.0. [R1SiO3/2]  (1) [Chem. 2] [RaSiO3/2]  (I) [Chem. 3] [RbSiO(ORc)]  (II) [Chem. 4] [R1SiO(ORc)]  (4)

公开(公告)号：US20180282485A1

公开(公告)日：2018-10-04

申请号：US16000313

申请日：2018-06-05

Applicant: DAICEL CORPORATION

Inventor： Akihiro KUWANA ,  Nobuhiko HARADA ,  Maya MASUI ,  Ichiro TAKASE ,  Shinji MAETANI ,  Naoko TSUJI

IPC: C08G77/14 ,  C09D183/06 ,  B32B29/00 ,  B32B27/42 ,  B32B27/38 ,  B32B27/36 ,  B32B27/34 ,  B32B27/32 ,  B32B27/30 ,  B32B27/28 ,  B32B27/08 ,  B32B21/08 ,  B32B15/08 ,  B32B9/04 ,  B32B9/00 ,  C08L63/00 ,  C08G59/24 ,  B32B27/10 ,  C09J7/20 ,  C08K5/5415 ,  B32B7/12 ,  C08J7/04 ,  C08L83/06 ,  C09J183/06

Abstract: Provided is a polyorganosilsesquioxane capable of forming, when cured, a cured product that offers high surface hardness and good heat resistance, is highly flexible, and has excellent processability. The present invention relates to a polyorganosilsesquioxane including a constitutional unit represented by Formula (1). The polyorganosilsesquioxane includes a constitutional unit represented by Formula (I) and a constitutional unit represented by Formula (II) in a mole ratio of the constitutional unit represented by Formula (I) to the constitutional unit represented by Formula (II) of 5 or more. The polyorganosilsesquioxane has a total proportion of the constitutional unit represented by Formula (1) and a constitutional unit represented by Formula (4) of 55% to 100% by mole based on the total amount (100% by mole) of all siloxane constitutional units. The polyorganosilsesquioxane has a number-average molecular weight of 1000 to 3000 and a molecular-weight dispersity (weight-average molecular weight to number-average molecular weight ratio) of 1.0 to 3.0. [R1SiO3/2]  (1) [Chem. 2] [RaSiO3/2]  (I) [Chem. 3] [RbSiO(ORc)]  (II) [Chem. 4] [R1SiO(ORc)]  (4)

公开(公告)号：US20220002494A1

公开(公告)日：2022-01-06

申请号：US17394031

申请日：2021-08-04

Applicant: DAICEL CORPORATION

Inventor： Akihiro KUWANA ,  Nobuhiko HARADA ,  Maya MASUI ,  Ichiro TAKASE ,  Shinji MAETANI ,  Naoko TSUJI

IPC: C08G77/14 ,  C09D183/06 ,  C09J183/06 ,  C08L83/06 ,  C08G59/24 ,  C08L63/00 ,  B32B9/00 ,  B32B9/04 ,  B32B15/08 ,  B32B21/08 ,  B32B27/08 ,  B32B27/28 ,  C08K5/5415 ,  C09J7/20 ,  C08J7/043 ,  C08J7/048 ,  B32B7/12

Abstract: Provided is a polyorganosilsesquioxane capable of forming, when cured, a cured product that offers high surface hardness and good heat resistance, is highly flexible, and has excellent processability. The present invention relates to a polyorganosilsesquioxane including a constitutional unit represented by Formula (1). The polyorganosilsesquioxane includes a constitutional unit represented by Formula (I) and a constitutional unit represented by Formula (II) in a mole ratio of the constitutional unit represented by Formula (I) to the constitutional unit represented by Formula (II) of 5 or more. The polyorganosilsesquioxane has a total proportion of the constitutional unit represented by Formula (1) and a constitutional unit represented by Formula (4) of 55% to 100% by mole based on the total amount (100% by mole) of all siloxane constitutional units. The polyorganosilsesquioxane has a number-average molecular weight of 1000 to 3000 and a molecular-weight dispersity (weight-average molecular weight to number-average molecular weight ratio) of 1.0 to 3.0. [R1SiO3/2]  (1) [Chem. 2] [RaSiO3/2]  (I) [Chem. 3] [RbSiO(ORc)]  (II) [Chem. 4] [R1SiO(ORc)]  (4)

公开(公告)号：US20150275043A1

公开(公告)日：2015-10-01

申请号：US14672635

申请日：2015-03-30

Applicant: DAICEL CORPORATION

Inventor： Shinji KIKUCHI ,  Nobuhiko HARADA

IPC: C09D183/04 ,  C09D7/06 ,  C09D5/00

CPC classification number: C09D183/04 ,  C08G77/14 ,  C09D5/00 ,  C09D5/16 ,  C09D7/47 ,  C09D183/06 ,  Y10T428/31663

Abstract: A curable composition comprises a cationic curable silicone resin and a leveling agent, the cationic curable silicone resin comprises a silsesquioxane unit, has a monomer unit having an epoxy group in a proportion of not less than 50% by mol in a total monomer unit, and has a number average molecular weight of 1000 to 3000.

Abstract translation: 可固化组合物包含阳离子可固化有机硅树脂和流平剂，阳离子可固化硅氧烷树脂包含倍半硅氧烷单元，具有在总单体单元中具有不小于50摩尔％的环氧基的单体单元，以及 数均分子量为1000〜3000。

公开(公告)号：US20180346759A1

公开(公告)日：2018-12-06

申请号：US16056983

申请日：2018-08-07

Applicant: DAICEL CORPORATION

Inventor： Shinji KIKUCHI ,  Nobuhiko HARADA

IPC: C09D183/04 ,  C09D7/47 ,  C09D5/00 ,  C09D183/06 ,  C08G77/14

CPC classification number: C09D183/04 ,  C08G77/14 ,  C09D5/00 ,  C09D5/16 ,  C09D7/47 ,  C09D183/06 ,  Y10T428/31663

Abstract: A shaped product comprising a hardcoat layer, wherein the hardcoat layer is a cured product of a curable composition comprising a cationic curable silicone resin and a leveling agent, the cationic curable silicone resin comprising a silsesquioxane unit, having a monomer unit having an epoxy group in a proportion of not less than 50% by mol in a total monomer unit, and having a number average molecular weight of 1000 to 3000.

公开(公告)号：US20180163049A1

公开(公告)日：2018-06-14

申请号：US15736078

申请日：2016-06-07

Applicant: DAICEL CORPORATION

Inventor： Naoko TSUJI ,  Hiroki TANAKA ,  Akira YAMAKAWA ,  Akihiro SHIBAMOTO ,  Nobuhiko HARADA

IPC: C08L83/06 ,  C08G59/32 ,  C09J7/35 ,  C09J11/04 ,  C09J183/06 ,  B32B7/12 ,  B32B27/28 ,  B32B37/14

CPC classification number: C08L83/06 ,  B32B7/12 ,  B32B27/283 ,  B32B37/142 ,  B32B2037/1253 ,  B32B2250/03 ,  B32B2305/72 ,  B32B2383/00 ,  C08G59/32 ,  C08G77/045 ,  C08G77/14 ,  C08L2205/025 ,  C09J7/20 ,  C09J7/35 ,  C09J11/04 ,  C09J11/06 ,  C09J183/06 ,  C08L83/00

Abstract: Provided is a curable composition having excellent film-formability and can be cured at low temperatures to form a cured product that has heat resistance, cracking resistance, and adhesiveness and adhesion to an adherend at excellent levels. The curable composition according to the present invention is a composition containing polyorganosilsesquioxanes (A). The polyorganosilsesquioxanes (A) include (a-1) an epoxy-containing polyorganosilsesquioxane having a weight-average molecular weight of 3000 or more, and (a-2) an epoxy-containing polyorganosilsesquioxane having a weight-average molecular weight of 2500 or less. The polyorganosilsesquioxanes (A) contain the components (a-1) and (a-2) in a total content of 50 weight percent or more of the total amount of the polyorganosilsesquioxanes (A). The polyorganosilsesquioxanes (A) have a ratio in content (weight ratio) of (a-1) to (a-2) of from 10:90 to 70:30.