摘要:
The invention provides an adhesive-carrying porous film for use as a battery separator, comprising: a substrate porous film, wherein when a 1 mm diameter penetrating thermomechanical analyzer probe is placed on the film under a 70 g load to measure a thickness while heating the film from room temperature at a rate of 200° C./minute to a temperature where the film thickness decreases by half when the probe was initially placed is 200° C. or more, a partially crosslinked adhesive carried on the film, the adhesive is prepared by reacting a reactive polymer having a functional group capable of reacting with an isocyanate group with a polyfunctional isocyanate so the reactive polymer is partially crosslinked, a porous film is temporarily bonded to an electrode to provide an electrode/separator laminate, the porous film in a battery functions as a separator which does not melt or break with small heat shrinkage under high temperatures.
摘要:
A partially crosslinked adhesive-supported porous film for battery separator, which in producing a battery, can effectively produce a battery as an electrode/separator laminate in which an electrode and a separator are temporarily bonded to each other without causing mutual slip movement between the electrode and the separator and which after producing a battery, functions itself as a separator having a small heat shrinkage factor even at high temperatures, and a process of producing a battery using such a partially crosslinked adhesive-supported porous film. The partially crosslinked adhesive-supported porous film for battery separator, includes a porous film substrate having supported thereon a partially crosslinked adhesive that is partially crosslinked by preparing a reactive polymer having a functional group in the molecule and capable of being crosslinked upon reaction with a polyfunctional compound having reactivity with the functional group and then reacting the reactive polymer with a polyfunctional compound.
摘要:
The invention provides an adhesive-carrying porous film for use as a battery separator, which comprises: a substrate porous film such that when a probe of a probe penetrating thermomechanical analyzer, said probe having a diameter of 1 mm, is placed on the porous film under a load of 70 g to measure a thickness thereof while heating the porous film from room temperature at a rate of 2° C./minute, a temperature at which the thickness of the porous film decreases to a half of the thickness of the porous film when the probe was initially placed thereon is 200° C. or more; and a partially crosslinked adhesive carried on the substrate porous film, the partially crosslinked adhesive being prepared by reacting a reactive polymer having a functional group capable of reacting with an isocyanate group therein with a polyfunctional isocyanate so that the reactive polymer is partially crosslinked. Such a porous film (a separator) is temporarily bonded to an electrode to provide an electrode/separator laminate. In manufacturing a battery, the use of the laminate makes it possible to manufacture a battery efficiently with no mutual slip movement between the electrode and the separator, and is addition, the porous film (the separator) itself, after manufacturing a battery, functions as a separator which does not melt or break, and has a small heat shrinkage under high temperatures
摘要:
A reactive polymer-supported porous film for separator, that has sufficient adhesiveness between electrodes and separator and can suitably be used to produce a battery having low internal resistance and high rate performance, a method for producing the porous film, a method for producing a battery using the porous film, and an electrode/porous film assembly are disclosed. The reactive polymer-supported porous film for battery separator includes a porous film substrate having supported thereon a reactive polymer obtained by reacting a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule, with an acid anhydride, thereby partially crosslinking the polymer.
摘要:
An adhesive composition-supporting separator for a battery includes a porous substrate supporting thereon a thermally cross-linkable adhesive composition comprising a multi-functional isocyanate and a reactive polymer having a functional group capable of reacting with an isocyanato group of the multi-functional isocyanate; an electrode/separator laminate is obtained by contact pressing the adhesive composition-supporting separator for a battery against electrodes; and an electrode/separator bonded material having a cross-linked adhesive composition is obtained by heating the electrode/separator laminate to thereby react the multifunctional isocyanate with the reactive polymer for causing cross-linking.
摘要:
A reactive polymer-supported porous film for separator, that has sufficient adhesiveness between electrodes and separator and can suitably be used to produce a battery having low internal resistance and high rate performance, a method for producing the porous film, a method for producing a battery using the porous film, and an electrode/porous film assembly are disclosed. The reactive polymer-supported porous film for battery separator includes a porous film substrate having supported thereon a reactive polymer obtained by reacting a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule, with an acid anhydride, thereby partially crosslinking the polymer.
摘要:
A reactive polymer-supported porous film for separator, that has sufficient adhesiveness between electrodes and separator and can suitably be used to produce a battery having low internal resistance and high rate performance, a method for producing the porous film, a method for producing a battery using the porous film, and an electrode/porous film assembly are disclosed. The reactive polymer-supported porous film for battery separator includes a porous film substrate having supported thereon a reactive polymer obtained by reacting a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule, with an acid anhydride, thereby partially crosslinking the polymer.
摘要:
An aromatic polycarbodiimide comprising a structure represented by the following formula (1) has excellent low moisture resistance, heat resistance and a low dielectric constant: wherein Q is one selected from the group consisting of —CH2—, m is 0 or 1, A is a divalent organic group having 4 or less carbon atoms, Ph is a phenyl group, X's are a hydrogen atom when Q is and the same or different halogen atoms when Q is —CH2—, and n is an integer of 2 to 300.
摘要:
A process for producing an aqueous dispersion-type acrylic polymer is disclosed, which comprises introducing a monomer comprising an alkyl (meth)acrylate as the main component into a polymerization vessel at a time at a monomer concentration of 40% by weight or higher, adding a water-soluble radical polymerization initiator thereto in an amount of from 0.001 to 0.05 parts by weight per 100 parts by weight of the monomer, and emulsion-polymerizing the monomer substantially at 20.degree. to 60.degree. C. The aqueous dispersion-type acrylic polymer thus obtained satisfies the equation log M>3log S-2, wherein S is a tetrahydrofuran (THF)-soluble content (wt %) of the polymer and M is a weight-average molecular weight (.times.10,000) of a soluble part of the polymer. This polymer is preferably used for a pressure-sensitive adhesive in pressure-sensitive adhesive-covered products.
摘要:
A method for bonding which comprises: interposing between the articles to be bonded at least one of which has an aqueous moisture content in a normal condition of at least about 1% by weight based on the weight of the article, a moisture curable adhesive material and then heating the assembly under pressure to supply water vapor from the moisture-containing article to cure the adhesive material, wherein said adhesive material comprises a sheet, film or tape of a thermofusible adhesive resin and/or rubber containing about 0.1 to 20% by weight based on the weight of the resin and/or rubber of a carboxyl group and not more than about 0.5% by weight free water and uniformly dispersed therein, a powder of an oxide of a metal of Group IIa of Mendeleev's Periodic Table having an average particle diameter of about 0.1 to 1,000.mu..