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    Compositions containing addition polymers prepared using crosslinkable protective colloids
    2.
    发明授权
    Compositions containing addition polymers prepared using crosslinkable protective colloids 失效
    含有使用可交联保护胶体制备的加成聚合物的组合物

    公开(公告)号：US06559259B2

    公开(公告)日：2003-05-06

    申请号：US09939992

    申请日：2001-08-27

    申请人： Klaus Kohlhammer ,  Gerhard Koegler ,  Monika Rockinger ,  Walter Dobler

    发明人： Klaus Kohlhammer ,  Gerhard Koegler ,  Monika Rockinger ,  Walter Dobler

    IPC分类号： C08F1230

    CPC分类号： C04B40/0042 ,  C04B2103/0057 ,  C08F2/24 ,  D21H17/39 ,  C04B24/163 ,  C04B24/26

    摘要： A water-soluble, crosslinkable protective colloid is provided having a molecular weight of least than 500,000 comprising: a) 20 to 959 by weight of monomer units containing sulphonic acid or sulphonate groups, b) 4 to 800 by weight of monomer units containing N-methylol or N-alkoxymethyl groups, and c) 0.1 to 20% by weight of hydrophobic monomer units such as water insoluble ethylenically unsaturated compounds and the hydrophobic end groups of initiator radicals or regulator molecules. Optionally, up to 50% by weight of the monomer units containing sulphonic acid or sulphonate groups can be replaced by monomer units containing carboxyl groups or monomer units containing amide groups.

    摘要翻译： 提供分子量小于500,000的水溶性可交联保护胶体，其包含：a）20至959重量份含有磺酸或磺酸酯基团的单体单元，b）4至800重量份含有N- 羟甲基或N-烷氧基甲基，和c）0.1至20重量％的疏水性单体单元如水不溶性烯属不饱和化合物和引发剂基团或调节剂分子的疏水端基。 任选地，含有磺酸或磺酸盐基团的多至50重量％的单体单元可以被含有羧基的单体单元或含有酰胺基团的单体单元代替。

    Solvent-resistant textile binder
    3.
    发明授权
    Solvent-resistant textile binder 有权
    耐溶剂织物粘合剂

    公开(公告)号：US06174568B1

    公开(公告)日：2001-01-16

    申请号：US09242034

    申请日：1999-02-05

    申请人： Klaus Kohlhammer ,  Gerhard Koegler ,  Andreas Lumpp ,  Monika Rockinger

    发明人： Klaus Kohlhammer ,  Gerhard Koegler ,  Andreas Lumpp ,  Monika Rockinger

    IPC分类号： B05D302

    CPC分类号： D04H1/4258 ,  C08F2/26 ,  D04H1/587 ,  D04H1/64 ,  D04H1/645 ,  D06M15/227 ,  D06M15/233 ,  D06M15/263 ,  D06M15/285 ,  D06M15/29 ,  D06M15/333 ,  D06M23/08

    摘要： A textile binder in the form an aqueous copolymer dispersion or of a copolymer powder obtainable by means of free-radical emulsion polymerization of a) one or more monomers from the group consisting of vinyl esters, esters of acrylic acid and methacrylic acid, vinylaromatics, vinyl halides and alpha-olefins and b) from 0.01 to 10% by weight, based on the overall weight of the copolymer, of one or more monomers b1) from the group consisting of the N-(alkoxymethyl)acrylamides and N-(alkoxymethyl)-methacrylamides or one or more monomers b2) from the group consisting of N-methylolacrylamide and N-methylolmethacrylamide, or mixtures b1) and b2), where as emulsifier(s) from 0.01 to 10% by weight, based on the overall weight of the copolymer, of one or more emulsifiers from the group of the monoesters or diesters of sulfosuccinic acid with linear, unbranched or branched, or cycloaliphatic alcohols, are employed or are added to the aqueous copolymer dispersion after the end of the emulsion polymerization.

    摘要翻译： 一种纺织粘合剂，其形式为水性共聚物分散体或通过自由基乳液聚合获得的共聚物粉末，a）一种或多种由乙烯基酯，丙烯酸和甲基丙烯酸酯，乙烯基芳族化合物，乙烯基卤化物组成的组中的单体 （α-烷氧基甲基）丙烯酰胺和N-（烷氧基甲基） - 甲基丙烯酰胺组成的组中的一种或多种单体b1），基于共聚物的总重量，重量比为0.01至10％ 或一种或多种单体b2），其由以下组分组成的组：N-羟甲基丙烯酰胺和N-羟甲基甲基丙烯酰胺，或混合物b1）和b2），其中，基于共聚物的总重量为0.01至10重量％的乳化剂 的一种或多种来自磺基琥珀酸的单酯或二酯与直链，无支链或支链或脂环族醇的乳化剂，或者在乳液聚合物结束后加入到水性共聚物分散体中 rization。

    Use of aqueous dispersions of two-phase emulsion graft copolymers as binders for stiffening materials in the textile and leather industry
    4.
    发明授权
    Use of aqueous dispersions of two-phase emulsion graft copolymers as binders for stiffening materials in the textile and leather industry 失效
    使用两相乳液接枝共聚物的水分散体作为粘合剂用于纺织和皮革工业中的加强材料

    公开(公告)号：US5614049A

    公开(公告)日：1997-03-25

    申请号：US633816

    申请日：1996-04-17

    申请人： Klaus Kohlhammer ,  Gerhard Koegler ,  Monika Schwemmer

    发明人： Klaus Kohlhammer ,  Gerhard Koegler ,  Monika Schwemmer

    IPC分类号： C08L51/00 ,  D04H1/435 ,  D04H1/64 ,  D04H3/011 ,  D04H3/12 ,  D06M15/227 ,  D06M15/263 ,  D06M15/327 ,  D06M15/333 ,  D06M17/04 ,  D06M17/06 ,  D06N3/04 ,  B29C65/00 ,  A43B23/08 ,  A43B23/14 ,  A43B23/16

    CPC分类号： D04H3/011 ,  C08L51/003 ,  D04H1/435 ,  D04H1/64 ,  D04H3/12 ,  D06M15/227 ,  D06M15/263 ,  D06M15/327 ,  D06M15/333 ,  D06M17/04 ,  D06M17/06 ,  D06N3/04 ,  Y10T156/1043

    摘要： Process for the stiffening of textile or leather materials, includes (a) applying an aqueous polymer dispersion to a textile structure on the basis of a woven or nonwoven fabric, or a leather material; (b) drying the textile structure or leather material; and (c) the stiffening material thus produced is deformed and glued with the textile and leather material to be stiffened, in which an aqueous dispersion of a two-phase, sealable emulsion graft copolymer having a soft phase and a hard phase is applied. The hard phase has a glass transition temperature of Tg of at least 50.degree. C. and includes monomer units such as methyl methacrylate, styrene, diisopropyl fumarate and vinyl chloride. The soft phase has a glass transition temperature Tg of at least 30.degree. C. lower than the Tg of the hard phase, and the soft phase has monomer units such as methyl acrylate, ethyl acrylate, isopropyl acrylate, n-butyl acrylate, t-butyl acrylate, 2-ethylhexyl acrylate, vinyl acetate, vinyl propionate, isopropenyl acetate, vinyl laurate, vinyl esters of saturated, .alpha.-branched monocarboxylic acids having 9 to 10 carbon atoms, ethylene, propylene or 1,3-butadiene.

    摘要翻译： PCT No.PCT / EP94 / 03721 Sec。 371日期：1996年4月17日 102（e）日期1996年4月17日PCT 1994年11月10日PCT PCT。 公开号WO95 / 13418 日期1995年5月18日纺织或皮革材料的加固过程包括（a）以纺织或非织造织物或皮革材料为基础，将纺织品结构上的聚合物水分散体涂覆; （b）干燥纺织结构或皮革材料; 和（c）由此产生的加强材料变形并与织物和皮革材料粘合以加固，其中施加具有软相和硬相的两相可密封的乳液接枝共聚物的水分散体。 硬相的玻璃化转变温度为Tg至少为50℃，并且包括单体单元如甲基丙烯酸甲酯，苯乙烯，富马酸二异丙酯和氯乙烯。 软相的玻璃化转变温度Tg低于硬相的Tg至少30℃，软相具有单体单元如丙烯酸甲酯，丙烯酸乙酯，丙烯酸异丙酯，丙烯酸正丁酯，叔丁基丙烯酸酯， 丙烯酸丁酯，丙烯酸2-乙基己酯，乙酸乙烯酯，丙酸乙烯酯，乙酸异丙烯酯，月桂酸乙烯酯，具有9〜10个碳原子的饱和的α-支化单羧酸乙烯酯，乙烯，丙烯或1,3-丁二烯。

    Fiber binding powder composition for consolidating fiber materials
    5.
    发明授权
    Fiber binding powder composition for consolidating fiber materials 失效
    用于固结纤维材料的纤维粘合粉末组合物

    公开(公告)号：US06511561B1

    公开(公告)日：2003-01-28

    申请号：US09336272

    申请日：1999-06-18

    申请人： Klaus Kohlhammer ,  Gerhard Koegler ,  Susanne Seidl ,  Sabine Gruber ,  Herbert Proebstl

    发明人： Klaus Kohlhammer ,  Gerhard Koegler ,  Susanne Seidl ,  Sabine Gruber ,  Herbert Proebstl

    IPC分类号： B32B3100

    CPC分类号： D06M23/08 ,  D06M15/227 ,  D06M15/233 ,  D06M15/248 ,  D06M15/263 ,  D06M15/327 ,  D06M15/333

    摘要： Disclosed is a fiber binding powder composition for consolidating fiber materials, comprising a) a polymer powder based on a polyvinyl alcohol stabilized polymer of one or more monomers selected from the group consisting of the vinyl esters of branched or unbranched carboxylic acids having 1 to 12 carbon atoms, the esters of acrylic acid and methacrylic acid with branched or unbranched alcohols having 1 to 12 carbon atoms, aromatic vinyl compounds, vinyl halides, olefins and dienes, and b) an inorganic compound which is solid at room temperature and which enters a chemical bond with the OH groups of the polyvinyl alcohol on introduction of said powder into water.

    摘要翻译： 公开了一种用于固结纤维材料的纤维结合粉末组合物，其包含：a）基于聚乙烯醇稳定化聚合物的一种或多种单体的聚合物粉末，所述单体选自具有1至12个碳原子的支链或非支链羧酸的乙烯基酯 丙烯酸和甲基丙烯酸与具有1至12个碳原子的支链或非支链醇的酯，芳族乙烯基化合物，乙烯基卤化物，烯烃和二烯的酯，和b）在室温下为固体并与其进入化学键的无机化合物 在将所述粉末引入水中时，聚乙烯醇的OH基团。

    Method of using aqueous polymer dispersions as lamination adhesives for glossy films
    6.
    发明授权
    Method of using aqueous polymer dispersions as lamination adhesives for glossy films 失效
    使用聚合物水分散体作为光泽膜的层压粘合剂的方法

    公开(公告)号：US5474638A

    公开(公告)日：1995-12-12

    申请号：US201266

    申请日：1994-02-24

    申请人： Klaus Kohlhammer ,  Wilfried Huster ,  Walter Dobler

    发明人： Klaus Kohlhammer ,  Wilfried Huster ,  Walter Dobler

    IPC分类号： B32B27/00 ,  B32B7/12 ,  C08F28/00 ,  C08F220/10 ,  C08F220/12 ,  C08F220/26 ,  C08F220/28 ,  C08F228/02 ,  C08J5/12 ,  C09J133/04 ,  C09J133/06 ,  C09J133/08 ,  C09J129/02

    CPC分类号： B32B7/12 ,  C09J133/06

    摘要： The invention relates to a method of using aqueous polymer dispersions based on acrylate-methacrylate copolymers as lamination adhesives for heat sealed glossy films, where the aqueous polymer dispersions have a solids content of from 20 to 65% by weight, the copolymer has a glass transition temperature of from -35.degree. to -10.degree. C., a K value of from 40 to 100 and a mean particle size of less than 200 nm, and the copolymer is obtainable by free-radical emulsion polymerization of:a) from 50 to 80 parts by weight of one or more comonomers from the group consisting of alkyl acrylates of alcohols having 2 to 10 carbon atoms,b) from 10 to 25 parts by weight of one or more comonomers from the group consisting of alkyl methacrylates of alcohols having 1 to 10 carbon atoms, andc1) from 0 to 10 parts by weight of one or more vinyl-aromatic comonomers,c2) from 0.1 to 4.0 parts by weight of one or more .alpha.,.beta.-unsaturated, monoolefinic carboxylic acids,c3) from 0 to 4.0 parts by weight of one or more .alpha..beta.-unsaturated, monoolefinic carboxamides,c4) from 0 to 8 parts by weight of one or more comonomers from the group consisting of hydroxyalkyl (meth)acrylates made from esters of acrylic acid or methacrylic acid and diols having 2 to 10 carbon atoms, andc5) from 0.1 to 4.0 parts by weight of one or more .alpha..beta.-unsaturated, monoolefinic compounds containing sulfonyl or sulfonate groups.

    摘要翻译： 本发明涉及使用基于丙烯酸酯 - 甲基丙烯酸酯共聚物的水性聚合物分散体作为热密封光泽膜的层压粘合剂的方法，其中聚合物水分散体的固体含量为20-65重量％，该共聚物具有玻璃化转变 温度为-35〜-10℃，K值为40〜100，平均粒径小于200nm，共聚物可通过自由基乳液聚合得到：a）从50〜 80重量份由具有2至10个碳原子的醇的丙烯酸烷基酯组成的组中的一种或多种共聚单体，b）10至25重量份的一种或多种共聚单体，其由具有1个 至少10个碳原子，和c1）0至10重量份的一种或多种乙烯基芳族共聚单体，c2）0.1至4.0份重量的一种或多种α，β-不饱和单烯烃羧酸，c3） 0〜4.0份重量 t的一种或多种αβ-不饱和单烯烃甲酰胺，c4）0至8份重量的一种或多种由丙烯酸或甲基丙烯酸的酯和二醇制成的（甲基）丙烯酸羟烷基酯的共聚单体，其具有2 至10个碳原子，和c5）0.1至4.0重量份的一种或多种含有磺酰基或磺酸酯基团的α不饱和单烯烃化合物。

    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase
    8.
    发明授权
    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase 失效
    具有改善接枝基质和接枝聚合物相之间的相结合的接枝共聚物

    公开(公告)号：US5384381A

    公开(公告)日：1995-01-24

    申请号：US152740

    申请日：1993-11-15

    申请人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    发明人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    IPC分类号： C08F291/00 ,  C07C409/38 ,  C08F4/34 ,  C08F261/06 ,  C08F293/00 ,  C08F218/04

    CPC分类号： C08F261/06 ,  C08F293/00

    摘要： Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.9% by weight of one or more comonomers from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and/or vinyl ethers.The graft copolymers are useful as binders in the textile industry as heat stable binders, as adhesives in plasters and as binders in emulsion paints.

    摘要翻译： 具有改进的接枝基质和接枝聚合物之间的相结合的接枝共聚物由以下物质制备：a）接枝聚合物相，其含有一种或多种由具有1至10个碳的醇的（甲基）丙烯酸酯组成的组中的单体 原子，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基卤化物，苯乙烯和苯乙烯衍生物，和b）含有0.01-20重量％的烯属不饱和过氧化合物 其中R 1是化学键或具有1至10个碳原子的直链或支链烷基或具有3至10个碳原子的环烷基，所述通式I或II其中R 1， R2和R3是具有1至4个碳原子的烷基，R4是烷基或具有3-12个碳原子的烷基取代的苯基，R5是具有3-12个碳原子的环烷基，从80到 99.9重量％的一种或多种共聚单体f 由具有1-10个碳原子的（甲基）丙烯酸酯，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基芳族化合物，乙烯基卤化物和/或乙烯基醚构成的组中。 接枝共聚物可用作纺织工业中的粘合剂，作为热稳定粘合剂，作为膏药中的粘合剂和乳液涂料中的粘合剂。

    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase
    9.
    发明授权
    Graft copolymers having improved phase binding between the graft base and the grafted-on polymer phase 失效
    具有改善接枝基质和接枝聚合物相之间的相结合的接枝共聚物

    公开(公告)号：US5304609A

    公开(公告)日：1994-04-19

    申请号：US967662

    申请日：1993-10-28

    申请人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    发明人： Klaus Kohlhammer ,  Hermann Petersen ,  Walter Dobler

    IPC分类号： C08F291/00 ,  C07C409/38 ,  C08F4/34 ,  C08F261/06 ,  C08F293/00 ,  C08F263/04

    CPC分类号： C08F261/06 ,  C08F293/00

    摘要： Graft copolymers having improved phase binding between the graft base and the grafted-on polymer, are prepared from:a) a grafted-on polymer phase containing one or more monomers from the group consisting of (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinyl halides, styrene and styrene derivatives, andb) a peroxy group-containing copolymer phase containing from 0.01 to 20% by weight of an olefinically unsaturated peroxy compound of the general formula I or II ##STR1## where R.sup.1 is a chemical bond or a linear or branched alkyl chain having 1 to 10 carbon atoms or a cycloalkyl group having 3 to 10 carbon atoms, R.sup.2 and R.sup.3 are an alkyl group having 1 to 4 carbon atoms, R.sup.4 is an alkyl group or an alkyl-substituted phenyl group having 3 to 12 carbon atoms, and R.sup.5 is a cycloalkyl group having 3 to 12 carbon atoms, and from 80 to 99.9% by weight of one or more comonomers from the group consisting of the (meth)acrylates of alcohols having 1 to 10 carbon atoms, vinyl esters of saturated aliphatic carboxylic acids having 2 to 10 carbon atoms, olefins, vinylaromatic compounds, vinyl halides and/or vinyl ethers.The graft copolymers are useful as binders in the textile industry as heat stable binders, as adhesives in plasters and as binders in emulsion paints.

    摘要翻译： 具有改进的接枝基质和接枝聚合物之间的相结合的接枝共聚物由以下物质制备：a）接枝聚合物相，其含有一种或多种由具有1至10个碳的醇的（甲基）丙烯酸酯组成的组中的单体 原子，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基卤化物，苯乙烯和苯乙烯衍生物，和b）含有0.01-20重量％的烯属不饱和过氧化合物 通式I或II（*化学结构*）（I）或（*化学结构*）（II）其中R1是化学键或具有1-10个碳原子的直链或支链烷基链或具有 3〜10个碳原子，R2和R3为碳原子数1〜4的烷基，R4为碳原子数3〜12的烷基或烷基取代苯基，R5为碳原子数为3〜12的环烷基 原子，从80到99.9％ 一种或多种由具有1-10个碳原子的醇的（甲基）丙烯酸酯组成的组中的一种或多种共聚单体的重量，具有2-10个碳原子的饱和脂族羧酸的乙烯基酯，烯烃，乙烯基芳族化合物，乙烯基卤化物和/或乙烯基 醚类。 接枝共聚物可用作纺织工业中的粘合剂，作为热稳定粘合剂，作为膏药中的粘合剂和乳液涂料中的粘合剂。