Abstract:
An estimated trapped amount (PM) that is an estimated value of an amount of particulate matter that is trapped in a particulate filter arranged in an engine exhaust passage is calculated based on an engine operating state, and PM removal control is performed when the estimated trapped amount exceeds an upper limit amount. Reference temperature increase control is performed to remove the particulate matter from the particulate filter, and an actual temperature that is the temperature of the particulate filter while the reference temperature increase control is being performed is detected. A reference temperature that is the temperature of the particulate filter when it is assumed that the reference temperature increase control has been performed when the amount of particulate matter trapped in the particulate filter is a reference initial trapped amount is stored in advance. The estimated trapped amount is corrected based on the actual temperature and the reference temperature.
Abstract:
An exhaust gas purification apparatus of an internal combustion engine includes: a reducing agent passage that connects a tank and an injection valve; a heater that heats up a hydrolysis catalyst that is provided in the reducing agent passage; and a controller comprising at least one processor configured to control a pump so that a reducing agent located further toward a side of the injection valve than the hydrolysis catalyst flows toward a side of the hydrolysis catalyst after completion of injection of a reducing agent in a state where the hydrolysis catalyst is at a temperature lower than the hydrolysis temperature and before start of injection of a reducing agent in a state where the hydrolysis catalyst is at a temperature equal to or higher than the hydrolysis temperature.
Abstract:
An object is to provide technology that enables an NOx catalyst to exercise its NOx reduction capability satisfactorily at any flow speed of the exhaust gas flowing into the NOx catalyst. An exhaust gas purification apparatus for an internal combustion engine includes a selective catalytic reduction NOx catalyst including at least a first catalyst layer having capability of reducing NOx and a second catalyst layer having oxidation capability and arranged closer to a catalyst substrate than the first catalyst layer. The apparatus has a supply valve for adding a specific addition quantity of reducing agent for reducing NOx to inflowing exhaust gas flowing into the selective catalytic reduction NOx catalyst. The apparatus further has a controller that is configured to control addition of the reducing agent by the supply valve based on the flow speed of the inflowing exhaust gas in such a way that the concentration of the reducing agent in a reducing agent atmosphere formed in the inflowing exhaust gas in a reducing agent addition period becomes equal to a specific concentration that is determined based on the flow speed of the inflowing exhaust gas and at which the reducing agent is assumed not to reach the second catalyst layer, when the temperature of the selective catalytic reduction NOx catalyst exceeds a specific temperature at which reduction of NOx by the first catalyst layer is carried out.
Abstract:
An exhaust purification device for an internal combustion engine is provided with an NOx adsorbent for adsorbing NOx in exhaust gas and an NOx purifying catalyst for purifying NOx in exhaust gas, which are arranged in an engine exhaust passage. An electric heater is provided for raising the temperature of the NOx adsorbent. When a signal requesting startup of an internal combustion engine is issued, the device starts to supply electric power to the electric heater before the internal combustion engine completely warms up, and supplies the electric heater with a quantity of electric power making the temperature of the NOx adsorbent equal to or higher than the moisture desorption temperature but lower than the NOx desorption temperature.
Abstract:
An exhaust gas control apparatus for an internal combustion engine includes: an SCR catalyst including transition metal ions for reducing NOX in exhaust gas with NH3 as a reducing agent; detection means for detecting temperature of the SCR catalyst; and a heater configured to heat the SCR catalyst. When NOX does not flow into the SCR catalyst, and the temperature detected by the detection means is below a first temperature that is a temperature causing exhibition of valence recovery of transition metal ions, the heater is controlled such that the SCR catalyst is heated up to a first temperature or above and that the SCR catalyst is maintained at or above the first temperature for a prescribed period so as to achieve valence recovery of the transition metal ions put in a deteriorated state.
Abstract:
An exhaust gas control apparatus for an internal combustion engine includes an addition valve, a tank, a urea water passage, a pump, a nitrogen oxides catalyst, and an electronic control unit. The electronic control unit is configured to: control the pump, as a first control, such that a specified amount of the urea water stored in the addition valve and the urea water passage is returned to the tank after the internal combustion engine is stopped; control the pump, as a second control, such that the specified amount or more of the urea water in the tank is discharged from the tank to the urea water passage after the first control is executed; and control the pump, as a third control, such that all the urea water stored in the addition valve and the urea water passage is returned to the tank after the second control is executed.
Abstract:
A gel which contains a component of a catalyst is prepared. The gel and another gel are arranged in layers at a position which faces open ends of exhaust flow passages of a wall flow-type particulate filter. Next, a pusher is used to push and pack the gel and other gel through the open ends to the insides of the exhaust flow passages. Next, the particulate filter is made to dry to thereby make the partition walls carry the catalyst on their surfaces or in their micropores.
Abstract:
An exhaust gas purification filter includes an inflow/outflow passage through which exhaust gas flows in/out, and a partition. The outflow passage and the inflow passage is alternately arranged. The partition is configured to divide the inflow passage and the outflow passage from each other, and being porous. The partition includes a coated zone where a surface of a base of the partition is covered with a first coating layer having an average pore diameter smaller than an average pore diameter of the base, and a non-coated zone where the surface of the base is not covered with the first coating layer on a downstream side of the coated zone. The average pore diameter of the base is large enough for ash to pass through the partition, and the first coating layer is constituted by a plurality of particle groups with different average particle diameters from each other.
Abstract:
An object is to prevent abrasion inside an addition valve and clogging of the addition valve due to an increase in the particle diameter of precipitates. A first control is performed by which a pump is caused to operate in such a way as to return urea solution contained in the addition valve and a urea solution channel to a tank by a predetermined quantity. After the lapse of a certain time after the end of the first control, a second control is performed by which the pump is caused to operate in such a way as to return the urea solution remaining in the addition valve and the urea solution channel thoroughly to the tank.
Abstract:
A NOx catalyst is provided that can realize a favorable NOx reduction in a broad temperature region and that can lighten the overhead involved in production. The NOx catalyst has active components exhibiting a selective reduction activity for NOx, wherein the active components exhibiting the selective reduction activity contains a high-temperature active component having a relatively high NOx reduction activity at high temperatures and a low-temperature active component having a relatively high NOx reduction activity at low temperatures; and the high-temperature active component and the low-temperature active component are disposed in a mixed state in a primary particle of the catalyst particle, and an active component ratio on a surface side of the primary particle is larger than an active component ratio on an interior side of the primary particle, with the active component ratio being is a ratio of a concentration of the high-temperature active component to a concentration of the low-temperature active component in the primary particle.