摘要:
Provided is a paper container having a window and being formed of a laminate that includes at least a paper layer and a gas barrier laminate, the paper layer having a cutout part for the window, the cutout part being covered with the gas barrier laminate, and the gas barrier laminate including a substrate and a gas barrier layer laminated on at least one surface of the substrate, wherein the gas barrier layer is formed of a composition containing a polymer having at least one functional group selected from a carboxyl group and a carboxylic anhydride group, and wherein —COO— groups contained in the at least one functional group are neutralized at least partly with a metal ion having a valence of two or more.
摘要:
A paper container is provided that allows the content to be checked, prevents the content from deteriorating for a long period of time, and is excellent in, for example, storage and preservation properties. Furthermore, a paper container is provided that can be subjected to a retort sterilization process, prevents the content from deteriorating for a long period of time, and is excellent in, for example, storage and preservation properties. A paper container formed of a laminate including at least a paper layer is provided. The paper layer has a cutout part that is covered with a gas barrier laminate. The gas barrier layer of the gas barrier laminate is formed of a composition containing a neutralized product of a polymer containing at least one functional group selected from a carboxyl group and a carboxylic anhydride group, and a hydrolysis condensation product of at least one compound (L) containing a metal atom to which at least one characteristic group selected from a halogen atom and an alkoxy group has been bonded. The —COO— groups contained in the at least one functional group are neutralized at least partly with a metal ion having a valence of two or more.
摘要:
Provided is a gas barrier layered product including a base material and a layer stacked on at least one surface of the base material, wherein the layer is formed of a composition including: a hydrolyzed and condensed product of at least one compound (L) containing a metal atom to which at least one characteristic group selected from a halogen atom and an alkoxy group has been bonded, wherein the compound (L) contains at least one compound (A) and at least one compound (B), wherein a mole ratio of the compound (A) / the compound (B) is in a range of 0.5/99.5 to 40/60; and a neutralized product of a polymer containing at least one functional group selected from a carboxyl group and a carboxylic anhydride group, wherein at least 55 mol % of a —COO— group contained in the at least one functional group has been neutralized with a metal ion having a valence of two or more. Also provided is a method for producing the gas barrier layered product.
摘要:
The present invention provides a gas barrier layered product exhibiting a high oxygen barrier property independent of humidity and having excellent transparency, and a method of manufacturing the same. The gas barrier layered product includes a base material and a layer stacked on the base material. The layer is formed of a composition includes: a hydrolyzed and condensed product of a compound (L) containing a metal atom to which at least one group selected from a halogen atom and an alkoxy group is bonded; a neutralized product of a polymer containing a functional group selected from a carboxyl group and a carboxylic anhydride group; and a compound (D). At least a part of a —COO— group contained in the at least one functional group is neutralized by a metal ion having a valence of two or more. The compound (L) includes at least one compound (A) in which an organic group having at least one characteristic group, selected from a halogen atom, a mercapto group and a hydroxyl group, further bonded to the metal atom. The compound (D) is a compound bonding to both the —COO— group of the neutralized product of the polymer and a group on the surface of the hydrolyzed and condensed product.
摘要:
A gas barrier layered product including a base material and a layer stacked on a surface of the base material, wherein the layer is formed of a composition including: a hydrolyzed and condensed product of a compound (L) containing a metal atom to which a group selected from a halogen atom and an alkoxy group is bonded, and a compound (A) in which an organic group selected from a halogen atom, a mercapto group and a hydroxyl group is further bonded to the metal atom; a neutralized product of a polymer containing a functional group selected from a carboxyl group and a carboxylic anhydride group, wherein at least 40 mol % of a —COO— group contained in the functional group has been neutralized with a metal ion having a valence of two or more; and a compound (D) bonded to both the —COO— group and a group on the surface of the hydrolyzed and condensed product of the compound (L). A method for producing the gas barrier layered product.
摘要:
Provided is a gas barrier layered product including a base material and a layer stacked on at least one surface of the base material, wherein the layer is formed of a composition including: a hydrolyzed and condensed product of at least one compound (L) containing a metal atom to which at least one characteristic group selected from a halogen atom and an alkoxy group has been bonded, wherein the compound (L) contains at least one compound (A) and at least one compound (B), wherein a mole ratio of the compound (A)/the compound (B) is in a range of 0.5/99.5 to 40/60; and a neutralized product of a polymer containing at least one functional group selected from a carboxyl group and a carboxylic anhydride group, wherein at least 55 mol % of a —COO— group contained in the at least one functional group has been neutralized with a metal ion having a valence of two or more. Also provided is a method for producing the gas barrier layered product.
摘要:
A gas barrier layered product and a method for producing the same are provided. The gas barrier layered product exhibits a high oxygen barrier property regardless of humidity, exhibits a high oxygen barrier property even after being subjected to retort processing, and is excellent in strength and transparency. In order to provide the gas barrier layered product, the gas barrier layered product includes a base material and a layer stacked on at least one surface of the base material. The layer is formed of a composition that includes: a hydrolyzed and condensed product of at least one compound (L) containing a metal atom to which at least one characteristic group selected from a halogen atom and an alkoxy group has been bonded; and a neutralized product of a polymer containing at least one functional group selected from a carboxyl group and a carboxylic anhydride group. At least a part of the —COO— group contained in the at least one functional group has been neutralized with metal ions having a valence of two or more.
摘要:
The composite structural material of the present invention includes a base (X) and a layer (Y) stacked on the base (X). The layer (Y) includes a reaction product (R) of a metal oxide (A) and a phosphorus compound (B). In the infrared absorption spectrum of the layer (Y) in the range of 800 to 1400 cm−1, the wave number (n1) at which the infrared absorption reaches maximum is in the range of 1080 to 1130 cm−1.
摘要:
The formed product of the present invention is a formed product selected from the group consisting of a vertical form fill seal pouch, a container cover and a vacuum packaging pouch. The formed product is formed using a gas barrier layered product. The gas barrier layered product includes a base, and at least one layer with gas barrier properties that is stacked on the base. The layer is formed of a composition that includes a hydrolyzed condensate of a compound (L) and a neutralized product of a polymer (X) containing a carboxyl group or a carboxylic acid anhydride group. The compound (L) includes a compound (A) that contains M1 (Al, Ti or Zr) to which a hydrolyzable characteristic group is bonded and a compound (B) that contains Si to which a hydrolyzable characteristic group is bonded. At least part of —COO— group of the polymer (X) is neutralized with a metal ion having a valence of at least two. At least 80 mol % of the compound (B) is a compound expressed by a specific formula. The ratio of [the number of moles of M1 in the compound (A)]/[the number of moles Si in the compound (B)] is in the range of 0.1/99.9 to 35.0/65.0.
摘要:
The layered product of the present invention has a base, and a gas barrier layer stacked on the base. The gas barrier layer is formed of a composition that includes a hydrolyzed condensate of a compound (L) containing a hydrolyzable characteristic group, and a neutralized product of a polymer (P) containing at least one functional group selected from the group consisting of carboxyl group and carboxylic acid anhydride group. The compound (L) includes a compound (L1) and a compound (L2). The compound (L1) and the compound (L2) each contains a silicon atom to which the hydrolyzable characteristic group is bonded. The compound (L1) contains an organic group having amino group. The compound (L2) does not contain an organic group having amino group. At least part of the —COO— group in the at least one functional group contained in the polymer (P) is neutralized with a divalent or higher valent ion (E) of a metal element that has a higher electronegativity than calcium.