公开(公告)号：US20080261010A1

公开(公告)日：2008-10-23

申请号：US11816556

申请日：2006-01-04

申请人： Roland Wursche ,  Sonja Bollmann ,  Harald Hager ,  Martin Wielputz ,  Kirsten Alting ,  Michael Beyer ,  Franz-Erich Baumann

发明人： Roland Wursche ,  Sonja Bollmann ,  Harald Hager ,  Martin Wielputz ,  Kirsten Alting ,  Michael Beyer ,  Franz-Erich Baumann

IPC分类号： B32B27/34 ,  C08L77/00

CPC分类号： C08L77/06 ,  B32B5/18 ,  B32B27/34 ,  C08L77/02 ,  C08L2205/02 ,  C09D177/00 ,  C09D177/06 ,  Y10T428/12493 ,  Y10T428/249992 ,  Y10T428/26 ,  Y10T428/269 ,  Y10T428/31725 ,  Y10T428/31728 ,  Y10T428/31732 ,  Y10T428/31739 ,  C08L2666/20

摘要： A film whose outer layer is composed of a molding composition which is in essence composed of the following components: a) from 3 to 50% by weight of a polyamide, selected from the group of PA11 and PA12, and b) from 50 to 97% by weight of a polyamide, selected from the group of PA1012 and PA1212, where the percentages are based on the entirety of components a) and b), is suitable for decoration of moldings which retain their gloss during their service time.

摘要翻译： 其外层由本发明组成的成型组合物构成的膜，该组合物本质上由以下组分组成：a）3至50重量％的选自PA11和PA12的聚酰胺，以及b）50至97 选自PA1012和PA1212的聚酰胺的重量％，其中百分比基于组分a）和b）的组分，适用于在其使用时间内保持其光泽的模制品的装饰。

公开(公告)号：US20070166560A1

公开(公告)日：2007-07-19

申请号：US10589264

申请日：2005-06-09

申请人： Roland Wursche ,  Sonja Bollmann ,  Martin Wielputz ,  Kirsten Alting ,  Harald Hager

发明人： Roland Wursche ,  Sonja Bollmann ,  Martin Wielputz ,  Kirsten Alting ,  Harald Hager

IPC分类号： B32B27/34

CPC分类号： B32B7/12 ,  B32B27/08 ,  B32B27/302 ,  B32B27/34 ,  B32B2355/02 ,  B32B2377/00 ,  B32B2605/003 ,  B60R13/00 ,  C09J133/14 ,  Y10T428/31511 ,  Y10T428/31725 ,  Y10T428/3175

摘要： An adhesion promoter which comprises from 2 to 100% by weight of a copolymer which contains the following monomer units: a) from 70 to 99.9% by weight of monomer units which derive from vinyl compounds selected from acrylic acid derivatives, methacrylic acid derivatives, and vinylaromatics, and also b) from 0.1 to 30% by weight of monomer units which contain a functional group selected from a carboxylic anhydride group, an epoxy group, and an oxazoline group, is used for production of a bond between I. a layer composed of a polyamide molding compound, and II. a part composed of an ABS molding composition.

摘要翻译： 一种粘合促进剂，其包含2至100重量％的共聚物，其含有以下单体单元：a）70至99.9重量％的衍生自选自丙烯酸衍生物，甲基丙烯酸衍生物和乙烯基化合物的乙烯基化合物的单体单元 乙烯基芳族化合物，以及b）0.1〜30重量％的含有选自羧酸酐基团，环氧基和恶唑啉基团的官能团的单体单元用于生成I. 的聚酰胺模塑料，II。 由ABS成型组合物构成的部分。

公开(公告)号：US20080119632A1

公开(公告)日：2008-05-22

申请号：US11813103

申请日：2005-11-09

申请人： Franz-Erich Baumann ,  Roland Wursche ,  Harald Hager ,  Sonja Bollmann ,  Kirsten Alting

发明人： Franz-Erich Baumann ,  Roland Wursche ,  Harald Hager ,  Sonja Bollmann ,  Kirsten Alting

IPC分类号： C08G69/10

CPC分类号： B32B27/34 ,  A63C5/124 ,  B32B27/08 ,  B32B2250/24 ,  B32B2307/412 ,  B32B2307/5825 ,  B32B2307/75 ,  B32B2519/00 ,  C08G69/265 ,  C08L77/06 ,  C08L2205/02 ,  C09D177/06 ,  Y10T156/10 ,  Y10T428/1345 ,  Y10T428/2969 ,  Y10T428/31725 ,  C08L2666/20

摘要： The invention relates to the use of a molding composition which comprises at least 50% by weight of a copolyamide, which is composed of the following monomer combination: a) from 65 to 99 mol % of a substantially equimolar mixture composed of an unbranched aliphatic diamine having from 6 to 18 carbon atoms and of an unbranched aliphatic dicarboxylic acid having from 6 to 18 carbon atoms, where the mixture composed of diamine and dicarboxylic acid comprises an average of from 8 to 12 carbon atoms, b) from 1 to 35 mol % of a substantially equimolar mixture composed of a cycloaliphatic diamine having from 8 to 20 carbon atoms and of a dicarboxylic acid having from 6 to 18 carbon atoms, for production of a printable or printed item, such as a ski topcoat.

摘要翻译： 本发明涉及包含至少50重量％共聚酰胺的模塑组合物的用途，该共聚酰胺由以下单体组合组成：a）65至99mol％的基本上等摩尔的混合物，其由无支链的脂族二胺 具有6至18个碳原子和具有6至18个碳原子的无支链脂族二羧酸，其中由二胺和二羧酸组成的混合物包含平均8至12个碳原子，b）1至35摩尔％ 的由具有8至20个碳原子的脂环族二胺和具有6至18个碳原子的二羧酸组成的基本上等摩尔的混合物，用于制造可印刷或印刷的物品，例如滑雪面漆。

公开(公告)号：US20070104971A1

公开(公告)日：2007-05-10

申请号：US11586526

申请日：2006-10-26

申请人： Roland Wursche ,  Franz-Erich Baumann ,  Beatrice Kuting ,  Martin Wielputz ,  Patrick Kreidler ,  Harald Hager

发明人： Roland Wursche ,  Franz-Erich Baumann ,  Beatrice Kuting ,  Martin Wielputz ,  Patrick Kreidler ,  Harald Hager

IPC分类号： B32B27/34

CPC分类号： B32B27/08 ,  B32B7/12 ,  B32B25/042 ,  B32B25/08 ,  B32B27/34 ,  B32B37/10 ,  B32B37/12 ,  B32B37/153 ,  B32B2307/718 ,  B32B2309/105 ,  B32B2377/00 ,  B32B2451/00 ,  B32B2605/003 ,  B32B2605/08 ,  C08G69/265 ,  C08L77/00 ,  C08L77/06 ,  C08L2205/02 ,  Y10T428/31725 ,  C08L2666/20

摘要： A decorative film having an outer layer containing a polyamide composition with the following components: a) from 50 to 100 parts by weight of polyamide prepared from: α) from 70 to 100 mol % of diamine selected from m-xylylenediamine, p-xylylenediamine and mixtures thereof, β) from 0 to 30 mol % of other diamines having from 6 to 14 carbon atoms, and γ) from 70 to 100 mol % of aliphatic dicarboxylic acids having from 10 to 18 carbon atoms and δ) from 0 to 30 mol % of other dicarboxylic acids having from 6 to 9 carbon atoms, and b) from 0 to 50 parts by weight of another polyamide, where a) and b) total 100, having good chemicals resistance, good stress cracking resistance, improved scratch resistance, and improved gloss.

摘要翻译： 一种具有外层的装饰膜，其含有具有以下成分的聚酰胺组合物：a）50-100重量份由以下组分制备的聚酰胺：α）70至100摩尔％的选自间苯二甲胺，对苯二甲胺和 其混合物，β）0至30mol％的具有6至14个碳原子的其它二胺，和γ）70至100mol％具有10至18个碳原子和δ的脂族二羧酸和0至30mol 具有6至9个碳原子的其它二羧酸的百分比，和b）0至50重量份的另一种聚酰胺，其中a）和b）总计100，具有良好的耐化学性，良好的抗应力开裂性，改善的耐刮擦性， 并改善光泽度。

公开(公告)号：US20070173581A1

公开(公告)日：2007-07-26

申请号：US10591289

申请日：2005-02-18

申请人： Harald Hager ,  Thomas Hasskerl ,  Roland Wursche ,  Gunther Ittmann ,  Hans-Gunther Lohkamper ,  Klaus-Dieter Schubel

发明人： Harald Hager ,  Thomas Hasskerl ,  Roland Wursche ,  Gunther Ittmann ,  Hans-Gunther Lohkamper ,  Klaus-Dieter Schubel

IPC分类号： C08K3/22

CPC分类号： B41M5/267 ,  B29C65/16 ,  B29C65/1606 ,  B29C65/1616 ,  B29C65/1619 ,  B29C66/71 ,  B29C66/73365 ,  B82Y30/00 ,  C08K3/22 ,  C08K2201/011

摘要： The present invention relates to high-transparency plastic materials which are laser-markable and/or laser-weldable due to a content of nanoscale laser-sensitive metal oxides. These plastic materials, which may be provided as molded bodies, semifinished products, molding compounds, or lacquers, particularly contain metal oxides having particle sizes from 5 to 100 nm and a content of 0.0001 to 0.1 weight-percent. Typical metal oxides are nanoscale indium-tin oxide or antimony-tin oxide. These materials may be used in particular for producing laser-markable production products.

摘要翻译： 本发明涉及由于纳米级激光敏感金属氧化物的含量而可激光标记和/或可激光焊接的高透明度塑料材料。 这些可以作为成型体，半成品，成型用化合物或者涂料提供的塑料材料，特别是含有粒径为5〜100nm，含量为0.0001〜0.1重量％的金属氧化物。 典型的金属氧化物是纳米级氧化铟锡或氧化锑锡。 这些材料特别可用于生产可激光标记的生产产品。

公开(公告)号：US20060281846A1

公开(公告)日：2006-12-14

申请号：US10544041

申请日：2005-02-18

申请人： Harald Hager ,  Thomas Hasskerl ,  Gunther Ittmann ,  Roland Wursche ,  Klaus-Dieter Schubel

发明人： Harald Hager ,  Thomas Hasskerl ,  Gunther Ittmann ,  Roland Wursche ,  Klaus-Dieter Schubel

IPC分类号： C08K3/22

CPC分类号： B82Y30/00 ,  B29C65/1606 ,  B29C65/1616 ,  B29C65/1619 ,  B29C65/1635 ,  B29C65/1654 ,  B29C65/1677 ,  B29C66/71 ,  B29C66/7332 ,  B29C66/73365 ,  B29C66/73774 ,  B29C66/73921 ,  B29C66/73941 ,  B29K2105/162 ,  B29K2995/0025 ,  B29K2995/0026 ,  B29K2995/0029 ,  C08K3/01 ,  C08K2201/011 ,  B29K2077/00 ,  B29K2075/00 ,  B29K2067/00 ,  B29K2061/00 ,  B29K2081/04 ,  B29K2033/12 ,  B29K2083/00 ,  B29K2081/06 ,  B29K2079/08 ,  B29K2071/12 ,  B29K2071/00 ,  B29K2069/00 ,  B29K2033/08 ,  B29K2027/12 ,  B29K2025/08 ,  B29K2025/04 ,  B29K2023/38 ,  B29K2023/00

摘要： The present invention relates to transparent, translucent, or opaque plastic materials that are tinted due to colorants, which are laser-weldable due to a content of nanoscale laser-sensitive particles. These plastic materials, which may be provided as molded bodies, semifinished products, or lacquer coatings, particularly contain laser-sensitive particles with a particle size from 5 to 100 nm and a content from 0.0001 to 0.1 weight had percent. Typical compounds are nanoscale indium-tin oxide, antimony-tin oxide, indium-zinc oxide, and lanthanum hexaboride.

摘要翻译： 本发明涉及由于着色剂而着色的透明，半透明或不透明的塑料材料，由于纳米尺度激光敏感颗粒的含量而可激光焊接。 这些可以作为成型体，半成品或漆涂料提供的塑料材料，特别是含有粒度为5〜100nm，含量为0.0001〜0.1重量％的激光敏感粒子。 典型的化合物是纳米级氧化铟锡，氧化锑锡，氧化铟锌和六硼化镧。

公开(公告)号：US20060099478A1

公开(公告)日：2006-05-11

申请号：US11246206

申请日：2005-10-11

申请人： Guido Schmitz ,  Harald Hager ,  Hans Ries ,  Olivier Farges

发明人： Guido Schmitz ,  Harald Hager ,  Hans Ries ,  Olivier Farges

IPC分类号： H01M8/02 ,  B32B27/34 ,  B32B27/32 ,  B32B27/08

CPC分类号： B32B27/34 ,  B32B1/08 ,  B32B27/08 ,  B32B27/18 ,  B32B27/306 ,  B32B27/32 ,  B32B2250/24 ,  B32B2307/21 ,  B32B2307/718 ,  B32B2307/7242 ,  B32B2307/7265 ,  B32B2457/18 ,  B32B2597/00 ,  B32B2605/08 ,  F16L9/12 ,  Y10T428/31728 ,  Y10T428/31757

摘要： An element of a line system of a fuel cell, in which the part which is in contact with the medium being conveyed comprises a polyamide molding composition and, in addition, at least one further layer selected from among: a) a layer II of a further polyamide molding composition; b) a layer III of a molding composition comprising a functionalized polyolefin; c) a layer IV of a polyolefin molding composition in which the polyolefin is not functionalized; and d) a layer V of an EVOH molding composition, is present, can be produced inexpensively and has a good barrier action against the medium being conveyed.

摘要翻译： 燃料电池的线路系统的元件，其中与所传送的介质接触的部分包括聚酰胺模制组合物，另外还有至少一个选自以下的另外的层：a） 进一步的聚酰胺模塑组合物; b）包含官能化聚烯烃的模塑组合物的层III; c）聚烯烃模塑组合物的层IV，其中聚烯烃未被官能化; 和d）存在EVOH模塑组合物的层V，可以廉价地生产并且对被输送的介质具有良好的屏障作用。

公开(公告)号：US20080249237A1

公开(公告)日：2008-10-09

申请号：US12089998

申请日：2006-10-12

申请人： Harald Hager ,  Franz-Erich Baumann ,  Wolfgang Lortz ,  Christoph Batz-Sohn

发明人： Harald Hager ,  Franz-Erich Baumann ,  Wolfgang Lortz ,  Christoph Batz-Sohn

IPC分类号： C08L77/06 ,  C08G69/26 ,  B29C45/00 ,  B29C47/00 ,  B29C49/00

CPC分类号： C08J3/12 ,  C08J3/128 ,  C08J3/14 ,  C08J2377/00 ,  C09D177/00 ,  Y10S524/904

摘要： Process for preparing ultrafine powders based on polyamides by contacting polyamides having a relative solution viscosity ηrel in the range from 1.5 to 2.0, measured in 0.5% m-cresol solution at 25° C., with an alcoholic medium in the presence of inorganic particles under the action of pressure and/or temperature to generate an at least partial solution, and then precipitating the polyamide from the at least partial solution, characterized in that a suspension of the inorganic particles suspended in the alcoholic medium is used. The resulting ultrafine polyamide powders have a specific BET surface area in the range of 5-100 m2/g; a fineness d50 of less than 70 μm; an apparent density AD in the range from 250 to 1000 g/l; and a particle content of 0.1 to 80% by weight of inorganic particles based on the total weight of the polyamide powder. They are equally suitable for coatings and for mouldings and components with improved mechanical properties.

摘要翻译： 通过使具有相对溶液粘度和相对粘度的聚酰胺在25℃下在0.5％间甲酚溶液中测量的1.5至2.0的范围内与醇混合来制备基于聚酰胺的超细粉末的方法 介质在无机颗粒存在下在压力和/或温度的作用下产生至少部分溶液，然后从至少部分溶液中沉淀聚酰胺，其特征在于悬浮在醇介质中的无机颗粒的悬浮液 用来。 得到的超细聚酰胺粉末的比BET比表面积为5-100m 2 / g; 细度d <50％小于70μm; 在250〜1000g / l范围内的表观密度AD; 和基于聚酰胺粉末的总重量的无机颗粒的0.1〜80重量％的颗粒含量。 它们同样适用于具有改善的机械性能的涂料和模制品和组分。

公开(公告)号：US20080317986A1

公开(公告)日：2008-12-25

申请号：US10588487

申请日：2005-08-10

申请人： Guido Schmitz ,  Harald Hager ,  Hans Ries

发明人： Guido Schmitz ,  Harald Hager ,  Hans Ries

IPC分类号： B32B1/08 ,  B32B27/08

CPC分类号： C08L23/04 ,  B32B1/08 ,  B32B3/28 ,  B32B7/12 ,  B32B27/08 ,  B32B27/16 ,  B32B27/18 ,  B32B27/304 ,  B32B27/306 ,  B32B27/32 ,  B32B27/322 ,  B32B27/34 ,  B32B2250/24 ,  B32B2264/0207 ,  B32B2270/00 ,  B32B2307/202 ,  B32B2307/558 ,  B32B2307/7242 ,  B32B2307/7265 ,  B32B2439/40 ,  B32B2597/00 ,  B32B2605/08 ,  C08L23/10 ,  C08L77/02 ,  C08L77/06 ,  C08L2666/04 ,  C09J177/02 ,  C09J177/06 ,  F16L9/133 ,  Y10S138/01 ,  Y10S138/07 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/31725 ,  Y10T428/31732 ,  C08L2666/20

摘要： A multilayer composite which comprises the following layers: I. an interior layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition; II. a bonding agent layer II which has the following composition: a) from 0 to 80 parts by weight of a polyamine-polyamide graft copolymer, b) from 0 to 85 parts by weight of polyamide, c) from 0 to 85 parts by weight of a polymer selected from among fluoropolymers and polyolefins, with the sum of the parts by weight of a), b) and c) being 100, and, in addition, the sum of the components a) and b) comprising at least 20 parts by weight of monomer units derived from caprolactam and/or the combination hexamethylenediamine/adipic acid, hexamethylenediamine/suberic acid, hexamethylenediamine/sebacic acid, hexamethylenediamine/dodecanedioic acid, hexamethylenediamine/isophthalic acid or hexamethylenediamine/terephthalic acid and d) not more than 50 parts by weight of additives selected from among impact-modifying rubber and customary auxiliaries and additives; III. a layer III comprising an EVOH molding composition, has improved adhesion of the layers.

摘要翻译： 一种多层复合材料，其包含以下层：I.选自氟聚合物模塑组合物和聚烯烃模塑组合物的内层I; 二， 具有以下组成的粘合剂层II：a）0至80重量份的聚胺 - 聚酰胺接枝共聚物，b）0至85重量份的聚酰胺，c）0至85重量份的 选自含氟聚合物和聚烯烃的聚合物，其中a），b）和c）的重量份的总和为100，另外，组分a）和b）的总和包含至少20份 衍生自己内酰胺和/或六亚甲基二胺/己二酸，六亚甲基二胺/辛二酸，六亚甲基二胺/癸二酸，六亚甲基二胺/十二烷二酸，六亚甲基二胺/间苯二甲酸或六亚甲基二胺/对苯二甲酸的单体单元的重量和d）不超过50份 选自改性橡胶和常规助剂和添加剂的添加剂的重量; 三， 包含EVOH模塑组合物的层III具有改善的层的粘附性。

公开(公告)号：US20080161469A1

公开(公告)日：2008-07-03

申请号：US11817407

申请日：2006-04-11

申请人： Werner Hoss ,  Klaus Albrecht ,  Krzysztof Sado ,  Harald Hager

发明人： Werner Hoss ,  Klaus Albrecht ,  Krzysztof Sado ,  Harald Hager

IPC分类号： C08L9/00 ,  C08K3/22 ,  C08K3/30 ,  C08K3/36

CPC分类号： C08J3/20 ,  C08J3/205 ,  C08K3/013 ,  Y02P20/544

摘要： (EN) The invention concerns a method for producing a thermoplastic molding material or element, said material or element containing nanometric inorganic particles. In molten state, the thermoplastic is mixed with the nanometric inorganic particles and with a solubilizing agent in a conveyor screw extruder, the pressures and temperatures being adjusted so that the plastic is in melt form and the solubilizing agent in supercritical state. The invention is characterized in that at the output of the extruder, the mixture passes through a slot with a passage less than 20 $g(m)m to penetrate into an expansion zone and the molten material, wherein are incorporated the nanometric inorganic particles, is evacuated, reduced into molding material after cooling or transferred into a molding tool to be molded. The invention also concerns the molding material and the molding elements obtained by this method, as well as the uses thereof.

摘要翻译： （EN）本发明涉及一种生产热塑性成型材料或元素的方法，所述材料或元素含有纳米无机颗粒。 在熔融状态下，将热塑性塑料与纳米无机颗粒和增溶剂在输送机螺杆挤出机中混合，调节压力和温度，使塑料呈熔体状态，增溶剂处于超临界状态。 本发明的特征在于，在挤出机的输出处，混合物通过具有小于20千克（m）m的通道的槽，以渗入膨胀区，并且其中掺入纳米无机颗粒的熔融材料， 被抽真空，冷却后还原成模制材料或转移到待模制的模具中。 本发明还涉及通过该方法获得的成型材料和成型元件及其用途。