公开(公告)号：US5053073A

公开(公告)日：1991-10-01

申请号：US378076

申请日：1989-07-11

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

IPC分类号： C07C241/00 ,  A01N37/36 ,  A01N37/42 ,  A01N37/44 ,  A01N37/48 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07C67/00 ,  C07C69/734 ,  C07C201/00 ,  C07C205/56 ,  C07C229/64 ,  C07C233/58 ,  C07C239/00 ,  C07C245/06 ,  C07C251/02 ,  C07C251/44 ,  C07C253/00 ,  C07C255/57 ,  C07C255/59 ,  C07C309/63 ,  C07C313/00 ,  C07C323/54 ,  C07D207/32 ,  C07D207/337 ,  C07D207/34 ,  C07D209/18 ,  C07D307/42 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/32 ,  C07D333/34 ,  C07D333/38 ,  C07D333/60 ,  C07F7/18

CPC分类号： C07D207/337 ,  A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60

摘要： Compounds of formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, wherein R.sup.1 and R.sup.2, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, --NR.sup.3 --, or --CR.sup.4 R.sup.5 --; X, Y and Z.sup.1, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted arylalkoxy, optionally substituted aryloxy, optionally substituted heteraryloxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, optionally substituted arylazo, nitro, cyano, --CO.sub.2 R.sup.6, --CONR.sup.7 R.sup.8, --COR.sup.9 --CR.dbd.NR.sup.10, --CR.dbd.NOR.sup.10 or --N.dbd.CR.sup.11 R.sup.12 groups; or the groups X and Y, when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; and R, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, and R.sup.12, which are the same or different, are hydrogen atoms (provided that R.sup.4 and R.sup.5 are not hydrogen) or optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heterarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted heteroaryl groups; and metal complexes thereof.The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.

公开(公告)号：US5073184A

公开(公告)日：1991-12-17

申请号：US506152

申请日：1990-04-09

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

IPC分类号： C07C241/00 ,  A01N37/36 ,  A01N37/42 ,  A01N37/44 ,  A01N37/48 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07C67/00 ,  C07C69/734 ,  C07C201/00 ,  C07C205/56 ,  C07C229/64 ,  C07C233/58 ,  C07C239/00 ,  C07C245/06 ,  C07C251/02 ,  C07C251/44 ,  C07C253/00 ,  C07C255/57 ,  C07C255/59 ,  C07C309/63 ,  C07C313/00 ,  C07C323/54 ,  C07D207/32 ,  C07D207/337 ,  C07D207/34 ,  C07D209/18 ,  C07D307/42 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/32 ,  C07D333/34 ,  C07D333/38 ,  C07D333/60 ,  C07F7/18

CPC分类号： C07D207/337 ,  A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60

摘要： Compounds of formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, wherein R.sup.1 and R.sup.2, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, --NR.sup.3 --, or --CR.sup.4 R.sup.5 --; X, Y and Z.sup.1, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted arylalkoxy, optionally substituted aryloxy, optionally substituted heteraryloxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, optionally substituted arylazo, nitro, cyano, --CO.sub.2 R.sup.6, --CONR.sup.7 R.sup.8, --COR.sup.9 --CR.dbd.NR.sup.10, --CR.dbd.NOR.sup.10 or --N.dbd.CR.sup.11 R.sup.12 groups; or the groups X and Y, when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; and R, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11 and R.sup.12, which are the same or different, are hydrogen atoms (provided that R.sup.4 and R.sup.5 are not hydrogen) or optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heterarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted heteroaryl groups; and metal compelxes thereof.The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.

公开(公告)号：US5258360A

公开(公告)日：1993-11-02

申请号：US915594

申请日：1992-07-21

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul deFraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

IPC分类号： A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D207/32 ,  C07D207/337 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60 ,  A01N43/10 ,  C07D333/56

CPC分类号： C07D207/337 ,  A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60

摘要： Compounds of formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, wherein R.sup.1 and R.sup.2, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, --NR.sup.3 --, or --CR.sup.4 R.sup.5 --; X, Y and Z.sup.1, which are the same or different, are, for example, hydrogen, halogen, hydroxy, optionally substituted alkyl, cycloalkyl or aryl among other possible substituents or X and Y when they are in adjacent positions on the ring optionally form a fused ring; and R, R.sup.3 -R.sup.12 are, for example, hydrogen or optionally substituted alkyl among other possible substituents provided R.sup.4 and R.sup.5 are not both hydrogen. The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.

摘要翻译： 式（I）化合物：其中R 1和R 2分别为烷基或氟代烷基，Z为二价或二者，其中W为R 1 O 2 C-C = CH-Z R 2， 氧或硫原子; A是氧或硫原子，-NR3-或-CR4R5-; X，Y和Z 1相同或不同，例如是氢，卤素，羟基，任选取代的烷基，环烷基或芳基，或其它可能的取代基，当它们位于环上的相邻位置时，X和Y任选地形成 稠环; 并且R，R 3 -R 12是例如氢或任选取代的烷基，其它可能的取代基提供，R 4和R 5不是氢。 这些化合物可用于农业，特别是杀真菌剂，也可用作杀虫剂和植物生长调节剂。

公开(公告)号：US5468857A

公开(公告)日：1995-11-21

申请号：US191163

申请日：1994-02-03

申请人： Alan J. Buckley ,  Michael G. Huchings ,  Ian Ferguson ,  Kevin Beautement ,  John M. Clough ,  Patrick J. Crowley ,  Christopher R. A. Godfrey ,  Paul J. deFraine ,  Vivienne M. Anthony ,  Stephen P. Heaney

发明人： Alan J. Buckley ,  Michael G. Huchings ,  Ian Ferguson ,  Kevin Beautement ,  John M. Clough ,  Patrick J. Crowley ,  Christopher R. A. Godfrey ,  Paul J. deFraine ,  Vivienne M. Anthony ,  Stephen P. Heaney

IPC分类号： C07C69/734 ,  A01N31/14 ,  A01N37/06 ,  A01N37/38 ,  A01N37/40 ,  A01N41/04 ,  A01N41/06 ,  A01N41/10 ,  A01N43/00 ,  A01N43/10 ,  A01N43/20 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/66 ,  A01N43/74 ,  A01N43/90 ,  A01N47/20 ,  A01N57/24 ,  C07C20060101 ,  C07C45/59 ,  C07C67/00 ,  C07C67/31 ,  C07C69/54 ,  C07C201/00 ,  C07C205/35 ,  C07C205/37 ,  C07C205/38 ,  C07C205/52 ,  C07C217/92 ,  C07C233/25 ,  C07C233/75 ,  C07C235/56 ,  C07C239/00 ,  C07C241/00 ,  C07C245/08 ,  C07C251/24 ,  C07C251/48 ,  C07C255/54 ,  C07C271/28 ,  C07C275/32 ,  C07C311/21 ,  C07C311/29 ,  C07C317/22 ,  C07C323/16 ,  C07C323/20 ,  C07C323/22 ,  C07C323/56 ,  C07C323/62 ,  C07C323/65 ,  C07C323/66 ,  C07C323/67 ,  C07C327/16 ,  C07C327/26 ,  C07C327/48 ,  C07C333/04 ,  C07C333/08 ,  C07D207/34 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/68 ,  C07D213/74 ,  C07D213/85 ,  C07D213/89 ,  C07D215/22 ,  C07D215/227 ,  C07D215/36 ,  C07D237/14 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D241/18 ,  C07D241/44 ,  C07D249/04 ,  C07D249/08 ,  C07D251/22 ,  C07D251/26 ,  C07D253/06 ,  C07D263/58 ,  C07D277/24 ,  C07D277/68 ,  C07D333/56 ,  C07D495/04 ,  C07D521/00 ,  C07F9/54 ,  C07D239/02

CPC分类号： C07D213/64 ,  A01N37/38 ,  A01N37/40 ,  A01N41/04 ,  A01N41/06 ,  A01N41/10 ,  A01N43/10 ,  A01N43/20 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/66 ,  A01N43/74 ,  A01N43/90 ,  A01N47/20 ,  A01N57/24 ,  C07C205/35 ,  C07C205/37 ,  C07C205/38 ,  C07C205/52 ,  C07C217/92 ,  C07C233/25 ,  C07C233/75 ,  C07C235/56 ,  C07C245/08 ,  C07C251/24 ,  C07C251/48 ,  C07C255/54 ,  C07C271/28 ,  C07C311/29 ,  C07C317/22 ,  C07C323/20 ,  C07C327/16 ,  C07C45/59 ,  C07D207/34 ,  C07D213/643 ,  C07D213/65 ,  C07D213/68 ,  C07D213/74 ,  C07D213/85 ,  C07D213/89 ,  C07D215/227 ,  C07D215/36 ,  C07D231/12 ,  C07D233/56 ,  C07D237/14 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D241/18 ,  C07D241/44 ,  C07D249/08 ,  C07D251/26 ,  C07D263/58 ,  C07D277/24 ,  C07D277/68 ,  C07D333/56 ,  C07D495/04 ,  C07F9/5456

摘要： Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is a specified linking group; and A, B and E, which may be the same or different, are H, hydroxy, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 haloalkyl, C.sub.1-4 haloalkoxy, C.sub.1-4 alkylcarbonyl, C.sub.1-4 alkoxycarbonyl, phenoxy, nitro or cyano; except that when Z is unsubstituted phenyl and X and K are oxygen, A, B and E are not all hydrogen.

摘要翻译： 式（I）的杀真菌化合物：其中K为氧或硫; Z是任选取代的芳基或任选取代的杂芳基; X是指定的连接组; 和A，B和E可以相同或不同，是H，羟基，卤素，C 1-4烷基，C 1-4烷氧基，C 1-4卤代烷基，C 1-4卤代烷氧基，C 1-4烷基羰基，C 1-4烷氧基羰基 ，苯氧基，硝基或氰基; 除了当Z是未取代的苯基且X和K是氧时，A，B和E不都是氢。

公开(公告)号：US5334748A

公开(公告)日：1994-08-02

申请号：US242760

申请日：1988-09-09

申请人： Alan J. Buckley ,  Michael G. Huchings ,  Ian Ferguson ,  Kevin Beautement ,  John M. Clough ,  Patrick J. Crowley ,  Christopher R. A. Godfrey ,  Paul J. deFraine ,  Vivienne M. Anthony ,  Stephen P. Heaney

发明人： Alan J. Buckley ,  Michael G. Huchings ,  Ian Ferguson ,  Kevin Beautement ,  John M. Clough ,  Patrick J. Crowley ,  Christopher R. A. Godfrey ,  Paul J. deFraine ,  Vivienne M. Anthony ,  Stephen P. Heaney

IPC分类号： C07C69/734 ,  A01N31/14 ,  A01N37/06 ,  A01N37/38 ,  A01N37/40 ,  A01N41/04 ,  A01N41/06 ,  A01N41/10 ,  A01N43/00 ,  A01N43/10 ,  A01N43/20 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/66 ,  A01N43/74 ,  A01N43/90 ,  A01N47/20 ,  A01N57/24 ,  C07C20060101 ,  C07C45/59 ,  C07C67/00 ,  C07C67/31 ,  C07C69/54 ,  C07C201/00 ,  C07C205/35 ,  C07C205/37 ,  C07C205/38 ,  C07C205/52 ,  C07C217/92 ,  C07C233/25 ,  C07C233/75 ,  C07C235/56 ,  C07C239/00 ,  C07C241/00 ,  C07C245/08 ,  C07C251/24 ,  C07C251/48 ,  C07C255/54 ,  C07C271/28 ,  C07C275/32 ,  C07C311/21 ,  C07C311/29 ,  C07C317/22 ,  C07C323/16 ,  C07C323/20 ,  C07C323/22 ,  C07C323/56 ,  C07C323/62 ,  C07C323/65 ,  C07C323/66 ,  C07C323/67 ,  C07C327/16 ,  C07C327/26 ,  C07C327/48 ,  C07C333/04 ,  C07C333/08 ,  C07D207/34 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/68 ,  C07D213/74 ,  C07D213/85 ,  C07D213/89 ,  C07D215/22 ,  C07D215/227 ,  C07D215/36 ,  C07D237/14 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D241/18 ,  C07D241/44 ,  C07D249/04 ,  C07D249/08 ,  C07D251/22 ,  C07D251/26 ,  C07D253/06 ,  C07D263/58 ,  C07D277/24 ,  C07D277/68 ,  C07D333/56 ,  C07D495/04 ,  C07D521/00 ,  C07F9/54 ,  C07C69/76

CPC分类号： C07D213/64 ,  A01N37/38 ,  A01N37/40 ,  A01N41/04 ,  A01N41/06 ,  A01N41/10 ,  A01N43/10 ,  A01N43/20 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/66 ,  A01N43/74 ,  A01N43/90 ,  A01N47/20 ,  A01N57/24 ,  C07C205/35 ,  C07C205/37 ,  C07C205/38 ,  C07C205/52 ,  C07C217/92 ,  C07C233/25 ,  C07C233/75 ,  C07C235/56 ,  C07C245/08 ,  C07C251/24 ,  C07C251/48 ,  C07C255/54 ,  C07C271/28 ,  C07C311/29 ,  C07C317/22 ,  C07C323/20 ,  C07C327/16 ,  C07C45/59 ,  C07D207/34 ,  C07D213/643 ,  C07D213/65 ,  C07D213/68 ,  C07D213/74 ,  C07D213/85 ,  C07D213/89 ,  C07D215/227 ,  C07D215/36 ,  C07D231/12 ,  C07D233/56 ,  C07D237/14 ,  C07D239/34 ,  C07D239/38 ,  C07D239/60 ,  C07D241/18 ,  C07D241/44 ,  C07D249/08 ,  C07D251/26 ,  C07D263/58 ,  C07D277/24 ,  C07D277/68 ,  C07D333/56 ,  C07D495/04 ,  C07F9/5456

摘要： Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is O, S(O).sub.n, NR.sup.4, CR.sup.1 R.sup.2 CHR.sup.5, CO, CR.sup.1 (OR.sup.2), C.dbd.CR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2, CR.sup.1 .dbd.CR.sup.2, CHR.sup.1 CR.sup.2 .dbd.CH, C.tbd.C, OCHR.sup.1, CHR.sup.1 O, OCHR.sup.1 O, S(O).sub.n CHR.sup.1 S(O).sub.n CHR.sup.1 O, CHR.sup.1 S(O).sub.n, CHR.sup.1 OSO.sub.2, NR.sup.4 CHR.sup.1, CHR.sup.1 NR.sup.4, CO.sub.2, O.sub.2 C, SO.sub.2 O, OSO.sub.2, CO.CO, COCHR.sup.1, COCHR.sup.1 O, CHR.sup.1 CO, CHOH.CHR.sup.1, CHR.sup.1.CHOH ##STR2## CONR.sup.4, OCONR.sup.4, NR.sup.4 CO, CSNR.sup.4, OCS.NR.sup.4, SCO.NR.sup.4, NR.sup.4 CO.sub.2, NR.sup.4 CS, NR.sup.4 CSO, NR.sup.4 COS, NR.sup.4 CONR.sup.4, S(O).sub.n NR.sup.4, NR.sup.4 S(O).sub.n, CS.sub.2, S.sub.2 C, CO.S, SCO, N.dbd.N, N.dbd.CR.sup.1, CR.sup.1 .dbd.N, CHR.sup.1 CHR.sup.2 CH(OH), CHR.sup.1 OCO, CHR.sup.1 SCO, CHR.sup.1 NR.sup.4 CO, CHR.sup.1 NR.sup.4 COR.sup.4, CHR.sup.1 CHR.sup.2 CO, O.N.dbd.CR.sup.1, CHR.sup.1 O.N.dbd.CR.sup.2, CO.OCR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2 CHR.sup.3, OCHR.sup.1 CHR.sup.2, (CH.sub.2).sub.m O, CHR.sup.1 OCHR.sup.2, CHR.sup.1 CHR.sup.2 O, OCHR.sup.1 CHR.sup.2 O, S(O).sub.n CHR.sup.1 CHR.sup.2, CHR.sup.1 S(O).sub.n CHR.sup.2. CHR.sup.1 CHR.sup.2 S(O).sub.n, CR.sup.1 .dbd.NNR.sup.4, NR.sup.4 N.dbd.CR.sup.1, CHR.sup.1 CONR.sup.2, CHR.sup.1 OCO.NR.sup.2, CH.dbd.CHCH.sub.2 O, COCHR.sup.1 CHR.sup.2 O or (R.sup.5).sub.2 P.sup. + CHR.sup.2 Q.sup.- ; A, B and E, which may be the same or different, are H, hydroxy, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 haloalkyl, C.sub.1-4 haloalkoxy, C.sub.1-4 alkylcarbonyl, C.sub.1-4 alkoxycarbonyl, phenoxy, nitro or cyano; R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, are H, C.sub.1-4 alkyl or phenyl; R.sup.4 is H, C.sub.1-4 alkyl or COR.sup.1 ; R.sup.5 is optionally substituted phenyl;

摘要翻译： 式（I）的杀真菌化合物：其中K为氧或硫; Z是任选取代的芳基或任选取代的杂芳基; X是O，S（O）n，NR 4，CR 1 R 2 CHR 5，CO，CR 1（OR 2），C = CR 1 R 2，CHR 1 CH 2，CR 1 = CR 2，CHR 1 CR 2 = CH，C 3 D C，OCHR 1，CHR 1 O，OCHR 1 O， nCHR1 S（O）nCHR1O，CHR1S（O）n，CHR1OSO2，NR4CHR1，CHR1NR4，CO2，O2C，SO2O，OSO2，CO.CO，COCHR1，COCHR1O，CHR1CO，CHOH.CHR1，CHR1.CHOH CONR4，OCONR4 ，NR4CO，CSNR4，OCS.NR4，SCO.NR4，NR4CO2，NR4CS，NR4CSO，NR4COS，NR4CONR4，S（O）nNR4，NR4S（O）n，CS2，S2C，CO.S，SCO，N = N，N = CR1，CR1 = N，CHR1CHR2CH（OH），CHR1OCO，CHR1SCO，CHR1NR4CO，CHR1NR4COR4，CHR1CHR2CO，ON = CR1，CHR1O.N = CR2，CO.OCR1R2，CHR1CHR2CHR3，OCHR1CHR2，（CH2）mO，CHR1OCHR2，CHR1CHR2O，OCHR1CHR2O ，S（O）n CHR1CHR2，CHR1S（O）nCHR2。 CHR1CHR2S（O）n，CR1 = NNR4，NR4N = CR1，CHR1CONR2，CHR1OCO.NR2，CH = CHCH2O，COCHR1CHR2O或（R5）2P + CHR2Q-; A，B和E可以相同或不同，是H，羟基，卤素，C 1-4烷基，C 1-4烷氧基，C 1-4卤代烷基，C 1-4卤代烷氧基，C 1-4烷基羰基，C 1-4烷氧基羰基 ，苯氧基，硝基或氰基; R 1，R 2和R 3可以相同或不同，为H，C 1-4烷基或苯基; R4是H，C1-4烷基或COR1; R5是任选取代的苯基;

公开(公告)号：US4863503A

公开(公告)日：1989-09-05

申请号：US39449

申请日：1987-04-17

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul de Fraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul de Fraine ,  Christopher R. A. Godfrey ,  Kevin Beautement

IPC分类号： C07C241/00 ,  A01N37/36 ,  A01N37/42 ,  A01N37/44 ,  A01N37/48 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07C67/00 ,  C07C69/734 ,  C07C201/00 ,  C07C205/56 ,  C07C229/64 ,  C07C233/58 ,  C07C239/00 ,  C07C245/06 ,  C07C251/02 ,  C07C251/44 ,  C07C253/00 ,  C07C255/57 ,  C07C255/59 ,  C07C309/63 ,  C07C313/00 ,  C07C323/54 ,  C07D207/32 ,  C07D207/337 ,  C07D207/34 ,  C07D209/18 ,  C07D307/42 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/32 ,  C07D333/34 ,  C07D333/38 ,  C07D333/60 ,  C07F7/18

CPC分类号： C07D207/337 ,  A01N43/06 ,  A01N43/36 ,  A01N43/38 ,  A01N43/58 ,  C07D209/18 ,  C07D307/54 ,  C07D307/79 ,  C07D333/24 ,  C07D333/60

摘要： Compounds of formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, wherein R.sup.1 and R.sup.2, which are the same or different, are alkyl or fluoroalkyl groups, and Z is either an oxygen or sulphur atom; A is an oxygen or sulphur atom, --NR.sup.3 --, or --CR.sup.4 R.sup.5 --; X, Y and Z.sup.1, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heteroarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted heteroaryl, optionally substituted alkoxy, optionally substituted arylalkoxy, optionally substituted aryloxy, optionally substituted heteraryloxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, optionally substituted arylazo, nitro, cyano, --CO.sub.2 R.sup.6, --CONR.sup.7 R.sup.8, --COR.sup.9 --CR.dbd.NR.sup.10, --CR.dbd.NOR.sup.10 or --N.dbd.CR.sup.11 R.sup.12 groups; or the groups X and Y, when they are in adjacent positions on the ring, optionally join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; and R, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8 R.sup.9, R.sup.10, R.sup.11 and R.sup.12, which are the same or different, are hydrogen atoms (provided that R.sup.4 and R.sup.5 are not hydrogen) or optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl, optionally substituted heterarylalkyl, optionally substituted aryloxyalkyl, optionally substituted heteroaryloxyalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted heteroaryl groups; and metal complexes thereof.The compounds are useful in agriculture, especially as fungicides but also as insecticides and plant growth regulators.

公开(公告)号：US4876264A

公开(公告)日：1989-10-24

申请号：US39450

申请日：1987-04-17

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey

IPC分类号： A01N43/40 ,  A01N43/54 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/70 ,  C07D239/34 ,  C07D239/38

CPC分类号： C07D213/643 ,  A01N43/40 ,  A01N43/54 ,  C07D213/65 ,  C07D213/70 ,  C07D239/34 ,  C07D239/38

摘要： Acrylic acid derivatives of the formula: ##STR1## an stereoisomers thereof wherein W is pyridyl or pyrimidinyl, A is oxygen or S(O).sub.n where n is 0, 1 or 2; X, Y and X are, for example, hydrogen, halogen, hydroxy or optionally substituted alkyl, alkenyl, alkynyl, alkoxy, aryl, aryloxy or aralkyl among other possible values; R.sup.1 and R.sup.2 are optionally substituted alkyl, and metal complexes thereof. The compounds are useful fungicides.

摘要翻译： 下式的丙烯酸衍生物：其中W是吡啶基或嘧啶基，A是氧或S（O）n，其中n是0,1或2;（I）其立体异构体。 X，Y和X是其它可能的值，例如氢，卤素，羟基或任选取代的烷基，烯基，炔基，烷氧基，芳基，芳氧基或芳烷基; R1和R2是任选取代的烷基及其金属配合物。 这些化合物是有用的杀真菌剂。

公开(公告)号：US5057146A

公开(公告)日：1991-10-15

申请号：US465526

申请日：1990-01-17

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey ,  Ian Ferguson ,  Patrick J. Crowley ,  Michael G. Hutchings

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey ,  Ian Ferguson ,  Patrick J. Crowley ,  Michael G. Hutchings

IPC分类号： C07D213/84 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01P3/00 ,  A01P5/00 ,  A01P7/04 ,  A01P13/00 ,  A01P21/00 ,  C07D213/62 ,  C07D213/63 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/66 ,  C07D213/68 ,  C07D213/69 ,  C07D213/70 ,  C07D213/71 ,  C07D213/73 ,  C07D213/79 ,  C07D213/80 ,  C07D213/81 ,  C07D213/85 ,  C07D215/22 ,  C07D215/227 ,  C07D239/10 ,  C07D239/34 ,  C07D239/38 ,  C07D239/46 ,  C07D239/52 ,  C07D239/56 ,  C07D239/58 ,  C07D239/80 ,  C07D239/88

CPC分类号： C07D213/65 ,  A01N43/40 ,  A01N43/54 ,  C07D213/643 ,  C07D213/66 ,  C07D213/68 ,  C07D213/69 ,  C07D213/70 ,  C07D213/71 ,  C07D213/80 ,  C07D213/84 ,  C07D213/85 ,  C07D215/22 ,  C07D215/227 ,  C07D239/10 ,  C07D239/34 ,  C07D239/38 ,  C07D239/52 ,  C07D239/56 ,  C07D239/58 ,  C07D239/80

摘要： This invention relates to derivatives of acrylic acid useful in agriculture (especially as fungicides but also as plant growth regulators, insecticides and nematocides), to processes for preparing them, to agricultural (especially fungicidal) compositions containing them, and to methods of using them to combat fungi, especially fungal infections in plants, to regulate plant growth and to kill or control insect or nematode pests.The invention provides a compound having the formula (I): ##STR1## and stereoisomers thereof, wherein W is a substituted pyridinyl or substituted pyrimidinyl group linked to A by any of its ring carbon atoms; A is either an oxygen atom or S(O).sub.n wherein n is 0, 1 or 2; X, Y and Z, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl (including haloalkyl), optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted alkoxy, (including haloalkoxy), optionally substituted alkylthio, optionally substituted aryloxy, optionally substituted arylalkoxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, nitro, cyano, --CO.sub.2 R.sup.3, --CONR.sup.4 R.sup.5, --COR.sup.6 or --S(O).sub.m R.sup.7 (wherein m is 0, 1 or 2) groups, or any two of the groups X, Y and Z, when they are in adjacent positions on the phenyl ring, may join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; R.sup.1 and R.sup.2, which are the same or different, are optionally substituted alkyl (including fluoroalkyl) groups provided that when W is 5-trifluoromethylpyridin-2-yl, A is oxygen, X is hydrogen, and R.sup.1 and R.sup.2 are both methyl, Y and Z are not both hydrogen, Y is not F, Cl, methyl, nitro, 5--CF.sub.3, 5--SCH.sub.3 or 4--(CH.sub.3).sub.2 N if Z is hydrogen and Y and Z together are not 3-nitro-5-chloro, 3,5-dinitro, 4,5-dimethoxy or 4,5-methylenedioxy; and R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7, which are the same or different, are hydrogen atoms or optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl or optionally substituted aralkyl groups; and metal complexes thereof.

公开(公告)号：US4826531A

公开(公告)日：1989-05-02

申请号：US39401

申请日：1987-04-17

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey ,  Patrick J. Crowley ,  Kenneth Anderton

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey ,  Patrick J. Crowley ,  Kenneth Anderton

IPC分类号： A01N43/40 ,  A01N43/54 ,  A01N43/58 ,  C07D213/30 ,  C07D213/55 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/67 ,  C07D213/69 ,  C07D213/70 ,  C07D213/79 ,  C07D213/80 ,  C07D401/12 ,  C07D413/12 ,  A61K31/44 ,  A61K31/47 ,  A61K31/495 ,  A61K31/50 ,  A61K31/505 ,  C07C107/04 ,  C07D211/72 ,  C07D211/84 ,  C07D213/63 ,  C07D215/16 ,  C07D215/20 ,  C07D215/36 ,  C07D401/00 ,  C07D403/00 ,  C07D405/00

CPC分类号： C07D213/64 ,  A01N43/40 ,  C07D213/55 ,  C07D213/643 ,  C07D213/65 ,  C07D213/67 ,  C07D213/69 ,  C07D213/70 ,  C07D213/80 ,  C07D401/12 ,  C07D413/12

摘要： Acrylic acid derivatives having the formula (I): ##STR1## and stereoisomers thereof, wherein W is R.sup.1 O.sub.2 C--C.dbd.CH--ZR.sup.2, R.sup.1 and R.sup.2 are alkyl or fluoroalkyl groups, and Z is oxygen or sulphur; A, B, D and E are hydrogen, halogen, hydroxy or optionally substituted alkyl, alkoxy, aralkyl, arylalkoxy, alkenyl, alkynyl, aryl, aryloxy, arylthio, heteroaryloxy, heteroarylthio, acyloxy, amino, arylazo or acylamino, nitro, cyano, --CO.sub.2 R.sup.3, --CONR.sup.3 R.sup.4, --COR.sup.3, --CR.sup.3 .dbd.NR.sup.4, --N.dbd.CR.sup.3 R.sup.4 or --S(O).sub.n R.sup.3 groups; any two of the groups A, B, D and E, when they are in adjacent positions on the ring, optionally join to form a fused ring, n is 0, 1 or 2; and R.sup.3 and R.sup.4 are hydrogen, alkyl, cycloalkyl, cycloalkylalkyl, alkenyl, alkynyl or optionally substituted aryl or aralkyl; and metal complexes thereof. These compounds are useful as fungicides, insecticides, nematicides or plant growth regulators.

摘要翻译： 具有式（I）的丙烯酸衍生物及其立体异构体，其中W为R 1 O 2 C-C = CH-ZR 2，R 1和R 2为烷基或氟烷基，Z为氧或硫; A，B，D和E是氢，卤素，羟基或任选取代的烷基，烷氧基，芳烷基，芳基烷氧基，烯基，炔基，芳基，芳氧基，芳硫基，杂芳氧基，杂芳硫基，酰氧基，氨基，芳基偶氮或酰氨基，硝基，氰基， -CO 2 R 3，-CONR 3 R 4，-COR 3，-CR 3 = NR 4，-N = CR 3 R 4或-S（O）n R 3基团; 组A，B，D和E中的任何两个当它们在环上的相邻位置时，任选地连接形成稠环，n为0,1或2; 并且R 3和R 4是氢，烷基，环烷基，环烷基烷基，烯基，炔基或任选取代的芳基或芳烷基; 及其金属络合物。 这些化合物可用作杀真菌剂，杀虫剂，杀线虫剂或植物生长调节剂。

公开(公告)号：US5602076A

公开(公告)日：1997-02-11

申请号：US412450

申请日：1995-03-29

申请人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey

发明人： Vivienne M. Anthony ,  John M. Clough ,  Paul DeFraine ,  Christopher R. A. Godfrey

IPC分类号： C07D213/84 ,  A01N43/40 ,  A01N43/42 ,  A01N43/54 ,  A01P3/00 ,  A01P5/00 ,  A01P7/04 ,  A01P13/00 ,  A01P21/00 ,  C07D213/62 ,  C07D213/63 ,  C07D213/64 ,  C07D213/643 ,  C07D213/65 ,  C07D213/66 ,  C07D213/68 ,  C07D213/69 ,  C07D213/70 ,  C07D213/71 ,  C07D213/73 ,  C07D213/79 ,  C07D213/80 ,  C07D213/81 ,  C07D213/85 ,  C07D215/22 ,  C07D215/227 ,  C07D239/10 ,  C07D239/34 ,  C07D239/38 ,  C07D239/46 ,  C07D239/52 ,  C07D239/56 ,  C07D239/58 ,  C07D239/80 ,  C07D239/88 ,  C07D239/22

CPC分类号： C07D213/65 ,  A01N43/40 ,  A01N43/54 ,  C07D213/643 ,  C07D213/66 ,  C07D213/68 ,  C07D213/69 ,  C07D213/70 ,  C07D213/71 ,  C07D213/80 ,  C07D213/84 ,  C07D213/85 ,  C07D215/22 ,  C07D215/227 ,  C07D239/10 ,  C07D239/34 ,  C07D239/38 ,  C07D239/52 ,  C07D239/56 ,  C07D239/58 ,  C07D239/80

摘要： This invention relates to derivatives of acrylic acid useful in agriculture (especially as fungicides but also as plant growth regulators, insecticides and nematocides), to processes for preparing them, to agricultural (especially fungicidal compositions containing them, and to methods of using them to combat fungi, especially fungal infections in plants, to regulate plant growth and to kill or control insect or nematode pests.The invention provides a compound having the formula (I): ##STR1## and stereoisomers thereof, wherein W is a substituted pyridinyl or substituted pyrimidinyl group linked to A by any of its ring carbon atoms; A is either an oxygen atom or S(O).sub.n wherein n is 0, 1 or 2; X, Y and Z, which are the same or different, are hydrogen or halogen atoms, or hydroxy, optionally substituted alkyl (including haloalkyl), optionally substituted alkenyl, optionally substituted alkynyI, optionally substituted alkoxy, (including haloalkoxy), optionally substituted alkylthio, optionally substituted aryloxy, optionally substituted arylalkoxy, optionally substituted acyloxy, optionally substituted amino, optionally substituted acylamino, nitro, cyano, --CO.sub.2 R.sup.3, --CONR.sup.4 R.sup.5, --COR.sup.6 or --S (O).sub.m R.sup.7 (wherein m is 0, 1 or 2) groups, or any two of the groups X, Y and Z, when they are in adjacent positions on the phenyl ring, may join to form a fused ring, either aromatic or aliphatic, optionally containing one or more heteroatoms; R.sup.1 and R.sup.2, which are the same or different, are optionally substituted alkyl (including fluoroalkyl) and the like.

摘要翻译： 本发明涉及可用于农业的丙烯酸衍生物（特别是作为杀真菌剂，也可作为植物生长调节剂，杀虫剂和杀线虫剂），其制备方法，农业（特别是含有它们的杀真菌组合物）及其使用方法 真菌，特别是植物中的真菌感染，调节植物生长并杀死或控制昆虫或线虫害虫本发明提供了具有式（I）的化合物：其中任何一个与A连接的取代的吡啶基或取代的嘧啶基 环碳原子; A是氧原子或S（O）n，其中n是0,1或2; X，Y和Z相同或不同，是氢或卤素原子，或羟基，任选取代的烷基 （包括卤代烷基），任选取代的烯基，任选取代的炔基，任选取代的烷氧基，（包括卤代烷氧基），任选取代的烷硫基，任选取代的芳氧基， 硝基，氰基，-CO 2 R 3，-CONR 4 R 5，-COR 6或-S（O）m R 7（其中m为0,1或2）基团，或任意取代的酰氧基，任选取代的氨基， 基团X，Y和Z当它们在苯环上的相邻位置时，可以连接形成任选含有一个或多个杂原子的芳族或脂族稠环; R 1和R 2相同或不同，为任选取代的烷基（包括氟代烷基）等。