Mixed anhydrides of isocyanates and carboxylic acids, mixtures thereof
with carboxylic acids, and the use thereof as blowing agents for the
production of cellular plastics
    1.
    发明授权
    Mixed anhydrides of isocyanates and carboxylic acids, mixtures thereof with carboxylic acids, and the use thereof as blowing agents for the production of cellular plastics 失效
    异氰酸酯和羧酸的混合酸酐,其与羧酸的混合物及其作为泡沫塑料生产发泡剂的用途

    公开(公告)号:US4377644A

    公开(公告)日:1983-03-22

    申请号:US312034

    申请日:1981-10-16

    IPC分类号: C08J9/08 C08G18/14

    CPC分类号: C08J9/08

    摘要: This invention relates to solid reaction products of aliphatic, cycloaliphatic or araliphatic mono- and/or polyisocyanates and organic, weakly acid mono- and/or polycarboxylic acids for the production of cellular plastics articles and particularly polyurethane foams. The products of the present invention may also be in the form of mixtures with carboxylic acids. The products are suitable for the production of cellular or porous plastics articles, but are preferably used in the preparation of cellular thermoplastic polyurethanes and semi-rigid and particularly rigid polyurethane integral skin foams having a compact outer skin formed by foaming the reaction mixture in closed molds.

    摘要翻译: 本发明涉及脂肪族,脂环族或芳脂族单 - 和/或多异氰酸酯和有机,弱酸单 - 和/或多元羧酸的固体反应产物,用于生产细胞塑料制品,特别是聚氨酯泡沫。 本发明的产品也可以是与羧酸的混合物的形式。 该产品适用于生产细胞或多孔塑料制品,但优选用于制备细胞热塑性聚氨酯和半刚性和特别硬的聚氨酯整体皮肤泡沫,其具有通过将闭合模具中的反应混合物发泡而形成的致密外皮 。

    Process for the preparation of low molecular weight
4,4'-diphenylmethane-uretdione-diisocyanates
    5.
    发明授权
    Process for the preparation of low molecular weight 4,4'-diphenylmethane-uretdione-diisocyanates 失效
    制备低分子量4,4'-二苯基甲烷 - 二酮二异氰酸酯的方法

    公开(公告)号:US4521338A

    公开(公告)日:1985-06-04

    申请号:US404106

    申请日:1982-08-02

    CPC分类号: C07D229/00 C08G18/798

    摘要: Low molecular weight 4,4'-diphenylmethane-uretdione-diisocyanates corresponding to the formula: ##STR1## wherein n is a number from 0 to 1,are made by dimerizing diphenylmethane-4,4'-diisocyanate at a temperature of 50.degree. C. or less in a mixture of non-polar and moderately polar solvents in the presence of a dimerization catalyst. The dimerization product may then be worked up at low temperatures (i.e., .ltoreq.50.degree. C.). The dimerization products of diphenylmethane-diisocyanate thus obtained generally have only a small amount of oligomeric uretdione-diisocyanates present. These dimerization products may be used advantageously in the synthesis of polyurethanes.

    摘要翻译: 对应于下式的低分子量4,4'-二苯基甲烷 - 脲二酮 - 二异氰酸酯:其中n为0至1的数,通过二苯基甲烷-4,4'- 二异氰酸酯在50℃或更低的温度下在非极性和中等极性溶剂的混合物中在二聚催化剂存在下进行。 然后可以在低温下(即

    Aromatic diisocyanates containing N,N-disubstituted sulfonamide groups
and processes for their production
    6.
    发明授权
    Aromatic diisocyanates containing N,N-disubstituted sulfonamide groups and processes for their production 失效
    含有N,N-二取代磺酰胺基团的芳族二异氰酸酯及其制备方法

    公开(公告)号:US4496491A

    公开(公告)日:1985-01-29

    申请号:US401036

    申请日:1982-07-22

    CPC分类号: C07D295/26 C08G18/775

    摘要: Diisocyanates corresponding to the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 (an isocyanate-containing radical) are as defined herein are made by several processes. These diisocyanates may be made by phosgenating the diamine in which the diisocyanate is based. They may also be produced by treating the bis-urethane of the tertiary alcohol corresponding to the diisocyanate with phosgene. Such diisocyanates may also be made by treating a specific type of bis-urea with hydrogen chloride. The diisocyanates corresponding to the above-given formula are particularly useful in the production of polyurethanes having good flame-proof and mechanical properties.

    摘要翻译: 其中R 1,R 2,R 3,R 4,R 5和R 6(含异氰酸酯的基团)如本文所定义的式“IMAGE”的二异氰酸酯通过几种方法制备。 这些二异氰酸酯可以通过使二异氰酸酯所基于的二胺光气化而制成。 它们也可以通过用光气处理对应于二异氰酸酯的叔醇的双 - 氨基甲酸酯来制备。 这种二异氰酸酯也可以通过用氯化氢处理特定类型的双脲来制备。 对应于上述给定配方的二异氰酸酯特别可用于生产具有良好的阻燃和机械性能的聚氨酯。

    Heat curable, one-component polyurethane reactive compositions
    8.
    发明授权
    Heat curable, one-component polyurethane reactive compositions 失效
    可热固化的单组分聚氨酯反应组合物

    公开(公告)号:US5574123A

    公开(公告)日:1996-11-12

    申请号:US396182

    申请日:1995-02-24

    摘要: The present invention relates to a heat curable, one-component polyurethane reactive compositions containingA) surface-modified, finely divided polyisocyanates in which 0.1 to 25 equivalent percent, based on the total number of NCO groups, of the NCO groups are deactivated andB) a mixture of relatively high molecular weight compounds having isocyanate-reactive groups containing1) 5 to 40 wt. %, based on the weight of component B), of one or more aliphatic polyether polyamines and2) 60 to 95 wt. %, based on the weight of component B), of a polyol mixture containingi) 10 to 60 wt. %, based on the weight of component B2), of at least one polyester polyol andii) 40 to 90 wt. %, based on the weight of component B2), of at least one polyether polyol with predominantly primary hydroxyl groups.The present invention also relates to use of the heat curable, one-component polyurethane reactive compositions to prepare coatings, adhesives, anti-drumming products and sealants, especially seam sealants.

    摘要翻译: 本发明涉及一种可热固化的单组分聚氨酯反应性组合物,其包含A)表面改性的细碎多异氰酸酯,其中NCO基团的NCO基团的总数为0.1至25当量百分数为失活,B为 )具有异氰酸酯反应性基团的相对高分子量化合物的混合物,其含有1〜5重量% 基于组分B)的重量),一种或多种脂族聚醚多胺,和2)60至95重量% 基于组分B)的重量,多元醇混合物含有i)10至60wt。 %,基于组分B2的重量),至少一种聚酯多元醇,和ii)40至90重量% 至少一种主要为伯羟基的聚醚多元醇,基于组分B2的重量%)。 本发明还涉及可热固化的单组分聚氨酯反应性组合物用于制备涂料,粘合剂,抗打击产品和密封剂,特别是缝隙密封剂的用途。

    Process for the preparation of highly elastic plastics
    9.
    发明授权
    Process for the preparation of highly elastic plastics 失效
    制备高弹性塑料的方法

    公开(公告)号:US5159046A

    公开(公告)日:1992-10-27

    申请号:US543649

    申请日:1990-06-26

    摘要: The present invention relates to a process for the preparation of a modified 1,5-naphthylene diisocyanate containing urea and biuret groups comprising reacting(a) 1,5-naphthylene diisocyanate in molten form with(b) a mixture comprising about 0.02 to about 0.5 mole of water per mole of 1,5-naphthylene diisocyanate and about 1 to about 10 parts for each part of water of an organic solvent.The present invention further relates to a process for the preparation of elastomeric moldings comprising reacting by the one-shot or prepolymer process at an isocyanate index of 70 to 130 a modified 1,5-naphthylene diisocyanate containing urea and biuret groups with compounds containing at least two isocyanate-reactive groups and having a molecular weight in the range from about 500 to about 10,000 and, optionally, organic compounds containing isocyanate-reactive groups and having a molecular weight in the range from 60 to 499.

    摘要翻译: 本发明涉及一种制备含脲和缩二脲基团的改性的1,5-亚萘基二异氰酸酯的方法,包括使(a)熔融形式的1,5-亚萘基二异氰酸酯与(b)约0.02至约0.5的混合物 摩尔水/摩尔1,5-亚萘基二异氰酸酯和约1至约10份的每份有机溶剂的水。 本发明还涉及一种制备弹性体模制品的方法,其包括通过一步或预聚物方法在异氰酸酯指数为70至130的情况下使含有脲和缩二脲基团的改性的1,5-亚萘基二异氰酸酯与至少含有化合物 两个异氰酸酯反应性基团,分子量在约500至约10,000的范围内,以及任选的含有异氰酸酯反应性基团并且分子量在60至499范围内的有机化合物。