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公开(公告)号：US08592522B2
公开(公告)日：2013-11-26
申请号：US11064149
申请日：2005-02-23
CPC分类号： B32B27/32 , B32B27/06 , B32B2367/00 , C08F8/42 , C08F10/00 , C08K5/098 , C08K2201/012 , C08L23/06 , C08L25/04 , C08L53/02 , C08L101/00 , Y10T428/31855 , Y10T428/31938 , C08L2666/04 , C08L2666/06
摘要： The object of the present invention is to provide an oxygen-absorbing resin composition having a high oxygen absorbability and capable of absorbing oxygen for a long period of time. The present invention provides an oxygen-absorbing resin composition comprising polyolefin resin (A) obtained by polymerizing an olefin having 2 to 8 carbon atoms, resin (B) which is other than resin (A) and which acts as a trigger for the oxidation of resin (A), and transition metal catalyst (C), wherein resin (B) is dispersed in the matrix of resin (A) so that the oxidation reaction of matrix resin (A) is caused and thus oxygen is absorbed when the oxygen-absorbing resin composition is brought into contact with oxygen. This oxygen absorbing resin composition has a high oxygen absorbability and is advantageous in cost because oxygen is absorbed in resin (A).
摘要翻译： 本发明的目的是提供一种氧吸收性高且能够长时间吸收氧气的氧吸收性树脂组合物。 本发明提供一种含有聚烯烃树脂（A）的氧吸收性树脂组合物，该聚烯烃树脂（A）通过聚合碳原子数2〜8的烯烃，除树脂（A）以外的树脂（B） 树脂（A）和过渡金属催化剂（C），其中树脂（B）分散在树脂（A）的基体中，从而引起基体树脂（A）的氧化反应，因此当氧 - 吸收树脂组合物与氧接触。 该氧吸收性树脂组合物具有高的氧吸收性，并且由于在树脂（A）中吸收氧而有利于成本。
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公开(公告)号：US08216651B2
公开(公告)日：2012-07-10
申请号：US11507087
申请日：2006-08-18
申请人： Yoshihiro Ohta , Takayuki Ishihara , Ikuo Komatsu , Hiroaki Goto
发明人： Yoshihiro Ohta , Takayuki Ishihara , Ikuo Komatsu , Hiroaki Goto
CPC分类号： B32B27/08 , B32B25/08 , B32B25/16 , B32B27/18 , B32B27/302 , B32B27/306 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2264/102 , B32B2272/00 , B32B2274/00 , B32B2307/412 , B32B2307/7244 , B32B2307/74 , B32B2439/46 , B32B2439/70 , Y10T428/1314 , Y10T428/1317 , Y10T428/1321 , Y10T428/1352
摘要： The present invention herein provides a plastic multi-layer structure which comprises an oxygen-barrier layer (A-1), an oxygen absorptive layer (B), and a thermoplastic resin layer (C) containing a high silica type zeolite material having a silica/alumina ratio of not less than 80; and a packaging material such as bottles for accommodating foods, for instance, a beverage and medical and pharmaceutical products. The plastic multi-layer structure possesses oxidation-barrier characteristics and the structure would permit the considerable reduction of the quantity of the oxidation by-products generated from the structure, even when used under a high humidity atmosphere.
摘要翻译： 本发明提供一种塑料多层结构，其包括氧阻隔层（A-1），氧吸收层（B）和含有二氧化硅的高二氧化硅型沸石材料的热塑性树脂层（C） /氧化铝比不小于80; 以及诸如用于容纳食物的瓶子的包装材料，例如饮料和医药产品。 塑料多层结构具有氧化屏障特性，即使在高湿度环境下使用时，结构也能大大减少由结构产生的氧化副产物的量。
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公开(公告)号：US07709567B2
公开(公告)日：2010-05-04
申请号：US11351737
申请日：2006-02-10
申请人： Hiroaki Goto , Ikuo Komatsu , Takayuki Ishihara , Yoshihiro Ohta , Shigenobu Murakami , Nobuo Hirakawa
发明人： Hiroaki Goto , Ikuo Komatsu , Takayuki Ishihara , Yoshihiro Ohta , Shigenobu Murakami , Nobuo Hirakawa
IPC分类号： C06B23/00
CPC分类号： C08L23/0815 , C08L53/02 , C08L2666/24
摘要： The present invention herein provides an oxygen-absorbing resin composition which is excellent in the oxygen-absorbability and which can inhibit any deterioration through oxidation during the molding operations of the composition and does not accordingly undergo any coloration during the molding operations. The present invention thus provides an oxygen-absorbing resin composition characterized in that it comprises (A) a hydrogenated styrene-diene copolymer; (B) a thermoplastic resin including ethylenic structural units in its molecular structure; and (C) a transition metal catalyst, wherein the oxidation of the thermoplastic resin (B) proceeds while the copolymer (A) serves as a trigger and the composition thus absorbs oxygen. In this respect, the copolymer (A) comprises carbon-carbon double bonds derived from the diene in an amount ranging from 1×10.5 to 1×10.2 eq/g.
摘要翻译： 本发明提供一种氧吸收性树脂组合物，其吸氧性优异，并且能够抑制组合物成型时的氧化劣化，并且在成型操作中不会发生任何着色。 因此，本发明提供了一种吸氧树脂组合物，其特征在于它包含（A）氢化苯乙烯 - 二烯共聚物; （B）其分子结构中含有乙烯结构单元的热塑性树脂; 和（C）过渡金属催化剂，其中当共聚物（A）用作触发剂时，热塑性树脂（B）的氧化进行，并且组合物因此吸收氧气。 在这方面，共聚物（A）包含衍生自二烯的碳 - 碳双键，其量为1×10 5〜1×10 2 eq / g。
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公开(公告)号：US20070042145A1
公开(公告)日：2007-02-22
申请号：US11507087
申请日：2006-08-18
申请人： Yoshihiro Ohta , Takayuki Ishihara , Ikuo Komatsu , Hiroaki Goto
发明人： Yoshihiro Ohta , Takayuki Ishihara , Ikuo Komatsu , Hiroaki Goto
CPC分类号： B32B27/08 , B32B25/08 , B32B25/16 , B32B27/18 , B32B27/302 , B32B27/306 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2264/102 , B32B2272/00 , B32B2274/00 , B32B2307/412 , B32B2307/7244 , B32B2307/74 , B32B2439/46 , B32B2439/70 , Y10T428/1314 , Y10T428/1317 , Y10T428/1321 , Y10T428/1352
摘要： The present invention herein provides a plastic multi-layer structure which comprises an oxygen-barrier layer (A-1), an oxygen absorptive layer (B), and a thermoplastic resin layer (C) containing a high silica type zeolite material having a silica/alumina ratio of not less than 80; and a packaging material such as bottles for accommodating foods, for instance, a beverage and medical and pharmaceutical products. The plastic multi-layer structure possesses oxidation-barrier characteristics and the structure would permit the considerable reduction of the quantity of the oxidation by-products generated from the structure, even when used under a high humidity atmosphere.
摘要翻译： 本发明提供一种塑料多层结构，其包括氧阻隔层（A-1），氧吸收层（B）和含有二氧化硅的高二氧化硅型沸石材料的热塑性树脂层（C） /氧化铝比不小于80; 以及诸如用于容纳食物的瓶子的包装材料，例如饮料和医药产品。 塑料多层结构具有氧化屏障特性，即使在高湿度环境下使用时，结构也能大大减少由结构产生的氧化副产物的量。
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公开(公告)号：US20060211811A1
公开(公告)日：2006-09-21
申请号：US11351737
申请日：2006-02-10
申请人： Hiroaki Goto , Ikuo Komatsu , Takayuki Ishihara , Yoshihiro Ohta , Shigenobu Murakami , Nobuo Hirakawa
发明人： Hiroaki Goto , Ikuo Komatsu , Takayuki Ishihara , Yoshihiro Ohta , Shigenobu Murakami , Nobuo Hirakawa
IPC分类号： C09B67/00
CPC分类号： C08L23/0815 , C08L53/02 , C08L2666/24
摘要： The present invention herein provides an oxygen-absorbing resin composition which is excellent in the oxygen-absorbability and which can inhibit any deterioration through oxidation during the molding operations of the composition and does not accordingly undergo any coloration during the molding operations. The present invention thus provides an oxygen-absorbing resin composition characterized in that it comprises (A) a hydrogenated styrene-diene copolymer; (B) a thermoplastic resin including ethylenic structural units in its molecular structure; and (C) a transition metal catalyst, wherein the oxidation of the thermoplastic resin (B) proceeds while the copolymer (A) serves as a trigger and the composition thus absorbs oxygen. In this respect, the copolymer (A) comprises carbon-carbon double bonds derived from the diene in an amount ranging from 1×10−5 to 1×10−2 eq/g.
摘要翻译： 本发明提供一种氧吸收性树脂组合物，其吸氧性优异，并且能够抑制组合物成型时的氧化劣化，并且在成型操作中不会发生任何着色。 因此，本发明提供了一种吸氧树脂组合物，其特征在于它包含（A）氢化苯乙烯 - 二烯共聚物; （B）其分子结构中含有乙烯结构单元的热塑性树脂; 和（C）过渡金属催化剂，其中当共聚物（A）用作触发剂时，热塑性树脂（B）的氧化进行，并且组合物因此吸收氧气。 在这方面，共聚物（A）包含衍生自二烯的碳 - 碳双键，其量为1×10 -5至1×10 -2 eq / g。
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公开(公告)号：US20050142373A1
公开(公告)日：2005-06-30
申请号：US11064149
申请日：2005-02-23
IPC分类号： B32B27/32 , C08F8/42 , C08F10/00 , C08K5/098 , C08L23/06 , C08L25/04 , C08L53/02 , C08L101/00
CPC分类号： B32B27/32 , B32B27/06 , B32B2367/00 , C08F8/42 , C08F10/00 , C08K5/098 , C08K2201/012 , C08L23/06 , C08L25/04 , C08L53/02 , C08L101/00 , Y10T428/31855 , Y10T428/31938 , C08L2666/04 , C08L2666/06
摘要： The object of the present invention is to provide an oxygen-absorbing resin composition having a high oxygen absorbability and capable of absorbing oxygen for a long period of time. The present invention provides an oxygen-absorbing resin composition comprising polyolefin resin (A) obtained by polymerizing an olefin having 2 to 8 carbon atoms, resin (B) which is other than resin (A) and which acts as a trigger for the oxidation of resin (A), and transition metal catalyst (C), wherein resin (B) is dispersed in the matrix of resin (A) so that the oxidation reaction of matrix resin (A) is caused and thus oxygen is absorbed when the oxygen-absorbing resin composition is brought into contact with oxygen. This oxygen absorbing resin composition has a high oxygen absorbability and is advantageous in cost because oxygen is absorbed in resin (A).
摘要翻译： 本发明的目的是提供一种氧吸收性高且能够长时间吸收氧气的氧吸收性树脂组合物。 本发明提供一种含有聚烯烃树脂（A）的氧吸收性树脂组合物，该聚烯烃树脂（A）通过聚合碳原子数2〜8的烯烃，除树脂（A）以外的树脂（B） 树脂（A）和过渡金属催化剂（C），其中树脂（B）分散在树脂（A）的基体中，从而引起基体树脂（A）的氧化反应，因此当氧 - 吸收树脂组合物与氧接触。 该氧吸收性树脂组合物具有高的氧吸收性，并且由于在树脂（A）中吸收氧而有利于成本。
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公开(公告)号：US08809465B2
公开(公告)日：2014-08-19
申请号：US12527721
申请日：2008-02-14
申请人： Ikuo Komatsu , Yoshiko Narikawa , Yuji Yamaguchi , Hiroaki Goto
发明人： Ikuo Komatsu , Yoshiko Narikawa , Yuji Yamaguchi , Hiroaki Goto
CPC分类号： C08L23/04 , B29B9/12 , C08J3/12 , C08J3/201 , C08J2323/08 , C08K5/098 , C08K9/08 , C08L23/0815 , C08L2666/02
摘要： The present invention relates to resin pellets which comprises a thermoplastic resin (A) and an oxidation catalyst (B) which is not supported by any carrier, wherein if the peak area in the vicinity of 1715 cm−1 is defined to be Ic and the peak area observed in the vicinity of 1470 cm−1 is defined to be Im in the IR spectroscopic measurement of the pellets, the ratio: Ic/Im observed for the surface of the pellet is greater than that observed for the interior thereof. The pellets are thermoplastic resin pellets excellent in the oxygen-absorbing capacity and accordingly, they can suitably used as pellets for molding an oxygen absorptive resin article.
摘要翻译： 本发明涉及不含任何载体的热塑性树脂（A）和氧化催化剂（B）的树脂粒料，其中如果将1715cm -1附近的峰面积定义为Ic， 在1470cm -1附近观察到的峰面积在颗粒的IR光谱测定中被定义为Im，对于颗粒表面观察到的比例Ic / Im大于其内部观察到的比率。 颗粒是氧吸收能力优异的热塑性树脂颗粒，因此它们可以适合用作模塑氧吸收树脂制品的颗粒。
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公开(公告)号：US20100048825A1
公开(公告)日：2010-02-25
申请号：US12527721
申请日：2008-02-14
申请人： Ikuo Komatsu , Yoshiko Narikawa , Yuji Yamaguchi , Hiroaki Goto
发明人： Ikuo Komatsu , Yoshiko Narikawa , Yuji Yamaguchi , Hiroaki Goto
CPC分类号： C08L23/04 , B29B9/12 , C08J3/12 , C08J3/201 , C08J2323/08 , C08K5/098 , C08K9/08 , C08L23/0815 , C08L2666/02
摘要： The present invention relates to resin pellets which comprises a thermoplastic resin (A) and an oxidation catalyst (B) which is not supported by any carrier, wherein if the peak area in the vicinity of 1715 cm−1 is defined to be Ic and the peak area observed in the vicinity of 1470 cm−1 is defined to be Im in the IR spectroscopic measurement of the pellets, the ratio: Ic/Im observed for the surface of the pellet is greater than that observed for the interior thereof. The pellets are thermoplastic resin pellets excellent in the oxygen-absorbing capacity and accordingly, they can suitably used as pellets for molding an oxygen absorptive resin article.
摘要翻译： 本发明涉及不含任何载体的热塑性树脂（A）和氧化催化剂（B）的树脂粒料，其中如果将1715cm -1附近的峰面积定义为Ic， 在1470cm -1附近观察到的峰面积在颗粒的IR光谱测定中被定义为Im，对于颗粒表面观察到的比例Ic / Im大于其内部观察到的比率。 颗粒是氧吸收能力优异的热塑性树脂颗粒，因此它们可以适合用作模塑氧吸收树脂制品的颗粒。
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公开(公告)号：US20060170113A1
公开(公告)日：2006-08-03
申请号：US11334373
申请日：2006-01-19
申请人： Takekazu Tanaka , Ikuo Komatsu
发明人： Takekazu Tanaka , Ikuo Komatsu
IPC分类号： H01L23/48
CPC分类号： H01L23/49822 , H01L23/13 , H01L23/49816 , H01L2224/05001 , H01L2224/05023 , H01L2224/05124 , H01L2224/05139 , H01L2224/05144 , H01L2224/05147 , H01L2224/05155 , H01L2224/05568 , H01L2224/16225 , H01L2224/32245 , H01L2224/73253 , H01L2924/00014 , H01L2924/01079 , H01L2924/10253 , H01L2924/12044 , H01L2924/13091 , H01L2924/15153 , H01L2924/15192 , H01L2924/15311 , H01L2924/1532 , H01L2924/15321 , H01L2924/3011 , H01L2924/00 , H01L2224/05541 , H01L2224/05005 , H01L2224/05599
摘要： A technology providing an improvement in the durability in the condition of changing the temperature, while ensuring characteristics such as the applicability to applications utilizing larger electric current, lower resistance and the like can be achieved. A semiconductor device 100 includes a ceramic multiple-layered interconnect substrate 120, a silicon chip 110 that is flip-bonded to a chip-carrying region of the ceramic multiple-layered interconnect substrate 120, and an external connecting bumps 161 and an external connecting bumps 163, which are provided in the side that the silicon chip 110 of the ceramic multiple-layered interconnect substrate 120 is carried. The silicon chip 110 includes a front surface electrode and a back surface electrode. The ceramic multiple-layered interconnect substrate 120 includes an interconnect layer composed of a conductive material, and the interconnect layer composes a multiple-layered interconnect layer provided on a front surface and in an interior of the ceramic multiple-layered interconnect substrate 120. The front surface electrode of the silicon chip is electrically connected to the external connecting bump 161 and the external connecting bump 163 through the multiple-layered interconnects in the multiple-layered interconnect layer.
摘要翻译： 可以实现在改变温度的条件下提高耐久性的技术，同时确保诸如对使用较大电流，较低电阻等的应用的适用性等特性。 半导体器件100包括陶瓷多层互连衬底120，与陶瓷多层互连衬底120的芯片承载区域翻转接合的硅芯片110以及外部连接凸块161和外部连接凸块 163设置在陶瓷多层互连基板120的硅芯片110的一侧。 硅芯片110包括前表面电极和背面电极。 陶瓷多层互连基板120包括由导电材料构成的互连层，并且互连层构成设置在陶瓷多层互连基板120的前表面和内部的多层互连层。 硅芯片的前表面电极通过多层互连层中的多层互连电连接到外部连接凸块161和外部连接凸块163。
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公开(公告)号：US5360649A
公开(公告)日：1994-11-01
申请号：US974521
申请日：1992-11-12
申请人： Nobuyuki Sato , Ikuo Komatsu , Katsuhiro Imazu , Tomomi Kobayashi
发明人： Nobuyuki Sato , Ikuo Komatsu , Katsuhiro Imazu , Tomomi Kobayashi
CPC分类号： B21D35/006 , B21D51/26 , B65D1/165 , Y10T428/12431 , Y10T428/1321 , Y10T428/1355
摘要： A thickness-reduced deep-draw-formed can obtained by using, as the substrate, a cold-rolled steel plate having a carbon content in the steel of 0.02 to 0.15% by weight, a manganese content in the steel of 0.2 to 1.0% by weight, a mean diameter of crystal grain of smaller than 6.0 .mu.m, a tensile strength over a range of from 35 to 55 kg/mm.sup.2, and a thickness of 0.17 to 0.30 mm in a step of subjecting an organic resin-coated structure of the surface-treated steel plate to the thickness-reducing deep-draw forming. This makes it possible to suppress the generation and accumulation of heat in the organic resin-coated steel plate to a level lower than the conventional levels. Therefore, the organic resin coating is prevented from being peeled off or damaged and, as a result, the corrosion resistance can be markedly improved. Moreover, wrinkles can be effectively prevented from developing at the time of reducing the thickness, and the forming can be continuously carried out at a high speed without being substantially affected by the generation or accumulation of heat. It is further possible to easily carry out the post treatments such as necking, flanging and multi-beading after the forming. The thickness-reduced deep-draw-formed can of the invention is effective particularly for preserving various kinds of juices, coffee, oolong tea and any other beverages after it is hermetically sealed, retort-sterilized and reduced for its internal pressure.
摘要翻译： 使用钢中碳含量为0.02〜0.15重量％，钢中的锰含量为0.2〜1.0％的冷轧钢板作为基材，可以得到厚度减薄的深拉成形物， ，在有机树脂被覆结构体的工序中，平均粒径小于6.0μm，拉伸强度为35〜55kg / mm 2，厚度为0.17〜0.30mm 的表面处理钢板进行厚度减薄深拉成形。 这使得可以将有机树脂涂覆钢板中的热的产生和积聚抑制到低于常规水平的水平。 因此，防止有机树脂涂层被剥离或损坏，结果可以显着提高耐腐蚀性。 此外，在减小厚度的同时可以有效地防止褶皱的发展，并且可以高速连续地进行成形，而不会受到热的产生或积累的显着影响。 还可以容易地进行后处理，例如成型后的颈缩，翻边和多重着色。 本发明的厚度减薄的深拉制罐尤其适用于在气密密封，蒸煮灭菌和内压降低后保存各种果汁，咖啡，乌龙茶和任何其他饮料。
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