公开(公告)号：US4863503A

公开(公告)日：1989-09-05

申请号：US39449

申请日：1987-04-17

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul de Fraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul de Fraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

IPC分类号： C07C241/00 ,  A01N37/36 ,  A01N37/42 ,  A01N37/44 ,  A01N37/48 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07C67/00 ,  C07C69/734 ,  C07C201/00 ,  C07C205/56 ,  C07C229/64 ,  C07C233/58 ,  C07C239/00 ,  C07C245/06 ,  C07C251/02 ,  C07C251/44 ,  C07C253/00 ,  C07C255/57 ,  C07C255/59 ,  C07C309/63 ,  C07C313/00 ,  C07C323/54 ,  C07D207/32 ,  C07D207/337 ,  C07D207/34 ,  C07D209/18 ,  C07D307/42 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/32 ,  C07D333/34 ,  C07D333/38 ,  C07D333/60 ,  C07F7/18

CPC分类号： C07D207/337 ,  A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60

摘要： Compounds of formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, wherein R.sup.1 and R.sup.2, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, --NR.sup.3 --, or --CR.sup.4 R.sup.5 --; X, Y and Z.sup.1, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted arylalkoxy, optionally substituted aryloxy, optionally substituted heteraryloxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, optionally substituted arylazo, nitro, cyano, --CO.sub.2 R.sup.6, --CONR.sup.7 R.sup.8, --COR.sup.9 --CR.dbd.NR.sup.10, --CR.dbd.NOR.sup.10 or --N.dbd.CR.sup.11 R.sup.12 groups; or the groups X and Y, when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; and R, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8 R.sup.9, R.sup.10, R.sup.11 and R.sup.12, which are the same or different, are hydrogen atoms (provided that R.sup.4 and R.sup.5 are not hydrogen) or optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heterarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted heteroaryl groups; and metal complexes thereof.The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.

公开(公告)号：US5053073A

公开(公告)日：1991-10-01

申请号：US378076

申请日：1989-07-11

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

IPC分类号： C07C241/00 ,  A01N37/36 ,  A01N37/42 ,  A01N37/44 ,  A01N37/48 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07C67/00 ,  C07C69/734 ,  C07C201/00 ,  C07C205/56 ,  C07C229/64 ,  C07C233/58 ,  C07C239/00 ,  C07C245/06 ,  C07C251/02 ,  C07C251/44 ,  C07C253/00 ,  C07C255/57 ,  C07C255/59 ,  C07C309/63 ,  C07C313/00 ,  C07C323/54 ,  C07D207/32 ,  C07D207/337 ,  C07D207/34 ,  C07D209/18 ,  C07D307/42 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/32 ,  C07D333/34 ,  C07D333/38 ,  C07D333/60 ,  C07F7/18

CPC分类号： C07D207/337 ,  A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60

摘要： Compounds of formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, wherein R.sup.1 and R.sup.2, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, --NR.sup.3 --, or --CR.sup.4 R.sup.5 --; X, Y and Z.sup.1, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted arylalkoxy, optionally substituted aryloxy, optionally substituted heteraryloxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, optionally substituted arylazo, nitro, cyano, --CO.sub.2 R.sup.6, --CONR.sup.7 R.sup.8, --COR.sup.9 --CR.dbd.NR.sup.10, --CR.dbd.NOR.sup.10 or --N.dbd.CR.sup.11 R.sup.12 groups; or the groups X and Y, when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; and R, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, and R.sup.12, which are the same or different, are hydrogen atoms (provided that R.sup.4 and R.sup.5 are not hydrogen) or optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heterarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted heteroaryl groups; and metal complexes thereof.The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.

公开(公告)号：US5468857A

公开(公告)日：1995-11-21

申请号：US191163

申请日：1994-02-03

申请人： Alan J. Buckley ,  Michael G. Huchings ,  Ian Ferguson ,  Kevin Beautement ,  John M. Clough ,  Patrick J. Crowley ,  Christopher R. A. Godfrey ,  Paul J. deFraine ,  Vivienne M. Anthony ,  Stephen P. Heaney

发明人： Alan J. Buckley ,  Michael G. Huchings ,  Ian Ferguson ,  Kevin Beautement ,  John M. Clough ,  Patrick J. Crowley ,  Christopher R. A. Godfrey ,  Paul J. deFraine ,  Vivienne M. Anthony ,  Stephen P. Heaney

IPC分类号： C07C69/734 ,  A01N31/14 ,  A01N37/06 ,  A01N37/38 ,  A01N37/40 ,  A01N41/04 ,  A01N41/06 ,  A01N41/10 ,  A01N43/00 ,  A01N43/10 ,  A01N43/20 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/66 ,  A01N43/74 ,  A01N43/90 ,  A01N47/20 ,  A01N57/24 ,  C07C20060101 ,  C07C45/59 ,  C07C67/00 ,  C07C67/31 ,  C07C69/54 ,  C07C201/00 ,  C07C205/35 ,  C07C205/37 ,  C07C205/38 ,  C07C205/52 ,  C07C217/92 ,  C07C233/25 ,  C07C233/75 ,  C07C235/56 ,  C07C239/00 ,  C07C241/00 ,  C07C245/08 ,  C07C251/24 ,  C07C251/48 ,  C07C255/54 ,  C07C271/28 ,  C07C275/32 ,  C07C311/21 ,  C07C311/29 ,  C07C317/22 ,  C07C323/16 ,  C07C323/20 ,  C07C323/22 ,  C07C323/56 ,  C07C323/62 ,  C07C323/65 ,  C07C323/66 ,  C07C323/67 ,  C07C327/16 ,  C07C327/26 ,  C07C327/48 ,  C07C333/04 ,  C07C333/08 ,  C07D207/34 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/68 ,  C07D213/74 ,  C07D213/85 ,  C07D213/89 ,  C07D215/22 ,  C07D215/227 ,  C07D215/36 ,  C07D237/14 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D241/18 ,  C07D241/44 ,  C07D249/04 ,  C07D249/08 ,  C07D251/22 ,  C07D251/26 ,  C07D253/06 ,  C07D263/58 ,  C07D277/24 ,  C07D277/68 ,  C07D333/56 ,  C07D495/04 ,  C07D521/00 ,  C07F9/54 ,  C07D239/02

CPC分类号： C07D213/64 ,  A01N37/38 ,  A01N37/40 ,  A01N41/04 ,  A01N41/06 ,  A01N41/10 ,  A01N43/10 ,  A01N43/20 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/66 ,  A01N43/74 ,  A01N43/90 ,  A01N47/20 ,  A01N57/24 ,  C07C205/35 ,  C07C205/37 ,  C07C205/38 ,  C07C205/52 ,  C07C217/92 ,  C07C233/25 ,  C07C233/75 ,  C07C235/56 ,  C07C245/08 ,  C07C251/24 ,  C07C251/48 ,  C07C255/54 ,  C07C271/28 ,  C07C311/29 ,  C07C317/22 ,  C07C323/20 ,  C07C327/16 ,  C07C45/59 ,  C07D207/34 ,  C07D213/643 ,  C07D213/65 ,  C07D213/68 ,  C07D213/74 ,  C07D213/85 ,  C07D213/89 ,  C07D215/227 ,  C07D215/36 ,  C07D231/12 ,  C07D233/56 ,  C07D237/14 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D241/18 ,  C07D241/44 ,  C07D249/08 ,  C07D251/26 ,  C07D263/58 ,  C07D277/24 ,  C07D277/68 ,  C07D333/56 ,  C07D495/04 ,  C07F9/5456

摘要： Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is a specified linking group; and A, B and E, which may be the same or different, are H, hydroxy, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 haloalkyl, C.sub.1-4 haloalkoxy, C.sub.1-4 alkylcarbonyl, C.sub.1-4 alkoxycarbonyl, phenoxy, nitro or cyano; except that when Z is unsubstituted phenyl and X and K are oxygen, A, B and E are not all hydrogen.

摘要翻译： 式（I）的杀真菌化合物：其中K为氧或硫; Z是任选取代的芳基或任选取代的杂芳基; X是指定的连接组; 和A，B和E可以相同或不同，是H，羟基，卤素，C 1-4烷基，C 1-4烷氧基，C 1-4卤代烷基，C 1-4卤代烷氧基，C 1-4烷基羰基，C 1-4烷氧基羰基 ，苯氧基，硝基或氰基; 除了当Z是未取代的苯基且X和K是氧时，A，B和E不都是氢。

公开(公告)号：US5334748A

公开(公告)日：1994-08-02

申请号：US242760

申请日：1988-09-09

申请人： Alan J. Buckley ,  Michael G. Huchings ,  Ian Ferguson ,  Kevin Beautement ,  John M. Clough ,  Patrick J. Crowley ,  Christopher R. A. Godfrey ,  Paul J. deFraine ,  Vivienne M. Anthony ,  Stephen P. Heaney

发明人： Alan J. Buckley ,  Michael G. Huchings ,  Ian Ferguson ,  Kevin Beautement ,  John M. Clough ,  Patrick J. Crowley ,  Christopher R. A. Godfrey ,  Paul J. deFraine ,  Vivienne M. Anthony ,  Stephen P. Heaney

IPC分类号： C07C69/734 ,  A01N31/14 ,  A01N37/06 ,  A01N37/38 ,  A01N37/40 ,  A01N41/04 ,  A01N41/06 ,  A01N41/10 ,  A01N43/00 ,  A01N43/10 ,  A01N43/20 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/66 ,  A01N43/74 ,  A01N43/90 ,  A01N47/20 ,  A01N57/24 ,  C07C20060101 ,  C07C45/59 ,  C07C67/00 ,  C07C67/31 ,  C07C69/54 ,  C07C201/00 ,  C07C205/35 ,  C07C205/37 ,  C07C205/38 ,  C07C205/52 ,  C07C217/92 ,  C07C233/25 ,  C07C233/75 ,  C07C235/56 ,  C07C239/00 ,  C07C241/00 ,  C07C245/08 ,  C07C251/24 ,  C07C251/48 ,  C07C255/54 ,  C07C271/28 ,  C07C275/32 ,  C07C311/21 ,  C07C311/29 ,  C07C317/22 ,  C07C323/16 ,  C07C323/20 ,  C07C323/22 ,  C07C323/56 ,  C07C323/62 ,  C07C323/65 ,  C07C323/66 ,  C07C323/67 ,  C07C327/16 ,  C07C327/26 ,  C07C327/48 ,  C07C333/04 ,  C07C333/08 ,  C07D207/34 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/68 ,  C07D213/74 ,  C07D213/85 ,  C07D213/89 ,  C07D215/22 ,  C07D215/227 ,  C07D215/36 ,  C07D237/14 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D241/18 ,  C07D241/44 ,  C07D249/04 ,  C07D249/08 ,  C07D251/22 ,  C07D251/26 ,  C07D253/06 ,  C07D263/58 ,  C07D277/24 ,  C07D277/68 ,  C07D333/56 ,  C07D495/04 ,  C07D521/00 ,  C07F9/54 ,  C07C69/76

CPC分类号： C07D213/64 ,  A01N37/38 ,  A01N37/40 ,  A01N41/04 ,  A01N41/06 ,  A01N41/10 ,  A01N43/10 ,  A01N43/20 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/66 ,  A01N43/74 ,  A01N43/90 ,  A01N47/20 ,  A01N57/24 ,  C07C205/35 ,  C07C205/37 ,  C07C205/38 ,  C07C205/52 ,  C07C217/92 ,  C07C233/25 ,  C07C233/75 ,  C07C235/56 ,  C07C245/08 ,  C07C251/24 ,  C07C251/48 ,  C07C255/54 ,  C07C271/28 ,  C07C311/29 ,  C07C317/22 ,  C07C323/20 ,  C07C327/16 ,  C07C45/59 ,  C07D207/34 ,  C07D213/643 ,  C07D213/65 ,  C07D213/68 ,  C07D213/74 ,  C07D213/85 ,  C07D213/89 ,  C07D215/227 ,  C07D215/36 ,  C07D231/12 ,  C07D233/56 ,  C07D237/14 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D241/18 ,  C07D241/44 ,  C07D249/08 ,  C07D251/26 ,  C07D263/58 ,  C07D277/24 ,  C07D277/68 ,  C07D333/56 ,  C07D495/04 ,  C07F9/5456

摘要： Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is O, S(O).sub.n, NR.sup.4, CR.sup.1 R.sup.2 CHR.sup.5, CO, CR.sup.1 (OR.sup.2), C.dbd.CR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2, CR.sup.1 .dbd.CR.sup.2, CHR.sup.1 CR.sup.2 .dbd.CH, C.tbd.C, OCHR.sup.1, CHR.sup.1 O, OCHR.sup.1 O, S(O).sub.n CHR.sup.1 S(O).sub.n CHR.sup.1 O, CHR.sup.1 S(O).sub.n, CHR.sup.1 OSO.sub.2, NR.sup.4 CHR.sup.1, CHR.sup.1 NR.sup.4, CO.sub.2, O.sub.2 C, SO.sub.2 O, OSO.sub.2, CO.CO, COCHR.sup.1, COCHR.sup.1 O, CHR.sup.1 CO, CHOH.CHR.sup.1, CHR.sup.1.CHOH ##STR2## CONR.sup.4, OCONR.sup.4, NR.sup.4 CO, CSNR.sup.4, OCS.NR.sup.4, SCO.NR.sup.4, NR.sup.4 CO.sub.2, NR.sup.4 CS, NR.sup.4 CSO, NR.sup.4 COS, NR.sup.4 CONR.sup.4, S(O).sub.n NR.sup.4, NR.sup.4 S(O).sub.n, CS.sub.2, S.sub.2 C, CO.S, SCO, N.dbd.N, N.dbd.CR.sup.1, CR.sup.1 .dbd.N, CHR.sup.1 CHR.sup.2 CH(OH), CHR.sup.1 OCO, CHR.sup.1 SCO, CHR.sup.1 NR.sup.4 CO, CHR.sup.1 NR.sup.4 COR.sup.4, CHR.sup.1 CHR.sup.2 CO, O.N.dbd.CR.sup.1, CHR.sup.1 O.N.dbd.CR.sup.2, CO.OCR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2 CHR.sup.3, OCHR.sup.1 CHR.sup.2, (CH.sub.2).sub.m O, CHR.sup.1 OCHR.sup.2, CHR.sup.1 CHR.sup.2 O, OCHR.sup.1 CHR.sup.2 O, S(O).sub.n CHR.sup.1 CHR.sup.2, CHR.sup.1 S(O).sub.n CHR.sup.2. CHR.sup.1 CHR.sup.2 S(O).sub.n, CR.sup.1 .dbd.NNR.sup.4, NR.sup.4 N.dbd.CR.sup.1, CHR.sup.1 CONR.sup.2, CHR.sup.1 OCO.NR.sup.2, CH.dbd.CHCH.sub.2 O, COCHR.sup.1 CHR.sup.2 O or (R.sup.5).sub.2 P.sup. + CHR.sup.2 Q.sup.- ; A, B and E, which may be the same or different, are H, hydroxy, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 haloalkyl, C.sub.1-4 haloalkoxy, C.sub.1-4 alkylcarbonyl, C.sub.1-4 alkoxycarbonyl, phenoxy, nitro or cyano; R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, are H, C.sub.1-4 alkyl or phenyl; R.sup.4 is H, C.sub.1-4 alkyl or COR.sup.1 ; R.sup.5 is optionally substituted phenyl;

摘要翻译： 式（I）的杀真菌化合物：其中K为氧或硫; Z是任选取代的芳基或任选取代的杂芳基; X是O，S（O）n，NR 4，CR 1 R 2 CHR 5，CO，CR 1（OR 2），C = CR 1 R 2，CHR 1 CH 2，CR 1 = CR 2，CHR 1 CR 2 = CH，C 3 D C，OCHR 1，CHR 1 O，OCHR 1 O， nCHR1 S（O）nCHR1O，CHR1S（O）n，CHR1OSO2，NR4CHR1，CHR1NR4，CO2，O2C，SO2O，OSO2，CO.CO，COCHR1，COCHR1O，CHR1CO，CHOH.CHR1，CHR1.CHOH CONR4，OCONR4 ，NR4CO，CSNR4，OCS.NR4，SCO.NR4，NR4CO2，NR4CS，NR4CSO，NR4COS，NR4CONR4，S（O）nNR4，NR4S（O）n，CS2，S2C，CO.S，SCO，N = N，N = CR1，CR1 = N，CHR1CHR2CH（OH），CHR1OCO，CHR1SCO，CHR1NR4CO，CHR1NR4COR4，CHR1CHR2CO，ON = CR1，CHR1O.N = CR2，CO.OCR1R2，CHR1CHR2CHR3，OCHR1CHR2，（CH2）mO，CHR1OCHR2，CHR1CHR2O，OCHR1CHR2O ，S（O）n CHR1CHR2，CHR1S（O）nCHR2。 CHR1CHR2S（O）n，CR1 = NNR4，NR4N = CR1，CHR1CONR2，CHR1OCO.NR2，CH = CHCH2O，COCHR1CHR2O或（R5）2P + CHR2Q-; A，B和E可以相同或不同，是H，羟基，卤素，C 1-4烷基，C 1-4烷氧基，C 1-4卤代烷基，C 1-4卤代烷氧基，C 1-4烷基羰基，C 1-4烷氧基羰基 ，苯氧基，硝基或氰基; R 1，R 2和R 3可以相同或不同，为H，C 1-4烷基或苯基; R4是H，C1-4烷基或COR1; R5是任选取代的苯基;

公开(公告)号：US5258360A

公开(公告)日：1993-11-02

申请号：US915594

申请日：1992-07-21

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

IPC分类号： A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D207/32 ,  C07D207/337 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60 ,  A01N43/10 ,  C07D333/56

CPC分类号： C07D207/337 ,  A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60

摘要： Compounds of formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, wherein R.sup.1 and R.sup.2, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, --NR.sup.3 --, or --CR.sup.4 R.sup.5 --; X, Y and Z.sup.1, which are the same or different, are, for example, hydrogen, halogen, hydroxy, optionally substituted alkyl, cycloalkyl or aryl among other possible substituents or X and Y when they are in adjacent positions on the ring optionally form a fused ring; and R, R.sup.3 -R.sup.12 are, for example, hydrogen or optionally substituted alkyl among other possible substituents provided R.sup.4 and R.sup.5 are not both hydrogen. The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.

摘要翻译： 式（I）化合物：其中R 1和R 2分别为烷基或氟代烷基，Z为二价或二者，其中W为R 1 O 2 C-C = CH-Z R 2， 氧或硫原子; A是氧或硫原子，-NR3-或-CR4R5-; X，Y和Z 1相同或不同，例如是氢，卤素，羟基，任选取代的烷基，环烷基或芳基，或其它可能的取代基，当它们位于环上的相邻位置时，X和Y任选地形成 稠环; 并且R，R 3 -R 12是例如氢或任选取代的烷基，其它可能的取代基提供，R 4和R 5不是氢。 这些化合物可用于农业，特别是杀真菌剂，也可用作杀虫剂和植物生长调节剂。

公开(公告)号：US5073184A

公开(公告)日：1991-12-17

申请号：US506152

申请日：1990-04-09

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

IPC分类号： C07C241/00 ,  A01N37/36 ,  A01N37/42 ,  A01N37/44 ,  A01N37/48 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07C67/00 ,  C07C69/734 ,  C07C201/00 ,  C07C205/56 ,  C07C229/64 ,  C07C233/58 ,  C07C239/00 ,  C07C245/06 ,  C07C251/02 ,  C07C251/44 ,  C07C253/00 ,  C07C255/57 ,  C07C255/59 ,  C07C309/63 ,  C07C313/00 ,  C07C323/54 ,  C07D207/32 ,  C07D207/337 ,  C07D207/34 ,  C07D209/18 ,  C07D307/42 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/32 ,  C07D333/34 ,  C07D333/38 ,  C07D333/60 ,  C07F7/18

CPC分类号： C07D207/337 ,  A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60

摘要： Compounds of formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, wherein R.sup.1 and R.sup.2, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, --NR.sup.3 --, or --CR.sup.4 R.sup.5 --; X, Y and Z.sup.1, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted arylalkoxy, optionally substituted aryloxy, optionally substituted heteraryloxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, optionally substituted arylazo, nitro, cyano, --CO.sub.2 R.sup.6, --CONR.sup.7 R.sup.8, --COR.sup.9 --CR.dbd.NR.sup.10, --CR.dbd.NOR.sup.10 or --N.dbd.CR.sup.11 R.sup.12 groups; or the groups X and Y, when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; and R, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11 and R.sup.12, which are the same or different, are hydrogen atoms (provided that R.sup.4 and R.sup.5 are not hydrogen) or optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heterarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted heteroaryl groups; and metal compelxes thereof.The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.

公开(公告)号：US4999042A

公开(公告)日：1991-03-12

申请号：US452333

申请日：1989-12-19

申请人： Vivienne M. Anthony ,  John M. Clough ,  Christopher R. A. Godfrey ,  Thomas E. Wiggins

发明人： Vivienne M. Anthony ,  John M. Clough ,  Christopher R. A. Godfrey ,  Thomas E. Wiggins

IPC分类号： A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/12 ,  A01N43/32 ,  A01N47/20 ,  C07C67/00 ,  C07C251/32 ,  C07C251/48 ,  C07C313/00 ,  C07C315/04 ,  C07C317/44 ,  C07C317/46 ,  C07C317/48 ,  C07C319/20 ,  C07C323/63 ,  C07D213/64 ,  C07D213/643 ,  C07D239/34 ,  C07D241/18 ,  C07D307/54 ,  C07D307/68 ,  C07D307/91 ,  C07D319/24 ,  C07D333/38 ,  C07D333/78 ,  C07F9/40

CPC分类号： C07D213/643 ,  A01N37/50 ,  A01N43/12 ,  A01N43/32 ,  A01N47/20 ,  C07D239/34 ,  C07D241/18 ,  C07D307/54 ,  C07D307/68 ,  C07D333/38 ,  C07F9/4056

摘要： Compounds of the fomrula (I): ##STR1## and sterioisomers thereof, wherein X is halogen, alkyl, cycloalkyl, aralkyl, aryloxyalkyl, alkenyl, alkynyl, aryl, amino, arylazo, heteroarylalkyl, heteroaryloxyalkyl, acylamino nitro, nitride, trifluoromethyl, -OR.sup.1, -SR.sup.1, -CO.sub.2 R.sup.2, -CONR.sup.3 R.sup.4, -COR.sup.5, -CR.sup.6 .dbd.NR.sup.7, -N.dbd.CR8R.sup.9, -SOR.sup.10 or -SO.sub.2 R.sup.11 ; W, Y and Z, which may be the same or different, are any of the atoms or groups listed for X above and, in addition, may be hydrogen atoms; or any two of the groups W, X, Y and Z, in adjacent positions on the phenyl ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; R.sup.1 is alkyl, or cycloalkyl optionally containing a heteroatom in the cycloalkyl ring, alkenyl, acyl, aryl, heteroaryl, aralkyl or heteroarylalkyl; R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.8, R.sup.9, R.sup.10 and R.sup.11, which may be the same or different, are hydrogen or alkyl, cycloalkyl, cycloalkylalkyl, alkenyl, aralkyl, aryl or heteroaryl; and R.sup.7 is aryl, the alkyl, cycloalkyl, aralkyl, aryloxyalkyl, alkeny, alkynyl, aryl, amino, arylazo, heteroarylalkyl, heteroaryloxyalkyl, acylamino, acyl, and heteroaryl being optionally substituted. The compounds are useful as fungicides and as plant growth regulators.

摘要翻译： （I）的化合物：其中X为卤素，烷基，环烷基，芳烷基，芳氧基烷基，烯基，炔基，芳基，氨基，芳基偶氮，杂芳基烷基，杂芳氧基烷基，酰基氨基硝基，氮化物， 三氟甲基，-OR1，-SR1，-CO2R2，-CONR3R4，-COR5，-CR6 = NR7，-N = CR8R9，-SOR10或-SO2R11; W，Y和Z可以相同或不同，是上述X所列的任何原子或基团，另外也可以是氢原子; 或在苯环的相邻位置中的基团W，X，Y和Z中的任何两个，任选地连接形成任选含有一个或多个杂原子的芳族或脂族的稠环; R 1是任选地在环烷基环，烯基，酰基，芳基，杂芳基，芳烷基或杂芳基烷基中含有杂原子的烷基或环烷基; R 2，R 3，R 4，R 5，R 6，R 8，R 9，R 10和R 11可以相同或不同，为氢或烷基，环烷基，环烷基烷基，烯基，芳烷基，芳基或杂芳基; 芳基，芳基，芳基，杂芳基烷基，杂芳氧基烷基，酰氨基，酰基和任选被取代的杂芳基，其中R 7为芳基，烷基，环烷基，芳烷基，芳氧基烷基，烯基，炔基，芳基，氨基，芳基偶氮，杂芳基烷基，杂芳氧基烷基。 这些化合物可用作杀真菌剂和植物生长调节剂。

公开(公告)号：US4876264A

公开(公告)日：1989-10-24

申请号：US39450

申请日：1987-04-17

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey

IPC分类号： A01N43/40 ,  A01N43/54 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/70 ,  C07D239/34 ,  C07D239/38

CPC分类号： C07D213/643 ,  A01N43/40 ,  A01N43/54 ,  C07D213/65 ,  C07D213/70 ,  C07D239/34 ,  C07D239/38

摘要： Acrylic acid derivatives of the formula: ##STR1## an stereoisomers thereof wherein W is pyridyl or pyrimidinyl, A is oxygen or S(O).sub.n where n is 0, 1 or 2; X, Y and X are, for example, hydrogen, halogen, hydroxy or optionally substituted alkyl, alkenyl, alkynyl, alkoxy, aryl, aryloxy or aralkyl among other possible values; R.sup.1 and R.sup.2 are optionally substituted alkyl, and metal complexes thereof. The compounds are useful fungicides.

摘要翻译： 下式的丙烯酸衍生物：其中W是吡啶基或嘧啶基，A是氧或S（O）n，其中n是0,1或2;（I）其立体异构体。 X，Y和X是其它可能的值，例如氢，卤素，羟基或任选取代的烷基，烯基，炔基，烷氧基，芳基，芳氧基或芳烷基; R1和R2是任选取代的烷基及其金属配合物。 这些化合物是有用的杀真菌剂。

公开(公告)号：US5157144A

公开(公告)日：1992-10-20

申请号：US708289

申请日：1991-05-31

申请人： Vivienne M. Anthony ,  John M. Clough ,  Christopher R. A. Godfrey ,  Thomas E. Wiggens

发明人： Vivienne M. Anthony ,  John M. Clough ,  Christopher R. A. Godfrey ,  Thomas E. Wiggens

IPC分类号： A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/12 ,  A01N43/32 ,  A01N47/20 ,  C07C67/00 ,  C07C251/32 ,  C07C251/48 ,  C07C313/00 ,  C07C315/04 ,  C07C317/44 ,  C07C317/46 ,  C07C317/48 ,  C07C319/20 ,  C07C323/63 ,  C07D213/64 ,  C07D213/643 ,  C07D239/34 ,  C07D241/18 ,  C07D307/54 ,  C07D307/68 ,  C07D307/91 ,  C07D319/24 ,  C07D333/38 ,  C07D333/78 ,  C07F9/40

CPC分类号： C07D213/643 ,  A01N37/50 ,  A01N43/12 ,  A01N43/32 ,  A01N47/20 ,  C07D239/34 ,  C07D241/18 ,  C07D307/54 ,  C07D307/68 ,  C07D333/38 ,  C07F9/4056

摘要： Compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein X is halogen, alkyl, cycloalkyl, aralkyl, aryloxyalkyl, alkenyl, alkynyl, aryl, amino, arylazo, heteroarylalkyl, heteroaryloxyalkyl, acylamino nitro, nitrile, trifluoromethyl, --OR.sup.1, SR.sup.1, --CO.sub.2 R.sup.2, --CONR.sup.3 R.sup.4, --COR.sup.5, --CR.sup.6 .dbd.NR.sup.7, --N.dbd.CR8R.sup.9, --SOR.sup.10 or --SO.sub.2 R.sup.11 ; W, Y and Z, which may be the same or different, are any of the atoms or groups listed for X above and, in addition, may be hydrogen atoms; or any two of the groups W, X, Y and Z, in adjacent positions on the phenyl ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; R.sup.1 is alkyl, or cycloalkyl optionally containing a heteroatom in the cycloalkyl ring, alkenyl, acyl, aryl, heteroaryl, aralkyl or heteroarylalkyl; R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.8, R.sup.9, R.sup.10 and R.sup.11, which may be the same or different, are hydrogen or alkyl, cycloalkyl, cycloalkylalkyl, alkenyl, aralkyl, aryl or heteroaryl; and R.sup.7 is aryl, the alkyl, cycloalkyl, aralkyl, aryloxyalkyl, alkenyl, alkynyl, aryl, amino, arylazo, heteroarylalkyl, heteroaryloxyalkyl, acylamino, acyl, and heteroaryl being optionally substituted. The compounds are useful as fungicides and as plant growth regulators.

摘要翻译： 式（I）化合物：其中X为卤素，烷基，环烷基，芳烷基，芳氧基烷基，烯基，炔基，芳基，氨基，芳基偶氮，杂芳基烷基，杂芳氧基烷基，酰氨基硝基，腈， 三氟甲基，-OR1，SR1，-CO2R2，-CONR3R4，-COR5，-CR6 = NR7，-N = CR8R9，-SOR10或-SO2R11; W，Y和Z可以相同或不同，是上述X所列的任何原子或基团，另外也可以是氢原子; 或在苯环的相邻位置中的基团W，X，Y和Z中的任何两个，任选地连接形成任选含有一个或多个杂原子的芳族或脂族的稠环; R 1是任选地在环烷基环，烯基，酰基，芳基，杂芳基，芳烷基或杂芳基烷基中含有杂原子的烷基或环烷基; R 2，R 3，R 4，R 5，R 6，R 8，R 9，R 10和R 11可以相同或不同，为氢或烷基，环烷基，环烷基烷基，烯基，芳烷基，芳基或杂芳基; 并且R 7是任选取代的芳基，烷基，环烷基，芳烷基，芳氧基烷基，烯基，炔基，芳基，氨基，芳基偶氮，杂芳基烷基，杂芳氧基烷基，酰氨基，酰基和杂芳基。 这些化合物可用作杀真菌剂和植物生长调节剂。

公开(公告)号：US4976771A

公开(公告)日：1990-12-11

申请号：US365015

申请日：1989-06-12

申请人： Vivienne M. Anthony ,  John M. Clough ,  Christopher R. A. Godfrey

发明人： Vivienne M. Anthony ,  John M. Clough ,  Christopher R. A. Godfrey

IPC分类号： A01N37/36 ,  A01N43/32 ,  C07D319/24 ,  C07D327/08 ,  C07D339/08

CPC分类号： C07D319/24 ,  A01N37/36 ,  A01N43/32 ,  C07D327/08 ,  C07D339/08

摘要： Compounds of the formula: ##STR1## and stereoisomers thereof, wherein X and Y, which may be the same or different, are oxygen or sulphur; A and B, which may be the same or different, are hydrogen, halogen, alkyl, alkoxy, optionally substituted phenyl, optionally substituted phenoxy, or optionally substituted benzyloxy.The compounds are useful as fungicides and also as plant growth regulators.