摘要:
A process for producing 2,6-naphthalenedicarboxylic acid by oxidizing 2,6-dimethylnaphthalene by molecular oxygen in the presence of a catalyst including cobalt, manganese and bromine. The oxidation reaction is performed by using a 2,6-dialkylnaphthalene mixture of 2,6-dimethynaphthalene and a small amount of 2,6-diisopropylnaphthalene as a raw material. Thus, the desired 2,6-naphthalenedicarboxylic acid can be produced at a high yield.
摘要:
A process for producing a polyhydroperoxy aromatic compound by oxidation of an aromatic hydrocarbon, e.g., 4,4'-diisopropylbiphenyl and 4,4'-diisopropylnaphthalene, with molecular oxygen is disclosed, in which the oxidation is carried out in the presence of a metal ion selected from cobalt, nickel, zinc and lead ions. Even in using a reaction apparatus made of an iron-containing metal generally employed in industry, a high conversion of secondary alkyl groups can be reached, and the desired polyhydroperoxy aromatic compound can be obtained in a high yield.
摘要:
A process for preparing p-hydroxybenzyl alcohol or a derivative thereof comprising reacting a phenol and a formaldehyde source under a basic condition is disclosed, wherein the reaction is carried out in an alcoholic organic solvent in the presence of a crown ether. The process achieves high selectivity toward the para position without involving high cost.
摘要:
A process for preparing 4,4'-dihydroxydiphenylmethane, which comprises reacting phenol with formaldehyde in the presence of an acidic catalyst and separating the aimed 4,4'-dihydroxydiphenylmethane from the crude dihydroxydiphenylmethane thus obtained, is disclosed. According to this process, 4,4'-dihydroxydiphenylmethane can be separated from its isomers and oligomers at a high purity and at a high yield, compared with those achieved by known methods. Thus highly useful 4,4'-dihydroxydiphenylmethane can be advantageously prepared on an industrial scale.
摘要:
A process for preparing phenols with high selectivities, comprising reacting a phenol compound and a formaldehyde source with a quaternary ammonium as a counter cation of a phenol anion in the presence of an alcoholic organic solvent.
摘要:
A process for preparing .alpha.-ketobutyric acid comprising contacting 1,2-butanediol with molecular oxygen in the presence of a platinum catalyst is disclosed. The process produces .alpha.-ketobutyric acid in high yield at low cost.
摘要:
The present invention provides a cosmetic exhibiting superior feeling to the touch and a superior uniformity using a novel organopolysiloxane. The cosmetic contains a liquid organopolysiloxane having fluidity at 25° C. and having a crosslinked three-dimensional network structure. The aforementioned liquid organopolysiloxane has a loss factor, tan δ, at a shear frequency of 10 Hz, which is 1 or more.
摘要:
The present invention resides in a control apparatus for an internal combustion engine in which selective use is made of a case where a first fuel, being easy to be ignited, is caused to combust by itself, and a case where a second fuel, being hard to be ignited, is also caused to combust by igniting the first fuel, and which is provided with an acquisition unit configured to acquire a combustion state of the second fuel in the case where the second fuel is also caused to combust by igniting the first fuel, and a decision unit configured to decide amounts of supply of the first fuel and the second fuel to be supplied to the internal combustion engine on and after next time, based on the combustion state of the second fuel determined by the acquisition unit.
摘要:
The invention relates to a method for producing a biomass-resource-derived polyurethane, which comprises: reacting a dicarboxylic acid and an aliphatic diol to produce a polyester polyol; and reacting the polyester polyol and a polyisocyanate compound, wherein the dicarboxylic acid contains at least one component derived from biomass resources, a content of an organic acid in the dicarboxylic acid is more than 0 ppm and not more than 1,000 ppm relative to the dicarboxylic acid, and a pKa value of the organic acid at 25° C. is not more than 3.7.
摘要:
Provided is a data recovery circuit including an input data phase detection circuit for outputting a gate signal synchronized with a rising phase of input data, a gated multiphase oscillator for instantly generating N-phase clocks based on the gate signal as a trigger, data discriminating and reproducing circuits for outputting sampled data of the input data which are synchronized with the clocks, a continuous clock generation circuit for generating a continuous clock which is a reference clock, continuous clock synchronization circuits for synchronizing the sampled data with the continuous clock and outputting the synchronized sampled data as phase synchronization data, and a phase selector for selecting the phase synchronization data having an optimum discrimination phase with the largest phase margin with respect to the input data and outputting the selected phase synchronization data as recovery data.