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    HIGH-THROUGHPUT SOLUTION PROCESSING OF LARGE SCALE GRAPHENE AND DEVICE APPLICATIONS
    1.
    发明申请
    HIGH-THROUGHPUT SOLUTION PROCESSING OF LARGE SCALE GRAPHENE AND DEVICE APPLICATIONS 有权
    大规模石墨和设备应用的高通量解决方案处理

    公开(公告)号：US20100273060A1

    公开(公告)日：2010-10-28

    申请号：US12747087

    申请日：2009-01-14

    申请人： Yang Yang ,  Richard B. Kaner ,  Chun-Chih Tung ,  Matthew J. Allen

    发明人： Yang Yang ,  Richard B. Kaner ,  Chun-Chih Tung ,  Matthew J. Allen

    IPC分类号： C01B31/02 ,  H01B1/04 ,  H01M4/583 ,  B29C43/00

    CPC分类号： H01G9/058 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/19 ,  C01B2204/02 ,  H01G11/36 ,  H01L51/0003 ,  H01L51/0048 ,  H01L51/0541 ,  H01L51/0545 ,  H01M4/96 ,  Y02E60/13

    摘要： A method of producing carbon macro-molecular structures includes dissolving a graphitic material in a solvent to provide a suspension of carbon-based macro-molecular structures in the solvent, and obtaining a plurality of the carbon macro-molecular structures from the suspension. The plurality of carbon macro-molecular structures obtained from the suspension each consists essentially of carbon. A material according to some embodiments of the current invention is produced according to the method of producing carbon macro-molecular structures. An electrical, electronic or electro-optic device includes material produced according to the methods of the current invention. A composite material according to some embodiments of the current invention has carbon macro-molecular structures produced according to methods of producing carbon macro-molecular structures according to some embodiments of the current invention. A hydrogen storage device according to some embodiments of the current invention has carbon macro-molecular structures produced according to methods of producing carbon macro-molecular structures according to some embodiments of the current invention. An electrode according to some embodiments of the current invention has carbon macro-molecular structures produced according to methods of producing carbon macro-molecular structures according to some embodiments of the current invention.

    摘要翻译： 制造碳宏观分子结构的方法包括将石墨材料溶解在溶剂中以提供碳基大分子结构在溶剂中的悬浮液，并从悬浮液中获得多个碳大分子结构。 从悬浮液中获得的多个碳宏观分子结构各自主要由碳组成。 根据本发明的一些实施方案的材料根据生产碳宏观分子结构的方法制备。 电气，电子或电光设备包括根据本发明的方法制造的材料。 根据本发明的一些实施方案的复合材料具有根据本发明的一些实施方案的根据生产碳宏观分子结构的方法制备的碳大分子结构。 根据本发明的一些实施方案的氢存储装置具有根据本发明的一些实施方案的根据生产碳宏观分子结构的方法产生的碳宏观分子结构。 根据本发明的一些实施方案的电极具有根据本发明的一些实施方案的根据生产碳宏观分子结构的方法产生的碳大分子结构。

    High-throughput solution processing of large scale graphene and device applications
    2.
    发明授权
    High-throughput solution processing of large scale graphene and device applications 有权
    大规模石墨烯和器件应用的高通量解决方案处理

    公开(公告)号：US09105403B2

    公开(公告)日：2015-08-11

    申请号：US12747087

    申请日：2009-01-14

    申请人： Yang Yang ,  Richard B. Kaner ,  Chun-Chih Tung ,  Matthew J. Allen

    发明人： Yang Yang ,  Richard B. Kaner ,  Chun-Chih Tung ,  Matthew J. Allen

    IPC分类号： H01M4/133 ,  C01B31/04 ,  H01G9/04 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  H01G11/36 ,  H01M4/96 ,  H01L51/00 ,  H01L51/05

    CPC分类号： H01G9/058 ,  B82Y10/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/19 ,  C01B2204/02 ,  H01G11/36 ,  H01L51/0003 ,  H01L51/0048 ,  H01L51/0541 ,  H01L51/0545 ,  H01M4/96 ,  Y02E60/13

    摘要： A method of producing carbon macro-molecular structures includes dissolving a graphitic material in a solvent to provide a suspension of carbon-based macro-molecular structures in the solvent, and obtaining a plurality of the carbon macro-molecular structures from the suspension. The plurality of carbon macro-molecular structures obtained from the suspension each consists essentially of carbon. A material according to some embodiments of the current invention is produced according to the method of producing carbon macro-molecular structures. An electrical, electronic or electro-optic device includes material produced according to the methods of the current invention. A composite material according to some embodiments of the current invention has carbon macro-molecular structures produced according to methods of producing carbon macro-molecular structures according to some embodiments of the current invention. A hydrogen storage device according to some embodiments of the current invention has carbon macro-molecular structures produced according to methods of producing carbon macro-molecular structures according to some embodiments of the current invention. An electrode according to some embodiments of the current invention has carbon macro-molecular structures produced according to methods of producing carbon macro-molecular structures according to some embodiments of the current invention.

    摘要翻译： 制造碳宏观分子结构的方法包括将石墨材料溶解在溶剂中以提供碳基大分子结构在溶剂中的悬浮液，并从悬浮液中获得多个碳大分子结构。 从悬浮液中获得的多个碳宏观分子结构各自主要由碳组成。 根据本发明的一些实施方案的材料根据生产碳宏观分子结构的方法制备。 电气，电子或电光设备包括根据本发明的方法制造的材料。 根据本发明的一些实施方案的复合材料具有根据本发明的一些实施方案的根据生产碳宏观分子结构的方法制备的碳大分子结构。 根据本发明的一些实施方案的氢存储装置具有根据本发明的一些实施方案的根据生产碳宏观分子结构的方法产生的碳宏观分子结构。 根据本发明的一些实施方案的电极具有根据本发明的一些实施方案的根据生产碳宏观分子结构的方法产生的碳大分子结构。

    Fabrication of polyaniline nanofiber dispersions and films
    4.
    发明授权
    Fabrication of polyaniline nanofiber dispersions and films 有权
    聚苯胺纳米纤维分散体和薄膜的制备

    公开(公告)号：US08470203B2

    公开(公告)日：2013-06-25

    申请号：US12724252

    申请日：2010-03-15

    申请人： Richard B. Kaner ,  Dan Li ,  Jiaxing Huang

    发明人： Richard B. Kaner ,  Dan Li ,  Jiaxing Huang

    IPC分类号： H01B1/00 ,  C08G73/00 ,  B05D5/12

    CPC分类号： C08G73/0266 ,  D01D5/38 ,  D01D5/40 ,  D01F6/76

    摘要： A new method for forming stable polyaniline nanofiber colloids uses electrostatic repulsion to maintain dispersion of the nanofibers and prevent aggregation during synthesis of the nanofibers. The colloidal suspensions are formed directly from the reactants in solution maintained at a pH of about 1.0 to about 4.0 and a temperature of about 10° C. to about 100° C. with minimal or no stirring. Also set forth are new methods for forming ultrathin films of polyaniline nanofibers via self-assembly.

    摘要翻译： 用于形成稳定的聚苯胺纳米纤维胶体的新方法使用静电排斥来保持纳米纤维的分散并防止在纳米纤维合成期间的聚集。 胶体悬浮液直接由溶液中的反应物形成，保持在约1.0至约4.0的pH和约10℃至约100℃的温度，同时最小或不搅拌。 还阐述了通过自组装形成聚苯胺纳米纤维超薄膜的新方法。

    Chiral recognition polymer and its use to separate enantiomers
    6.
    发明授权
    Chiral recognition polymer and its use to separate enantiomers 有权
    手性识别聚合物及其分离对映异构体的用途

    公开(公告)号：US06265615B1

    公开(公告)日：2001-07-24

    申请号：US09322327

    申请日：1999-05-28

    申请人： Richard B. Kaner ,  Charles M. Knobler ,  Hailan Guo

    发明人： Richard B. Kaner ,  Charles M. Knobler ,  Hailan Guo

    IPC分类号： B01D1508

    CPC分类号： C07B57/00 ,  C08G73/0266

    摘要： A new polymeric material, a process for forming the material and method of using the material to separate enantiomers of chiral compounds, particularly amino acids and pharmaceuticals are disclosed. A polymeric material can be formed from polyaniline doped with a chiral acid and then extracted with a suitable base. This leaves behind a polymeric material which preferentially traps, and then selectively releases, one enantiomer of a chiral mixture brought in contact with the surface of the polymeric material. In particular, when polyaniline is doped with either R- or S-camphorsulfonic acid (CSA) it takes on a chiral structure. Removing the chiral acid dopant leads to a new chiral polyaniline. The dedoped chiral polyanilines have the ability to discriminate among enantiomers of many compounds which exist in chiral mixtures.

    摘要翻译： 公开了一种新的聚合物材料，用于形成材料的方法和使用该材料分离手性化合物，特别是氨基酸和药物的对映异构体的方法。聚合物材料可以由掺杂有手性酸的聚苯胺形成，然后用 合适的基地。 这留下聚合物材料，其优先捕获，然后选择性地释放与聚合物材料的表面接触的手性混合物的一种对映异构体。 特别地，当聚苯胺掺杂有R-或S-樟脑磺酸（CSA）时，其具有手性结构。 去除手性酸性掺杂物导致新的手性聚苯胺。 去掺杂的手性聚苯胺具有区分手性混合物中存在的许多化合物的对映异构体的能力。

    Membranes having selective permeability
    7.
    发明授权
    Membranes having selective permeability 失效
    具有选择性渗透性的膜

    公开(公告)号：US5358556A

    公开(公告)日：1994-10-25

    申请号：US988935

    申请日：1993-02-25

    申请人： Richard B. Kaner ,  Mark R. Anderson ,  Howard Reiss ,  Benjamin R. Mattes

    发明人： Richard B. Kaner ,  Mark R. Anderson ,  Howard Reiss ,  Benjamin R. Mattes

    IPC分类号： B01D71/60 ,  B01D53/22 ,  B01D67/00 ,  B01D69/02 ,  B01D71/72 ,  H01B1/12

    CPC分类号： B01D67/0093 ,  B01D53/228 ,  B01D69/02 ,  B01D71/72 ,  H01B1/128 ,  Y02C10/10 ,  Y10S264/48 ,  Y10S264/62

    摘要： Dopable, fully dense polymer membranes are used to form membranes having selective permeabilities. To improve selectivity, the membranes may be subjected to chemical or electrochemical treatment with electron donors or acceptors to alter the doping level of the polymer membrane, generally in a reversible fashion. This leads to significant changes in gas permeation rates relative to what is observed for the non-doped, fully dense polymers. This change in doping level of the polymer films can be precisely controlled by varying the concentration and nature of chemical dopants used. Desirable changes in permeation rates are achieved by a treatment which comprises a reversal doping of the polymeric material, followed by removal of the dopants (to provide an "undoped" polymer). Further addition of controlled amounts of at least one dopant species to the undoped polymer by a second, "redoping" procedure can still more dramatically change the permeability of large species, leading to particularly large separation factors.

    摘要翻译： 可掺杂的，完全致密的聚合物膜用于形成具有选择性渗透性的膜。 为了提高选择性，膜可以用电子给体或受体进行化学或电化学处理，以改变聚合物膜的掺杂水平，通常以可逆的方式。 这导致相对于未掺杂的，完全致密的聚合物观察到的气体渗透速率的显着变化。 可以通过改变所用化学掺杂剂的浓度和性质来精确地控制聚合物膜的掺杂水平的这种变化。 渗透速率的期望变化通过包括反向掺杂聚合物材料，然后除去掺杂剂（以提供“未掺杂的”聚合物）的处理来实现。 通过第二个“重做”程序进一步向未掺杂的聚合物添加受控量的至少一种掺杂剂物质仍然可以更大地改变大物种的渗透性，导致特别大的分离因子。

    SYNTHESIS OF CONDUCTING POLYMER NANOFIBERS USING AN OLIGOMER OF A MONOMER AS AN INITIATOR
    10.
    发明申请
    SYNTHESIS OF CONDUCTING POLYMER NANOFIBERS USING AN OLIGOMER OF A MONOMER AS AN INITIATOR 有权
    使用作为发动机的单体的低聚物的导电聚合物纳米纤维的合成

    公开(公告)号：US20120091402A1

    公开(公告)日：2012-04-19

    申请号：US13334608

    申请日：2011-12-22

    申请人： Richard B. Kaner ,  Koo Shin ,  Henry Hiep D. Tran

    发明人： Richard B. Kaner ,  Koo Shin ,  Henry Hiep D. Tran

    IPC分类号： H01B1/12 ,  H01B1/00 ,  H01B1/08 ,  B82Y30/00 ,  B82Y40/00

    CPC分类号： C08G61/124 ,  C08G61/126 ,  C08G2261/3221 ,  C08G2261/3223 ,  H01M2/30 ,  H01M4/624 ,  H01M4/668

    摘要： The present invention involves synthesizing conducting polymer nanofibers by mixing an oxidant solution with a monomer solution, which includes a monomer and an oligomer of the monomer that is used as an initiator. The oxidant solution includes an oxidizing agent, or oxidant, such as ferric chloride to oxidize the monomer, the oligomer, or both, and begin polymerization. By including an initiator in the form of the oligomer, which may have a lower oxidation potential than the monomer, the rate of polymerization is accelerated, resulting in the nanofibrous morphology. Therefore, the conducting polymer nanofibers may be synthesized without the use of surfactants, hard templates, or seeds, resulting in a simplified and accelerated polymerization process, which enhances homogenous nucleation of the conducting polymer nanofibers.

    摘要翻译： 本发明涉及通过将氧化剂溶液与包含用作引发剂的单体的单体和低聚物的单体溶液混合来合成导电聚合物纳米纤维。 氧化剂溶液包括氧化剂或氧化剂，例如氯化铁，以氧化单体，低聚物或两者，并开始聚合。 通过包含低聚物形式的引发剂，其可能具有比单体低的氧化电位，聚合速度加快，导致纳米纤维形态。 因此，可以不使用表面活性剂，硬模板或种子来合成导电聚合物纳米纤维，导致简化和加速的聚合过程，这增强了导电聚合物纳米纤维的均匀成核。