摘要:
There is provided a process for industrial production of simple 3-carboxy-cis,cis-muconic acid and/or 3-carboxymuconolactone from low molecular mixtures derived from plant components such as vanillin, vanillic acid and protocatechuic acid, via a multistage enzyme reaction. A recombinant plasmid containing a vanillate demethylase gene (vanAB genes), benzaldehyde dehydrogenase gene (ligV gene) and protocatechuate 3,4-dioxygenase gene (pcaHG genes); transformants incorporating the plasmid; and a process for production of 3-carboxy-cis,cis-muconic acid and/or 3-carboxymuconolactone characterized by culturing the transformants in the presence of vanillin, vanillic acid, protocatechuic acid or a mixture of two or more thereof.
摘要:
To provide an industrial purification method of PDC obtained by fermentative production.A method of purifying 2-pyrone-4,6-dicarboxylic acid which comprises including a salt of monovalent to tetravalent cations in a fermentation liquid containing microbially-produced 2-pyrone-4,6-dicarboxylic acid; and a method of purifying 2-pyrone-4,6-dicarboxylic acid which method comprises extracting 2-pyrone-4,6-dicarboxylic acid from a fermentation liquid containing microbially-produced 2-pyrone-4,6-dicarboxylic acid without forming 2-pyrone-4,6-dicarboxylate.
摘要:
There is provided a process for industrial production of simple 3-carboxy-cis,cis-muconic acid and/or 3-carboxymuconolactone from low molecular mixtures derived from plant components such as vanillin, vanillic acid and protocatechuic acid, via a multistage enzyme reaction.A recombinant plasmid containing a vanillate demethylase gene (vanAB genes), benzaldehyde dehydrogenase gene (ligV gene) and protocatechuate 3,4-dioxygenase gene (pcaHG genes); transformants incorporating the plasmid; and a process for production of 3-carboxy-cis,cis-muconic acid and/or 3-carboxymuconolactone characterized by culturing the transformants in the presence of vanillin, vanillic acid, protocatechuic acid or a mixture of two or more thereof.
摘要:
A polyester containing a biomass-derived material in a repeating unit structure and having all of sufficient mechanical strength, easy mold processability into a molded product such as fiber or film, and biodegradability, is provided.A PDC-L-lactic acid copolyester represented by the following formula: —[R1—PDC]x—[OCH(CH3)CO]1-x— (I) [wherein PDC is a dicarboxylic acid residue represented by the following formula (II): R1 is selected from —O(CH2)nO—, —O(CH2CH2O)m— and —O[CH(CH3)CH2O]m—, where n represents an integer of 3 to 6 and m represents an integer of 1 to 4; and is 0.005≦x≦0.2 when n≦4 or m≦2, and is 0.005≦x≦0.4 in other cases]; and a molded product containing the PDC-L-lactic acid copolyester.
摘要:
Industrial-scale fermentative production of 3-carboxy-cis,cis-muconic acid from terephthalic acid. Also, a protocatechuate 4,5-ring-cleaving enzyme gene-disrupted strain in which the gene coding for (a) the amino acid sequence set forth in SEQ ID NO: 1 or 3, or (b) the amino acid sequence set forth in SEQ ID NO: 1 or 3 which has a deletion, substitution, addition and/or insertion of one or more amino acids and exhibits protocatechuate 4,5-ring cleavage activity, present in the chromosomal DNA of microbial cells, has been disrupted; recombinant plasmids comprising the Tph gene and protocatechuate 3,4-dioxygenase gene; transformants obtained by introducing the recombinant plasmids into the disrupted strain; and a process for production of 3-carboxy-cis,cis-muconic acid and/or 3-carboxymuconolactone characterized by culturing the transformants in the presence of terephthalic acid.
摘要翻译:从对苯二甲酸工业规模发酵生产3-羧基 - 顺式,顺式 - 粘康酸。 此外,原儿茶素4,5环切割酶基因破坏的菌株,其中编码(a)SEQ ID NO:1或3所示的氨基酸序列的基因,或(b)阐述的氨基酸序列 在具有一个或多个氨基酸的缺失,取代,添加和/或插入并且表现出存在于微生物细胞的染色体DNA中的原儿茶素4,5-环切割活性的SEQ ID NO:1或3已被破坏; 包含Tph基因和原儿茶素3,4-双加氧酶基因的重组质粒; 通过将重组质粒导入破碎的菌株获得的转化体; 以及3-羧基 - 顺式,顺式 - 粘酸和/或3-羧基粘土内酯的制备方法,其特征在于在对苯二甲酸存在下培养转化体。
摘要:
The invention provides biodegradable polyesters, polyurethanes, comprising 3-carboxymuconolactone as a structural unit, 3-carboxymuconolactone esters and a process for their production.Polyesters comprising a repeating unit represented by the following formula (I): [wherein R represents a hydrocarbon-based divalent residue which, in the structure, optionally contains a heteroatom without an active hydrogen], polyurethanes comprising the polyester structure; 3-carboxymuconolactone esters; and a process for their production.
摘要:
A high-elasticity biodegradable polymer comprising PDC, which has excellent solubility in solvents and reactants, in their repeating unit structures is provided in an inexpensive manner.A polymer comprising a repeating unit represented by the following formula (I): wherein R1 and R2 each independently represent a divalent hydrocarbon residue with no active hydrogens in its structure and optionally containing a heteroatom; X represents O or NH; x represents an integer of at least 1; and m and n represent 0 or 1; and a process for their production.
摘要:
Disclosed is an active energy ray-curing composition containing an active energy ray-curing prepolymer (A) obtainable by a reaction of an acrylic-based prepolymer having a hydroxyl group and an acrylic monomer (a4) having an isocyanate group, an active energy ray-curing compound (B) having a benzotriazole group, another active energy ray-curing compound (C) differing from the (A) component and the (B) component, and inorganic oxide particles (D). The acrylic-based prepolymer having the hydroxyl group is a copolymer that includes an acrylic monomer (a1) having a piperidinyl group, an acrylic monomer (a2) having a hydroxyl group, etc., as monomer units.
摘要:
A curing-type coating-agent composition according to the present invention contains: Component (A) including a urethane adduct compound exhibiting weatherability in an amount of from 99 to 65 parts by mass; Component (B) comprising a reaction product between a colloidal silica and an alkoxysilane compound having a maleimide group in an amount of from 1 to 35 parts by mass; a radical-polymerization initiator serving as Component (C) in an amount of from 0.1 to 10 parts by mass; an ultraviolet absorber serving as Component (D) in an amount of from 1 to 12 parts by mass; and an organic solvent serving as Component (E) in an amount of from 10 to 1,000 parts by mass; with respect to a sum of Component (A) and Component (B) being taken as 100 parts by mass.The composition according to the present invention demonstrates excellent wear resistance and weatherability as a coating agent for plastic substrate, or the like, which is employed outside.
摘要:
The present invention provides a noninvasive alcohol sensor that measures ethanol concentration with high accuracy by suppressing error dependent on glucose concentration. An alcohol sensor 10 includes first light-emitting means 21, second light-emitting means 22 and third light-emitting means 23. The first light-emitting means 21 radiates light having a wavelength of 1185 nm. This wavelength of 1185 nm is a wavelength at which the light absorbance of water and the light absorbance of ethanol are equal. The second light-emitting means 22 radiates light having a wavelength of 1710 nm. The third light-emitting means 23 radiates light having a wavelength of 1750 nm. Light detection means 30 detects the intensity of each light, and control means 60 calculates ethanol concentration based on the detected light intensity.