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    Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation
    4.
    发明授权
    Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation 有权
    通过非均相催化气相部分氧化制备至少一种有机靶化合物的方法

    公开(公告)号：US08394345B2

    公开(公告)日：2013-03-12

    申请号：US12146807

    申请日：2008-06-26

    申请人： Martin Dieterle ,  Klaus Joachim Mueller-Engel ,  Jochen Petzoldt ,  Ulrich Hammon

    发明人： Martin Dieterle ,  Klaus Joachim Mueller-Engel ,  Jochen Petzoldt ,  Ulrich Hammon

    IPC分类号： B01J8/10

    CPC分类号： C07C51/252 ,  C07C57/04

    摘要： A process for preparing an organic target compound by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound with molecular oxygen in two oxidation reactor lines operated in parallel and removal of the target compound from the mixture of the product gas streams in a workup line, wherein the catalysts charge of one of the oxidation lines comprises a portion of catalyst over which the heterogeneously catalyzed gas phase partial oxidation has already been carried out for longer than over the portions of catalyst of the catalyst charge of the other oxidation reactor line.

    摘要翻译： 通过在两个平行操作的氧化反应器管线中的有机前体化合物与分子氧的非均相催化气相部分氧化来制备有机靶化合物的方法，并且从处理线中的产物气流的混合物中除去目标化合物， 其中氧化线之一的催化剂装料包括一部分催化剂，其上已经进行非均相催化的气相部分氧化比在另一个氧化反应器管线的催化剂装料的催化剂的部分长。

    Process for preparing acrolein or acrylic acid or a mixture thereof from propane
    8.
    发明授权
    Process for preparing acrolein or acrylic acid or a mixture thereof from propane 有权
    从丙烷制备丙烯醛或丙烯酸或其混合物的方法

    公开(公告)号：US07897812B2

    公开(公告)日：2011-03-01

    申请号：US11751202

    申请日：2007-05-21

    申请人： Otto Machhammer ,  Klaus Joachim Mueller-Engel ,  Martin Dieterle

    发明人： Otto Machhammer ,  Klaus Joachim Mueller-Engel ,  Martin Dieterle

    IPC分类号： C07C51/16 ,  C07B41/00

    CPC分类号： C07C45/35 ,  C07C45/33 ,  C07C51/215 ,  C07C51/252 ,  C07C47/22 ,  C07C57/04

    摘要： A process for preparing acrolein or acrylic acid or a mixture thereof as the target product from propane, in which propane is partially dehydrogenated under heterogeneous catalysis in a reaction zone A, molecular hydrogen formed is at least partly combusted to water, any water present in the product gas A formed in reaction zone A is removed therefrom and product gas A is otherwise used to charge a reaction zone B in which propylene formed in reaction zone A is partially oxidized in the presence of remaining propane to give the target product. The target product is removed from the product gas B formed in reaction zone B and propane present in the remaining residual gas is absorbed therefrom into a solvent and, after release from the absorbate, recycled into reaction zone A.

    摘要翻译： 制备丙烯醛或丙烯酸或其混合物的方法作为丙烷的目标产物，其中丙烷在反应区A中在非均相催化下部分脱氢，形成的分子氢至少部分地燃烧到水中，存在于 在反应区A中形成的产物气体A被除去，产物气体A另外用于给反应区B充电，其中反应区A中形成的丙烯在剩余的丙烷存在下被部分氧化，得到目标产物。 将目标产物从反应区B中形成的产物气体B中除去，剩余的残余气体中存在的丙烷从其中吸收到溶剂中，并且在从吸收物质释放后再循环到反应区A中。