Polyurethane nanocomposites
    3.
    发明授权
    Polyurethane nanocomposites 有权
    聚氨酯纳米复合材料

    公开(公告)号:US09540479B2

    公开(公告)日:2017-01-10

    申请号:US12978699

    申请日:2010-12-27

    摘要: Polyurethane nanocomposites are provided which include a polyurethane and surface modified silica nanoparticles covalently bound into the polyurethane. High loadings in excess of 30% may be achieved. In some embodiments, the silica nanoparticles are covalently bound to the polyurethane polymer through a linkage derived from a surface-modifying compound comprising a silane functional group and a polyol segment. In some embodiments the polyurethane nanocomposite may be provided as a tape or film. In addition, precursors for a polyurethane nanocomposites are provided comprising: a first polyol and surface modified silica nanoparticles dispersed within the first polyol. In some embodiments, the silica nanoparticles are surface-modified by reaction with a surface-modifying compound comprising a silane functional group and a polyol segment derived from a second polyol, which may be the same or different from the first polyol.

    摘要翻译: 提供聚氨酯纳米复合材料,其包括共聚在聚氨酯中的聚氨酯和表面改性的二氧化硅纳米粒子。 可以实现超过30%的高负荷。 在一些实施方案中,二氧化硅纳米颗粒通过源自包含硅烷官能团和多元醇链段的表面改性化合物的连接键与聚氨酯聚合物共价结合。 在一些实施方案中,聚氨酯纳米复合材料可以作为带或膜提供。 此外,提供了聚氨酯纳米复合材料的前体,其包含:分散在第一多元醇内的第一多元醇和表面改性的二氧化硅纳米颗粒。 在一些实施方案中,二氧化硅纳米颗粒通过与包含硅烷官能团的表面改性化合物和衍生自可与第一多元醇相同或不同的第二多元醇的多元醇部分的反应进行表面改性。

    FILLED RESINS AND METHOD FOR MAKING FILLED RESINS
    6.
    发明申请
    FILLED RESINS AND METHOD FOR MAKING FILLED RESINS 有权
    填充树脂和填充填料的方法

    公开(公告)号:US20110028605A1

    公开(公告)日:2011-02-03

    申请号:US12933526

    申请日:2009-03-26

    摘要: A method of making a filled resin includes providing functionalized particles; and combining and homogenously mixing the functionalized particles with an organic matrix in a vacuum kneader to provide the filled resin so that the functionalized particles comprise at least about 20% by weight of the filled resin. The step of providing functionalized particles can also include providing a feedstock of (i) untreated particles, (ii) a surface treatment agent reactive with the particles, and (iii) solvent, and directing the feedstock through a continuous reactor maintained at a temperature sufficient to react the particles with the surface treatment agent to provide the functionalized particles in less than about 4 hours; and directing the functionalized particles from the continuous reactor directly into the vacuum kneader. In another aspect, the a finished resin comprises at least about 20% by weight of functionalized particles in an organic matrix.

    摘要翻译: 制备填充树脂的方法包括提供官能化颗粒; 并在真空捏合机中将官能化颗粒与有机基质混合并均匀混合以提供填充的树脂,使得官能化颗粒占填充树脂的至少约20重量%。 提供官能化颗粒的步骤还可以包括提供(i)未处理颗粒的原料,(ii)与颗粒反应的表面处理剂,和(iii)溶剂,并引导原料通过维持在足够温度的连续反应器 使颗粒与表面处理剂反应以在小于约4小时内提供官能化颗粒; 并将来自连续反应器的官能化颗粒直接引入真空捏合机中。 在另一方面,成品树脂包含至少约20重量%的有机基质中的官能化颗粒。

    Filled resins and method for making filled resins
    8.
    发明授权
    Filled resins and method for making filled resins 有权
    填充树脂和填充树脂的制造方法

    公开(公告)号:US08487019B2

    公开(公告)日:2013-07-16

    申请号:US12933526

    申请日:2009-03-26

    IPC分类号: C08J3/02 C08K9/00

    摘要: A method of making a filled resin includes providing functionalized particles; and combining and homogenously mixing the functionalized particles with an organic matrix in a vacuum kneader to provide the filled resin so that the functionalized particles comprise at least about 20% by weight of the filled resin. The step of providing functionalized particles can also include providing a feedstock of (i) untreated particles, (ii) a surface treatment agent reactive with the particles, and (iii) solvent, and directing the feedstock through a continuous reactor maintained at a temperature sufficient to react the particles with the surface treatment agent to provide the functionalized particles in less than about 4 hours; and directing the functionalized particles from the continuous reactor directly into the vacuum kneader. In another aspect, the a finished resin comprises at least about 20% by weight of functionalized particles in an organic matrix.

    摘要翻译: 制备填充树脂的方法包括提供官能化颗粒; 并在真空捏合机中将官能化颗粒与有机基质混合并均匀混合以提供填充的树脂,使得官能化颗粒占填充树脂的至少约20重量%。 提供官能化颗粒的步骤还可以包括提供(i)未处理颗粒的原料,(ii)与颗粒反应的表面处理剂,和(iii)溶剂,并引导原料通过维持在足够温度的连续反应器 使颗粒与表面处理剂反应以在小于约4小时内提供官能化颗粒; 并将来自连续反应器的官能化颗粒直接引入真空捏合机中。 在另一方面,成品树脂包含至少约20重量%的有机基质中的官能化颗粒。