Flame-proofed moulding materials
    1.
    发明授权
    Flame-proofed moulding materials 失效
    防火成型材料

    公开(公告)号:US6103797A

    公开(公告)日:2000-08-15

    申请号:US284416

    申请日:1999-04-14

    摘要: Thermoplastic molding compositions compriseA) from 30 to 97% by weight of a polyester,B) from 1 to 30% by weight of melamine cyanurate,C) from 1 to 30% by weight of at least one phosphorus-containing flame retardant which contains phosphorus in the valence state -1, -2 or -3,D) from 0 to 60% by weight of other additives and processing aids,where the total of the percentages by weight of components A) to D) is 100%.

    摘要翻译: PCT No.PCT / EP97 / 05605 371 1999年4月14日第 102(e)1999年4月14日PCT 1997年10月10日PCT公布。 第WO98 / 17719号公报 1998年4月30日热塑性成型组合物包含A)30至97重量%的聚酯,B)1至30重量%的三聚氰胺氰尿酸酯,C)1至30重量%的至少一种磷 - 含有阻燃剂,其含有价态为-1,-2或-3的磷,D)0至60重量%的其它添加剂和加工助剂,其中组分A)至D)的重量百分数的总和) 是100%。

    Flame-proof moulding compounds
    2.
    发明授权
    Flame-proof moulding compounds 失效
    防火成型料

    公开(公告)号:US06538054B1

    公开(公告)日:2003-03-25

    申请号:US09284414

    申请日:1999-04-14

    IPC分类号: C08K53492

    摘要: Thermoplastic molding compositions comprise A) from 30 to 96% by weight of a polyester B) from 1 to 30% by weight of melamine cyanurate C) from 1 to 30% by weight of at least one phosphorus-containing flame retardant D) from 0.01 to 5% by weight of at least one ester or amide derived from a saturated or unsaturated aliphatic carboxylic acid having from 10 to 40 carbon atoms and a saturated aliphatic alcohol or &mine having from 2 to 40 carbon atoms E) from 0 to 60% by weight of other additives and processing aids where the total of the percentages by weight of components A) to E) is 100%.

    摘要翻译: 热塑性模塑组合物包含A)30至96重量%的聚酯B)1至30重量%的三聚氰胺氰尿酸酯C)1至30重量%的至少一种含磷阻燃剂D)0.01至5重量% 至少一种衍生自具有10至40个碳原子的饱和或不饱和脂族羧酸的酯或酰胺的重量和具有2至40个碳原子的饱和脂族醇或矿物E)0至60重量%的其它添加剂,以及 加工助剂,其中组分A)至E)的重量百分比的总和为100%。

    Copolymers having long-chain acrylates
    3.
    发明授权
    Copolymers having long-chain acrylates 有权
    具有长链丙烯酸酯的共聚物

    公开(公告)号:US08841363B2

    公开(公告)日:2014-09-23

    申请号:US13123990

    申请日:2009-10-02

    摘要: The present invention relates to copolymers obtainable by free-radical polymerization of i) 10% to 90% by weight, based on the total weight of components i to iv, of at least one monomer selected from the group consisting of a C8-C30 alkyl (meth)acrylate, C8-C30 vinyl ester, C8-C30 vinyl ether, C8-C30 olefin, and triglyceride of unsaturated C8-C30 carboxylic acids; ii) 0.5% to 70% by weight, based on the total weight of components i to iv, of a double-bond-containing monomer having at least one epoxide, isocyanate, carbodiimide, silane, β-dicarbonyl, oxazoline, or anhydride group; iii) 0% to 75% by weight, based on the total weight of components i to iv, of one or more monomers selected from the group consisting of vinylaromatic, C1-C7-alkyl (meth)acrylate, ethylenically unsaturated acetophenone derivative or benzophenone derivative, C1-C7 vinyl ester, C1-C7 vinyl ether, ethylenically unsaturated nitrile, ethylenically unsaturated amide, vinyl halide, C2-C7 olefin, cyclic lactam, and mixtures of these monomers; and iv) 0% to 10% by weight, based on the total weight of components i to iv, of a free-radically polymerizable monomer with carboxylic acid, sulfonic acid or phosphonic acid groups or salts thereof. The invention further relates to polymer mixtures comprising these copolymers and also to the use of the copolymers as chain extenders, compatibilizers and/or hydrolysis stabilizers, to produce paper and cardboard, for surface finishing in the paper, textile, and leather industries, and in adhesives.

    摘要翻译: 本发明涉及可通过自由基聚合获得的共聚物,i)10至90重量%,基于组分i至iv的总重量,至少一种选自下组的单体:C 8 -C 30烷基 (甲基)丙烯酸酯,C8-C30乙烯基酯,C8-C30乙烯基醚,C8-C30烯烃和不饱和C8-C30羧酸的甘油三酯; ii)基于i至iv组分的含有至少一种环氧化物,异氰酸酯,碳二亚胺,硅烷,二羰基,恶唑啉或酸酐的含双键的单体的总重量的0.5重量%至70重量% 组; iii)0至75重量%,基于组分i至iv的总重量,选自乙烯基芳族化合物,(甲基)丙烯酸C 1 -C 7烷基酯,烯属不饱和苯乙酮衍生物或二苯甲酮的一种或多种单体 衍生物,C1-C7乙烯基酯,C1-C7乙烯基醚,烯键式不饱和腈,烯属不饱和酰胺,卤代乙烯基,C 2 -C 7烯烃,环状内酰胺和这些单体的混合物; 和iv)基于组分i至iv的具有羧酸,磺酸或膦酸基团的可自由基聚合的单体或其盐的0重量%至10重量%。 本发明还涉及包含这些共聚物的聚合物混合物,并且还涉及使用共聚物作为增链剂,增容剂和/或水解稳定剂来生产纸和纸板,用于纸,纺织和皮革工业中的表面处理,以及 粘合剂。

    Active Ingredient Compositions for Plant Protection
    6.
    发明申请
    Active Ingredient Compositions for Plant Protection 审中-公开
    用于植物保护的活性成分组合物

    公开(公告)号:US20100122379A1

    公开(公告)日:2010-05-13

    申请号:US12597113

    申请日:2008-04-25

    摘要: The present invention relates to novel active substance compositions for plant protection in the form of finely divided active-substance-containing particles which compositions comprise a) at least one plant protectant; b) at least one polymer P which is not soluble in water and which is degradable by enzymatic hydrolysis, in an amount of at least 20% by weight based on the total amount of the components of the active-substance-comprising particles, and c) at least one hydrolase (EC 3), where at least 90% by weight of the active substance-containing particles of the active substance composition do not exceed a diameter of 500 μm (D90-value) and where components a), b) and c) account for at least 30% by weight of the active substance particles. The invention also relates to a process for their preparation, and to the use of the active substance compositions for the treatment of plants, soils and of seed.

    摘要翻译: 本发明涉及用于植物保护的新颖的活性物质组合物,其形式为细碎的含活性物质的颗粒,其组合物包含a)至少一种植物保护剂; b)至少一种聚合物P,其不溶于水并且可通过酶水解降解,其量为至少20重量%,基于含活性物质颗粒的组分的总量,c )至少一种水解酶(EC 3),其中至少90重量%的活性物质组合物的含活性物质的颗粒不超过500μm的直径(D90值),并且其中组分a),b) 和c)占活性物质颗粒的至少30重量%。 本发明还涉及其制备方法,以及活性物质组合物用于处理植物,土壤和种子的用途。

    Method For Producing an Aqueous Polymer Dispersion
    7.
    发明申请
    Method For Producing an Aqueous Polymer Dispersion 审中-公开
    生产水性聚合物分散体的方法

    公开(公告)号:US20080199925A1

    公开(公告)日:2008-08-21

    申请号:US11916664

    申请日:2006-05-31

    IPC分类号: C12P7/62 C08L67/04

    摘要: A process for preparing an aqueous polymer dispersion, in which, in an aqueous medium, in a first reaction stage, a hydroxycarboxylic acid compound is reacted in the presence of an enzyme and of a dispersant, and also, if appropriate, of a low water solubility organic solvent and/or of an ethylenically unsaturated monomer, to give a polyester, and thereafter, in the presence of the polyester, in a second reaction stage, an ethylenically unsaturated monomer is free-radically polymerized.

    摘要翻译: 一种水性聚合物分散体的制备方法,其中在水性介质中,在第一反应阶段,羟基羧酸化合物在酶和分散剂的存在下,以及如果合适的话,低水 溶解性有机溶剂和/或烯属不饱和单体,得到聚酯,然后在聚酯存在下,在第二反应阶段,烯属不饱和单体自由基聚合。

    Method for producing polyamide 6 of a low extract content, high viscosity stability and low remonomerization rate
    9.
    发明授权
    Method for producing polyamide 6 of a low extract content, high viscosity stability and low remonomerization rate 失效
    低提取物含量的聚酰胺6的制备方法,高粘度稳定性和低再聚合速率

    公开(公告)号:US06525167B1

    公开(公告)日:2003-02-25

    申请号:US09913122

    申请日:2001-08-09

    IPC分类号: C08G6904

    CPC分类号: C08G69/04 C08G69/16

    摘要: The continuous process for producing polyamides by reacting at least one aminonitrile with water comprises the following steps: (10) reacting at least one aminonitrile with water at a temperature of from 200 to 290° C. at a pressure of from 40 to 70 bar in a flow tube containing a Brönsted acid catalyst selected from a beta-zeolite, sheet-silicate or metal oxide catalyst in the form of a fixed bed, (11) diabatically or adiabatically expanding the reaction mixture from step (1) into a first separation zone to a pressure of from 20 to 40 bar, the pressure being at least 10 bar lower than the pressure in step (1), and to a temperature within the range from 220 to 290° C. by flash evaporation and removal of ammonia, water and any aminonitrile monomer and oligomer, (12) further reacting the reaction mixture from step (2) in the presence of water at a temperature of from 200 to 290° C. and a pressure of from 25 to 55 bar and in the presence or absence of a Brönsted acid catalyst selected from a beta-zeolite, sheet-silicate or metal oxide catalyst in the form of a fixed bed, (13) diabatically or adiabatically expanding the reaction mixture from step (3) into a second separation zone to a pressure of from 0.01 to 20 bar, the pressure being at least 20 bar lower than the pressure in step (3), and to a temperature within the range from 220 to 290° C. by flash evaporation and removal of ammonia, water and any aminonitrile monomer and oligomer.

    摘要翻译: 通过使至少一种氨基腈与水反应生产聚酰胺的连续方法包括以下步骤:(10)在200至290℃的温度下,在40至70巴的压力下使至少一种氨基腈与水反应, 含有布朗斯台德酸催化剂的流动管,其选自固体床形式的β-沸石,硅酸盐或金属氧化物催化剂,(11)将反应混合物从步骤(1)进行绝热或绝热膨胀到第一分离区 压力为20至40巴,压力比步骤(1)中的压力低至少10巴,并且通过闪蒸和除去氨,水的温度在220至290℃的范围内 和任何氨基腈单体和低聚物,(12)在水存在下,在200-290℃的温度和25至55巴的压力下,使步骤(2)的反应混合物进一步反应,并在 没有布朗斯台德酸催化剂选择f 以固定床形式的β-沸石,片状硅酸盐或金属氧化物催化剂(13)将步骤(3)的反应混合物从第二分离区中分离或绝热膨胀至压力为0.01至20巴 ,压力比步骤(3)中的压力低至少20巴,并通过闪蒸和氨,水和任何氨基腈单体和低聚物的除去而达到220-290℃的温度。

    Biodegradable polymers, the production thereof and use thereof for
producing biodegradable moldings
    10.
    发明授权
    Biodegradable polymers, the production thereof and use thereof for producing biodegradable moldings 有权
    生物可降解聚合物,其生产方法和用于生产可生物降解的模制品的用途

    公开(公告)号:US6114042A

    公开(公告)日:2000-09-05

    申请号:US395773

    申请日:1999-09-14

    摘要: Biodegradable polyesters P1 obtainable by reaction of a mixture consisting essentially of(a1) a mixture consisting essentially offrom 35 to 95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof,from 5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, andfrom 0 to 5 mol % of a sulfonate compound,the sum of the individual mole percentages being 100 mol %, and(a2) a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,the molar ratio of (a1) to (a2) being chosen within the range from 0.4:1 to 1.5:1,with the proviso that the polyesters P1 have a molecular weight (M.sub.n) within the range from 5000 to 50,000 g/mol, a viscosity number within the range from 30 to 350 g/ml (measured in 50:50 w/w dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester P1 at 25.degree. C.) and a melting point within the range from 50 to 170.degree. C. and with the further proviso that the polyesters P1 are prepared using from 0.01 to 5 mol %, based on the molar quantity used of component (a1), of a compound D having at least three groups capable of ester formation,and further biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, use thereof for producing biodegradable moldings, and adhesives, biodegradable moldings, foams and blends with starch obtainable from the polymers or molding compositions of the present invention.

    摘要翻译: 可生物降解的聚酯P1可通过基本上由(a1)基本上由35-95mol%的己二酸或其酯形成衍生物或其混合物组成的混合物,混合物,5-65mol%的对苯二甲酸或酯 和0-5mol%的磺酸盐化合物,各摩尔百分数之和为100mol%,和(a2)选自C 2 -C 6烷二醇的二羟基化合物 和C 5 -C 10 - 环烷二醇,(a1)至(a2)的摩尔比选择在0.4:1至1.5:1的范围内,条件是聚酯P1的分子量(Mn)在 5000至50,000g / mol,粘度数在30至350g / ml的范围内(在25℃下在50:50w / w二氯苯/苯酚中的浓度为聚酯P1的0.5重量%测量)和 熔点在50至170℃的范围内,进一步的条件是 基于组分(a1)使用的摩尔量,具有至少三个能够进行酯形成的基团的化合物D,以及进一步的可生物降解的聚合物和热塑性模塑组合物的方法,使用0.01至5mol%的聚酯P1 用于制备可生物降解的模制品的用途,以及可从本发明的聚合物或模塑组合物获得的粘合剂,可生物降解的模制品,泡沫和与淀粉的共混物。