Copolyester from 1,6-bis(phenoxy)hexane-4,4'-dicarboxylate
    2.
    发明授权
    Copolyester from 1,6-bis(phenoxy)hexane-4,4'-dicarboxylate 失效
    1,6-双(苯氧基)己烷-4,4'-二羧酸酯的共聚酯

    公开(公告)号:US4983707A

    公开(公告)日:1991-01-08

    申请号:US473153

    申请日:1990-01-31

    CPC分类号: C08G63/60

    摘要: A melt-processable copolyester comprising:a structural unit (I) of the formula (1), ##STR1## a structural unit (II) of the formula (2),--OC--X--CO-- (2)wherein X is at least one member selected from the group consisting of ##STR2## a structural unit (III) of the formula (3)--O--Y--O-- (3)wherein Y is at least one member selected from the group consisting of ##STR3## and a structural unit (IV) of the formula (4)--O--Z--CO-- (4)wherein Z represents at least one member selected from the group consisting of ##STR4## the ratio of the structural unit (IV) (III) to the structural units [(I)+(II)+(III)+(IV)] in total being 5 to 80 mole%, the structural units [(I)+(II)] being substantially equimolar to the structural unit (III), the ratio of the structural unit (I) to the structural units [(I)+(II)] in total being 10 to 90 mole %, and the copolyester having an inherent viscosity (ln .eta..sub.rel)/C, measured in a concentration of 0.16 g/dl in pentafluorophenol at 60.degree. C., of not less than 0.3 dl/g.

    Polyamide resin
    3.
    发明授权
    Polyamide resin 有权
    聚酰胺树脂

    公开(公告)号:US06841651B2

    公开(公告)日:2005-01-11

    申请号:US10408566

    申请日:2003-04-08

    摘要: The polyamide resin of the present invention is produced by polycondensation of a diamine component comprising 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component comprising 70 mol % or more of a C4-C20 α, ω-straight-chain aliphatic dicarboxylic acid in the presence of at least one phosphorus compound selected from the group consisting of phosphinic acid compounds and phosphonous acid compounds and in the presence of an alkali metal compound of a weak acid. The weak acid has a dissociation constant lower than a first dissociation constant of a dicarboxylic acid mainly constituting the polyamide resin. The polyamide resin satisfies the following requirements (A), (B) and (C): 14000≦a≦40000  (A) b≦1.000  (B) 0.9930≦b−1.1a2×10−11+3.2a×10−7≦0.9980  (C) wherein a and b are as defined in the disclosure.

    摘要翻译: 本发明的聚酰胺树脂通过由70摩尔%以上的间苯二甲胺和含有70摩尔%以上的C4〜C20α,ω-直链脂肪族二羧酸的二羧酸成分的二胺成分缩聚而制造 在至少一种选自次膦酸化合物和膦酸化合物的磷化合物存在下,并在弱酸碱金属化合物存在下进行。 弱酸的解离常数低于主要构成聚酰胺树脂的二羧酸的第一解离常数。 聚酰胺树脂满足以下要求(A),(B)和(C):其中a和b如本公开中所定义。

    Shaped article of polyamide resin and production thereof
    4.
    发明授权
    Shaped article of polyamide resin and production thereof 有权
    聚酰胺树脂成型品及其制造

    公开(公告)号:US06515099B2

    公开(公告)日:2003-02-04

    申请号:US09859539

    申请日:2001-05-18

    IPC分类号: B32B2700

    摘要: The polyamide resin shaped article of the present invention is produced by preliminarily melt-kneading a m-xylylene-containing polyamide resin and a layered silicate subjected to a swelling treatment to prepare a resin composition containing the layered silicate in high concentration, melt-kneading the resin composition with another portion of m-xylylene-containing polyamide resin, and then formed into the shaped article. Since the amount of the m-xylylene-containing polyamide resin exposed to the heat history twice in the melt-kneading steps is minimized, the gel formation due to the thermal degradation can be reduced and the lowering of the relative viscosity due to the decrease of the molecular weight caused by the thermal degradation of the m-xylylene-containing polyamide resin is prevented.

    摘要翻译: 本发明的聚酰胺树脂成型体是通过对含有间亚二甲苯的聚酰胺树脂和进行了溶胀处理的层状硅酸盐进行预先熔融混炼来制备含有高浓度的层状硅酸盐的树脂组合物,熔融混炼 树脂组合物与另一部分含间亚二甲苯的聚酰胺树脂,然后形成成型制品。 由于在熔融捏合步骤中暴露于热历程两次的含间亚二甲苯的聚酰胺树脂的量最小化,因此可以降低由于热降解引起的凝胶形成,并且由于降低 可以防止由含间亚二甲苯的聚酰胺树脂的热降解引起的分子量。

    Process for production of polyamide composite material
    5.
    发明授权
    Process for production of polyamide composite material 有权
    聚酰胺复合材料生产工艺

    公开(公告)号:US07265187B2

    公开(公告)日:2007-09-04

    申请号:US10675951

    申请日:2003-10-02

    IPC分类号: C08J3/20 C08J3/22

    摘要: In the process of the present invention, a polyamide A1 and an organized clay B are mixed mainly by dispersive mixing, and after added with a polyamide A2, mixed mainly by distributive mixing in a corotating intermeshing twin-screw extruder so designed as to effect the dispersive mixing and the distributive mixing. The organized clay B is completely and finely dispersed and distributed throughout the resultant polyamide composite material. Shaped articles such as films and sheets made of the polyamide composite material exhibit excellent gas barrier properties and transparency with little malodor mainly attributable to the decomposed products of the organizing agent for preparing the organized clay B.

    摘要翻译: 在本发明的方法中,主要通过分散混合将聚酰胺A1和有机粘土B混合,并且在加入聚酰胺A2之后,主要通过分配混合在相互啮合的双螺杆挤出机中进行混合, 分散混合和分配混合。 有机粘土B完全精细地分散并分布在所得的聚酰胺复合材料中。 由聚酰胺复合材料制成的薄膜和薄片等成型体,具有优异的阻气性和透明性,主要是由于用于制备有机粘土B的组织剂的分解产物而产生的恶臭。

    Multilayer Bottle
    7.
    发明申请
    Multilayer Bottle 有权
    多层瓶

    公开(公告)号:US20090277858A1

    公开(公告)日:2009-11-12

    申请号:US12158504

    申请日:2006-12-21

    IPC分类号: B65D23/00

    摘要: There is provided a multilayer bottle including an outermost layer and an innermost layer which are each made of a thermoplastic polyester resin, and at least one barrier layer interposed between the outermost layer and the innermost layer. The barrier layer contains at least two components including a polyamide obtained by polycondensing a diamine component containing m-xylylenediamine as a main component with a dicarboxylic acid component containing an α,ω-linear aliphatic dicarboxylic acid as a main component, and a thermoplastic resin having a lower molecular weight than that of the polyamide. The multilayer bottle hardly suffers from delamination upon impact or dropping and, therefore, is not required to have a shape with less irregularities or less bends for preventing the delamination, and further has a large freedom of design choice.

    摘要翻译: 提供了包括由热塑性聚酯树脂制成的最外层和最内层的多层瓶,以及插入在最外层和最内层之间的至少一个阻挡层。 阻挡层含有至少两种成分,包括通过将含有间苯二甲胺作为主要成分的二胺成分与含有α,ω-直链脂族二羧酸为主要成分的二羧酸成分缩聚得到的聚酰胺,以及具有 比聚酰胺低的分子量。 多层瓶几乎不会在冲击或滴落时发生分层,因此不需要具有较少的不规则形状或较少弯曲的形状以防止分层,并且还具有大的设计选择自由度。

    Fuel-barrier polyamide resin and multilayer shaped article
    8.
    发明授权
    Fuel-barrier polyamide resin and multilayer shaped article 有权
    燃料阻隔聚酰胺树脂和多层成型制品

    公开(公告)号:US07053172B2

    公开(公告)日:2006-05-30

    申请号:US10837699

    申请日:2004-05-04

    IPC分类号: C08G69/08 B32B27/00

    摘要: The fuel-barrier polyamide resin of the present invention is a product of the polycondensation of a diamine component comprising 70 mol % or higher of m-xylylenediamine and a dicarboxylic acid component comprising 70 mol % or higher of a mixed dicarboxylic acid which comprises a C4 to C20 α,ω-linear aliphatic dicarboxylic acid and at least one dicarboxylic acid selected from the group consisting of isophthalic acid and naphthalenedicarboxylic acid in a molar ratio of 30:70 to 95:5. The polyamide resin is excellent in not only fuel-barrier property and heat resistance, but also moldability and recyclability, and therefore suitably used as a barrier material of fuel containers.

    摘要翻译: 本发明的燃料阻隔性聚酰胺树脂是包含70摩尔%以上的间苯二甲胺的二胺成分和含有70摩尔%以上的混合二羧酸的二羧酸成分的缩聚物的产物,其包含C 4〜20%,ω-直链脂肪族二羧酸和选自间苯二甲酸和萘二甲酸的至少一种二羧酸,摩尔比为30: 70至95:5。 聚酰胺树脂不仅具有优异的燃料阻隔性和耐热性,而且还具有成型性和再循环性,因此适合用作燃料容器的阻隔材料。

    Multi-Layer Bottle
    10.
    发明申请
    Multi-Layer Bottle 有权
    多层瓶

    公开(公告)号:US20100233401A1

    公开(公告)日:2010-09-16

    申请号:US12160469

    申请日:2007-01-15

    IPC分类号: B32B1/02 B32B27/34 B32B27/36

    摘要: There is provided a multilayer bottle including outermost and innermost layers each made mainly of a polyester (A) and at least one barrier layer interposed between the outermost and innermost layers. The polyester (A) is a thermoplastic resin obtained by polymerizing a dicarboxylic acid component containing 80 mol % or more of terephthalic acid with a diol component containing 80 mol % or more of ethylene glycol. The barrier layer is composed of a polyamide (B) and a polyamide (C). The polyamide (B) is obtained by polycondensing a diamine component containing 70 mol % or more of m-xylylenediamine with a dicarboxylic acid component containing 70 mol % or more of an α,ω-linear aliphatic dicarboxylic acid having 4 to 20 carbon atoms. The polyamide (C) has a higher saturation water content than that of the polyamide (B) as measured at 23° C. and 50% RH under 1 atm, and a content of the polyamide (C) in the barrier layer is 20% by weight or less on the basis of a weight of the barrier layer. The multilayer bottle hardly suffers from delamination upon dropping or upon exposure to impact and, therefore, is not required to have a shape with less irregularities or less bends for preventing the delamination, and further has a large freedom of design choice.

    摘要翻译: 提供了包括最外层和最内层的多层瓶,它们分别由聚酯(A)和至少一个介于最外层和最内层之间的阻挡层制成。 聚酯(A)是通过使含有80摩尔%以上的对苯二甲酸的二羧酸成分与含有80摩尔%以上的乙二醇的二醇成分聚合而得到的热塑性树脂。 阻挡层由聚酰胺(B)和聚酰胺(C)组成。 聚酰胺(B)通过将含有70摩尔%以上的间苯二甲胺的二胺成分与含有70摩尔%以上的具有4〜20个碳原子的α,ω-直链脂肪族二羧酸的二羧酸成分缩聚而获得。 聚酰胺(C)在23℃,50%RH,1atm以下测定的聚酰胺(B)的饱和水分含量较高,阻挡层中聚酰胺(C)的含量为20% 以阻挡层的重量为基准。 多层容器在滴下或暴露于冲击时几乎不会发生分层,因此不需要具有较少的不规则形状或较少弯曲的形状,以防止分层,并且还具有大的设计自由度。