公开(公告)号：US07723729B2

公开(公告)日：2010-05-25

申请号：US12036396

申请日：2008-02-25

申请人： Tingkai Li ,  Sheng Teng Hsu

发明人： Tingkai Li ,  Sheng Teng Hsu

IPC分类号： H01L31/0312 ,  H01L29/20 ,  H01L29/06

CPC分类号： H01L29/0665 ,  B82Y10/00 ,  H01L21/02381 ,  H01L21/02433 ,  H01L21/02447 ,  H01L21/0245 ,  H01L21/02502 ,  H01L21/0254 ,  H01L21/02546 ,  H01L21/02639 ,  H01L21/0265 ,  H01L29/045 ,  H01L29/0673

摘要： A compound semiconductor-on-silicon (Si) wafer with a Si nanowire buffer layer is provided, along with a corresponding fabrication method. The method forms a Si substrate. An insulator layer is formed overlying the Si substrate, with Si nanowires having exposed tips. Compound semiconductor is selectively deposited on the Si nanowire tips. A lateral epitaxial overgrowth (LEO) process grows compound semiconductor from the compound semiconductor-coated Si nanowire tips, to form a compound semiconductor layer overlying the insulator. Typically, the insulator layer overlying the Si substrate is a thermally soft insulator (TSI), silicon dioxide, or SiXNY, where x≦3 and Y≦4. The compound semiconductor can be GaN, GaAs, GaAlN, or SiC. In one aspect, the Si nanowire tips are carbonized, and SiC is selectively deposited overlying the carbonized Si nanowire tips, prior to the selective deposition of compound semiconductor on the Si nanowire tips.

摘要翻译： 提供了具有Si纳米线缓冲层的化合物半导体硅（Si）晶片以及相应的制造方法。 该方法形成Si衬底。 在Si衬底上形成绝缘体层，Si纳米线具有暴露的尖端。 化合物半导体选择性沉积在Si纳米线尖端上。 横向外延生长（LEO）工艺从化合物半导体涂覆的Si纳米线尖端生长化合物半导体，以形成覆盖绝缘体的化合物半导体层。 通常，覆盖Si衬底的绝缘体层是热软绝缘体（TSI），二氧化硅或SiXNY，其中x和nlE; 3和Y和nlE; 4。 化合物半导体可以是GaN，GaAs，GaAlN或SiC。 在一个方面，将Si纳米线尖端碳化，并且在Si纳米线尖端上选择性沉积化合物半导体之前，选择性地将SiC沉积在碳化Si纳米线尖端上。

公开(公告)号：US07633108B2

公开(公告)日：2009-12-15

申请号：US11893402

申请日：2007-08-15

申请人： Tingkai Li ,  Sheng Teng Hsu ,  Wei-Wei Zhuang ,  David R. Evans

发明人： Tingkai Li ,  Sheng Teng Hsu ,  Wei-Wei Zhuang ,  David R. Evans

IPC分类号： H01L27/108 ,  H01L29/76 ,  H01L29/94 ,  H01L31/119

CPC分类号： H01L27/101 ,  G11C13/0007 ,  G11C2213/31 ,  H01L27/2409 ,  H01L27/2463 ,  H01L29/66143 ,  H01L29/872 ,  H01L45/04 ,  H01L45/1233 ,  H01L45/147

摘要： A method is provided for forming a metal/semiconductor/metal (MSM) current limiter and resistance memory cell with an MSM current limiter. The method provides a substrate; forms an MSM bottom electrode overlying the substrate; forms a ZnOx semiconductor layer overlying the MSM bottom electrode, where x is in the range between about 1 and about 2, inclusive; and, forms an MSM top electrode overlying the semiconductor layer. The ZnOx semiconductor can be formed through a number of different processes such as spin-coating, direct current (DC) sputtering, radio frequency (RF) sputtering, metalorganic chemical vapor deposition (MOCVD), or atomic layer deposition (ALD).

摘要翻译： 提供了一种用于形成具有MSM限流器的金属/半导体/金属（MSM）限流器和电阻存储器单元的方法。 该方法提供基底; 形成覆盖衬底的MSM底部电极; 形成覆盖MSM底部电极的ZnOx半导体层，其中x在约1和约2之间的范围内; 并且形成覆盖半导体层的MSM顶部电极。 可以通过旋涂，直流（DC）溅射，射频（RF）溅射，金属有机化学气相沉积（MOCVD）或原子层沉积（ALD）等多种不同的工艺形成ZnO x半导体。

公开(公告)号：US07625595B2

公开(公告)日：2009-12-01

申请号：US11403022

申请日：2006-04-11

申请人： Wei-Wei Zhuang ,  David R. Evans ,  Tingkai Li ,  Sheng Teng Hsu

发明人： Wei-Wei Zhuang ,  David R. Evans ,  Tingkai Li ,  Sheng Teng Hsu

IPC分类号： B05D5/12

CPC分类号： H01L22/20 ,  H01L21/31691 ,  H01L22/14

摘要： A method of monitoring synthesis of PCMO precursor solutions includes preparing a PCMO precursor solution and withdrawing samples of the precursor solution at intervals during a reaction phase of the PCMO precursor solution synthesis. The samples of the PCMO precursor solution are analyzed by UV spectroscopy to determine UV transmissivity of the samples of the PCMO precursor solution and the samples used to form PCMO thin films. Electrical characteristics of the PCMO thin films formed from the samples are determined to identify PCMO thin films having optimal electrical characteristics. The UV spectral characteristics of the PCMO precursor solutions are correlated with the PCMO thin films having optimal electrical characteristics. The UV spectral characteristics are used to monitor synthesis of future batches of the PCMO precursor solutions, which will result in PCMO thin films having optimal electrical characteristics.

摘要翻译： 监测PCMO前体溶液合成的方法包括制备PCMO前体溶液，并在PCMO前体溶液合成反应期间间隔取出前体溶液样品。 通过紫外光谱分析PCMO前体溶液的样品，以确定PCMO前体溶液和用于形成PCMO薄膜的样品的UV透射率。 确定由样品形成的PCMO薄膜的电特性以鉴定具有最佳电特性的PCMO薄膜。 PCMO前体溶液的UV光谱特性与具有最佳电学特性的PCMO薄膜相关。 UV光谱特性用于监测未来批次的PCMO前体溶液的合成，这将导致具有最佳电特性的PCMO薄膜。

公开(公告)号：US20080171424A1

公开(公告)日：2008-07-17

申请号：US11653802

申请日：2007-01-16

申请人： Tingkai Li ,  Jer-Shen Maa ,  Douglas J. Tweet ,  Wei-Wei Zhuang ,  Sheng Teng Hsu

发明人： Tingkai Li ,  Jer-Shen Maa ,  Douglas J. Tweet ,  Wei-Wei Zhuang ,  Sheng Teng Hsu

IPC分类号： H01L21/205

CPC分类号： H01L21/02513 ,  H01L21/02381 ,  H01L21/0245 ,  H01L21/02529 ,  H01L21/0254 ,  H01L21/02639 ,  H01L21/02647 ,  H01L21/0265

摘要： A method of fabricating a continuous layer of a defect sensitive material on a silicon substrate includes preparing a silicon substrate; forming a nanostructure array directly on the silicon substrate; depositing a selective growth enhancing layer on the substrate; smoothing the selective growth enhancing layer; and growing a continuous layer of the defect sensitive material on the nanostructure array.

摘要翻译： 在硅衬底上制造缺陷敏感材料的连续层的方法包括制备硅衬底; 在硅衬底上直接形成纳米结构阵列; 在衬底上沉积选择性生长增强层; 平滑选择性生长增强层; 并在纳米结构阵列上生长不连续的缺陷敏感材料层。

公开(公告)号：US20080164569A1

公开(公告)日：2008-07-10

申请号：US11582275

申请日：2006-10-16

申请人： Tingkai Li ,  Wei Gao ,  Yoshi Ono ,  Sheng Teng Hsu

发明人： Tingkai Li ,  Wei Gao ,  Yoshi Ono ,  Sheng Teng Hsu

IPC分类号： H01L29/00

CPC分类号： H01L27/15 ,  H01L33/0004 ,  H01L33/343

摘要： A method of fabricating an electroluminescent device includes, on a prepared substrate, depositing a rare earth-doped silicon-rich layer on gate oxide layer as a light emitting layer; and annealing and oxidizing the structure to repair any damage caused to the rare earth-doped silicon-rich layer; and incorporating the electroluminescent device into a CMOS IC. An electroluminescent device fabricated according to the method of the invention includes a substrate, a rare earth-doped silicon-rich layer formed on the gate oxide layer for emitting a light of a pre-determined wavelength; a top electrode formed on the rare earth-doped silicon-rich layer; and associated CMOS IC structures fabricated thereabout.

摘要翻译： 一种制造电致发光器件的方法包括：在制备的衬底上，在作为发光层的栅极氧化物层上沉积稀土掺杂的富硅层; 并对该结构进行退火和氧化以修复对稀土掺杂的富硅层造成的任何损伤; 并将电致发光器件并入CMOS IC。 根据本发明的方法制造的电致发光器件包括：衬底，形成在栅极氧化物层上的用于发射预定波长的光的稀土掺杂富硅层; 在稀土掺杂的富硅层上形成的顶部电极; 并在其附近制造相关的CMOS IC结构。

公开(公告)号：US07358160B2

公开(公告)日：2008-04-15

申请号：US11481437

申请日：2006-07-06

申请人： Tingkai Li ,  Sheng Teng Hsu

发明人： Tingkai Li ,  Sheng Teng Hsu

IPC分类号： H01L21/36

CPC分类号： H01L21/02381 ,  H01L21/0245 ,  H01L21/02488 ,  H01L21/02505 ,  H01L21/02529 ,  H01L21/02538 ,  H01L21/7624

摘要： A compound semiconductor-on-silicon (Si) wafer with a Si nanowire buffer layer is provided, along with a corresponding fabrication method. The method forms a Si substrate. An insulator layer is formed overlying the Si substrate, with Si nanowires having exposed tips. Compound semiconductor is selectively deposited on the Si nanowire tips. A lateral epitaxial overgrowth (LEO) process grows compound semiconductor from the compound semiconductor-coated Si nanowire tips, to form a compound semiconductor layer overlying the insulator. Typically, the insulator layer overlying the Si substrate is a thermally soft insulator (TSI), silicon dioxide, or SiXNY, where X≦3 and Y≦4. The compound semiconductor can be GaN, GaAs, GaAlN, or SiC. In one aspect, the Si nanowire tips are carbonized, and SiC is selectively deposited overlying the carbonized Si nanowire tips, prior to the selective deposition of compound semiconductor on the Si nanowire tips.

摘要翻译： 提供了具有Si纳米线缓冲层的化合物半导体硅（Si）晶片以及相应的制造方法。 该方法形成Si衬底。 在Si衬底上形成绝缘体层，Si纳米线具有暴露的尖端。 化合物半导体选择性沉积在Si纳米线尖端上。 横向外延生长（LEO）工艺从化合物半导体涂覆的Si纳米线尖端生长化合物半导体，以形成覆盖绝缘体的化合物半导体层。 通常，覆盖Si衬底的绝缘体层是热软绝缘体（TSI），二氧化硅或Si X N Y ，其中 X <= 3 AND Y <= 4。 化合物半导体可以是GaN，GaAs，GaAlN或SiC。 在一个方面，将Si纳米线尖端碳化，并且在Si纳米线尖端上选择性沉积化合物半导体之前，选择性地将SiC沉积在碳化Si纳米线尖端上。

公开(公告)号：US07297602B2

公开(公告)日：2007-11-20

申请号：US10659547

申请日：2003-09-09

申请人： Sheng Teng Hsu ,  Tingkai Li

发明人： Sheng Teng Hsu ,  Tingkai Li

IPC分类号： H01L21/331 ,  H01L21/335

CPC分类号： G11C11/22 ,  H01L21/28273 ,  H01L21/28291 ,  H01L29/66545 ,  H01L29/66553 ,  H01L29/66825 ,  H01L29/6684 ,  H01L29/78391

摘要： The present invention discloses a ferroelectric transistor having a conductive oxide in the place of the gate dielectric. The conductive oxide gate ferroelectric transistor can have a three-layer metal/ferroelectric/metal or a two-layer metal/ferroelectric on top of the conductive oxide gate. By replacing the gate dielectric with a conductive oxide, the bottom gate of the ferroelectric layer is conductive through the conductive oxide to the silicon substrate, thus minimizing the floating gate effect. The memory retention degradation related to the leakage current associated with the charges trapped within the floating gate is eliminated. The fabrication of the ferroelectric transistor by a gate etching process or a replacement gate process is also disclosed.

摘要翻译： 本发明公开了一种具有导电氧化物代替栅电介质的铁电晶体管。 导电氧化物栅极铁电晶体管可以在导电氧化物栅极的顶部上具有三层金属/铁电/金属或两层金属/铁电体。 通过用导电氧化物代替栅极电介质，铁电层的底栅通过导电氧化物导电到硅衬底，从而最小化浮栅效应。 消除了与在浮动栅极内捕获的电荷相关的泄漏电流相关的存储器保持性降低。 还公开了通过栅极蚀刻工艺或替代栅极工艺制造铁电晶体管。

公开(公告)号：US07271081B2

公开(公告)日：2007-09-18

申请号：US11216398

申请日：2005-08-31

申请人： Tingkai Li ,  Sheng Teng Hsu ,  Wei-Wei Zhuang ,  David R. Evans

发明人： Tingkai Li ,  Sheng Teng Hsu ,  Wei-Wei Zhuang ,  David R. Evans

IPC分类号： H01L27/082 ,  H01L27/102 ,  H01L29/70 ,  H01L31/11

CPC分类号： H01L27/101 ,  G11C13/0007 ,  G11C2213/31 ,  H01L27/2409 ,  H01L27/2463 ,  H01L29/66143 ,  H01L29/872 ,  H01L45/04 ,  H01L45/1233 ,  H01L45/147

摘要： A method is provided for forming a metal/semiconductor/metal (MSM) current limiter and resistance memory cell with an MSM current limiter. The method includes the steps of: providing a substrate; forming an MSM bottom electrode overlying the substrate; forming a ZnOx semiconductor layer overlying the MSM bottom electrode, where x is in the range between about 1 and about 2, inclusive; and, forming an MSM top electrode overlying the semiconductor layer, The ZnOx semiconductor can be formed through a number of different processes such as spin-coating, direct current (DC) sputtering, radio frequency (RF) sputtering, metalorganic chemical vapor deposition (MOCVD), or atomic layer deposition (ALD).

摘要翻译： 提供了一种用于形成具有MSM限流器的金属/半导体/金属（MSM）限流器和电阻存储器单元的方法。 该方法包括以下步骤：提供衬底; 形成覆盖所述衬底的MSM底部电极; 形成覆盖MSM底部电极的ZnO x半导体层，其中x在约1和约2之间的范围内; 并形成覆盖在半导体层上的MSM顶部电极。ZnOx半导体可以通过许多不同的工艺形成，例如旋涂，直流（DC）溅射，射频（RF）溅射，金属有机化学气相沉积（MOCVD） ）或原子层沉积（ALD）。

公开(公告)号：US07256429B2

公开(公告)日：2007-08-14

申请号：US11314222

申请日：2005-12-21

申请人： Sheng Teng Hsu ,  Tingkai Li ,  Fengyan Zhang ,  Wei Pan ,  Wei-Wei Zhuang ,  David R. Evans ,  Masayuki Tajiri

发明人： Sheng Teng Hsu ,  Tingkai Li ,  Fengyan Zhang ,  Wei Pan ,  Wei-Wei Zhuang ,  David R. Evans ,  Masayuki Tajiri

IPC分类号： H01L21/00

CPC分类号： H01L27/101 ,  G11C13/0007 ,  G11C13/0069 ,  G11C2013/0073 ,  G11C2213/31 ,  G11C2213/51 ,  G11C2213/56 ,  G11C2213/79 ,  H01L27/2436 ,  H01L45/04 ,  H01L45/12 ,  H01L45/1233 ,  H01L45/147

摘要： A method is provided for forming a buffered-layer memory cell. The method comprises: forming a bottom electrode; forming a colossal magnetoresistance (CMR) memory film overlying the bottom electrode; forming a memory-stable semiconductor buffer layer, typically a metal oxide, overlying the memory film; and, forming a top electrode overlying the semiconductor buffer layer. In some aspects of the method the semiconductor buffer layer is formed from YBa2Cu3O7−X (YBCO), indium oxide (In2O3), or ruthenium oxide (RuO2), having a thickness in the range of 10 to 200 nanometers (nm). The top and bottom electrodes may be TiN/Ti, Pt/TiN/Ti, In/TiN/Ti, PtRhOx compounds, or PtIrOx compounds. The CMR memory film may be a Pr1−XCaXMnO3 (PCMO) memory film, where x is in the region between 0.1 and 0.6, with a thickness in the range of 10 to 200 nm.

摘要翻译： 提供了一种用于形成缓冲层存储单元的方法。 该方法包括：形成底部电极; 形成覆盖底部电极的巨大磁阻（CMR）记忆膜; 形成存储器稳定的半导体缓冲层，通常为覆盖存储膜的金属氧化物; 并且形成覆盖半导体缓冲层的顶部电极。 在该方法的一些方面，半导体缓冲层由YBa 2 N 3 O 7-X（YBCO），氧化铟（In 2或2 O 3）或氧化钌（RuO 2 N 2），其厚度在10-200纳米（nm）的范围内。 顶部和底部电极可以是TiN / Ti，Pt / TiN / Ti，In / TiN / Ti，PtRhOx化合物或PtIrOx化合物。 CMR存储器膜可以是Pr 1-X C x MnO 3（PCMO）存储膜，其中x在0.1之间的区域 和0.6，厚度在10至200nm的范围内。

公开(公告)号：US07226504B2

公开(公告)日：2007-06-05

申请号：US10062336

申请日：2002-01-31

申请人： Jer-Shen Maa ,  Douglas James Tweet ,  Tingkai Li ,  Jong-Jan Lee ,  Sheng Teng Hsu

发明人： Jer-Shen Maa ,  Douglas James Tweet ,  Tingkai Li ,  Jong-Jan Lee ,  Sheng Teng Hsu

IPC分类号： C30B33/02

CPC分类号： H01L21/3247 ,  H01L21/02381 ,  H01L21/0245 ,  H01L21/02532 ,  H01L21/02694 ,  H01L21/324

摘要： A method of forming a SiGe layer having a relatively high germanium content and a relatively low threading dislocation density includes preparing a silicon substrate; depositing a layer of SiGe to a thickness of between about 100 nm to 500 nm, wherein the germanium content of the SiGe layer is greater than 20%, by atomic ratio; implanting H+ ions into the SiGe layer at a dose of between about 1·1016 cm−2 to 5·1016 cm−2, at an energy of between about 20 keV to 45 keV; patterning the SiGe layer with photoresist; plasma etching the structure to form trenches about regions; removing the photoresist; and thermal annealing the substrate and SiGe layer, to relax the SiGe layer, in an inert atmosphere at a temperature of between about 650° C. to 950° C. for between about 30 seconds and 30 minutes.

摘要翻译： 形成具有较高锗含量和较低穿透位错密度的SiGe层的方法包括制备硅衬底; 将SiGe层沉积至约100nm至500nm的厚度，其中SiGe层的锗含量按原子比大于20％; 将H +离子以约1.10×16cm -2至0.0010±0.2cm的剂量注入SiGe层中， SUP>，在约20keV至45keV之间的能量; 用光致抗蚀剂图案化SiGe层; 等离子体蚀刻结构以形成关于区域的沟槽; 去除光致抗蚀剂; 以及对基板和SiGe层进行热退火，以在惰性气氛中在约650℃至950℃的温度下放置SiGe层约30秒至30分钟。