α-Sulfin and α-Sulfonamino amide derivatives
    1.
    发明授权
    α-Sulfin and α-Sulfonamino amide derivatives 失效
    α-亚砜和α-磺酰氨基酰胺衍生物

    公开(公告)号:US06864392B2

    公开(公告)日:2005-03-08

    申请号:US10257085

    申请日:2001-04-11

    摘要: The invention relates to novel pesticidally active α-sulfin- and α-sulfonamino acid amides of the general formula (I) including the optical isomers thereof and mixtures of such isomers, wherein n is a number zero or one, R1-R7 have the meanings given in the specification. R8 is either hydrogen, (a), (b), (c), (d) or (e) wherein R11, R12, R14, R15 and R17 are each independently hydrogen or C1-C4alkyl, R13 is C4-C12alkyl; C1-C12 halogenalkyl; C3-C8 cycloalkyl; optionally substituted aryl or optionally substituted heteroaryl, R16 is optionally substituted aryl or optionally substituted heteroaryl; and Z is oxygen, sulfur —CR18R19— or —NR20—, wherein R18, R19, R20 independently of each other are hydrogen or C1-C4alkyl. The novel compounds possess plant-protecting properties and are suitable for protecting plants against infestation by phytopathogenic microorganisms

    摘要翻译: 本发明涉及通式(I)的新型农药活性α-亚磺酸和α-磺氨基酰胺,其包括其旋光异构体和这些异构体的混合物,其中n为数个零或一个,R 1 -R 7具有 在规范中给出。 R8是氢,(a),(b),(c),(d)或(e)其中R11,R12,R14,R15和R17各自独立地是氢或C1-C4烷基,R13是C4-C12烷基; C1-C12卤代烷基; C3-C8环烷基; 任选取代的芳基或任选取代的杂芳基,R 16是任选取代的芳基或任选取代的杂芳基; Z为氧,硫-CR 18 R 19 - 或-NR 20 - ,其中R 18,R 19,R 20彼此独立地为氢或C 1 -C 4烷基。 新型化合物具有植物保护性质,适用于保护植物免受植物病原微生物侵扰

    Dihydrobenzene pesticides
    2.
    发明授权
    Dihydrobenzene pesticides 失效
    二氢苯类农药

    公开(公告)号:US06316389B1

    公开(公告)日:2001-11-13

    申请号:US09202887

    申请日:1997-06-16

    IPC分类号: A01N3708

    摘要: Compounds of the formula I in which: where: X is CH or N; Y is O; S, S═O or NR5; Z is OR2, SR2, N(R3)R4; or Y and Z together form 5- to 7-membered ring which contains, 2 or 3 hetero atoms O and/or N and which is unsubstituted or substituted by C1-C4alkyl, halo-C1-C4alkyl, halogen, ═O or cyclopropyl; V is a direct bond or C1-C6alkylene, which is unsubstituted or substituted by C1-C3alkyl, C2-C3alkylidene or C3-C6cycloalkylidene; U is O, S, NR7, SO or SO2; W is substituted or unsubstituted aryl or substituted or unsubstituted heteroaryl; R1 is cyclopropyl, C1C6alkyl or halo-C1-C6alkyl; R2 and R3 independently of one another are C1-C6alkyl or halo-C1-C6alkyl; R4 and R5 independently of one another are hydrogen, C1-C6alkyl or C1-C6alkoxy; R7 is hydrogen, C1-C6alkyl, benzyl, C1-C6alkylcarbonyl, halo-C1-C6alkylcarbonyl, halo-C2-C6alkenylcarbonyl; R21 and R22 independently of one another are hydrogen, halogen, C1-C8alkyl or C1-C8alkoxy or C1-C8alkylthio; R23, R24, R25, R26 independently of one another are hydrogen, halogen, C1-C8alkyl or C1-C8alkoxy; are pesticidally active. They can be used for pest control, in particular as fungicides, acaricides and insecticides in crop protection.

    摘要翻译: 式Iin的化合物,其中:其中:X为CH或N; Y为O; S,S = O或NR5; Z是OR2,SR2,N(R3)R4; 或Y和Z一起形成5-至7-元环,其含有2或3个杂原子O和/或N,并且其未被取代或被C 1 -C 4烷基,卤代-C 1 -C 4烷基,卤素,O或环丙基取代; V C 1 -C 3亚烷基或C 3 -C 6亚烷基; U是O,S,NR 7,SO或SO 2; W是取代或未取代的芳基或取代或未取代的杂芳基 R 1和R 2各自独立地为C 1 -C 6烷基或卤代-C 1 -C 6烷基; R 4和R 5彼此独立地为氢,C 1 -C 6烷基或C 1 -C 6烷氧基; R 7为 R 2和R 22彼此独立地是氢,卤素,C 1 -C 8烷基或C 1 -C 8烷氧基或C 1 -C 8烷硫基; R 23是氢,C 1 -C 6烷基,苄基,C 1 -C 6烷基羰基,卤代C 1 -C 6烷基羰基 R 24,R 25,R 26彼此独立地是氢,卤素,C 1 -C 8烷基或C 1 -C 8烷氧基; 具有杀虫活性,可用于防治害虫,特别是杀虫剂,杀螨剂和作物保护中的杀虫剂。

    Cyclohexadiene-derivatives as pesticides
    6.
    发明授权
    Cyclohexadiene-derivatives as pesticides 失效
    环己二烯衍生物作为农药

    公开(公告)号:US06310096B1

    公开(公告)日:2001-10-30

    申请号:US09555613

    申请日:2000-06-01

    申请人: Henry Szczepanski

    发明人: Henry Szczepanski

    IPC分类号: A01N3712

    摘要: Certain cyclohexadiene derivatives are useful as pesticides. The derivatives are of the formula: wherein X is N; Y is O; S, S═O or NR5; Z is OR2, SR2, N(R3)R4; V is a direct bond or a 1 to 4 membered, saturated or unsaturated carbon chain which is unsubstituted or substituted by C1-C3alkyl, halogen, hydroxy, C1-C4alkoxy, halo-C1-C4alkoxy or oxo; W is hydrogen or C1-C6 alkyl or a group of the formula: wherein n is an integer of from 0 to 5 and each D is identical or different and represents a moiety selected from the group consisting of halogen, cyano, nitro, C1 to C12 alkyl, halo-C1 to C12 alkyl, C2 to C12 alkenyl, halo-C2 to C12 alkenyl, C2 to C12 alkynyl, halo-C2 to C12 alkynyl, C3 to C6 cycloalkyl, halo-C3 to C6 cycloalkyl, C3 to C6 cycloalkylmethyl, halo-C3 to C6 cycoloalkylmethyl, etc.

    摘要翻译: 某些环己二烯衍生物可用作杀虫剂。 衍生物具有下式:其中X是N; Y是O; S,S = O或NR 5; Z是OR 2,SR 2,N(R 3)R 4; V是直接键或1至4元饱和或不饱和的碳链,其未被取代或被C 1 -C 3烷基,卤素,羟基 ,C 1 -C 4烷氧基,卤代-C 1 -C 4烷氧基或氧代; W是氢或C 1 -C 6烷基或下式的基团:其中n是0至5的整数,并且每个D相同或不同,并且表示选出的部分 由卤素,氰基,硝基,C1至C12烷基,卤代-C1至C12烷基,C2至C12烯基,卤代-C2至C12烯基,C2至C12炔基,卤代-C2至C12炔基,C3至C6组成的组 环烷基,卤代-C 3至C 6环烷基,C 3至C 6环烷基甲基,卤代-C 3至C 6环烷基甲基等。

    N-(cyclopropyl-pyrimidinyl-N'-(aryl-sulfonyl) ureas having herbicidal
activity
    8.
    发明授权
    N-(cyclopropyl-pyrimidinyl-N'-(aryl-sulfonyl) ureas having herbicidal activity 失效
    具有除草活性的N-(环丙基 - 嘧啶基-N' - (芳基 - 磺酰基)脲)

    公开(公告)号:US4600428A

    公开(公告)日:1986-07-15

    申请号:US693655

    申请日:1985-01-22

    申请人: Henry Szczepanski

    发明人: Henry Szczepanski

    摘要: N-(Cyclopropyl-pyrimidinyl)-N'-aryl-sulfonyl ureas of the formula ##STR1## wherein Ar is a phenyl group ##STR2## or a naphthyl group andQ is a group X-A or R.sub.3,A is alkynyl, alkyl which is unsubstituted or substituted by halogen, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkoxy, haloalkylthio, haloalkylsulfinyl or haloalkylsulfonyl, or alkenyl which is unsubstituted or substituted by the substituents given above for alkyl, or A is a phenyl or benzyl group,E is methine,X is oxygen, sulfur, or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,R.sub.1 is hydrogen, alkyl or alkoxy,R.sub.2 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, amino, alkylamino, di-alkylamino, cycloalkyl or alkoxyalkyl, R.sub.3 is hydrogen, halogen, alkyl, alkenyl, haloalkyl, --CO--NR.sub.8 R.sub.9, --CN, --COR.sub.10, --NR.sub.1 R.sub.7 or --NR.sub.1 --COR.sub.12,R.sub.4 is hydrogen, alkyl, alkoxy, alkylthio, haloalkyl, haloalkoxy, halogen, or alkoxyalkyl,R.sub.5 is independently selected from the same groups as R.sub.3 or --X--R.sub.6,R.sub.6 and R.sub.7 are each alkyl, alkenyl or alkynyl,R.sub.8 and R.sub.9 independently of one another are each hydrogen, alkyl, alkenyl or alkynyl,R.sub.10 is hydrogen, alkyl or haloalkyl,R.sub.11 is hydrogen, alkyl, haloalkyl, alkenyl, alkynyl, phenyl or benzyl, andR.sub.12 is the same as R.sub.1 but independent thereof, and the salts of these compounds with amines, metal bases, or quaternary ammonium bases, have good herbicidal and plant-growth-regulating properties.

    摘要翻译: 式(I)的N-(环丙基 - 嘧啶基)-N'-芳基磺酰基脲其中Ar是苯基或萘基,Q是基团XA或R3,A是炔基, 未取代或被卤素,烷氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,卤代烷氧基,卤代烷硫基,卤代烷基亚磺酰基或卤代烷基磺酰基取代的烷基,或未取代或被上述烷基取代的取代基的烯基,或A是苯基或苄基,E 是次甲基,X是氧,硫或亚磺酰基或磺酰基桥,Z是氧或硫,R1是氢,烷基或烷氧基,R2是卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,氨基,烷基氨基,二烷基氨基, 环烷基或烷氧基烷基,R3是氢,卤素,烷基,烯基,卤代烷基,-CO-NR8R9,-CN,-COR10,-NR1R7或-NR1-COR12,R4是氢,烷基,烷氧基,烷硫基,卤代烷基,卤代烷氧基, 或烷氧基烷基,R 5独立地选自与R 3或-X-R 6相同的基团,R 6和R 7各自为烷基,烯基 1或炔基,R 8和R 9彼此独立地各自为氢,烷基,烯基或炔基,R 10为氢,烷基或卤代烷基,R 11为氢,烷基,卤代烷基,烯基,炔基,苯基或苄基,R 12为 作为R1但不相关,并且这些化合物与胺,金属碱或季铵碱的盐具有良好的除草和植物生长调节性质。