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    Sulfonyl compounds
    1.
    发明授权
    Sulfonyl compounds 失效
    磺酰化合物

    公开(公告)号：US3966769A

    公开(公告)日：1976-06-29

    申请号：US444810

    申请日：1974-02-22

    申请人： Steffen Piesch ,  Friedrich Engelhardt

    发明人： Steffen Piesch ,  Friedrich Engelhardt

    IPC分类号： C07D233/40 ,  C07D317/56

    CPC分类号： C07D233/40

    摘要： Compounds of the formulaR -- SO.sub.2 -- Xwherein X is ##EQU1## R and R.sup.5 are aryl, aralkyl, heteroaryl, cycloalkyl or alkyl; R.sup.1 and R.sup.4 are R, hydrogen, carboxy or carboxylate; R.sup.2 is aryl, aralkyl, cycloalkyl or alkyl; R.sup.3 is R.sup.2 or hydrogen; Y is alkylene, cycloalkylene or phenylene, Y.sup.1 is Y or a direct bond and Z is alkylene, hydroxy substituted alkylene, alkylene interrupted by a hetero atom or ##EQU2## and methods of preparing the same.

    摘要翻译： 式R-SO2-X的化合物，其中X为Z -CH-SR2，-CH-N角度N-R3，| | CR R1平行OZ -CH-N角度N-CH-SO2-R5，| C | R1并行R4 O -CH-NH-COO-Y-OOC-NH-CH-SO2-R，|| R1R1 -CH-SR2，-CH-NH-COR3OR | | Y1 Y1 | | R-SO2-CH- SR2R-SO2-CH-NH-COR3 -CH-NH-SO2R2; | Y1 | R-SO2-CH-NH-SO2R2 R和R5是芳基，芳烷基，杂芳基，环烷基或烷基; R1和R4是R，氢，羧基或羧酸酯; R2是芳基，芳烷基，环烷基或烷基; R3是R2或氢; Y是亚烷基，亚环烷基或亚苯基，Y1是Y或直接键，Z是亚烷基，羟基取代的亚烷基，被杂原子间隔的亚烷基或-CH --- CH- || HNNH ANGLE C PARALLEL O和制备 相同。

    Water soluble, crosslinkable polymer compositions, their preparation and use
    2.
    发明授权
    Water soluble, crosslinkable polymer compositions, their preparation and use 失效
    水溶性，可交联聚合物组合物，其制备和用途

    公开(公告)号：US4499232A

    公开(公告)日：1985-02-12

    申请号：US423026

    申请日：1982-09-24

    申请人： Friedrich Engelhardt ,  Steffen Piesch ,  Juliane Balzar ,  Jeffery C. Dawson

    发明人： Friedrich Engelhardt ,  Steffen Piesch ,  Juliane Balzar ,  Jeffery C. Dawson

    IPC分类号： C08F8/30 ,  C09K8/72 ,  C08L33/26 ,  C08L39/06

    CPC分类号： C09K8/74 ,  C08F8/30 ,  C09K8/78 ,  Y10S507/903 ,  Y10S507/933

    摘要： The present invention relates to macromolecular compositions crosslinked by a novel bridge having the formula --NR.sup.x --CH.dbd.N--CO--. This novel bridge is obtained by reacting a macro-molecule, preferably a polymer, having at least two amidocarbonyl groups with a compound having at least two formylamido groups in an aqueous medium under highly acidic conditions. The crosslinking bridge formed by the reaction of this invention is produced in accord with the following formula: ##STR1## Compositions containing macromolecules having at least two amidocarbonyl groups and a compound having at least two formylamido groups can act as viscosifying or gelling agents for aqueous acids where when added to aqueous acids, crosslinking occurs. Acids gelled in this manner have important use in the recovery of oil and natural gas from subterranean formations.

    摘要翻译： 本发明涉及通过具有式-NR x-CH = N-CO-的新型桥交联的高分子组合物。 通过在高度酸性条件下，在含水介质中使具有至少两个酰氨基羰基的大分子，优选聚合物与具有至少两个甲酰胺基的化合物反应来获得该新型桥。 通过本发明的反应形成的交联桥根据下式生产：含有至少两个酰氨基羰基的大分子和具有至少两个甲酰胺基的化合物的组合物可以作为增粘剂 或凝胶剂，其中当加入酸性水中时，发生交联。 以这种方式凝胶化的酸在从地层中回收油和天然气方面具有重要的用途。

    Cross-linkable and cross linked macromolecular compositions wherein cross-linking is by structural bridges of the formula --NR.sup.x --CH.dbd.N--CO-- and their preparation
    5.
    发明授权
    Cross-linkable and cross linked macromolecular compositions wherein cross-linking is by structural bridges of the formula --NR.sup.x --CH.dbd.N--CO-- and their preparation 失效
    可交联和交联的大分子组合物，其中交联是通过式-NR x-CH = N-CO-的结构桥接及其制备

    公开(公告)号：US4507440A

    公开(公告)日：1985-03-26

    申请号：US399682

    申请日：1982-07-19

    申请人： Friedrich Engelhardt ,  Steffen Piesch ,  Juliane Balzer ,  Jeffery C. Dawson

    发明人： Friedrich Engelhardt ,  Steffen Piesch ,  Juliane Balzer ,  Jeffery C. Dawson

    IPC分类号： C08F8/30 ,  C08K5/20 ,  C09K8/68 ,  C09K8/72 ,  C08L33/26

    CPC分类号： C09K8/72 ,  C08F8/30 ,  C08K5/20 ,  C09K8/685 ,  Y10S507/903 ,  Y10S507/933

    摘要： The present invention relates to macromolecular compositions crosslinked by a novel bridge having the formula --NR.sup.x --CH.dbd.N--CO--. This novel bridge is obtained by reacting a macro-molecule, preferably a polymer, having at least two amidocarbonyl groups with a compound having at least two formylamido groups in an aqueous medium under highly acidic conditions. The crosslinking bridge formed by the reaction of this invention is produced in accord with the following formula: ##STR1## Compositions containing macromolecules having at least two amidocarbonyl groups and a compound having at least two formylamido groups can act as viscosifying or gelling agents for aqueous acids where when added to aqueous acids, crosslinking occurs. Acids gelled in this manner have important use in the recovery of oil and natural gas from subterranean formations.

    摘要翻译： 本发明涉及通过具有式-NR x-CH = N-CO-的新型桥交联的高分子组合物。 通过在高度酸性条件下，在含水介质中使具有至少两个酰氨基羰基的大分子，优选聚合物与具有至少两个甲酰胺基的化合物反应来获得该新型桥。 通过本发明的反应形成的交联桥根据下式生产：含有至少两个酰氨基羰基的大分子和具有至少两个甲酰胺基的化合物的组合物可以作为增粘剂 或凝胶剂，其中当加入酸性水中时，发生交联。 以这种方式凝胶化的酸在从地层中回收油和天然气方面具有重要的用途。

    Polymers based on N-formyl-N'-acryloyl-methylenediamines
    6.
    发明授权
    Polymers based on N-formyl-N'-acryloyl-methylenediamines 失效
    基于N-甲酰基-N {40-丙烯酰 - 亚甲基二胺的聚合物

    公开(公告)号：US3966689A

    公开(公告)日：1976-06-29

    申请号：US545550

    申请日：1975-01-30

    申请人： Joachim Ribka ,  Friedrich Engelhardt ,  Steffen Piesch

    发明人： Joachim Ribka ,  Friedrich Engelhardt ,  Steffen Piesch

    IPC分类号： C08F20/60 ,  C08F22/38

    CPC分类号： C08F20/60

    摘要： Linear addition polymers of a compound of the formula ##EQU1## wherein R.sup.1, R.sup.2 and R.sup.3 are hydrogen or alkyl having 1 to 5 carbon atoms, said polymers being thermally crosslinkable at temperatures below 100.degree.C. to produce moulded products, lacquers and coatings and to fix pigments to fibers and films of natural and synthetic origin.

    摘要翻译： 式H-CO-N-CH2-NH-CO-C = CH || R1R2R3的化合物的直链加成聚合物，其中R 1，R 2和R 3是氢或具有1至5个碳原子的烷基，所述聚合物是可热交联的 在低于100℃的温度下生产模塑产品，漆和涂料，并将颜料固定在天然和合成来源的纤维和薄膜上。

    Hydrophilic hydrogels with a high swelling capacity and method for producing and using them
    9.
    发明授权
    Hydrophilic hydrogels with a high swelling capacity and method for producing and using them 失效
    具有高溶胀能力的亲水性水凝胶及其制造和使用方法

    公开(公告)号：US06602950B1

    公开(公告)日：2003-08-05

    申请号：US09806944

    申请日：2001-04-06

    申请人： Joachim Dentler ,  Rüdiger Funk ,  Norbert Herfert ,  Mariola Wanior ,  Friedrich Engelhardt

    发明人： Joachim Dentler ,  Rüdiger Funk ,  Norbert Herfert ,  Mariola Wanior ,  Friedrich Engelhardt

    IPC分类号： A61L1524

    CPC分类号： C08F283/06 ,  A61L15/60 ,  C08F8/00 ,  C08F251/00 ,  C08F283/02 ,  Y10S524/916 ,  Y10S526/932 ,  Y10S604/904 ,  C08F283/00

    摘要： A hydrophilic, highly swellable hydrogel based on (co)polymerized monomers or based on graft (co)polymers and prepared by a) free-radically (co)polymerizing one-or more hydrophilic monomers or graft (co)polymerizing one or more hydrophilic monomers onto a grafting base, the average degree of neutralization of the acid-functional monomers being from 0 to 40 mol %, b) comminuting the acidic hydrogel, c) neutralizing the acidic hydrogel to an ultimate degree of neutralization of 50-85 mol % by adding a neutralizing agent, d) drying, grinding and sieving the hydrogel particles characterized by a centrifuge retention and a vertical absorption swell height, each having a specified minimum.value, coupled with an extractables content having a specified maximum value or a centrifuge retention and a vertical absorption swell height, each having a specified minimum value and an extractables content having a specified maximum value.

    摘要翻译： 基于（共）聚合单体或基于接枝（共）聚合物的亲水性，高度可溶胀的水凝胶，并通过自由基（共）聚合一种或多种亲水单体或将一种或多种亲水性单体接枝（共）聚合到 接枝碱，酸官能单体的平均中和度为0〜40摩尔％，b）粉碎酸性水凝胶，c）通过加入酸性水凝胶中和酸性水凝胶至50-85摩尔％的最终中和度 中和剂，d）干燥，研磨和筛分水凝胶颗粒，其特征在于离心机保留和垂直吸收膨胀高度，每个具有特定的最小值，加上具有特定最大值的可提取物含量或离心机保留和垂直吸收 每个具有指定的最小值的膨胀高度，以及具有指定的最大值的可提取物内容。