摘要:
A composition for asphalt modification which comprises (a) a block (co)polymer represented by general formula (I); (S-B)m-S′n (in formula (1), S and S′ are each a polymer block mainly composed of an aromatic vinyl compound, B is a polymer block mainly composed of a conjugated diene, and m and n are each an integer of 0 or 1, provided that m+n is 1 or more), wherein the total combined aromatic vinyl compound content in the block (co) polymer is from more than 10% by weight to 100% by weight, and (b) a block copolymer represented by general formula (II); S-B-S, general formula (III); S-B-S′ and/or general formula (IV); and (S-B)2-X (in formulas (II) to (IV), S, S′ and B have the same meanings as given in general formula (I), and X is a residue of a coupling agent), at a block copolymer (a)/block copolymer (b) ratio (weight ratio) of 10-40/90-60.
摘要:
A block copolymer composition comprising40-85% by weight of a block copolymer A.sub.1 -B.sub.1 from an aromatic vinyl compound and a conjugated diene, respectively, A.sub.1 being 12,000 and >150,000, respectively, and15-60% by weight of a block copolymer A.sub.2 -B.sub.2 -A.sub.3 from an aromatic vinyl compound, a conjugated diene and aromatic vinyl compound, respectively, A.sub.2 +A.sub.3 being >20% by weight of A.sub.2 +B.sub.2 +A.sub.3, A.sub.2 and A.sub.3 having a molecular weight >12,000 and(molecular weight of B.sub.2).ltoreq.(molecular weight of B.sub.1)/1.5. an adhesive composition comprising100 parts by weight (pbw) of said block copolymer composition, 20-300 pbw of a tackifying resin, and0-200 pbw of a softener, anda process for the preparation of said adhesive composition by mixing the components in question.
摘要:
A medical device produced by molding a composition comprising (I) 10 to 50% by weight of a polyolefin resin (II) 1 to 89% by weight of a hydrogenated diene polymer obtained by hydrogenating not less than 90 mol % of a butadiene moiety of a linear or branched copolymer consisting of a polybutadiene block segment (C) having a 1,2-vinyl bond content of not more than 20 mol % and a block segment (D) of either polybutadiene or a vinyl aromatic compound-butadiene copolymer whose butadiene moiety has a 1,2-vinyl bond content in the range of from 25 to 95 mol % and having a block structure represented by C-(D-C).sub.n or (C-D).sub.m, wherein n stands for an integer of at least 1 and m for an integer of at least 2, and (III) 1 to 89% by weight of at least one member selected from the group consisting of (i) a block copolymer composed of a polymer block having a vinyl aromatic compound as a main component thereof and a polymer block having a conjugate diene compound as a main component thereof, (ii) a hydrogenated random copolymer of a vinyl aromatic compound and a conjugated diene compound, and (iii) a hydrogenated block copolymer composed of a polymer block having a vinyl aromatic compound as a main component thereof and a polymer block having a conjugate diene compound as a main component thereof, wherein the sum of (1)+(R)+(III) is 100% by weight.
摘要:
A crosslinked thermoplastic elastomer composition obtained by mixing 100 weight parts of at least one type of thermoplastic elastomer, 0-200 weight parts of a rubber-like polymer, and 1-50 weight parts of ultra fine carbon fibrils whose diameter is 3.5-70 nm and whose aspect ratio is greater than 5 against 100 weight parts of the combined mixture of the aforementioned elastomer and rubber like polymer.
摘要:
A thermoplastic elastomer composition which comprises 25-95% by weight of a polyamide and 75-5% by weight of a halogenated butyl rubber, a chlorosulfonated polyethylene or both thereof. Said composition is excellent in resistance to Freon gas permeation and has good oil resistance and low-temperature resistance. A hose wherein the layer to be contacted with a gas is made of the above thermoplastic elastomer composition is suitable as a Freon gas R-22 hose.
摘要:
Thermoplastic elastomer composition characterized by excellent oil resistance while preserving high tear resistance and tension pull resistance comprises non-functionalized block copolymer of aromatic vinyl compound and conjugated diene or selectively hydrogenated product thereof (e.g. styrene-butadiene-styrene block copolymer), rubber polymer having at least one functional group selected from the group consisting of carboxyl, amino, epoxy and hydroxyl (e.g. acrylonitrile-butadiene copolymer containing a carboxyl group as a reactive functional group), and reactive aromatic vinyl polymer having a functional group which is reactive with the functional group of the rubber (e.g. reactive polystyrene containing 1% by weight oxazolinyl group when the rubber polymer is carboxyl group containing acrylonitrile-butadiene copolymer).
摘要:
A thermoplastic polymer composition consisting essentially of:(a) at least one member selected from the group consisting of a block copolymer consisting of a polymer block comprising at least 60% by weight of an alkenyl aromatic compound and a polymer block comprising at least 60% by weight of a conjugated diene compound and a hydrogenated product of said copolymer;(b) a thermoplastic polyurethane elastomer and(c) at least one member selected from the group consisting of the following (c-1) and (c-2) components:(c-1): a copolymer of an alkenyl aromatic compound with at least one compound selected from the group consisting of an unsaturated carboxylic acid and its derivative,(c-2): a modified (co)polymer obtained by reacting an isocyanate with a (co)polymer of at least one compound selected from the group consisting of an alkenyl aromatic compound and a conjugated diene compound; or a hydrogenated product of the modified (co)polymer or a mixture of the isocyanate-modified (co)polymer with the hydrogenated product,wherein the (a)/(b) weight ratio is 2/98-98/2 and the proportion of the (c) component is 1-100 parts by weight per 100 parts by weight of a total of the (a) and (b) components. The above composition is excellent in compatibility between the (a) component and the (b) component, and hence, has excellent heat resistance, mechanical strengths and wear resistance.
摘要:
A catalyst consisting essentially of (A) a cobalt compound and (B) an organic phosphorus compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen atoms, alkyl groups or aryl groups, and three X's, which may be the same or different, are electron-donating groups. This catalyst is effectively used in a process for producing a conjugated diene polymer by polymerizing a conjugated diene in a hydrocarbon or halogenated hydrocarbon solvent in the presence of the above catalyst together with (C) an organoaluminum compound and (D) 0.25-1.5 mols, per mol of the organoaluminum compound (C), of water.