公开(公告)号：US10833019B2

公开(公告)日：2020-11-10

申请号：US16668409

申请日：2019-10-30

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  GlobalFoundries, Inc.

Inventor： Takashi Ando ,  Hiroaki Niimi ,  Tenko Yamashita

IPC: H01L29/78 ,  H01L23/535 ,  H01L27/092 ,  H01L21/8238 ,  H01L21/02 ,  H01L21/768 ,  H01L29/51 ,  H01L23/485 ,  H01L21/285 ,  H01L29/66

Abstract: A method of making a semiconductor device includes forming a first source/drain trench and a second source/drain trench over a first and second source/drain region, respectively; forming a first silicon dioxide layer in the first source/drain trench and a second silicon dioxide layer in the second source/drain trench; forming a first source/drain contact over the first source/drain region, the first source/drain contact including a first tri-layer contact disposed between the first silicon dioxide layer and a first conductive material; and forming a second source/drain contact over the second source/drain region, the second source/drain contact including a second tri-layer contact disposed between the second silicon dioxide layer and a second conductive material; wherein the first tri-layer contact includes a first metal oxide layer in contact with the first silicon dioxide layer, and the second tri-layer contact includes a second metal oxide layer in contact with the second silicon dioxide layer.

公开(公告)号：US10361281B2

公开(公告)日：2019-07-23

申请号：US15911892

申请日：2018-03-05

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  GLOBALFOUNDRIES Inc.

Inventor： Takashi Ando ,  Eduard A. Cartier ,  Kisik Choi ,  Vijay Narayanan

IPC: H01L21/02 ,  H01L21/28 ,  H01L29/66 ,  H01L21/321 ,  H01L21/324 ,  H01L29/423 ,  H01L21/3205

Abstract: A method of fabricating a replacement gate stack for a semiconductor device includes the following steps after removal of a dummy gate: growing a high-k dielectric layer over the area vacated by the dummy gate; depositing a thin metal layer over the high-k dielectric layer; depositing a sacrificial layer over the thin metal layer; performing a first rapid thermal anneal; removing the sacrificial layer; and depositing a metal layer of low resistivity metal for gap fill.

公开(公告)号：US20180197972A1

公开(公告)日：2018-07-12

申请号：US15911892

申请日：2018-03-05

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  GLOBALFOUNDRIES Inc.

Inventor： Takashi Ando ,  Eduard A. Cartier ,  Kisik Choi ,  Vijay Narayanan

IPC: H01L29/66 ,  H01L21/02 ,  H01L21/3205 ,  H01L21/324 ,  H01L21/28 ,  H01L29/423 ,  H01L21/321

CPC classification number: H01L29/66795 ,  H01L21/02532 ,  H01L21/02592 ,  H01L21/02595 ,  H01L21/28017 ,  H01L21/28088 ,  H01L21/32055 ,  H01L21/321 ,  H01L21/324 ,  H01L29/4232 ,  H01L29/66 ,  H01L29/66545 ,  H01L29/6681

Abstract: A method of fabricating a replacement gate stack for a semiconductor device includes the following steps after removal of a dummy gate: growing a high-k dielectric layer over the area vacated by the dummy gate; depositing a thin metal layer over the high-k dielectric layer; depositing a sacrificial layer over the thin metal layer; performing a first rapid thermal anneal; removing the sacrificial layer; and depositing a metal layer of low resistivity metal for gap fill.

公开(公告)号：US09960252B2

公开(公告)日：2018-05-01

申请号：US15258597

申请日：2016-09-07

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  GLOBALFOUNDRIES Inc.

Inventor： Takashi Ando ,  Eduard A. Cartier ,  Kisik Choi ,  Vijay Narayanan

IPC: H01L21/3205 ,  H01L29/66 ,  H01L21/28 ,  H01L21/324 ,  H01L29/423 ,  H01L21/321 ,  H01L21/02

CPC classification number: H01L29/66545 ,  H01L21/02532 ,  H01L21/02592 ,  H01L21/02595 ,  H01L21/28017 ,  H01L21/28088 ,  H01L21/32055 ,  H01L21/321 ,  H01L21/324 ,  H01L29/4232 ,  H01L29/66 ,  H01L29/66795 ,  H01L29/6681

Abstract: A method of fabricating a replacement gate stack for a semiconductor device includes the following steps after removal of a dummy gate: growing a high-k dielectric layer over the area vacated by the dummy gate; depositing a thin metal layer over the high-k dielectric layer; depositing a sacrificial layer over the thin metal layer; performing a first rapid thermal anneal; removing the sacrificial layer; and depositing a metal layer of low resistivity metal for gap fill.

公开(公告)号：US09748145B1

公开(公告)日：2017-08-29

申请号：US15055826

申请日：2016-02-29

Applicant: GLOBALFOUNDRIES INC.

Inventor： Balaji Kannan ,  Unoh Kwon ,  Siddarth Krishnan ,  Takashi Ando ,  Vijay Narayanan

IPC: H01L21/8238 ,  H01L21/324 ,  H01L21/225 ,  H01L29/66 ,  H01L27/092

CPC classification number: H01L29/66545 ,  H01L21/823842 ,  H01L21/823857 ,  H01L27/092 ,  H01L29/4966 ,  H01L29/517 ,  H01L29/518

Abstract: Semiconductor device fabrication methods are provided which include: providing a structure with at least one region and including a dielectric layer disposed over a substrate; forming a multilayer stack structure including a threshold-voltage adjusting layer over the dielectric layer, the multilayer stack structure including a first threshold-voltage adjusting layer in a first region of the at least one region, and a second threshold-voltage adjusting layer in a second region of the at least one region; and annealing the structure to define a varying threshold voltage of the at least one region, the annealing facilitating diffusion of at least one threshold voltage adjusting species from the first threshold-voltage adjusting layer and the second threshold-voltage adjusting layer into the dielectric layer, where a threshold voltage of the first region is independent of the threshold voltage of the second region.

公开(公告)号：US20150243762A1

公开(公告)日：2015-08-27

申请号：US14699843

申请日：2015-04-29

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  GLOBALFOUNDRIES Inc.

Inventor： Takashi Ando ,  Eduard A. Cartier ,  Kisik Choi ,  Vijay Narayanan

IPC: H01L29/66 ,  H01L21/321 ,  H01L21/28

CPC classification number: H01L29/66545 ,  H01L21/02532 ,  H01L21/02592 ,  H01L21/02595 ,  H01L21/28017 ,  H01L21/28088 ,  H01L21/32055 ,  H01L21/321 ,  H01L21/324 ,  H01L29/4232 ,  H01L29/66 ,  H01L29/66795 ,  H01L29/6681

Abstract: A method of fabricating a replacement gate stack for a semiconductor device includes the following steps after removal of a dummy gate: growing a high-k dielectric layer over the area vacated by the dummy gate; depositing a thin metal layer over the high-k dielectric layer; depositing a sacrificial layer over the thin metal layer; performing a first rapid thermal anneal; removing the sacrificial layer; and depositing a metal layer of low resistivity metal for gap fill.

公开(公告)号：US20140187028A1

公开(公告)日：2014-07-03

申请号：US13732455

申请日：2013-01-02

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  GLOBALFOUNDRIES INC.

Inventor： Takashi Ando ,  Maryjane Brodsky ,  Michael P. Chudzik ,  Min Dai ,  Siddarth A. Krishnan ,  Joseph F. Shepard, JR. ,  Yanfeng Wang ,  Jinping Liu

IPC: H01L21/8238

CPC classification number: H01L21/823857

Abstract: Embodiments include methods of forming an nFET-tuned gate dielectric and a pFET-tuned gate dielectric. Methods may include forming a high-k layer above a substrate having a pFET region and an nFET region, forming a first sacrificial layer, a pFET work-function metal layer, and a second sacrificial layer above the first high-k layer in the pFET region, and an nFET work-function metal layer above the first high-k layer in the nFET region and above the second sacrificial layer in the pFET region. The first high-k layer then may be annealed to form an nFET gate dielectric layer in the nFET region and a pFET gate dielectric layer in the pFET region. The first high-k layer may be annealed in the presence of a nitrogen source to cause atoms from the nitrogen source to diffuse into the first high-k layer in the nFET region.

Abstract translation: 实施例包括形成nFET调谐的栅极电介质和pFET调谐的栅极电介质的方法。 方法可以包括在pFET区域和nFET区域上形成高k层，形成第一牺牲层，pFET功函数金属层和在pFET中的第一高k层上方的第二牺牲层 区域，以及在nFET区域中的第一高k层上方的nFET功函数金属层，并且在pFET区域中的第二牺牲层上方。 第一高k层然后可以退火以在nFET区域中形成nFET栅极介电层，并在pFET区域中形成pFET栅极电介质层。 第一高k层可以在存在氮源的情况下进行退火，以使来自氮源的原子扩散到nFET区域中的第一高k层。

公开(公告)号：US09735111B2

公开(公告)日：2017-08-15

申请号：US14862894

申请日：2015-09-23

Applicant: International Business Machines Corporation ,  GlobalFoundries, Inc.

Inventor： Takashi Ando ,  Hiroaki Niimi ,  Tenko Yamashita

IPC: H01L21/02 ,  H01L21/768 ,  H01L23/535 ,  H01L27/092 ,  H01L21/8238

CPC classification number: H01L23/535 ,  H01L21/02164 ,  H01L21/02178 ,  H01L21/02192 ,  H01L21/285 ,  H01L21/76802 ,  H01L21/76831 ,  H01L21/76832 ,  H01L21/76846 ,  H01L21/76877 ,  H01L21/823871 ,  H01L23/485 ,  H01L27/092 ,  H01L29/517 ,  H01L29/66545

Abstract: A method of making a semiconductor device includes forming a first source/drain trench and a second source/drain trench over a first and second source/drain region, respectively; forming a first silicon dioxide layer in the first source/drain trench and a second silicon dioxide layer in the second source/drain trench; forming a first source/drain contact over the first source/drain region, the first source/drain contact including a first tri-layer contact disposed between the first silicon dioxide layer and a first conductive material; and forming a second source/drain contact over the second source/drain region, the second source/drain contact including a second tri-layer contact disposed between the second silicon dioxide layer and a second conductive material; wherein the first tri-layer contact includes a first metal oxide layer in contact with the first silicon dioxide layer, and the second tri-layer contact includes a second metal oxide layer in contact with the second silicon dioxide layer.

公开(公告)号：US09620384B2

公开(公告)日：2017-04-11

申请号：US14323036

申请日：2014-07-03

Applicant: GLOBALFOUNDRIES Inc.

Inventor： Takashi Ando ,  Claude Ortolland ,  Kai Zhao

IPC: H01L21/3115 ,  H01L21/02 ,  H01L21/28 ,  H01L29/51 ,  H01L29/66 ,  H01L29/49

CPC classification number: H01L21/3115 ,  H01L21/02323 ,  H01L21/02337 ,  H01L21/28176 ,  H01L21/28194 ,  H01L29/4966 ,  H01L29/511 ,  H01L29/517 ,  H01L29/66545 ,  H01L29/6656

Abstract: A method of manufacturing a semiconductor structure, by depositing a dielectric layer is a dummy gate, or an existing gate structure, prior to the formation of gate spacers. Following the formation of spacers, and in some embodiments replacing a dummy gate with a final gate structure, oxygen is introduced to a gate dielectric through a diffusion process, using the deposited dielectric layer as a diffusion pathway.

公开(公告)号：US09484438B2

公开(公告)日：2016-11-01

申请号：US14699427

申请日：2015-04-29

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION ,  GLOBALFOUNDRIES Inc.

Inventor： Takashi Ando ,  Eduard A. Cartier ,  Kisik Choi ,  Vijay Narayanan

IPC: H01L21/3205 ,  H01L29/66 ,  H01L21/324 ,  H01L21/28 ,  H01L21/02

CPC classification number: H01L29/66545 ,  H01L21/02532 ,  H01L21/02592 ,  H01L21/02595 ,  H01L21/28017 ,  H01L21/28088 ,  H01L21/32055 ,  H01L21/321 ,  H01L21/324 ,  H01L29/4232 ,  H01L29/66 ,  H01L29/66795 ,  H01L29/6681

Abstract: A method of fabricating a replacement gate stack for a semiconductor device includes the following steps after removal of a dummy gate: growing a high-k dielectric layer over the area vacated by the dummy gate; depositing a thin metal layer over the high-k dielectric layer; depositing a sacrificial layer over the thin metal layer; performing a first rapid thermal anneal; removing the sacrificial layer; and depositing a metal layer of low resistivity metal for gap fill.