公开(公告)号：US20150125709A1

公开(公告)日：2015-05-07

申请号：US14139482

申请日：2013-12-23

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Cheng-Hsing FAN ,  Chun-Yen CHEN ,  Ming-Tsong LEU ,  Chien-Pang WU

IPC: C08L67/03 ,  B29C47/00 ,  B29C55/16 ,  C08J5/18

CPC classification number: B29C55/16 ,  B29C47/00 ,  B29C47/0021 ,  B29C47/0057 ,  B29C47/36 ,  B29C47/40 ,  B29C47/88 ,  B29C55/00 ,  B29C55/02 ,  B29C55/10 ,  B29C55/12 ,  B29D11/00 ,  B29K2067/00 ,  B29K2105/0085 ,  B29K2105/0088 ,  B29L2007/008 ,  B29L2011/00 ,  B32B27/36 ,  B32B2307/518 ,  B32B2307/734 ,  C08G63/12 ,  C08G63/123 ,  C08G63/127 ,  C08G63/137 ,  C08G63/16 ,  C08G63/18 ,  C08G63/183 ,  C08G63/199 ,  C08J5/18 ,  C08J2367/02 ,  C08J2367/03 ,  C08J2467/03 ,  C08L67/00 ,  C08L67/02 ,  C08L67/03 ,  C08L2203/16 ,  C08L2203/20 ,  C08L2205/025 ,  Y10T428/31786

Abstract: Disclosed is a method for manufacturing a film. 50 wt % to 85 wt % of a first polyester and 50 wt % to 15 wt % of a second polyester are dried and mixed to form a mixture. The first polyester is polyethylene terephthalate (PET), polyethylene naphthalate (PEN), or combinations thereof. The second polyester is copolymerized of 1 part by mole of terephthalic acid, m parts by mole of 1,4-cyclohexanedimethanol (1,4-CHDM), n parts by mole of 1,3-cyclohexanedimethanol (1,3-CHDM), and o parts by mole of ethylene glycol (EG). m+n+o=1, 0≦o≦0.4, 0.6≦m+n≦1, and 0.06≦n/m≦1.31. The mixture is melted and blended to form a polyester composition, which is extruded to form a sheet. The sheet is then biaxially stretched to obtain a film. The biaxially stretched film is then treated with a thermal setting.

Abstract translation: 公开了一种制造薄膜的方法。 将50重量％至85重量％的第一聚酯和50重量％至15重量％的第二聚酯干燥并混合以形成混合物。 第一聚酯是聚对苯二甲酸乙二醇酯（PET），聚萘二甲酸乙二醇酯（PEN）或其组合。 第二聚酯共聚有1份摩尔对苯二甲酸，m份摩尔的1,4-环己烷二甲醇（1,4-CHDM），n份摩尔的1,3-环己烷二甲醇（1,3-CHDM）， 和o摩尔份的乙二醇（EG）。 m + n + o = 1，0＆nlE; o＆nlE; 0.4,0.6＆nlE; m + n＆nlE; 1和0.06＆nlE; n / m＆nlE; 1.31。 将混合物熔融并共混以形成聚酯组合物，其被挤出以形成片材。 然后将片材双轴拉伸得到薄膜。 然后用热定形处理双轴拉伸的膜。

公开(公告)号：US20170204225A1

公开(公告)日：2017-07-20

申请号：US15381684

申请日：2016-12-16

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Po-Hsien HO ,  Chih-Hsiang LIN ,  Meng-Hsin CHEN ,  Cheng-Hsing FAN ,  Hsin-Ching KAO ,  Yih-Her CHANG

IPC: C08G75/025 ,  C08G75/0227

CPC classification number: C08G75/025 ,  C07C319/14 ,  C07C381/12 ,  C08G75/02 ,  C08G75/0204 ,  C08G75/0227 ,  C07C321/30

Abstract: A method for preparing a polyarylene sulfide includes reacting a methyl 4-(arylthio)aryl sulfoxide compound with sulfuric acid, methanesulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid or trifluoromethanesulfonic acid to obtain a polysulfonium intermediate; and demethylating the polysulfonium intermediate to obtain a polyarylene sulfide, wherein the polysulfonium intermediate is demethylated with aqueous HCl, HBr, or HI.

公开(公告)号：US20170197914A1

公开(公告)日：2017-07-13

申请号：US15389785

申请日：2016-12-23

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Po-Hsien HO ,  Chih-Hsiang LIN ,  Meng-Hsin CHEN ,  Cheng-Hsing FAN ,  Hsin-Ching KAO ,  Yih-Her CHANG

IPC: C07C323/20 ,  C07C319/14 ,  C07C321/28

CPC classification number: C07C323/20 ,  C07C319/14 ,  C07C321/28 ,  C07C381/12

Abstract: A method for preparing an aromatic sulfide or a salt thereof is provided. The method for preparing an aromatic sulfide or a salt thereof includes reacting a compound having a structure represented by Formula (I) to a compound having a structure represented by Formula (III) in the presence of a compound having a structure represented by Formula (II) to obtain a compound having a structure represented by Formula (IV) wherein R1 and R2 are independently C1-6 alkyl group, or C5-7 cycloalkyl group; R3 is independently C1-6 alkyl group, C5-7 cycloalkyl group, C1-6 haloalkyl group, or aryl group; R4 is independently H, or C1-6 alkyl group; Y is H, aryl group, or —X—R5; X is —O—, —NH—, —PH—, or —S—, or Y and an adjacent R4 are optionally combined with the carbon atoms to which they are attached, to form an aryl group; and R5 is H, C1-6 alkyl group, C5-7 cycloalkyl group, or aryl group; and Z− is R3SO3−.

公开(公告)号：US20140142247A1

公开(公告)日：2014-05-22

申请号：US13728565

申请日：2012-12-27

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Cheng-Hsing FAN ,  Kuo-Chen SHIH ,  Ming-Tsong LEU ,  Li-Cheng JHENG

IPC: C08G63/181 ,  C08K3/26 ,  C08K3/34

CPC classification number: C08G63/181 ,  C08G63/199 ,  C08K3/013 ,  C08K3/26 ,  C08K3/34 ,  C08K3/36 ,  C08K2003/265 ,  G02B1/04 ,  C08L67/02

Abstract: Disclosed is an amorphous copolyester polymerized of a diacid and diols. The diacid is selected from a group consisting of terephthalic acid, 5-tert-butylisophthalic acid, and dimethyl 2,6-naphthalenedicarboxylate. The diols are selected at least two from a group consisting of ethylene glycol, 2,2-dimethyl-1,3-propanediol, and tricyclodecanedimethanol. The molar ratio of the tricyclodecanedimethanol is 30% to 95% of the diols.

Abstract translation: 公开了二酸和二醇聚合的无定形共聚酯。 二酸选自对苯二甲酸，5-叔丁基间苯二甲酸和2,6-萘二甲酸二甲酯。 二醇选自由乙二醇，2,2-二甲基-1,3-丙二醇和三环癸烷二甲醇组成的组中的至少两种。 三环癸烷二甲醇的摩尔比为二醇的30％至95％。

公开(公告)号：US20190040202A1

公开(公告)日：2019-02-07

申请号：US16047674

申请日：2018-07-27

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Po-Hsien HO ,  Chih-Hsiang LIN ,  Feng-Jen TSAI ,  Cheng-Hsing FAN ,  Yih-Her CHANG ,  Hsin-Ching KAO ,  Chien-Ming CHEN

IPC: C08G75/0236 ,  C07C319/14 ,  C07C315/02 ,  C08G75/02 ,  C08G75/029 ,  C08G75/23 ,  C08G75/0227

Abstract: A method for preparing a compound and a method for preparing a polymer employing the same are provided. The method for preparing a compound includes reacting a compound having a structure represented by Formula (I) with a compound having a structure represented by Formula (III) in the presence of a compound having a structure represented by Formula (II) to obtain a compound having a structure represented by Formula (IV) wherein Ar1 is substituted or unsubstituted aryl group; X is —O—, —S—, or —NH—; R1 is independently hydrogen or C1-6 alkyl group; R2 is hydroxyl group, C1-6 alkyl group, phenyl group, or tolyl group; and R3 is independently C1-6 alkyl group, C5-8 cycloalkyl group, or C2-6 alkoxyalkyl group.

公开(公告)号：US20180298146A1

公开(公告)日：2018-10-18

申请号：US16013168

申请日：2018-06-20

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Po-Hsien HO ,  Chih-Hsiang LIN ,  Meng-Hsin CHEN ,  Cheng-Hsing FAN ,  Hsin-Ching KAO ,  Yih-Her CHANG

IPC: C08G75/14

CPC classification number: C08G75/14 ,  C08G75/04

Abstract: A method for preparing a polymer is provided. The method for preparing a polymer includes subjecting at least one monomer having a structure represented by Formula (I) to a reaction in the presence of sulfonic acid, diphenyl amine, and oxygen-containing phosphide, obtaining a sulfonium salt polymer wherein x is 0, 1, or 2; R1 is C1-6 alkyl group; and R2 is independently hydrogen, or C1-6 alkyl group. In particular, the molar ratio of the diphenyl amine to the oxygen-containing phosphide is from 4:1 to 1:1.

公开(公告)号：US20170198141A1

公开(公告)日：2017-07-13

申请号：US15389711

申请日：2016-12-23

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Po-Hsien HO ,  Chih-Hsiang LIN ,  Meng-Hsin CHEN ,  Cheng-Hsing FAN ,  Hsin-Ching KAO ,  Yih-Her CHANG

IPC: C08L81/02 ,  C08L33/14 ,  C08G75/02 ,  C08G75/04

CPC classification number: C08L81/02 ,  C08G75/02 ,  C08G75/0204 ,  C08G75/04 ,  C08L33/14

Abstract: A method for preparing a polymer is provided. The method for preparing a polymer includes subjecting at least one monomer having a structure represented by Formula (I) to a reaction in the presence of sulfonic acid, diphenyl amine, and oxygen-containing phosphide, obtaining a sulfonium salt polymer wherein x is 0, 1, or 2, R1 is C1-6 alkyl group; and R2 is independently hydrogen, or C1-6 alkyl group.

公开(公告)号：US20170198098A1

公开(公告)日：2017-07-13

申请号：US15393913

申请日：2016-12-29

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Po-Hsien HO ,  Chih-Hsiang LIN ,  Meng-Hsin CHEN ,  Cheng-Hsing FAN ,  Hsin-Ching KAO ,  Yih-Her CHANG

IPC: C08G75/0227 ,  C08G75/025 ,  C08G75/029

CPC classification number: C08G75/0227 ,  C08G75/025 ,  C08G75/029 ,  Y02P20/582

Abstract: A polymer is provided. The polymer has a repeating unit having a structure represented by Formula (I) or Formula (II) wherein Ar1 and Ar2 can be substituted or unsubstituted aryl diradical; Y− can be R2SO3− or ClO4−; R1 can be C1-6 alkyl; Ar1 and Ar2 are different; and, R2 can be C1-6 alkyl, substituted or unsubstituted aromatic ring, or C1-6 haloalkyl.