Surface-modified metal and method for modifying metal surface

    公开(公告)号:US10556040B2

    公开(公告)日:2020-02-11

    申请号:US15223965

    申请日:2016-07-29

    Abstract: Provided are surface-modified metals and methods for modifying a metal surface, which involve a lubricating surface layer chemically fixed to the metal surface to provide excellent lubricity and excellent lubricant durability, and further which have good productivity and good economic efficiency. Included is a surface-modified metal whose surface is at least partially provided with a treatment layer having a thickness of 50 to 800 nm, the treatment layer being formed by treating a surface of a metal with a silane coupling agent, followed by adsorbing a hydrogen abstraction type photopolymerization initiator onto the surface and then polymerizing a monomer.

    Surface modification method and surface-modified elastic body
    5.
    发明授权
    Surface modification method and surface-modified elastic body 有权
    表面改性法和表面改性弹性体

    公开(公告)号:US09540493B2

    公开(公告)日:2017-01-10

    申请号:US14107746

    申请日:2013-12-16

    CPC classification number: C08J7/18 C08F2/50 C08F291/00 C08J2311/00

    Abstract: The present invention aims to provide a method for surface-modifying a rubber vulcanizate or a thermoplastic elastomer, which is capable of cost-effectively imparting a variety of functions, such as sliding properties and biocompatibility, according to the applications. The present invention relates to a surface modification method for surface-modifying an object of a rubber vulcanizate or a thermoplastic elastomer, the method including: step 1 of forming polymerization initiation points A on a surface of the object; step 2 of radically polymerizing a non-functional monomer, starting from the polymerization initiation points A, to grow non-functional polymer chains; step 3 of forming polymerization initiation points B on the surface of the object where the non-functional polymer chains are formed; and step 4 of radically polymerizing a functional monomer, starting from the polymerization initiation points B, to grow functional polymer chains.

    Abstract translation: 本发明的目的在于提供一种橡胶硫化橡胶或热塑性弹性体的表面改性方法,其能够根据应用成本有效地赋予各种功能,如滑动性能和生物相容性。 本发明涉及一种表面改性橡胶硫化橡胶或热塑性弹性体物体表面改性方法,该方法包括:在物体表面上形成聚合起始点A的步骤1; 从聚合引发点A开始自由基聚合非官能单体的步骤2,生长非功能性聚合物链; 在形成非功能性聚合物链的物体的表面上形成聚合引发点B的步骤3; 以及从聚合引发点B开始自由基聚合官能单体的步骤4,以生长功能性聚合物链。

    Method for predicting resistance to heat deterioration of isoprene rubber
    6.
    发明授权
    Method for predicting resistance to heat deterioration of isoprene rubber 有权
    预测异戊二烯橡胶耐热劣化性的方法

    公开(公告)号:US09488707B2

    公开(公告)日:2016-11-08

    申请号:US13829595

    申请日:2013-03-14

    CPC classification number: G01R33/46 G01N24/08

    Abstract: A method for predicting the resistance to heat deterioration of a sulfur-vulcanized isoprene rubber is disclosed. The nuclear magnetic resonance spectrum of the isoprene rubber is obtained by the use of a solid state nuclear magnetic resonance method employing magic angle spinning. The spectrum of a cross-linked structure α and the spectrum of a cross-linked structure β in the nuclear magnetic resonance spectrum are identified. The percentage of the cross-linked structure α and the percentage of the cross-linked structure β in the overall cross-linked structures of the sulfur are computed from the spectrum. From the computed percentages, the resistance to heat deterioration of the isoprene rubber is predicted.

    Abstract translation: 公开了一种用于预测硫硫化异戊二烯橡胶的耐热劣化性的方法。 异戊二烯橡胶的核磁共振谱通过使用魔角旋转的固态核磁共振法获得。 确定交联结构α的光谱和核磁共振谱中交联结构β的光谱。 从光谱计算交联结构α的百分比和交联结构β在硫的整体交联结构中的百分比。 从计算出的百分比,预测异戊二烯橡胶的耐热劣化性。

    SURFACE MODIFICATION METHOD AND SURFACE-MODIFIED ELASTIC BODY
    8.
    发明申请
    SURFACE MODIFICATION METHOD AND SURFACE-MODIFIED ELASTIC BODY 审中-公开
    表面改性方法和表面改性弹性体

    公开(公告)号:US20150203612A1

    公开(公告)日:2015-07-23

    申请号:US14421319

    申请日:2013-09-09

    Abstract: The present invention aims to provide methods for surface-modifying a rubber vulcanizate or a thermoplastic elastomer, which can cost-effectively impart a variety of functions, such as sliding properties or biocompatibility, according to the application. The present invention relates to a method for surface-modifying an object of a rubber vulcanizate or a thermoplastic elastomer, the method including: step 1 of forming polymerization initiation points A on the surface of the object; and step 2 of radically polymerizing a non-functional monomer, starting from the polymerization initiation points A, to grow non-functional polymer chains, and further radically polymerizing a fluorine-containing functional monomer to grow fluorine-containing functional polymer chains.

    Abstract translation: 本发明的目的是提供一种橡胶硫化橡胶或热塑性弹性体的表面改性方法,其可根据应用成本有效地赋予各种功能,如滑动性能或生物相容性。 本发明涉及橡胶硫化橡胶或热塑性弹性体的表面改性方法,该方法包括:步骤1,在物体的表面上形成聚合起始点A. 以及从聚合引发点A开始自由基聚合非官能单体的步骤2,生长非官能聚合物链,并进一步自由基聚合含氟官能单体生长含氟官能聚合物链。

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