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公开(公告)号：US06265205B1
公开(公告)日：2001-07-24
申请号：US09013729
申请日：1998-01-27
IPC分类号： C12S1300
CPC分类号： C12P5/02 , B09C1/08 , B09C1/10 , Y02E50/343
摘要： This invention is a novel method for bioremediation of soil and ground water based on supplying hydrogen (H2) to naturally occurring anaerobic bacteria in the soil or ground water. These organisms use the hydrogen as an electron donor to perform adventitious chemical reactions including the dehalogenation of chlorinated organic compounds. The hydrogen can be supplied from a number of sources, including; stored hydrogen, hydrogen generated above ground on site, either electrochemically or by reforming a fuel source, or by electrolysis in the soil, either using an electric current supplied from above ground or an electric current generated by the corrosion of metal particles in the ground. For the last of these cases, a novel multi-metallic particle especially useful for the generation of hydrogen, and a method for making these particles, are disclosed.
摘要翻译： 本发明是一种基于向土壤或地下水中的天然存在的厌氧细菌供应氢（H2）的土壤和地下水生物修复的新方法。 这些生物体使用氢作为电子给体来进行不定期的化学反应，包括氯化有机化合物的脱卤。 氢可以从许多来源提供，包括： 储存的氢气，现场地面上产生的氢气，电化学或通过燃料源重整，或通过土壤中的电解，使用从地面提供的电流或由地下金属颗粒的腐蚀产生的电流。 对于这些情况中的最后一种，公开了特别可用于产生氢的新型多金属颗粒和制造这些颗粒的方法。
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2.发明授权Method of manufacturing passive elements using conductive polypyrrole formulations 失效使用导电聚吡咯制剂制造无源元件的方法
公开(公告)号：US5948232A
公开(公告)日：1999-09-07
申请号：US881107
申请日：1997-06-23
申请人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
发明人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
IPC分类号： C08G61/12 , C23C26/00 , C25D5/54 , G03F7/004 , G03F7/027 , H01B1/12 , H01C7/00 , H01C17/242 , H01G9/02 , H01G9/025 , H05K1/09 , H05K1/16 , H05K3/10 , H05K3/42 , H05K9/00 , C25D5/02 , B05D3/02 , C08F2/48
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C25D5/54 , G03F7/0045 , G03F7/027 , H01B1/12 , H01C17/242 , H01C7/005 , H05K1/167 , H05K1/095 , H05K1/162 , H05K1/165 , H05K2201/0329 , H05K2203/0514 , H05K3/105 , H05K3/424
摘要： The present invention provides electronically conducting polymer films formed from formulations of pyrrole and an electron acceptor. The formulations may include photoinitiators, flexibilizers, solvents and the like. These formulations can be used to manufacture multichip modules on typical multichip module substrates, such as alumina, fiberglass epoxy, silicon and polyimide. The formulations and methods of the invention enable the formation of passive electronic circuit elements such as resistors, capacitors and inductors in multichip modules or printed wiring boards.
摘要翻译： 本发明提供由吡咯和电子受体的制剂形成的电子导电聚合物膜。 制剂可以包括光引发剂，柔韧剂，溶剂等。 这些配方可用于在典型的多芯片模块衬底（例如氧化铝，玻璃纤维环氧树脂，硅和聚酰亚胺）上制造多芯片模块。 本发明的配方和方法能够在多芯片模块或印刷电路板中形成无源电子电路元件，例如电阻器，电容器和电感器。
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3.发明授权Method of forming electronically conducting polymers on conducting and nonconducting substrates 失效在导电和非导电基材上形成电子导电聚合物的方法公开(公告)号：US06210537B1
公开(公告)日：2001-04-03
申请号：US08492235
申请日：1995-06-19
申请人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
发明人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
IPC分类号： C07C100
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C7/005 , H01C17/242 , H05K1/095 , H05K1/16 , H05K1/162 , H05K1/165 , H05K1/167 , H05K3/105 , H05K3/185 , H05K3/188 , H05K9/0081 , H05K2201/0329 , H05K2203/0514
摘要： The present invention provides electronically conducting polymer films formed from photosensitive formulations of pyrrole and an electron acceptor that have been selectively exposed to UV light, laser light, or electron beams. The formulations may include photoinitiators, flexibilizers, solvents and the like. These solutions can be used in applications including printed circuit boards and through-hole plating and enable direct metallization processes on non-conducting substrates. After forming the conductive polymer patterns, a printed wiring board can be formed by sensitizing the polymer with palladium and electrolytically depositing copper.
摘要翻译： 本发明提供了由已经选择性地暴露于紫外光，激光或电子束的吡咯和电子受体的光敏剂形成的电子导电聚合物膜。 制剂可以包括光引发剂，柔韧剂，溶剂等。 这些解决方案可用于包括印刷电路板和通孔电镀在内的应用，并可在非导电基板上进行直接金属化处理。 在形成导电聚合物图案之后，可以通过使用钯和电沉积铜使聚合物敏化来形成印刷线路板。
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4.发明授权Stable powders made from photosensitive polycrystalline complexes of heterocyclic monomers and their polymers 失效由杂环单体的光敏多晶配合物及其聚合物制成的稳定粉末
公开(公告)号：US5859085A
公开(公告)日：1999-01-12
申请号：US787270
申请日：1997-01-24
IPC分类号： C08F2/48 , C08G61/12 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C7/00 , H01C17/242 , H01G9/02 , H01G9/025 , H05K1/09 , H05K1/16 , H05K3/10 , H05K3/18 , H05K3/42 , H05K9/00 , C08G73/06
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C17/242 , H01C7/005 , H05K1/095 , H05K1/16 , H05K1/167 , H05K3/185 , H05K3/188 , H05K9/0083 , H05K1/162 , H05K1/165 , H05K2201/0329 , H05K2203/0514 , H05K3/105 , H05K3/424
摘要： The present invention relates to a low electronic conductivity polymer composition having well dispersed metal granules, a stable powder made from photosensitive polycrystalline complexes of pyrrole, or its substituted derivatives and silver cations for making the polymer composition, and methods of forming the stable powder and polymer composition, respectively. A polycrystalline complex of silver and a monomer, such as pyrrole, its substituted derivatives or combinations thereof, is precipitated in the form of a stable photosensitive powder upon addition of the monomer to a solvent solution, such as toluene containing an electron acceptor. The photosensitive powder can be stored in the dark until needed. The powder may be dissolved in a solvent, cast onto a substrate and photopolymerized.
摘要翻译： 本发明涉及具有良好分散的金属颗粒的低电子导电性聚合物组合物，由吡咯的光敏多晶配合物制成的稳定的粉末或其取代的衍生物和用于制备聚合物组合物的银阳离子，以及形成稳定的粉末和聚合物的方法 组成。 当将单体添加到溶剂溶液（例如含有电子受体的甲苯）时，银和单体如吡咯，其取代的衍生物或其组合的多晶复合物以稳定的感光性粉末的形式沉淀。 光敏粉末可以在黑暗中储存，直至需要。 粉末可以溶解在溶剂中，浇铸到基材上并进行光聚合。
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5.发明授权Method of manufacturing passive elements using conductive polypyrrole formulations 失效使用导电聚吡咯制剂制造无源元件的方法
公开(公告)号：US5855755A
公开(公告)日：1999-01-05
申请号：US630063
申请日：1996-04-12
申请人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
发明人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
IPC分类号： C08F2/48 , C08G61/12 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C7/00 , H01C17/242 , H01G9/02 , H01G9/025 , H05K1/09 , H05K1/16 , H05K3/10 , H05K3/18 , H05K3/42 , H05K9/00 , C25D5/02 , B21F41/00
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C17/242 , H01C7/005 , H05K1/095 , H05K1/16 , H05K1/167 , H05K3/105 , H05K3/185 , H05K3/188 , H05K9/0083 , H05K1/162 , H05K1/165 , H05K2201/0329 , H05K2203/0514 , H05K3/424 , Y10T29/417
摘要： The present invention provides electronically conducting polymer films formed from photosensitive formulations of pyrrole and an electron acceptor that have been selectively exposed to UV light, laser light, or electron beams. The formulations may include photoinitiators, flexibilizers, solvents and the like. These formulations can be used to manufacture multichip modules on typical multichip module substrates, such as alumina, fiberglass epoxy, silicon and polyimide. The formulations and methods of the invention enable the formation of passive electronic circuit elements such as resistors, capacitors and inductors in multichip modules or printed wiring boards.
摘要翻译： 本发明提供了由已经选择性地暴露于紫外光，激光或电子束的吡咯和电子受体的光敏剂形成的电子导电聚合物膜。 制剂可以包括光引发剂，柔韧剂，溶剂等。 这些配方可用于在典型的多芯片模块衬底（例如氧化铝，玻璃纤维环氧树脂，硅和聚酰亚胺）上制造多芯片模块。 本发明的配方和方法能够在多芯片模块或印刷电路板中形成无源电子电路元件，例如电阻器，电容器和电感器。
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6.发明授权
公开(公告)号：US5545308A
公开(公告)日：1996-08-13
申请号：US491625
申请日：1995-06-19
申请人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
发明人： Oliver J. Murphy , G. Duncan Hitchens , Dalibor Hodko , Eric T. Clarke , David L. Miller , Donald L. Parker
IPC分类号： C08G61/12 , C23C26/00 , C23C28/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C7/00 , H01C17/242 , H01G9/02 , H01G9/025 , H05K1/16 , H05K3/10 , H05K3/18 , H05K3/42 , H05K9/00 , C25D5/02
CPC分类号： H01G9/025 , C08G61/124 , C23C26/00 , C23C28/00 , C25D5/54 , G03F7/027 , H01B1/12 , H01C17/242 , H01C7/005 , H05K1/16 , H05K1/167 , H05K3/188 , H05K1/162 , H05K1/165 , H05K2201/0329 , H05K2203/0514 , H05K3/105 , H05K3/424
摘要： The present invention provides electronically conducting polymer films formed from photosensitive formulations of pyrrole and an electron acceptor that have been selectively exposed to UV light, laser light, or electron beams. The formulations may include photoinitiators, flexibilizers, solvents and the like. These solutions can be used in applications including printed circuit boards and through-hole plating and enable direct metallization processes on non-conducting substrates. After forming the conductive polymer patterns, a printed wiring board can be formed by sensitizing the polymer with palladium and electrolytically depositing copper.
摘要翻译： 本发明提供了由已经选择性地暴露于紫外光，激光或电子束的吡咯和电子受体的光敏剂形成的电子导电聚合物膜。 制剂可以包括光引发剂，柔韧剂，溶剂等。 这些解决方案可用于包括印刷电路板和通孔电镀在内的应用，并可在非导电基板上进行直接金属化处理。 在形成导电聚合物图案之后，可以通过使用钯和电沉积铜使聚合物敏化来形成印刷线路板。
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公开(公告)号：US5916505A
公开(公告)日：1999-06-29
申请号：US806785
申请日：1997-02-26
IPC分类号： B01D53/22 , B01D53/32 , B01F3/02 , B01J8/00 , B01J19/24 , C02F1/00 , C02F1/32 , C02F1/461 , C02F1/467 , C02F1/78 , C25B1/13 , C25B1/30 , C25B9/08 , C25B13/02 , H01M8/02 , H01M8/04 , H01M8/10 , H01M8/18 , B29C43/00
CPC分类号： C25B1/30 , B01D53/22 , B01D53/326 , B01F3/022 , B01J19/2475 , B01J8/009 , C02F1/4618 , C02F1/4672 , C02F1/78 , C25B1/13 , C25B13/02 , C25B9/08 , H01M8/0289 , H01M8/1007 , H01M8/1023 , H01M8/1039 , H01M8/1065 , H01M8/1067 , B01J2208/00061 , B01J2208/00132 , B01J2208/00256 , B01J2208/00539 , B01J2208/00584 , B01J2219/00063 , B01J2219/00081 , B01J2219/00099 , B01J2219/00103 , B01J2219/00162 , B01J2219/00171 , C02F1/32 , C02F2001/46128 , C02F2001/46142 , C02F2001/46166 , C02F2101/30 , C02F2201/46115 , C02F2201/46195 , C02F2201/782 , C02F2303/04 , C02F2305/023 , H01M2300/0082 , H01M8/0202 , H01M8/04291 , H01M8/186 , Y02C20/30 , Y02E60/528 , Y02P70/56
摘要： The invention provides in improved proton exchange membrane for use in electrochemical cells having internal passages parallel to the membrane surface, an apparatus and process for making the membrane, membrane and electrode assemblies fabricated using the membrane, and the application of the membrane and electrode assemblies to a variety of devices, both electrochemical and otherwise. The passages in the membrane extend from one edge of the membrane to another and allow fluid flow through the membrane and give access directly to the membrane for purposes of hydration.
摘要翻译： 本发明提供了用于电化学电池的改进的质子交换膜，其具有平行于膜表面的内部通道，用于制造使用膜制造膜，膜和电极组件的装置和工艺，以及将膜和电极组件应用于 各种器件，电化学和其他。 膜中的通道从膜的一个边缘延伸到另一个边缘，并允许流体流过膜并且直接进入膜以获得水合的目的。
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8.发明授权Membrane with internal passages to permit fluid flow and an electrochemical cell containing the same 失效具有允许流体流动的内部通道的膜和包含该流体的电化学电池
公开(公告)号：US5635039A
公开(公告)日：1997-06-03
申请号：US344813
申请日：1994-11-23
IPC分类号： B01D53/22 , B01D53/32 , B01F3/02 , B01J8/00 , B01J19/24 , C02F1/00 , C02F1/32 , C02F1/461 , C02F1/467 , C02F1/78 , C25B1/13 , C25B1/30 , C25B9/08 , C25B13/02 , H01M8/02 , H01M8/04 , H01M8/10 , H01M8/18 , C25B1/00
CPC分类号： C25B1/30 , B01D53/22 , B01D53/326 , B01F3/022 , B01J19/2475 , B01J8/009 , C02F1/4618 , C02F1/4672 , C02F1/78 , C25B1/13 , C25B13/02 , C25B9/08 , H01M8/0289 , H01M8/1007 , H01M8/1023 , H01M8/1039 , H01M8/1065 , H01M8/1067 , B01J2208/00061 , B01J2208/00132 , B01J2208/00256 , B01J2208/00539 , B01J2208/00584 , B01J2219/00063 , B01J2219/00081 , B01J2219/00099 , B01J2219/00103 , B01J2219/00162 , B01J2219/00171 , C02F1/32 , C02F2001/46128 , C02F2001/46142 , C02F2001/46166 , C02F2101/30 , C02F2201/46115 , C02F2201/46195 , C02F2201/782 , C02F2303/04 , C02F2305/023 , H01M2300/0082 , H01M8/0202 , H01M8/04291 , H01M8/186 , Y02C20/30 , Y02E60/528 , Y02P70/56
摘要： The invention provides an improved proton exchange membrane for use in electrochemical cells having internal passages parallel to the membrane surface, an apparatus and process for making the membrane, membrane and electrode assemblies fabricated using the membrane, and the application of the membrane and electrode assemblies to a variety of devices, both electrochemical and otherwise. The passages in the membrane extend from one edge of the membrane to another and allow fluid flow through the membrane and give access directly to the membrane for purposes of hydration.
摘要翻译： 本发明提供了一种用于电化学电池的改进的质子交换膜，其具有平行于膜表面的内部通道，用于制造使用膜制造膜，膜和电极组件的装置和方法，以及将膜和电极组件应用于 各种器件，电化学和其他。 膜中的通道从膜的一个边缘延伸到另一个边缘，并允许流体流过膜并且直接进入膜以获得水合的目的。
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9.发明授权公开(公告)号：US06183623B2
公开(公告)日：2001-02-06
申请号：US09034527
申请日：1998-03-03
IPC分类号： C25B124
CPC分类号： C25B1/26 , B01D53/22 , B01D53/326 , B01F3/022 , B01J8/009 , B01J19/2475 , B01J2208/00061 , B01J2208/00132 , B01J2208/00256 , B01J2208/00539 , B01J2208/00584 , B01J2219/00063 , B01J2219/00081 , B01J2219/00099 , B01J2219/00103 , B01J2219/00162 , B01J2219/00171 , C02F1/32 , C02F1/4618 , C02F1/4672 , C02F1/78 , C02F2001/46128 , C02F2001/46142 , C02F2001/46166 , C02F2101/12 , C02F2101/30 , C02F2201/46115 , C02F2201/782 , C02F2303/04 , C02F2305/023 , C25B1/24 , C25B9/08 , C25B9/206 , H01M4/8605 , H01M4/9083 , H01M4/92 , H01M8/0202 , H01M8/04291 , H01M8/1007 , H01M8/186 , H01M2300/0082 , Y02E60/528 , Y02P70/56
摘要： The invention relates to a process for electrochemically converting anhydrous hydrogen halide, such as hydrogen chloride, hydrogen fluoride, hydrogen bromide and hydrogen iodide, to essentially dry halogen gas, such as chlorine, fluorine, bromine and iodine gas, respectively. In a preferred embodiment, the present invention relates to a process for electrochemically converting anhydrous hydrogen chloride to essentially dry chlorine gas. This process allows the production of high-purity chlorine gas. In this process, molecules of essentially anhydrous hydrogen chloride are transported through an inlet of an electrochemical cell. The molecules of the essentially anhydrous hydrogen chloride are oxidized at the anode of the cell to produce essentially dry chlorine gas and protons, which are transported through the membrane of the cell. The transported protons are reduced at the cathode to form either hydrogen gas, water or hydrogen peroxide.
摘要翻译： 本发明涉及一种将无水卤化氢如氯化氢，氟化氢，溴化氢和碘化氢电化学转化成基本上干燥的卤素气体如氯，氟，溴和碘气的方法。 在优选的实施方案中，本发明涉及将无水氯化氢电化学转化为基本上干氯气的方法。 这个过程允许生产高纯度氯气。 在该过程中，基本上无水氯化氢的分子通过电化学电池的入口输送。 基本上无水氯化氢的分子在电池的阳极被氧化，以产生基本上干的氯气和质子，其被输送通过电池的膜。 输送的质子在阴极处还原，形成氢气，水或过氧化氢。
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公开(公告)号：US6149810A
公开(公告)日：2000-11-21
申请号：US9061
申请日：1998-01-20
申请人： Anuncia Gonzalez-Martin , Carlos E. Salinas , Alan J. Cisar , G. Duncan Hitchens , Oliver J. Murphy
发明人： Anuncia Gonzalez-Martin , Carlos E. Salinas , Alan J. Cisar , G. Duncan Hitchens , Oliver J. Murphy
IPC分类号： B01D53/22 , B01D53/32 , B01F3/02 , B01J8/00 , B01J19/24 , C02F1/461 , C02F1/467 , C02F1/78 , C25B1/13 , C25B9/08 , C25B13/02 , H01M8/02 , H01M8/04 , H01M8/10 , H01M8/18 , B01D69/06 , B01D71/40
CPC分类号： H01M8/1065 , B01D53/22 , B01D53/326 , B01F3/022 , B01J19/2475 , B01J8/009 , C02F1/4618 , C02F1/4672 , C02F1/78 , C25B1/13 , C25B13/02 , C25B9/08 , H01M8/1007 , H01M8/1023 , H01M8/1039 , B01J2219/00162 , C02F2001/46128 , C02F2001/46142 , C02F2001/46166 , C02F2101/30 , C02F2201/46115 , C02F2201/46195 , C02F2201/782 , C02F2303/04 , H01M2300/0082 , H01M8/0202 , H01M8/04291 , H01M8/186 , Y02C20/30 , Y02E60/528 , Y02P70/56
摘要： The invention provides an improved proton exchange membrane for use in electrochemical cells having internal passages parallel to the membrane surface comprising permanent tubes preferably placed at the ends of the fluid passages. The invention also provides an apparatus and process for making the membrane, membrane and electrode assemblies fabricated using the membrane, and the application of the membrane and electrode assemblies to a variety of devices, both electrochemical and otherwise. The passages in the membrane extend from one edge of the membrane to another and allow fluid flow through the membrane and give access directly to the membrane.
摘要翻译： 本发明提供了一种用于电化学电池的改进的质子交换膜，其具有平行于膜表面的内部通道，其包括优选放置在流体通道端部的永久管。 本发明还提供了一种用于制造使用膜制造的膜，膜和电极组件的装置和方法，以及将膜和电极组件应用于电化学和其它装置的各种装置。 膜中的通道从膜的一个边缘延伸到另一个边缘，并允许流体流过膜并且允许直接进入膜。
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