公开(公告)号：US08420431B2

公开(公告)日：2013-04-16

申请号：US13460525

申请日：2012-04-30

申请人： Nobuaki Nagao ,  Takahiro Hamada ,  Akio Matsushita

发明人： Nobuaki Nagao ,  Takahiro Hamada ,  Akio Matsushita

IPC分类号： H01L21/00

CPC分类号： H01L31/1884 ,  H01L31/035281 ,  H01L31/0735 ,  H01L31/1848 ,  H01L31/1852 ,  H01L31/1856 ,  Y02E10/544 ,  Y02P70/521

摘要： A method of fabricating a solar cell includes steps of: forming an amorphous carbon layer, an AlN layer and a first n-type nitride semiconductor layer on the surface of the graphite substrate, forming a mask layer with a plurality of openings on the first n-type nitride semiconductor layer; forming a plurality of second n-type nitride semiconductor layers on the portions of the first n-type nitride semiconductor layer which are exposed by the plurality of openings; forming a plurality of light absorption layers on the plurality of second n-type nitride semiconductor layers; forming a plurality of p-side nitride semiconductor layers on the plurality of the light absorption layers; forming a p-side electrode; and forming an n-side electrode.

摘要翻译： 制造太阳能电池的方法包括以下步骤：在石墨基板的表面上形成非晶碳层，AlN层和第一n型氮化物半导体层，在第一n上形成具有多个开口的掩模层 型氮化物半导体层; 在所述第一n型氮化物半导体层的由所述多个开口露出的部分上形成多个第二n型氮化物半导体层; 在所述多个第二n型氮化物半导体层上形成多个光吸收层; 在所述多个所述光吸收层上形成多个p侧氮化物半导体层; 形成p侧电极; 并形成n侧电极。

公开(公告)号：US20140154510A1

公开(公告)日：2014-06-05

申请号：US14131197

申请日：2012-07-04

申请人： Akihiro Odagawa ,  Akio Matsushita ,  Nozomu Matsukawa

发明人： Akihiro Odagawa ,  Akio Matsushita ,  Nozomu Matsukawa

IPC分类号： H01L29/16 ,  C23C14/08 ,  C23C14/06 ,  C23C14/35

CPC分类号： H01L29/1606 ,  B82Y10/00 ,  B82Y40/00 ,  C23C14/06 ,  C23C14/0694 ,  C23C14/081 ,  C23C14/3407 ,  C23C14/352 ,  H01L21/02175 ,  H01L21/02266 ,  H01L43/08 ,  Y10T428/30

摘要： A film structure (carbon material-insulating film structure) of the present invention includes a carbon material and an insulating film disposed on the carbon material and composed of fluorine-added magnesium oxide. The amount of added fluorine in the magnesium oxide is 0.0049 atomic percent or more and 0.1508 atomic percent or less. This film structure facilitates the realization of an electronic device, such as a spin device, which uses a carbon material such as graphene. This film structure is formed, for example, by sputtering using a target containing magnesium oxide and magnesium fluoride.

摘要翻译： 本发明的膜结构（碳材料绝缘膜结构）包括碳材料和设置在碳材料上并由含氟氧化镁构成的绝缘膜。 氧化镁中的氟的添加量为0.0049原子％以上且0.1508原子％以下。 该薄膜结构有助于实现诸如石墨烯之类的碳材料的诸如旋转装置的电子装置。 该膜结构例如通过使用含有氧化镁和氟化镁的靶进行溅射而形成。

公开(公告)号：US07816528B2

公开(公告)日：2010-10-19

申请号：US11933626

申请日：2007-11-01

申请人： Akio Matsushita ,  Mizuho Oda ,  Yasuhiro Kawachi ,  Jun-ichi Chika

发明人： Akio Matsushita ,  Mizuho Oda ,  Yasuhiro Kawachi ,  Jun-ichi Chika

IPC分类号： C07D239/34 ,  C07D239/22 ,  C07D239/42 ,  A61K31/505 ,  A61P3/06

CPC分类号： C07D239/22 ,  C07D239/30 ,  C07D239/34 ,  C07D239/36 ,  C07D239/42

摘要： A 2-(N-methyl-N-methanesulfonylamino)pyrimidine compound of the formula (3): [R is a hydrocarbyl group], is prepared by the steps of: (I) reacting an isobutyrylacetate ester with 4-fluorobenzaldehyde and urea in the presence of a protonic compound and a metal salt; (II) oxidizing the reaction product of the step (I); (III) reacting the oxidation product of the step (II) with an organic sulfonyl halide or an organic sulfonyl anhydride; and (IV) reacting the reaction product of the step (III) with N-methyl-N-methanesulfonamide.

摘要翻译： 通过以下步骤制备式（3）的2-（N-甲基-N-甲磺酰基氨基）嘧啶化合物：[R是烃基]：（I）使异丁酰乙酸酯与4-氟苯甲醛和尿素反应 质子化合物和金属盐的存在; （II）氧化步骤（I）的反应产物; （III）使步骤（II）的氧化产物与有机磺酰卤或有机磺酰酐反应; 和（IV）使步骤（III）的反应产物与N-甲基-N-甲磺酰胺反应。

公开(公告)号：US20090009417A1

公开(公告)日：2009-01-08

申请号：US12059885

申请日：2008-03-31

申请人： Akio Matsushita ,  Tomoyasu Fujishima

发明人： Akio Matsushita ,  Tomoyasu Fujishima

IPC分类号： H01Q13/10

CPC分类号： H01P1/165 ,  H01P1/161 ,  H01Q3/24 ,  H01Q13/10 ,  H01Q21/245

摘要： A polarization switching/variable directivity antenna according to the present invention includes a ground conductor plate 12 on a surface of a dielectric substrate 11, and has a radiation element 13, a directivity switching element 15, and polarization switching elements 16 provided on the ground conductor plate 12 side of the dielectric substrate 11. The radiation element 13 includes a first slot 17a formed by removing a loop-like portion from the ground conductor plate 12. The directivity switching element 15 includes a second slot 17b formed by removing a loop-like portion from the ground conductor plate 12 and directivity switching switches 18. The polarization switching elements 16 includes a third slot 17c formed by removing a linear-shaped portion from the ground conductor plate 12 and polarization switching switches 19a to 19d. Through control of the directivity switching switches 18, switching of a maximum gain direction of radiation directivity of the antenna is realized. Through control of the polarization switching switches 19a to 19d, switching of a rotation direction of a circularly polarized wave which is emitted from the antenna can be realized.

摘要翻译： 根据本发明的偏振切换/可变方向性天线包括在电介质基板11的表面上的接地导体板12，并且具有辐射元件13，方向性开关元件15和设置在接地导体上的偏振开关元件16 电介质基板11的板12侧。辐射元件13包括通过从接地导体板12去除环状部而形成的第一槽17a。方向性切换元件15包括通过除去环状形成的第二槽17b 来自接地导体板12和方向性切换开关18.偏振切换元件16包括通过从接地导体板12和偏振切换开关19a至19d去除直线形部分而形成的第三槽17c。 通过控制方向性切换开关18，实现了天线的辐射方向性的最大增益方向的切换。 通过极化切换开关19a〜19d的控制，可以实现从天线发射的圆偏振波的旋转方向的切换。

公开(公告)号：US5387575A

公开(公告)日：1995-02-07

申请号：US894557

申请日：1992-06-05

申请人： Katsumasa Harada ,  Takaaki Abe ,  Yuji Akiyoshi ,  Akio Matsushita ,  Mikio Kojima ,  Ikuo Shiraishi ,  Kaoru Yamamoto ,  Takashi Hayama ,  Shohei Fukuda

发明人： Katsumasa Harada ,  Takaaki Abe ,  Yuji Akiyoshi ,  Akio Matsushita ,  Mikio Kojima ,  Ikuo Shiraishi ,  Kaoru Yamamoto ,  Takashi Hayama ,  Shohei Fukuda

IPC分类号： A01N43/54 ,  A01N43/66 ,  C07D239/60 ,  C07D251/30 ,  C07D251/38 ,  C07D521/00 ,  C07D239/52 ,  A01N73/54

CPC分类号： C07D231/12 ,  A01N43/54 ,  A01N43/66 ,  C07D233/56 ,  C07D239/60 ,  C07D249/08 ,  C07D251/30 ,  C07D251/38

摘要： Disclosed are a pyrimidine or triazine compound represented by the following formula (I): ##STR1## wherein R.sup.1 represents cyano group, a halogen atom, hydroxy group or --O--R.sup.7 where R.sup.7 represents a lower alkyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group or a cyano-lower alkyl group; R.sup.2 represents hydrogen atom or a lower alkyl group; R.sup.3 represents hydrogen atom or a lower alkyl group; R.sup.4 represents a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 represents a lower alkyl group or a phenyl group which may have a substituent, hydroxy group, a lower alkoxy group or a benzyloxy group when Z is nitrogen atom; or a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 has the same meaning as defined above, hydroxy group, OK, a lower alkoxy group which may have a substituent, a lower alkenyloxy group, a lower alkynyloxy group, a cycloalkoxy group which may have a substituent, a phenoxy group, a benzyloxy group, a lower alkylthio group, a phenylthio group or an alkylsulfonylamino group when Z is --CH.dbd. group; R.sup.5 represents a lower alkoxy group; R.sup.6 represents a lower alkoxy group or a lower alkyl group; X represents oxygen atom or sulfur atom; and Z represents nitrogen atom or --CH.dbd. group. processes for preparing the same and a herbicide containing the same as an active ingredient(s).

摘要翻译： 公开了由下式（I）表示的嘧啶或三嗪化合物：其中R 7表示低级烷基，低级烯基，低级炔基，卤代烷基， 低级烷基或氰基 - 低级烷基; R2代表氢原子或低级烷基; R3表示氢原子或低级烷基; R 4表示当Z为氮原子时，可以具有取代基，羟基，低级烷氧基或苄氧基的低级烷基或苯基，-NHSO 2 -R 8， 或1-咪唑基，-NHSO 2 -R 8，其中R8具有与上述相同的含义，羟基，OK，可具有取代基的低级烷氧基，低级链烯氧基，低级炔氧基，环烷氧基 当Z为-CH =基团时，可具有取代基，苯氧基，苄氧基，低级烷硫基，苯硫基或烷基磺酰基氨基; R5代表低级烷氧基; R6代表低级烷氧基或低级烷基; X表示氧原子或硫原子; Z表示氮原子或-CH =基团。 其制备方法和含有其作为活性成分的除草剂。

公开(公告)号：US20090137822A1

公开(公告)日：2009-05-28

申请号：US11920568

申请日：2006-05-16

申请人： Akio Matsushita ,  Kiyotaka Yoshii ,  Mizuho Oda ,  Masayoshi Oue ,  Shuji Yamada

发明人： Akio Matsushita ,  Kiyotaka Yoshii ,  Mizuho Oda ,  Masayoshi Oue ,  Shuji Yamada

IPC分类号： C07D333/38 ,  C07D333/22 ,  C07D333/16

CPC分类号： C07D333/38 ,  C07D333/22

摘要： The present invention relates to a process for preparing a 3-substituted thiophene represented by the formula (2): wherein R represents a cyano group, a formyl group, a carboxyl group, a hydrocarbyloxycarbonyl group which may have a substituent(s) or an acyl group which may have a substituent(s), which comprises reacting a vinyl compound represented by the formula (1): RCH═CHY  (1) wherein R has the same meaning as defined above, and Y represents a leaving group, and an α-mercaptoacetaldehyde or a multimer thereof.

摘要翻译： 本发明涉及一种由式（2）表示的3-取代噻吩的制备方法：其中R表示氰基，甲酰基，羧基，可具有取代基的烃氧基羰基或 可以具有取代基的酰基，其包括使由式（1）表示的乙烯基化合物：<？in-line-formula description =“In-line formula”end =“lead”→RCH-CHY （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R具有与上述相同的含义，Y表示离去基团，而α-巯基乙醛或多聚体 其中。

公开(公告)号：US5994553A

公开(公告)日：1999-11-30

申请号：US211446

申请日：1998-12-15

申请人： Katsumasa Harada ,  Akio Matsushita ,  Taku Nakamura ,  Katsuhiko Mizutare ,  Takafumi Hirakawa ,  Ken Ikuno ,  Noriaki Iwase

发明人： Katsumasa Harada ,  Akio Matsushita ,  Taku Nakamura ,  Katsuhiko Mizutare ,  Takafumi Hirakawa ,  Ken Ikuno ,  Noriaki Iwase

IPC分类号： C07D277/20 ,  C07D277/36

CPC分类号： C07D277/36

摘要： Disclosed is a method for preparing 2-mercaptothiazole, which comprises adding a dithiocarbamate salt represented by the formula (1): ##STR1## wherein M is a cation, to a chloroacetaldehyde solution in the presence of an acid.

摘要翻译： 公开了一种2-巯基噻唑的制备方法，该方法包括在酸存在下，向氯乙醛溶液中加入由式（1）表示的二硫代氨基甲酸盐：其中M为阳离子。

公开(公告)号：US5677455A

公开(公告)日：1997-10-14

申请号：US524045

申请日：1995-09-06

申请人： Katsumasa Harada ,  Akio Matsushita ,  Yasuhiro Kawachi ,  Hiroshi Sasaki

发明人： Katsumasa Harada ,  Akio Matsushita ,  Yasuhiro Kawachi ,  Hiroshi Sasaki

IPC分类号： C07F7/18 ,  C07F7/02 ,  C07D213/30

CPC分类号： C07F7/1852 ,  C07F7/1856 ,  C07F7/1892

摘要： Methyl (3R,6E)-3-�(tert-butyldimethylsilyl)oxy!-7-�2',6'-diisopropyl-4'-(4"-fluorophenyl)-5'-(methoxymethyl)pyridin-3'-yl!-5-oxy-6-heptenoate or other 3-oxy-5-oxo-6-heptenoic acid derivative is prepared by the reaction of an aromatic aldehyde and an oxyglutaric acid derivative in an aliphatic alcohol containing a small amount of water in the presence of an alkali metal carbonate or hydrogen carbonate.

摘要翻译： 将（3R，6E）-3 - [（叔丁基二甲基甲硅烷基）氧基] -7- [2'，6'-二异丙基-4' - （4“ - 氟苯基）-5' - （甲氧基甲基） - 基] -5-氧基-6-庚烯酸乙酯或其它3-氧基-5-氧代-6-庚烯酸衍生物通过芳族醛和羟基戊二酸衍生物在含少量水的脂族醇中的反应来制备 在碱金属碳酸盐或碳酸氢盐存在下进行。

公开(公告)号：US5529977A

公开(公告)日：1996-06-25

申请号：US326830

申请日：1994-10-21

申请人： Katsumasa Harada ,  Takaaki Abe ,  Yuji Akiyoshi ,  Akio Matsushita ,  Mikio Kojima ,  Ikuo Shiraishi ,  Kaoru Yamamoto ,  Takashi Hayama

发明人： Katsumasa Harada ,  Takaaki Abe ,  Yuji Akiyoshi ,  Akio Matsushita ,  Mikio Kojima ,  Ikuo Shiraishi ,  Kaoru Yamamoto ,  Takashi Hayama

IPC分类号： A01N43/54 ,  A01N43/66 ,  C07D239/60 ,  C07D251/30 ,  C07D251/38 ,  C07D521/00 ,  C07D251/34 ,  C07D251/16 ,  C07D403/12

CPC分类号： C07D231/12 ,  A01N43/54 ,  A01N43/66 ,  C07D233/56 ,  C07D239/60 ,  C07D249/08 ,  C07D251/30 ,  C07D251/38

摘要： Disclosed are a pyrimidine or triazine compound represented by the following formula (I): ##STR1## wherein R.sup.1 represents cyano group, a halogen atom, hydroxy group or --O--R.sup.7 where R.sup.7 represents a lower alkyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group or a cyano-lower alkyl group; R.sup.2 represents hydrogen atom or a lower alkyl group; R.sup.3 represents hydrogen atom or a lower alkyl group; R.sup.4 represents a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 represents a lower alkyl group or a phenyl group which may have a substituent, hydroxy group, a lower alkoxy group or a benzyloxy group when Z is nitrogen atom; or a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 has the same meaning as defined above, hydroxy group, OK, a lower alkoxy group which may have a substituent, a lower alkenyloxy group, a lower alkynyloxy group, a cycloalkoxy group which may have a substituent, a phenoxy group, a benzyloxy group, a lower alkylthio group, a phenylthio group or an alkylsulfonylamino group when Z is --CH.dbd. group; R.sup.5 represents a lower alkoxy group; R.sup.6 represents a lower alkoxy group or a lower alkyl group; X represents oxygen atom or sulfur atom; and Z represents nitrogen atom or --CH.dbd. group.processes for preparing the same and a herbicide containing the same as an active ingredient(s).

摘要翻译： 公开了由下式（I）表示的嘧啶或三嗪化合物：其中R 1表示氰基，卤素原子，羟基或-O-R 7，其中R 7表示低级烷基，低级烯基 基，低级炔基，卤代低级烷基或氰基 - 低级烷基; R2表示氢原子或低级烷基; R3表示氢原子或低级烷基; R 4表示当Z为氮原子时，可以具有取代基，羟基，低级烷氧基或苄氧基的低级烷基或苯基，-NHSO 2 -R 8， 或1-咪唑基，-NHSO 2 -R 8，其中R8具有与上述相同的含义，羟基，OK，可具有取代基的低级烷氧基，低级链烯氧基，低级炔氧基，环烷氧基 当Z为-CH =基团时，可具有取代基，苯氧基，苄氧基，低级烷硫基，苯硫基或烷基磺酰基氨基; R5代表低级烷氧基; R6代表低级烷氧基或低级烷基; X表示氧原子或硫原子; Z表示氮原子或-CH =基团。 其制备方法和含有其作为活性成分的除草剂。

公开(公告)号：US5457225A

公开(公告)日：1995-10-10

申请号：US302342

申请日：1994-09-07

申请人： Nobuki Oguni ,  Masahiko Hayashi ,  Katsumasa Harada ,  Akio Matsushita

发明人： Nobuki Oguni ,  Masahiko Hayashi ,  Katsumasa Harada ,  Akio Matsushita

IPC分类号： C07C67/46 ,  C07C69/716 ,  C07C69/76 ,  C07C69/66

CPC分类号： C07C69/716 ,  C07C67/46

摘要： Disclosed is a process for the preparation of a 5-hydroxy-3-ketoester derivative of the formula: ##STR1## in which R.sup.1 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, and R.sup.2 represents an alkyl group or an aryl group, which comprises causing the reaction of an aldehyde compound of the formula R.sup.1 CHO in which R.sup.1 has the meanings as defined above and diketene in the presence of a metal compound selected from a titanium or aluminum compound having at least one group of --OR.sup.3 in which R.sup.3 represents an alkyl group or an aryl group. Further, a process for the preparation of an optically active substance of the 5-hydroxy-3-ketoester derivative causing the reaction of the above compounds in the presence of the metal compound and optically active Schiff base or a complex compound obtained by reacting the metal compound with the optically active Schiff base, also is disclosed.

摘要翻译： 公开了制备下式的5-羟基-3-酮酯衍生物的方法：其中R 1表示烷基，烯基，炔基，芳基或杂环基，R 2 表示烷基或芳基，其包括在选自具有至少具有上述含义的钛或铝化合物的金属化合物的存在下使式R 1 CHO的醛化合物与其中R 1具有如上所定义的二烯酮反应 一组-OR 3，其中R 3表示烷基或芳基。 此外，制备5-羟基-3-酮酯衍生物的光学活性物质的方法，其导致上述化合物在金属化合物和光学活性席夫碱存在下的反应或通过使金属 与光学活性席夫碱的化合物也被公开。