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    Silica supported transition metal catalyst
    1.
    发明授权
    Silica supported transition metal catalyst 失效
    二氧化硅负载过渡金属催化剂

    公开(公告)号：US5231151A

    公开(公告)日：1993-07-27

    申请号：US854175

    申请日：1992-03-20

    申请人： Lee Spencer ,  Brian W. S. Kolthammer ,  Miriam P. Ripplinger ,  Jeffrey J. Wooster ,  Pak-Wing S. Chum ,  Jacquelyn A. deGroot

    发明人： Lee Spencer ,  Brian W. S. Kolthammer ,  Miriam P. Ripplinger ,  Jeffrey J. Wooster ,  Pak-Wing S. Chum ,  Jacquelyn A. deGroot

    IPC分类号： C08J5/18 ,  B29C55/02 ,  B29K23/00 ,  B29L7/00 ,  C08F4/646 ,  C08F4/658 ,  C08F4/685 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/16

    CPC分类号： C08F10/00 ,  Y10S428/91 ,  Y10T428/26 ,  Y10T428/31855

    摘要： A transition metal containing catalyst useful for the polymerization of .alpha.-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m.sup.2 /g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to saturate the surface of the support material; (C) mixing the product form (B) with (3) a titanium compound or a combination of a titanium compound and (4) a vanadium compound and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to allow complete reaction of the titanium compound and the vanadium compound with the organomagnesium moieties remaining on the solid support; (D) mixing the product from (C) with an inert organic solution of (5) a Group IIIA metal alkyl halide at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to complete the reduction of the titanium and vanadium, if present, compounds to their final oxidation state.

    摘要翻译： 用于α-烯烃聚合的含过渡金属的催化剂通过以下步骤制备：（A）在惰性气氛中形成不含氧和水分的淤浆（1）多孔无机氧化物载体材料，其选自二氧化硅，氧化铝 ，或二氧化硅和氧化铝的组合，所述载体材料每克载体材料含有不大于约5毫摩尔羟基，粒度不大于约10微米，表面积为约50至约800平方米/ g在惰性有机液体介质中; （B）将所述浆料与（2）醇盐混合并在约-20℃至约120℃的温度下搅拌所得混合物足以使载体材料表面饱和的时间; （C）将产品形式（B）与（3）钛化合物或钛化合物和（4）钒化合物的组合混合并在约-20℃至约120℃的温度下搅拌所得混合物 在足以允许钛化合物和钒化合物与残留在固体载体上的有机镁部分完全反应的时间; （D）将来自（C）的产物与（5）IIIA族金属烷基卤的惰性有机溶液在约-20℃至约120℃的温度下混合足以完成还原的时间 的钛和钒（如果存在）化合物达到其最终氧化态。

    Silica supported transition metal catalyst
    2.
    发明授权
    Silica supported transition metal catalyst 失效
    二氧化硅负载过渡金属催化剂

    公开(公告)号：US5487938A

    公开(公告)日：1996-01-30

    申请号：US336947

    申请日：1994-11-10

    申请人： Lee Spencer ,  Brian W. S. Kolthammer ,  Miriam P. Ripplinger ,  Jeffrey J. Wooster ,  Pak-Wing S. Chum ,  Jacquelyn A. deGroot

    发明人： Lee Spencer ,  Brian W. S. Kolthammer ,  Miriam P. Ripplinger ,  Jeffrey J. Wooster ,  Pak-Wing S. Chum ,  Jacquelyn A. deGroot

    IPC分类号： C08J5/18 ,  B29C55/02 ,  B29K23/00 ,  B29L7/00 ,  C08F4/646 ,  C08F4/658 ,  C08F4/685 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/16 ,  B32B7/12

    CPC分类号： C08F10/00 ,  Y10S428/91 ,  Y10T428/26 ,  Y10T428/31855

    摘要： A transition metal containing catalyst useful for the polymerization of .alpha.-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m.sup.2 /g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to saturate the surface of the support material; (C) mixing the product form (B) with (3) a titanium compound or a combination of a titanium compound and (4) a vanadium compound and stirring the resultant mixture at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to allow complete reaction of the titanium compound and the vanadium compound with the organomagnesium moieties remaining on the solid support; (D) mixing the product from (C) with an inert organic solution of (5) a Group IIIA metal alkyl halide at a temperature of from about -20.degree. C. to about 120.degree. C. for a time sufficient to complete the reduction of the titanium and vanadium, if present, compounds to their final oxidation state. Ethylene/alpha-olefin copolymers which have greater than 17 percent high density fraction and a M.sub.w /M.sub.n ratio of less than about 3.6 are shown to be useful in making cast films which have good stretchability and good puncture resistance. Copolymers of the present invention having the specified properties are especially useful in making the films.

    摘要翻译： 用于α-烯烃聚合的含过渡金属的催化剂通过以下步骤制备：（A）在惰性气氛中形成不含氧和水分的淤浆（1）多孔无机氧化物载体材料，其选自二氧化硅，氧化铝 ，或二氧化硅和氧化铝的组合，所述载体材料每克载体材料含有不大于约5毫摩尔羟基，粒度不大于约10微米，表面积为约50至约800平方米/ g在惰性有机液体介质中; （B）将所述浆料与（2）醇盐混合并在约-20℃至约120℃的温度下搅拌所得混合物足以使载体材料表面饱和的时间; （C）将产品形式（B）与（3）钛化合物或钛化合物和（4）钒化合物的组合混合并在约-20℃至约120℃的温度下搅拌所得混合物 在足以允许钛化合物和钒化合物与残留在固体载体上的有机镁部分完全反应的时间; （D）将来自（C）的产物与（5）IIIA族金属烷基卤的惰性有机溶液在约-20℃至约120℃的温度下混合足以完成还原的时间 的钛和钒（如果存在）化合物达到其最终氧化态。 显示出具有大于17％的高密度分数和小于约3.6的Mw / Mn比的乙烯/α-烯烃共聚物可用于制备具有良好的拉伸性和良好的耐穿刺性的流延薄膜。 具有特定性质的本发明的共聚物在制备膜中特别有用。

    Silica supported transition metal catalyst
    3.
    发明授权
    Silica supported transition metal catalyst 失效
    二氧化硅负载过渡金属催化剂

    公开(公告)号：US06172173B2

    公开(公告)日：2001-01-09

    申请号：US08946785

    申请日：1997-10-08

    申请人： Lee Spencer ,  Brian W. S. Kolthammer ,  Miriam P. Ripplinger ,  Jeffrey J. Wooster ,  Pak-Wing S. Chum ,  Jacquelyn A. deGroot

    发明人： Lee Spencer ,  Brian W. S. Kolthammer ,  Miriam P. Ripplinger ,  Jeffrey J. Wooster ,  Pak-Wing S. Chum ,  Jacquelyn A. deGroot

    IPC分类号： C08F1014

    CPC分类号： C08L23/04 ,  C08F110/02 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2308/00 ,  C08L2314/02 ,  C08L2666/04 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/24

    摘要： A polymer produced by a transition metal containing catalyst useful for the polymerization of &agr;-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m2/g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about −20° C. to about 120° C. for a time sufficient to saturate the surface of the support material; (C) mixing the product form (B) with (3) a titanium compound or a combination of a titanium compound and (4) a vanadium compound and stirring the resultant mixture at a temperature of from about −20° C. to about 120° C. for a time sufficient to allow complete reaction of the titanium compound and the vanadium compound with the organomagnesium moieties remaining on the solid support; (D) mixing the product from (C) with an inert organic solution of (5) a Group IIIA metal alkyl halide at a temperature of from about −20° C. to about 120° C. for a time sufficient to complete the reduction of the titanium and vanadium, if present, compounds to their final oxidation state. Ethylene/alpha-olefin copolymers which have greater than 17 percent high density fraction and a Mw/Mn ratio of less than about 3.6 are shown to be useful in making cast films which have good stretchability and good puncture resistance. Copolymers of the present invention having the specified properties are especially useful in making the films.

    摘要翻译： 由用于α-烯烃聚合的含过渡金属的催化剂制备的聚合物是通过（A）在惰性气氛中形成的，其中不包括氧气和水分，（1）多孔无机氧化物载体材料的浆料选自 的二氧化硅，氧化铝或二氧化硅和氧化铝的组合，所述载体材料每克载体材料含有不大于约5毫摩尔羟基，粒径不大于约10微米，表面积为约50至 在惰性有机液体介质中约800m 2 / g; （B）将所述浆料与（2）醇盐混合并在约-20℃至约120℃的温度下搅拌所得混合物足以使载体材料表面饱和的时间; （C）将产品形式（B）与（3）钛化合物或钛化合物和（4）钒化合物的组合混合并在约-20℃至约120℃的温度下搅拌所得混合物 在足以允许钛化合物和钒化合物与残留在固体载体上的有机镁部分完全反应的时间; （D）将来自（C）的产物与（5）IIIA族金属烷基卤的惰性有机溶液在约-20℃至约120℃的温度下混合足以完成还原的时间 的钛和钒（如果存在）化合物达到其最终氧化态。 显示出具有大于17％的高密度分数和小于约3.6的Mw / Mn比的乙烯/α-烯烃共聚物可用于制备具有良好的拉伸性和良好的耐穿刺性的流延薄膜。 具有特定性质的本发明的共聚物在制备膜中特别有用。

    Cast stretch film of interpolymer compositions
    4.
    发明授权
    Cast stretch film of interpolymer compositions 有权
    互聚物组合物的拉伸膜

    公开(公告)号：US06812289B2

    公开(公告)日：2004-11-02

    申请号：US10200814

    申请日：2002-07-22

    申请人： Jozef J. I. Van Dun ,  Jacquelyn A. deGroot ,  Pradeep Jain ,  Kalyan Sehanobish ,  Pak-Wing S. Chum

    发明人： Jozef J. I. Van Dun ,  Jacquelyn A. deGroot ,  Pradeep Jain ,  Kalyan Sehanobish ,  Pak-Wing S. Chum

    IPC分类号： C08L2300

    CPC分类号： B32B27/32 ,  Y10S526/943

    摘要： This invention relates to cast films prepared from interpolymer compositions comprising; (A) a substantially linear ethylene/&agr;-olefin interpolymer present in the composition in an amount of from about 10 to about 100% by weight based on the combined weight of Components A and B; and (B) a heterogeneous interpolymer present in the composition in an amount of from about 0 to about 90% by weight based on the combined weight of Components A and B; and wherein said interpolymer composition has an I10/I2 value of −1.2−1.3* log(I2) The interpolymer compositions are useful in cast stretch film manufacture with the resulting cast films having an excellent balance of strength and processability.

    摘要翻译： 本发明涉及由互聚物组合物制备的流延膜，其包含：（A）组合物中基本上线性的乙烯/α-烯烃互聚物，其量为约10至约100重量％，基于组分A和 B; 和（B）基于组分A和B的组合重量，组合物中存在的异构互聚物的量为约0至约90重量％; 并且其中所述互聚物组合物的I 10 / I 2值<约10.0，并且其特征在于具有100rad / s的粘度和满足以下关系之一的弛豫时间（τ）;或所述互聚物组合物可用于铸塑拉伸膜 制造出具有优异的强度和加工性能的所得流延薄膜。

    Blends of .alpha.-olefin/vinyl aromatic monomer and/or aliphatic or cycloaliphatic vinyl or vinylidene monomer interpolymers
    10.
    发明授权
    Blends of .alpha.-olefin/vinyl aromatic monomer and/or aliphatic or cycloaliphatic vinyl or vinylidene monomer interpolymers 失效
    α-烯烃/乙烯基芳族单体和/或脂族或脂环族乙烯基或亚乙烯基单体互聚物的共混物

    公开(公告)号：US6166145A

    公开(公告)日：2000-12-26

    申请号：US121461

    申请日：1998-07-23

    申请人： Martin J. Guest ,  Yunwa W. Cheung ,  John J. Gathers ,  Pak-Wing S. Chum

    发明人： Martin J. Guest ,  Yunwa W. Cheung ,  John J. Gathers ,  Pak-Wing S. Chum

    IPC分类号： C08J5/18 ,  C08J9/00 ,  C08L23/00 ,  C08L23/04 ,  C08L23/08 ,  C08L25/02 ,  C08L25/04 ,  C08L25/08 ,  C09J123/02 ,  C09J125/02 ,  C09J145/00 ,  C09K3/10 ,  D01F6/44 ,  C08L45/00

    CPC分类号： C08L23/04 ,  C08L23/0815 ,  C08L23/0838 ,  C08L25/02 ,  C08L2205/02 ,  Y10T428/1397 ,  Y10T428/2913 ,  C08L2666/04

    摘要： Blends of polymeric materials comprising a plurality of substantially random interpolymers each interpolymer comprising:(1) from about 1 to about 65 mole percent of polymer units derived from either(a) at least one vinyl aromatic monomer or(b) at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, or(c) a combination of at least one vinyl aromatic monomer and at least one aliphatic or cycloaliphatic vinyl or vinylidene monomer, and(2) from about 35 to about 99 mole percent of polymer units derived from ethylene and/or at least one aliphatic alpha olefin having from 3 to 20 carbon atoms; and wherein:the amount of polymer units derived from vinyl aromatic monomer and/or aliphatic or cycloaliphatic vinyl or vinylidene monomer in any interpolymer component differs from that amount in another interpolymer component by at least 0.5 mole percent.These blends of interpolymer components give enhanced properties or processability when compared to the individual polymers comprising the blend.

    摘要翻译： 包含多个基本无规共聚体的聚合材料的共混物，每个共聚体包含：（1）约1至约65摩尔％的衍生自（a）至少一种乙烯基芳族单体的聚合物单元或（b）至少一种脂族或 脂环族乙烯基或亚乙烯基单体，或（c）至少一种乙烯基芳族单体和至少一种脂族或脂环族乙烯基或亚乙烯基单体的组合，和（2）约35至约99摩尔％的衍生自乙烯和 /或至少一种具有3至20个碳原子的脂族α-烯烃; 并且其中：衍生自乙烯基芳族单体和/或任何互聚物组分中的脂族或脂环族乙烯基或亚乙烯基单体的聚合物单元的量与另一互聚物组分中的量的量不同至少为0.5摩尔％。 当与包含共混物的各种聚合物相比时，互聚物组分的这些共混物提供了增强的性能或加工性能。