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11 条记录 (耗时 0.021 秒)

    Cyclodextrin-silica composite and a method for the preparation thereof
    1.
    发明授权
    Cyclodextrin-silica composite and a method for the preparation thereof 失效
    环糊精 - 二氧化硅复合物及其制备方法

    公开(公告)号：US4781858A

    公开(公告)日：1988-11-01

    申请号：US73766

    申请日：1987-07-15

    申请人： Fujio Mizukami ,  Makoto Toba ,  Shuichi Niwa ,  Sumi Imai

    发明人： Fujio Mizukami ,  Makoto Toba ,  Shuichi Niwa ,  Sumi Imai

    IPC分类号： A61K9/26 ,  C01B33/113 ,  C07B63/02 ,  C08B37/16 ,  C08L5/16 ,  C12N11/14 ,  A01N25/10 ,  B01J13/00 ,  B01J13/02

    CPC分类号： C08B37/0012 ,  C08L5/16 ,  C12N11/14 ,  Y10S514/963 ,  Y10S514/965 ,  Y10T428/2989

    摘要： A mixture of a cyclodextrin and an alkoxy silane compound, e.g., tetraethoxy silane, is admixed with water and an acidic or alkaline catalyst, e.g., acetic acid, to effect ligand exchange and hydrolysis of the alkoxy silane followed by gelation into a gelled mass which is dried and, preferably, leached with water to remove excess of the cyclodextrin. The thus obtained gelled material is a composite having a structure in which the cyclodextrin molecules are incorporated into the matrix of amorphous silica presumably by forming Si-O-C linkages. The composite has characteristics as a combination of the properties of both of the component materials and can expand the applicability of the materials, for example, as a carrier of catalysts and immobilized enzymes, absorbent and adsorbent and so on.

    摘要翻译： 将环糊精和烷氧基硅烷化合物（例如四乙氧基硅烷）的混合物与水和酸性或碱性催化剂（例如乙酸）混合，以实现烷氧基硅烷的配体交换和水解，然后凝胶化成凝胶状物质 干燥，优选用水淋洗以除去过量的环糊精。 由此获得的胶凝材料是具有这样的结构的复合物，其中环糊精分子掺入无定形二氧化硅的基质中，可能通过形成Si-O-C键。 复合材料具有作为两种组分材料的性质的组合的特征，并且可以扩展材料的适用性，例如作为催化剂和固定化酶的载体，吸收剂和吸附剂等。

    Process for preparing cordierite
    4.
    发明授权
    Process for preparing cordierite 失效
    堇青石制备工艺

    公开(公告)号：US5089456A

    公开(公告)日：1992-02-18

    申请号：US606281

    申请日：1990-10-31

    申请人： Kazuyuki Maeda ,  Fujio Mizukami ,  Shuichi Niwa ,  Makoto Toba ,  Kazuo Shimizu

    发明人： Kazuyuki Maeda ,  Fujio Mizukami ,  Shuichi Niwa ,  Makoto Toba ,  Kazuo Shimizu

    IPC分类号： C01B33/26 ,  C04B35/195 ,  C04B35/624 ,  C07F7/02

    CPC分类号： C01B33/26 ,  C04B35/195 ,  C04B35/624

    摘要： A process for preparing a cordierite, which includes dissolving a silicon compound, an aluminum compound and a magnesium compound in a molar ratio of 1:0.7 to 1:0.3 to 0.5 in a complexing agent represented by the formula R(OCH.sub.2 CH.sub.2).sub.n OH, wherein R is an alkyl group and n is an integer of 1 to 4; heating the resulting solution to bring about a ligand exchange reaction of the silicon compound, aluminum compound and magnesium compound with the complexing agent; conducting hydrolysis to form a gel; drying the gel and sintering the dried gel at 800.degree. to 1450.degree. C.

    摘要翻译： 一种制备堇青石的方法，其包括在由式R（OCH 2 CH 2）nOH表示的络合剂中将摩尔比为1:0.7至1:0.3至0.5的硅化合物，铝化合物和镁化合物溶解，其中 R为烷基，n为1〜4的整数。 加热所得溶液以引起硅化合物，铝化合物和镁化合物与络合剂的配体交换反应; 进行水解以形成凝胶; 干燥凝胶并将干燥的凝胶烧结在800°至1450℃。

    Porous inorganic oxide support and hydrotreating catalyst of catalytic cracking gasoline using the same
    5.
    发明授权
    Porous inorganic oxide support and hydrotreating catalyst of catalytic cracking gasoline using the same 有权
    多孔无机氧化物载体和催化裂化汽油加氢处理催化剂使用相同

    公开(公告)号：US07795168B2

    公开(公告)日：2010-09-14

    申请号：US11885414

    申请日：2006-02-28

    申请人： Makoto Toba ,  Yuji Yoshimura ,  Nobuyuki Matsubayashi ,  Takashi Matsui

    发明人： Makoto Toba ,  Yuji Yoshimura ,  Nobuyuki Matsubayashi ,  Takashi Matsui

    IPC分类号： B01J27/20

    CPC分类号： B01J23/882 ,  B01J23/88 ,  B01J27/22 ,  B01J31/0201 ,  B01J35/002 ,  B01J37/0203 ,  C10G2300/104 ,  C10G2400/02

    摘要： A porous inorganic oxide support comprising an oxygen-containing carbonaceous material supported thereon, preferably a porous inorganic oxide support wherein the oxygen-containing carbonaceous material is a carbide of an oxygen-containing organic compound, wherein the ratio of the supported carbon amount with respect to the mass of the support for preparing the catalyst is from 0.05 to 0.2, the atomic ratio of the supported hydrogen amount with respect to the supported carbon amount is from 0.4 to 1.0, and the atomic ratio of the supported oxygen amount with respect to the supported carbon amount is from 0.1 to 0.6; and a hydrotreating catalyst of catalytic cracking gasoline which comprises the support and a catalyst containing a Group 8 metal of the periodic table, molybdenum (Mo), phosphorus and sulfur which is supported on the support are useful as a desulfurization catalyst of, for example, catalytic cracking gasoline at a hyperdesulfurized level, because of having functions of suppressing the hydrogenation activity of olefins and minimizing the decrease in the octane number even under reaction conditions with a high desulfurization ratio.

    摘要翻译： 一种多孔无机氧化物载体，其包含负载在其上的含氧碳质材料，优选多孔无机氧化物载体，其中所述含氧碳质材料是含氧有机化合物的碳化物，其中所述负载碳量相对于 用于制备催化剂的载体的质量为0.05至0.2，负载氢量相对于负载碳量的原子比为0.4至1.0，并且负载氧量相对于负载的碳原子比 碳量为0.1〜0.6; 和催化裂化汽油的加氢处理催化剂，其包含载体和含有周期表第8族金属的催化剂，负载在载体上的钼（Mo），磷和硫，可用作例如脱硫催化剂， 催化裂化汽油处于高脱硫水平，因为即使在高脱硫比的反应条件下也具有抑制烯烃的氢化活性和最小化辛烷值降低的作用。

    HYDROGENATION METHOD AND PETROCHEMICAL PROCESS
    6.
    发明申请
    HYDROGENATION METHOD AND PETROCHEMICAL PROCESS 审中-公开
    氢化方法和石油化工过程

    公开(公告)号：US20100087692A1

    公开(公告)日：2010-04-08

    申请号：US12531454

    申请日：2008-04-14

    申请人： Yuuji Yoshimura ,  Makoto Toba ,  Yasuo Miki ,  Masako Miki ,  Shigeru Hatanaka ,  Tetsuo Kudo ,  Tetsuo Nakajo

    发明人： Yuuji Yoshimura ,  Makoto Toba ,  Yasuo Miki ,  Masako Miki ,  Shigeru Hatanaka ,  Tetsuo Kudo ,  Tetsuo Nakajo

    IPC分类号： C07C5/32 ,  C07C5/02

    CPC分类号： C10G45/44 ,  C10G9/00 ,  C10G9/14 ,  C10G45/00 ,  C10G45/52 ,  C10G45/54 ,  C10G65/04 ,  C10G69/06 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2400/20 ,  C10G2400/30

    摘要： The present invention provides a hydrogenation method capable of converting cracked kerosene into the raw materials for petrochemical cracking having a high thermal decomposition yield by a hydrogenation reaction. The present invention is a petrochemical process for producing at least any of ethylene, propylene, butane, benzene or toluene by carrying out a thermal decomposition reaction at least using naphtha for the main raw material, wherein cracked kerosene produced from a thermal cracking furnace is hydrogenated using a Pd or Pt catalyst in a two-stage method consisting of a first stage (I), in which a hydrogenation reaction is carried out within the range of 50 to 180° C., and a second stage (II), in which a hydrogenation reaction is carried out within the range of 230 to 350° C., followed by re-supplying all or a portion of these hydrogenated hydrocarbons to a thermal cracking furnace.

    摘要翻译： 本发明提供一种氢化方法，其能够将裂解的煤油转化为通过氢化反应具有高热分解产率的石化裂化原料。 本发明是通过对主要原料至少使用石脑油进行热分解反应来制造乙烯，丙烯，丁烷，苯或甲苯中的至少任一种的石油化学方法，其中由热裂解炉生产的裂解煤油被氢化 使用由第一阶段（I）组成的两阶段方法的Pd或Pt催化剂，其中氢化反应在50至180℃的范围内进行，第二阶段（II），其中 氢化反应在230〜350℃的范围内进行，然后将全部或部分氢化烃再供给热裂解炉。

    METHOD FOR PRODUCING BIODEISEL FUEL AND BIODEISEL FUEL COMPOSITION
    8.
    发明申请
    METHOD FOR PRODUCING BIODEISEL FUEL AND BIODEISEL FUEL COMPOSITION 有权
    生物柴油燃料和生物柴油燃料组合物的生产方法

    公开(公告)号：US20130055625A1

    公开(公告)日：2013-03-07

    申请号：US13580430

    申请日：2011-02-18

    申请人： Makoto Toba ,  Yuji Yoshimura ,  Yoko Abe

    发明人： Makoto Toba ,  Yuji Yoshimura ,  Yoko Abe

    IPC分类号： C07C51/36 ,  C22C5/00 ,  C22C5/04 ,  C10L1/188 ,  B01J23/40

    CPC分类号： B01J23/44 ,  B01J23/40 ,  B01J29/068 ,  B01J29/126 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/18 ,  B01J2229/18 ,  B01J2229/42 ,  C10G3/47 ,  C10G3/50 ,  C10L1/026 ,  C10L1/08 ,  C11C3/003 ,  C11C3/126 ,  Y02E50/13 ,  Y02P30/20

    摘要： Provided is a method for producing biodiesel fuel having an excellent oxidative stability and fluidity at low temperature, wherein the method provides selective hydrogenation of a poly-unsaturated fatty acid alkyl ester to the mono-unsaturated fatty acid alkyl ester while inhibiting the formation of the trans-isomer, and a biodiesel fuel composition. In the method for producing biodiesel fuel, a fatty acid alkyl ester prepared from fat and/or waste edible oil by transesterification reaction, and/or (2) a fatty acid alkyl ester treated by esterification reaction of a fatty acid is hydrogenated in the presence of a hydrogenation catalyst containing at least one of noble metals selected from those of Groups 8-10 in the periodic table under low hydrogen pressure.

    摘要翻译： 本发明提供了一种在低温下具有优异的氧化稳定性和流动性的生物柴油燃料的方法，其中该方法提供了将多不饱和脂肪酸烷基酯选择性氢化成单不饱和脂肪酸烷基酯，同时抑制反式 异构体和生物柴油燃料组合物。 在生产生物柴油燃料的方法中，通过酯交换反应由脂肪和/或废食用油制备的脂肪酸烷基酯和/或（2）通过脂肪酸酯化反应处理的脂肪酸烷基酯在存在下氢化 的氢化催化剂，其在低氢压下含有选自元素周期表第8-10族的贵金属中的至少一种。